crop-chem-docs/corpus/epa_ppls/5905-493.md

# DIMETHOATE 4 E.C.

- EPA Reg No: **5905-493**
- Registrant: HELENA AGRI-ENTERPRISES, LLC, D/B/A HELENA CHEMICAL COMP
- Signal word: Warning
- Active ingredients: Dimethoate (44.8%)
- Label accepted: 2005-12-27
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/005905-00493-20051227.pdf

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225 Schilling Boulevard, Suite 300 to: 
Collierville, Tennessee 38017 EPA Reg. No. 
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NOTIFICATIUI'f A.-geney letter dated 
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DEC 2 7 2005 . 
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Notification of Other Revisions per PR Notice 98-10. This notification is consistent with the provisions of PR Notice 98-10 and EPA regulations at 40 CFR 
1 ~2.46. and no other changes have been made to the labeling or the confidential statement of formula of this product. I understand that it is a viotatlon of 18 
U.S.C. Sac. 1001 to willfully make any false statement to EPA. I furthe, understand that nthis notification is not consistent with the terms of PR Notice 98-10 
and 40 CFR H;2.46. this produd may be in violation of FIFRA and I may be subjeclto enforcement action and penalties under sections 12 and 1401 FIFRA. 
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Certification 6. Dei. Application 
I certify that the statements I heve mede on this form and all attachments thereto are true. accurate and C'ompIet_. R.c.;vod 
I acknowledge that eny knowfinglty felse or miale8ding .tatement may be punishable by fine or impri80"""""'~. ' , " . 'I3tamped) 
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EPA Form 8670-1 !Rev. 3-94' editions are obaoletl. _ • EPA fie Cop, y_. leo"

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DIMETHOATE 4 EC 
NOTIFICATION 
• Do not induce vomiting unless told to do so by 
DEC 2 7 2005 the poison control center or doctor. 
SYSTEMIC INSECTICIDE • Do not give anything by mouth to an unconscious 
person. 
ACTIVE ~NGREDIENT: IF ON SKIN: 
DimethoalE, (O,O-dimethyl S-(N-methylcarbamoylmethyl) 
• Take off contaminated clothing (phosphorodithioate) ........................................ 44.8% 
• Rinse skin immediately with plelltx pf yrcrter for OTHER INI:;REDIENTS*: ................................. 55.2% . TOTAL .................................................... , ............. 100.0% 15-20 minutes. '" " 
This produl~ contains 4 Ibs. dimethoate per gallon. • Call a poison control center or cIootPr for 
'This product contains petroleUm distillale. treatment 
~" t C' ., . 
KEEP OUT OF REACH OF CHILDREN IF INHALED: ~---: . 
, 
DANGER·PELIGRO • Move person to fresh ('ir. : " ' .. Si usted no entiende la etiqueta, busque a alguien para que sa la • If person is not brea:t,iRg. call 9'11 or an explique a liSted en detalle. (If you do nol understand this label, find 
ambulance, then give artificiilr respiration, p.~ferably by someone teo explain it to you.) 
mouth-to-mouth, if possible. SEE ADDITIONAL PRECAUTIONARY STATEMENTS INSIDE '" 
BOOKLET. • Call a poison control center or dcct9~ for further 
SN 129810105 NET CONTENTS: 2.5 Gal (9.46 L) treatment advice. EPA REG. NO. 5905-493 
HOT LINE NUMI3ER EPA EST NO.: First letters of batch code indicate producing 
-eslablishmEmr . In case of emergency, call 800-424-9300. Have the 
59<J5.GA-1 = CG; 5905-AR-l = WA; 59<J5.1A-1 = 01; 5905-Fl-l "TF; product container with you when calling a poison control -5905-CA-l = KC . center or doctor, or going for treatment. "RQ", Orgllnophosphorus Pesticide, Liquid, Toxic, Flammable 
NOTE TO PHYSICIAN: This product may cause (Dlmethoate), UN3017 
cholinesterase inhibition. Antidote is Atropine. 
MANUFACTURED FOR Contains petroleum distillate. Vomiting may cause 
HELENA CHEMICAL COMPANY aspiration pneumonia 
225 SCHILLING BOULEVARD, SUITE 300 Probable mucosal damage may contraindicate the .. COLLIERVILLE, TENNESSEE 38017 use of gastric lavage • 
. 
PRECAUTIONARY STATEMENTS PERSONAL PROTECTIVE EQUIPMENT HAZARDS TO HUMANS AND DOMESTIC ANIMALS Some materials that are chemical-resistant to this product DANGER·PELIGRO are listed below. If you want more options, follow the Corrosive. Causes irreversible eye damage. May be instruction for category F on an EPA chemiGaI resistance fatal if swallowed. Hanmful if inhaled or absorbed through category selection chart. the skin. Avoid breathing spray mist. Avoid contact with 
skin, eyes, or cloth if!!!: Applicators and other handlers (other than mixers 
FIRST AIID and loaders) must wear: 
Organophosphate Long-sleeved shirt and long pants 
IF IN EYES: Chemical-resistant gloves, such as barrier 
• Hold eye open and rinse slowly and gently with laminate, butyl rubber, nitrile rubber, or viton 
Chemical-resistant footwear plus socks water for '15-20 minutes. 
Protective eyewear • Remove contact lenses, if present after the first 5 
Chemical-resistant headgear for overhead minutes, then continue rinsing eye. 
• Call a poison control center or doctor for exposure 
treatment advice. 
Mixers and loaders must wear: IF SWALLOWED: 
Long-sleeved shirt and long pants 
• Call a poison control center or doctor Chemical-resistant gloves, such as barrier immediate!ly for treatment advice. laminate, butyl rubber, nitrile rubber, or viton 
• Do not give any liquid to the person. Chemical-resistant footwear plus socks 
Protective eyewear

Chemical-resistant headgear for overhead 
E!xpOsure 
For exposures in enclosed areas, a respirator with either 
an organic vapor-removing cartridge with a prefilter 
approved for pesticides (MSHAINIOSH approval number 
prefix TC-23C), or a canister approved for pesticides 
(MSHAlIllIOSH approval number prefix TC-14G), or a 
NIOSH approved respirator with an organic vapor (OV) 
cartridge or canister with any N, R, P, or HE prefilter. 
For exposures outdoors, dust/mist filtering respirator 
(MSHAINIOSH approval number prefix TC-21C), or a 
NIOSH approved respirator with any N, R, P, or HE 
filter. 
Discard clothing and other absorbent materials that have 
been drenched or heavily contaminated with this 
producfs concentrate. Do not reuse them. Follow 
. manufacturer's instructions for cleaning/maintaining PPE. 
If no such instructions for washables, use detergent and 
hot water. Keep and wash PPE separately from other 
laundry. 
ENGINEERING CONTROLS STATEMENT 
When handlers use closed systems, enclosed cabs, or 
aircraft in a manner that meets the requirements listed in 
the Worker Protection Standard (WPS) for agricultural 
pesticide!. [40 CFR 170.240 (d) (4-S)J, the handler PPE 
requiremEmts may be reduced or modified as specified in 
theWPS. 
USER SAFETY RECOMMENDATIONS 
Users should: 
Wash hands before eating, drinking. chewing 
gum, Llsing tobacco, or using the toilet 
Remove clothing immediately if pesticide gets 
inside. Then wash thoroughly and put on clean 
clothing. 
Remove PPE immediately after handling this 
product. Wash the outside of gloves before 
mmoving. As soon as possible. wash thoroughly 
and change into clean clothing. 
ENVlRO~IMENTAl HAZARDS 
This pesticide is highly toxic to bees exposed to direct 
treatment or residues on blooming crops or weeds. Do 
not apply this product or allow it to drift to blooming crops 
or weeds if bees are visiting the treatment area. 
This pesticide is toxic to wildlife and aquatic 
invertebrates. For terrestrial uses, do not apply directly to 
Sh~ 
water or to areas where surface water is present or to 
intertidal areas below the mean high water mark. Runoff 
from treated areas may be hazardous to aquatic 
organisms in neighboring areas. Do not contaminate 
water by cleaning of equipment or disposal of wastes. 
PHYSICAL OR CHEMICAL HAZARDS 
Flammable. Keep away from heat and open flame. Do 
not use, pour, spill or store near heat or flame. 
DIRECTIONS FOR USE 
It is a violation of Federal Law to use this product in a 
manner inconsistent with its labeling. 
Do not apply this product in a way that will contact 
workers or other persons, either directly or through drift. 
Only protected handlers may be in the area during 
applicatlon. For any requirements specific to your State 
or Tribe, consult the agency responsible for pesticide 
regulation. 
ORNAMENTAL PLANTS GROWN IN NURSERIES 
ONLY 
Do not use on ornamental plants grown in greenhouses, 
shade houses, Christmas tree and conifer plantations, 
landscapes, interiorscapes and residential, public, 
recreational, commercial, industrial and institutional 
establishments. 
AGRICULTURAL USE REQUIREMENTS 
Use this product only in accordance with its labeling and 
with the Worker Protection Standard, 40 CFR part 170. 
This Standard contains requirements for the protection of 
agricultural workers on fanns, forests, nurseries, and 
greenhouses, and handlers of agricultural pesticides. It 
contains requirements for training, decontamination, 
notification, and emergency assistance. It also contains 
specific instructions and exceptions pertaining to the 
statements on this label about personal protective 
equipment (PPE) and restricted-~mtry interval. The 
requirements in this box only apply to uses of this product 
that are covered by the Worker Protection Standard. 
Do not enter or allow worker entry into treated areas 
during the restricted entry interval (REI) of 48 hours. 
PPE required for early entry to treated areas that is 
pennitted under the Worker Protection Standard and that 
involves contact with anything that has been treated, 
such as plants, soil, or water, is: 
Coveralls 
Chemical-resistant gloves, such as barrier laminate, butyl

rubber, nitrile rubber, or viton 
Chemical-resistant footwear plus socks 
ProtectiVI~ eyewear 
Chemical-resistant headgear for overhead exposure. 
STORAGE AND DISPOSAL 
Do not contaminate water, food or feed by storage cir 
disposal. 
STORAGE: Store in a cool, dry area. Do not store 
DIMETHOATE 4 EC below 32oF, as it may tend to 
CrystalliZE!. Avoid storage above 9O<>F, as prolonged 
storage above 9QoF may cause some loss in grade. 
PESTICI[)E DISPOSAL: Pesticide wastes are acutely 
hazardous. Improper disposal of excess pesticide, spray 
mixture, or rinsate is a violation of Federal Law. If these 
wastes cannot be disposed of by use according to label 
instructions, contact your State Pesticide or 
Environmental Control Agency, or the Hazardous Waste 
representative at the nearest EPA regional Office for 
guidance. 
CONTAI~IER DISPOSAL: Thoroughly clean container 
before rellse unless this is a refillable container. If this is 
a refillablE! container, and is to be refilled, do not rinse or 
introduce any pesticide other than DIMETHOATE4 EC. 
Reseal and retum the container to an authorized Helena 
Chemical Company refilling facility. If the container is not 
to be refilled, triple rinse (or equivalent). Then offer for 
recycling IX reconditioning, or puncture and dispose of in 
a sanitary landfill, or incineration, or if allowed by state 
and local .authorities, by buming. If bumed, stay out of 
smoke. 
DIMETHClATE 4 EC is a clear liquid. When added to 
water, it will disperse readily and will remain physically 
. stable with a minimum amount of agitation. Apply this 
product only as specified on this label. 
Application equipment: DIMETHOATE 4 EC can be 
applied b~' any pressure sprayer that will give uniform 
distribution of the spray such as ground sprayers, aerial 
sprayers.or portable sprayers. 
Aerial Application: 
Automatic flagging devices should be used whenever 
feasible. 
If human flaggers are employed, they must wear the . 
protective clothing and respirator specified on this label. 
APPLICATION THROUGH IRRIGATION SYSTEMS-
CHEMIGA TION 
Apply this product only through sprinkler, inCluding center 
pivot, lateral move, end tow, side (wheel) roll, !rave,ler, big 
gun, solid set, or hard move; flood (basin); furrow; border; 
or drip (trickle) irrigation systems. Do not apply this 
product through any other type of irrigation system. 
Crop injury, lack of effectiveness, or illegal pesticide 
residues in the crop can result from nonuniform 
distribution of treated water. 
If you have questions about calibration, you should 
contact State Extension Service specialists, equipment 
manufacturers or other experts. 
. Do not connect an irrigation system (including 
greenhouse systems) used for pesticide application to a 
public water system unless the pesticide label-prescribed 
safety devices for public water systems are in place. 
A person knowledgeable of the chemigation system and 
responsible for its operation, or under the supervision of 
the responsible person, shall shut the system down and 
make necessary adjustments should the need arise. 
Mix in clean supply tank the recommended amount of this 
product for acreage to be covered, and needed quantity 
of water. . 
This product should not be tank-mixed with other 
pesticides, surfactants or fertilizers unless prior use has 
. shown the. combination noninjurious Linder your 
conditions of use and provided chemigation is permitted 
on the label of products to be tanked-mixed. 
Follow precautionary statements and directions for all 
tank-mixed products. 
On all crops, use sufficient gallonage of water to obtain 
thorough and uniform coverage, but not cause runoff or 
excessive leaching. This will vary depending on 
equipment, pest problem and stage of crop growth. 
Application of more or less than optimal quantity of water 
may result in decreased chemical performance, crop 
injury or illegal pesticide residues. 
Meter this product into the irrigation water uniformly 
during the period of operation. Do not overlap application. 
Follow recommended label rates, application timing, and 
other directions and precautions for crop being treated. 
Continuous mild agitation of pesticide mixture may be . 
needed to assure a uniform application, particularly if the 
supply tank requires a number of hours to empty.

CHEMIGA nON SYSTEMS CONNECTED TO PUBLIC 
WATER SYSTEMS 
Note: This company does not encourage connecting 
chemigation systems to public water supplies. The 
folloWing infoiTnation is provided for users who have 
diligently considered all other application and water 
supply olltions before electing to make such a 
connection. 
Public wllter system means a system for the provision to 
the publi(; of piped water for human consumption if such 
system has at least 15 service connections or regularly 
serves all average of atleast 25 individuals daily at least 
60 days out of the year. Chemigation systems connected 
to public water systems must contain a functional, 
reduced-pressure zone, backflow preventer (RPZ) or the 
functional equivalent in the water supply line upstream 
from the point of pesticide introduction. As an option to 
the RPZ, the water from the public water system should 
be dischclrged into a ~servoir tank prior to pesticide 
introduction. There shall be a complete physical break 
(air gap) between the outlet end of the fill pipe and the top 
or overfiow rim of the reservoir tank of at least twice the 
inside diameter of the fill pipe. 
The pesticide injection pipeline must contain a functional, 
automatic;, quick-closing check valve to prevent the flow 
of fluid bclck toward the injection pump. 
The pesticide injection pipeline must contain a functional, . 
normally dosed, solenoid-operated valve located on the . 
intake side of the injection pump and connected to the 
system interlock to prevent fluid from being withdrawn 
from the supply tank when the irrigation system is either 
automatic:ally or manually shut down. 
The system must contain functional interlocking controls 
to automatically shut off the pesticide injection pump 
when the water pump motor stops, or in cases where 
there is no water pump, when the water pressure 
decrease:> to the point where pesticide distribution is 
adversely affected, 
Systems must use a metering pump, such as a positive 
displacement injection pump (e.g., diaphragm pump) 
effectivel)' designed and constructed of materials that are 
compatible with pesticides and capable of being filled 
with a system interlock. 
Do not apply when wind speed favors drift beyond the 
area intended for treatment. 
SPRINKLER CHEMIGATION (FOLIAR SPRAY USES) 
The system must contain a functional check valve, 
vacuum relief valve, and low pressure drain appropriately 
located on the irrigation pipeline to prevent water source 
contamination from backflow, ' 
The pesticide injection pipeline must contain a functional, 
automatic, quick-closing check valve to prevent the flow 
of fluid back toward the injection pump. 
The pesticide injection pipeline must also contain a 
functional, normally closed, solenoid-operated valve 
located on the intake side of the injection pump and 
· connected to the system interlock to prevent fluid from 
being withdrawn from the S!!pply tank when the irrigation 
system is either automatically or manually shut down. 
The system must contain functional interfocking controls 
to automatically shut off the pesticide injection pump 
when the water pump motor stops. 
The irrigation line or water pump must include a 
functional pressure switch which will stop the water pump 
motor when the water pressure decreases to the point 
where pesticide distribution is adversely affected. 
· Systems must use a metering pump, such as a positive 
displacement injection pump (e.g., diaphragm pump) 
effectively designed and constructed of materials that are 
compatible with pesticides and capable of being filled 
with a system interlock. 
Do not apply when wind speed favors drift beyond the 
area intended for treatment. 
FLOOD (BASIN), FURROW AND BORDER 
CHEMIGATION (SOIL DRENCH USES) 
Systems using a gravity flow pesticide dispenSing system 
· must meter the pesticide into the water at the head of the 
field and downstream of a hydraulic discontinuity, such 
as a drop structure of weir box, to decrease potential for 
water source contamination from backflow if water flow 
stops. 
Systems utilizing a pressurized water and pesticide 
injection system must meet the following requirements: 
a. The system must contain a functional check 
valve, vacuum relief valve, and low pressure 
drain appropriately located on the irrigation 
pipeline to prevent water source contamination 
from backflow. 
b. The pesticide injection pipeline must contain a 
functional, automatic, quick closing checkvalve to 
prevent the flow of fluid back toward the injection 
pump.

c. The pesticide injection pipeline must also contain 
a functional, normally closed, solenoid-operated 
'Ialve located on the intake side of the injection 
pump and connected to the system interlock to 
prevent fluid from being withdrawn from the 
supply tank when the irrigation system is either 
automatically or manually shut down. 
d. The system must contain functional interlocking 
Gontrols to automatically shut off the pesticide 
injection pump when the water pump motor 
!ltOPS· 
e. The irrigation line or water pump must include a 
functional pressure switch which will stop the 
water pump motor when the water pressure 
decreases to the point where pesticide 
distribution is adversely affected. 
f. Systems must use a metering pump, such as a 
positive displacement injection pump (e.g. 
diaphragm pump) effectively designed and 
constructed of materials that are compatible with 
pesticides and capable of being fitted with a 
system interlock. 
DRIP (TRICKLE) CHEMIGATION (SOIL DRENCH 
. USES) 
The system must contain a functional check valve, 
vacuum ~elief valve and low pressure drain appropriately 
located on the irrigation pipeline to prevent water sou~ 
contamination from backflow. 
The pesticide injection pipeline must contain a functional, 
automatic:, quick-closing check valve to prevent the flow 
of fluid back towarn the injection pump. 
The pesticide injection pipeline must also contain a 
functional, normally closed, solenoid-operated valve 
located 011 the intake side of the injection pump and 
connected to the system interlock to prevent fluid from 
being withdrawn from the supply tank when the irrigation 
system is either automatically or manually shut down. 
The system must contain functional interlocking controls 
to automatically shut off the pesticide injection pump 
when the water pump motor stops. 
The irrigation line or water pump must include a 
functional pressure switch which will stop the water pump 
motor when the water pressure decreases to the point 
where pesticide distribution is adversely affected. 
Systems must use a metering pump such as a positive 
displacement injection pump (e.g., diaphragm pump) 
effectively designed and constructed of materials that are 
compatible with pesticides and capable 6f being fitted 
with a system interlock. 
GENERAL INFORMATION 
This product is intended for use by the commercial 
grower or commercial applicator in conventional hydraulic 
sprayers, concentrate application equipment; ground 
applicators or airplane sprayers. This product is 
prohibited from use in or around any structure used as a 
residence or domestic dwelling, or on any articles or 
areas associated with such structures (including 
household contents, home garnens, and home 
greenhouses); and, from any use in or around public or 
private buildings or structures (including ~reational 
facilities, theaters, hotels, or other buildings used for 
public accommodation, or in any other commercial, 
industrial, or institutional building), or on any articles 
associated with such structures, including refuse areas, 
building contents and landscaping (but not including 
outdoon:ommercial ornamental tree and shrub 
production areas). When applying by ground equipment, 
use the recommended amount in sufficient water for 
thorough coverage: by aircraft, in 1 to 10 gallons of water 
unless otherwise specified. The rates of DIMETHOATE 4 
EC are recommended on a per 100 gallons of dilute 
spray, except where indicated. Application rates applied 
by concentrate methods should equal the total amount of 
dimethoate applied per acre on the per 100 gallon basis 
except where the actual concentrate rates are specified. 
(If a dilute application is recommended at 1 pint per 100 
gallons and it requires 400 gallons per acre for proper. 
coverage, the concentrate rate would equal 4 pints per 
acre). The optimum spray gallonage is dependent on tree 
size, density and growth stage. Typical spray gallonages 
. per acre range from, but are not limited to 100-600 
gallons for dilute spray, 20-100 gallons for concentrate 
and 1-25 gallons for aerial. Do not apply when weather 
conditions favor drift of spray from areas treated. Repeat 
applications as necessary unless otherwise specified. 
Consult your state experiment station or state extension 
service for proper timing of applications. 
DIMETHOATE 4 EC is compatible in spray tank mixes 
with most insecticides, miticides, and fungicides, provided 
they are not alkaline in reaction. DIMETHOATE 4 EC 
has systemic and contact activity against a broad 
spectrum of piercing, sucking and chewing insects. 
For proper mixing, spray tank should be at least 3/4 filled 
with water before adding DIMETHOATE 4 EC. 
Mechanical agitation or ~irculation through pump 
bypass to tank is usually sufficient for maintaining a good 
dispersion. Spray tank mixtures of OtMETHOATE 4 EC 
with fertilizers that are alkaline should be applied

immediately. 
All Spray mixes should be made in accordance with the 
product that has the more restrictive label limitations and 
precautions. 
Dimethoilte may produce a distinctive odor during the 
spray operation, but under normal conditions 
this odor does not persist. 
APPLICATION INSTRUCTIONS 
FRUIT 
PEARS: Aphids, Leafhoppers, Leafrollers, Mites 
(except RUllt Mites), Pear Psylla - % to 1 pt. per 100 
gallons water. Do not apply when trees or substantial 
numbers of weeds in the orchard (grove) are in bloom. 
Do not apply within 28 days of harvest. Do not feed 
treated forage or graze livestock on treated orchards. 
CITRUS, GRAPEFRUIT, LEMONS, ORANGES, 
TANGER.lNES: Aphids - Ground Equipment: % to 1 pt. 
per 100 gallons of water. Apply as an outside coverage 
spray. AircraftEquipment: 1 to 2 qts. per acre in 5 to 10 
gallons water. Do not apply within 15 days of harvest. 
Mites (except Rust M"rtes) - Ground Equipment: % to 1 
pt. per 100 gallons of water. Apply as a thorough 
distribution coverage spray. Do not apply within 15 days 
of harvest. Scales (except Black or Snow) - Ground 
Equipment: 1 to 1 % pis. per 100 gallons of water. Apply 
as a thorough coverage spray. Do not apply within 45 
days of harvest. Thrips - Ground Equipment: % to 1 pt. 
per 100 gallons of water. Apply as a mist spray. Aircraft 
Equipment: 1 to 2 qts. per acre in 5 to 10 gallons water. 
Do not apply within 15 days of harvest. Whiteflies -
Ground Equipment: 1 pt. per 100 gallons of water. Apply 
as a thorough distribution coverage spray. Do not apply 
within 15 days of harvest. 
Do not apply when trees or substantial numbers of weeds 
in the orchard (grove) are in bloom. Do not use on citrus 
seedlings. Make no more than 2 applications to mature 
fruit. Do not enter treated groves within 4 days of last 
application. Do not graze livestock or cover crops in 
treated orchards. 
CITRUS, GRAPEFRUIT, LEMONS, ORANGES, 
TANGERINES (ARIZONA ONLY): Thrips - Use 
specified dosage of DIMETHOATE 4 EC in the amount of 
water necessary to achieve adequate coverage of foliage. 
. The type of equipment used will determine the 
concentration required. Aerial: Apply up to 2.0 Ibs. of a.i. 
(2 qts.) in not less than 5 gallons water/acre. Ground: 
Apply up to 2.0 Ibs. a.i. (2 qts.) in not less than 20 gals. 
~~ 
water/acre. Do not apply within 15 days of harvest. Do 
not enter treated groves within 4 days of last application. 
Use of dimethoate is prohibited during any time of day in 
any given orchard from when that orchard has 10% oPen 
blooms until such time as there has been at least 75% 
petal fall on the north side of the trees. Applications of 
dimethoate shall be limited to that period of time between 
one (1) hour after sunset to three (3) hours before sunrise 
when anyone of the following conditions prevail: 1) 
before the onset of petal fall, the orchard to be treated 
has open blooms present and these open blooms 
represent less than 10% of the total anticipated blooms in 
the orchard; 2) after the initiation of petal fall there are 
less than 25% of open blooms remaining in the orchard to 
be treated; or 3) it is between the calendar dates of 
February 15th and May 1 st. 
All applfcations of difTlethoate on citrus must be 
documented on Form 1080 written either by a pest 
control advisor, farm owner or farm manager as is 
normally required for custom applications of pesticides, 
except that private applicators may omit the 'Pesticide 
Application Report' section. The description of the status 
of bloom of the orchard to be treated as it was at the time 
of the application shall be indicated in the section for 
'label Restrictions/Special Instruction.' Both private and 
custom applicators shall mail to the Agriculture 
Department's Phoenix office the original of each 
completed Form 1080 done in accordance with this label. 
Each Form 1080 shall be postmarked not later than 
Monday following the week in which the application was 
made, except when holidays intervene. 
NUTS 
PECANS: Aphids, Mites, Leafhoppers - Ground 
Equipment: 213 pt. per acre. Aphids - Aerial Equipment: 
213 pt. per acre in a minimum of 5 gallons of finished 
spray. Do not graze livestock in treated groves. Do not 
apply within 21 days of harvest. 
VEGETABLE CROPS 
BEANS (GREEN, LIMA, SNAP, DRY): Aphids, Bean 
Leaf Beetle, Grasshoppers, Leafhoppers, Leaf 
Miners, Lygus Bugs, Mexican Bean Beetle, Mites - % 
to 1 pI. per acre. Do not feed treated vines. This 
pesticide is highly toxic to bees, do not apply if bees are 
visiting the areas to be treated when crop or weeds are in 
bloom. Do not apply within 7 days of harvest 
BROCCOLI, CAULIFLOWER: Aphids - % to 1 pt per 
acre. Do not apply within 7 days of harvest.

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CELERY (F~ORIDA): Leaf Miners, Cannine Mite, Two­
spotted Spider Mite - Ground Equipment: 1 pt. per acre. 
Do not apply within 7 days of harvest. 
LEAF LE:rTUCE, KALE, TURNIP (GREENS AND 
ROOTS), MUSTARD GREENS, SWISS CHARD, 
ENDIVE (ESCAROLE): Aphids, Leafhoppers, Leaf 
Miners -14 pt. per acre. Do not apply within 14 days of 
harvest. 
LENTILS: Lygus Bugs - 1 pI. per acre. Aphids - Y. to 1 
pt. per acre. Do not apply within 14 days of harvest. Do 
not feed or graze treated plants. Do not make more than 
two applications per growing season. This pesticide is 
highly toxic to bees, do not apply if bees are visiting the 
areas to be treated when crop or weeds are in bloom. 
LUPINE: Aphids, Lygus Bugs - Y. to 1 pt. per acre. 
. Apply when Aphids first appear. Make only 2 
applications per season. Lupine may be harvested on day 
of application. Do not feed or graze, forage or hay. This 
pesticide is highly toxic to bees, do not apply if bees are 
visiting the areas to be treated when crop or weeds are in 
bloom. 
MELONS (except Watermelons): Aphids, 
Leafhoppers, Leaf Miners, Thrips - 1 pt. per acre. Do 
not apply within 3 days of harvest. 
MELONS (Watennelons): Aphids, Leafminers, 
LeafhoPJl8rs, Maggots - 112 to 1 pt. per acre. Do not 
apply within 3 days of harvest. 
PEAS: AI)hids - 113 pt. per acre. Lygus - 1 pt. per acre. 
Do not feHd or graze hay within 21 days after last 
application when a stationary viner is used. Do not feed 
or graze when amobile viner is used. This pesticide is 
highly toxic to bees, do not apply if bees are visiting the 
areas to be treated when crop or weeds are in bloom. Do 
not make more than one application per season. Do not . 
apply wittJin 7 days of harvest. 
PEPPERS: Aphids, Leaf Miners, Maggots - 1/2 to 213 
pt. per acre. Do not apply within 7 days of harvest. 
POTATOI~S: Aphids, Grasshoppers, Leaf Miners, 
Leafhoppers - Yo to 1 pt. per acre. Do not apply wiihin 7 
days of h'lrvest. 
TOMATOES: Aphids, Leaf Miners, Leafhoppers - Yo to 
1 pt. per acre. Do not apply within 7 days of harvest. 
Where cabbage worms and cabbage loopers are a 
problem, the above rates are compatible with endosulfan, 
malathion or parathion. Use in accordance with the 
manufacturer's directions for control of these insects. 
FIELD CROPS 
ALFALFA: Aphids, GrasshoPJlers, LeafhoPJlers, Plant 
Bugs including Lygus Bugs, Reduction of Alfalfa 
Weevil Larvae - Y. to 1 pt. per acre. This pesticide is 
highly toxic to bees, do not apply if bees are visiting the 
areas to be treated when crop or weeds are in.bloom. Do 
not apply within 10 days of harvest or pasturing. Make 
only one application per culling. Effective only on culling 
. to which applied. 
FIELD CORN: Banks Grass Mites (excluding Trans­
Pecos area ofTexas), Aphids, Bean Beetle, Com . 
Rootwonn Adult", Two-spotted Spider Mite - 213 to 1 
pt. per acre. Aerial Application: Spray over the foliage 
when mites appear. Apply above rates in 1 or more 
gallons of water per acre. GrasshoPJlers - 1 pt. per acre. 
Ground Application: Apply above rate in 20 to 40 gallons 
of water per acre. Aerial Application: Apply above rate in 
1 or more gallons of water per acre. Apply as necessary. 
Make no more than three applications per year. Do not 
feed or graze within 14 days of last application. Do not 
apply within 14 days of harvest. Do not apply to com 
during the pollen-shed period if bees are visiting the area .. 
"NOTE - Com Rootwonn Adult not registered for use in 
California. -
COTTON. (GROWN IN CALIFORNIA AND ARIZONA): . 
Plant Bugs including Lygus Bugs, Leafhoppers, 
Black Fleahoppers - Yo to 1 pt. per-acre. Repeat 
applications should not be made at intervals closer than 
14 days. Make only 2 applications per season at the 
higher rate. Do not feed treated forage or graze livestock 
. on treated fields. Do not apply within 14 days of harvest. 
COTTON: Aphids, Mites, Thrips, FleahoPJlers - Yo to Yo 
pt. per acre. Plant Bugs including Lygus Bugs - Yo pt. per 
acre. Repeat applications should not be made at intervals 
closer than 14 days. Do not feed treated forage or graze 
livestock on treated fields. Do not apply within 14 days of 
harvest. 
SAFFLOWER (GROWN IN CALIFORNIA AND 
ARIZONA): Aphids, Leafhoppers, Plant Bugs 
including Lygus and Thrips - Y. to 1 pI. per acre. 
Repeat applications should not be made at intervals 
closer than 14 days. Make only 2 applications per seasan 
at the higher rate. Do not apply within 14 days of harvest. 
SORGHUM (MILO): Aphids - Yo to 1 pI. per acre. Ground

. Application: Apply above rates in 25 to 40 gallons of 
water per aCre. Aerial Application: Apply above rates in 1 
or more ~Iallons of water per acre. Banks Grass Mites 
(excluding Trans-Pecos area of Texas), 
Grasshoppers, Spider Mites - 1 pI. per acre. Ground 
Application: Apply above rate in 25 to 40 gallons of water 
per acre. Aerial Application: Apply above rate in 1 or 
more gallons of water per acre. Sorghum Midge - % to Yo 
pI. per acre. Aerial Application: Apply above rates in 1 or 
more gallons of water per acre. Do not feed or graze 
within 28 days of last application. Make no more than 3 
applications as needed per season. 
SOYBEANS: Mexican Bean BeeUe, Leafhopper, 
Spider Mites, Bean Leaf Beetle, Grasshoppers, Three 
Cornered Alfalfa Hopper* - 1 pI. per acre. Aerial 
Application: Apply recommended rate in a minimum 012 
gallons of water per acre. Grasshoppers - 1 pI. per 
acre. Ground Application: Apply rate in 25 to 40 gallons of 
water per acre. Aerial Application: Apply rate in 1 or more 
gallons of water per acre. Do not feed or graze within 5 
days of last application. Do not apply within 21 days of 
harvesl. 
"Note - Three Cornered Alfalfa Hopper not registered 
for use in Califomia. 
WHEAT: Aphids (Greenbugs) - Yo to r. pI. per acre. 
Brown Wheat Mite - 1/3 to Yo pI. per acre. 
Grasshollpers - r. pI. per acre. Do not apply within 14 
days of grazing immature planl. Do not harvest grain 
within 35 Ijays of last application. Do not make more than 
2 applications per season. 
SEED CROPS 
ALFALFA: Aphids, Leafhoppers, Lygus Bugs, 
Grasshollpers, Reduction of Alfalfa Weevil Larvae - Yo 
to 1 pI. per acre. This pesticide is highly toxic to bees, do 
not apply if bees are visiting the areas to be treated when 
. crop or wE!edS are in bloom. Do not feed or graze 
livestock in treated crops, hay, threshings or stubble 
within 10 days of application. 
ATTENTION: DO NOT USE ON SEED ONIONS, SEED 
CARROl'S, OR SEED BERMUDA GRASSI 
CITRUS TREES - NONBEARING AND NURSERY 
STOCK 
Consult your state agricultural experimental station or 
state agric:ulturalextension service for proper timing of 
applications. 
CITRUS (CALIFORNIA, ARIZONA) GRAPEFRUIT, 
9/\~ 
LEMONS, ORANGES, TANGERINES: Aphids, Thrips­
Foliar Spray: 1 pint per acre. Repeat applications as 
necessary. May be applied in the year grapefruit, lemon, 
orange and tangerine trees begin to bear fruil.· Do not 
enter treated groves within 4 days of last application. Soil 
Drench (Trees 1 to 3 years old): 2 Quarts per acre applied 
in the furrow or basin around the base of tree. Apply 
when insect injury to new growth appears. Do not apply 
to trees that will bear fruit within one year. Do not apply 
when trees or substantial numbers of weeds in the 
orcham (grove) are in bloom. Do not feed treated forage 
. or graze livestock on treated orchams. 
ORNAMENTALS 
DIMETHOATE 4 EC is effective in controlling many 
sucking, piercing and chewing insects that attack 
valuable omamental plantings. Apply sprays uniformly 
and thoroughly to foliage, except as otherwise directed, 
when insects or their damage is first observed. Repeat 
applications as needed. Do not ovemose or overspray. 
Use only on the omamental plants listed below. 
IMPORTANT - When making soil injections, use a low 
pressure soil injection device. DO NOT inject into soil 
areas where children or pets may dig or exhume treated 
soil. Do not make soil injections within 20 feet of edible 
crop gamens. 
A small test area should always be sprayed first before 
general use. Do not use on any omamental stock plants 
grown as a source of propagation material, such as 
cuttings, layers, root stocks or scions for grafting or 
budding. Do not use in spray mixtures containing oil. be 
not use on ornamental plants grown in greenhouses, 
shade houses, Christmas tree and conifer plantations, 
landscapes, interiorscapes and residential, public, 
recreational, commercial, industrial and institutional 
establishments. 
HACKBERRY: Hackberry Nipplegall Psyllid, 
Hackberry Budgall Psyllid - Soil injection: Use a 1:3 
dilution. (1 part DIMETHOATE 4 EC to 3 parts water). 
Apply using a low-pressure injector. Inject 1 fl. oz. of 
dilution, 6 inches below ground, for each 112 inch of trunk 
diameter. Make insertions within dripline of tree. Apply 
prior to bud break. Do not apply to plants that have not 
been established for at least 3 years. 
HONEYSUCKLE: Honeysuckle Aphid - Soil injection: 
Use a 1:3 dilution. Apply using a low-pressure injector. 
Inject 1% fl. ozs. of dilution, 6 inches beneath ground 
surface, for each 1/2 inch of trunk diameter.. Do not apply 
to plants that have not been established for at least 3

yea~. 
PINYON PINE: Pinyon Needle Scale " 25% ozs. in 10 
gals. water. Apply spray to egg masses at the base of the 
trees' and to all rough bark and crotches that can be 
reached from the ground. Make this bark application 
when crawlers start to emerge from the eggs. Use .. 
hydraulic or backpack sprayer. Do not spray leaves or 
needles since phytotoxicity may result. Pinyon "Pitch 
Mass" Borer, Pinyon Spindle Gall Midge, Tip Moth -
Soil injection: Use a 1:3 dilution. Apply using a low­
pressure injector. Inject 1 % fl. ozs. of dil\ltion, 6 inches 
below ground surface, for each 1 inch of trunk diameter. 
Make insertions within dripline of tree. For Spindle Gall 
Midge and Tip Moth, apply in mid to late spring. For 
Pinyon Borer make application in early summer. 
DOUGLAS FIR: Fir Cone Midge - 6% ozs. in 10 gals. 
water. Make thorough coverage application when cones 
are closed and pendant. Use hydraulic or backpack . 
sprayer. 
PINES: loblolly Pine Sawfly, Nantucket Pine Tip Moth 
- 6 ozs. in 10 gals. water. Apply when most larvae are in 
the second and third instars. Zimmennan Pine Moth -
3% ozs. in 10 gals. water. Spray in mid-April and/or in 
early September for larvae control. 
ARBORVITAE: Aphids, Bagwonn, Mites - 3% ozs. in 
10 gals. water. 
AZALEAS: Aphids, Lace Bug, Leafminers, Mites, Tea 
Scale, Thrips, Whiteflies - 10/. ozs. in 10 gals. water. 
BIRCH: Aphids, Leafminers - 10/. ozs. in 10 gals. water. 
For leafminers, apply when leaves are expanded, about 
mid-May, and repeat in early July. 
BOXWOOD: Leafminers, Mealy Bug, Mites· 10/. ozs. in 
10 gals. water. For leafminers, apply in spring when 
leafminer flies first appear, or in early summer for control 
of larvae in the infested leaves. 
CARNATIONS: Aphids, Thrips, Mites· Soil drench: 2 
ozs. per 500 sq. ft. of bed or bench. Apply in sufficient 
water for Ilven distribution. Water in thoroughly following 
application. 
CAMELLIAS: Aphids, Camellia Scale, Mites, Tea 
Scale - Foliar Spray: 10/. ozs. in 10 gals. water. Apply 2 
sprays 6 weeks apart the first year, followed by annual 
applications soon after first growth begins in the spring. 
Soil drench: 2 ozs. in 1 gal. water. For plants up to 6' tall, 
\b)(~ 
increase rate proportionately for larger plants. Apply as a 
soil drench around the base of plants in early spring. 
CEDAR: Mites - 3% ozs. in 10 gals. water. ' . 
CHRISTMAS TREES: Balsam Twig, Aphid, Blue 
Aphid, Bagworms, European Pine Shoot Moth, Mites, 
Nantucket Pine Tip Moth, Zimmennan Pine Moths -
Use 1 tablespoon in a backpack or hand held sprayer. 
Use 1 to 1 % pints per acre in a minimum of 10 gallons by 
air application. Use 1 to 1 % pints per acre in 30 to 50 
gallons of water with a mist blower. NOTE: DO NOT 
USE ON JAPANESE MAPLES .OR RED LEAF 
. ORNAMENTAL SPP. 
. CYPRESS: Bactra Moth Larvae - 10/. ozs. in 10 gals. 
water. Apply as a drenching spray. 
DAYlILlES: Aphids, Thrips - 3% ozs. in 10 gals. water. 
EUONYMUS: Aphids, Scale - 3% ozs. in 10 gals. water. 
FICUS NITIDA: Thrips - 10/. ozs. in 10 gals. water. 
GARDENIAS: Tea Scale, Whitefly - 10/. ozs. in 10 gals. 
water. 
GERBERAS: Thrips - 10/. ozs. in 10 gals. water. 
GLADIOLUS: Aphids, Thrips -10/. ozs. in 10 gals. 
water. 
HEMLOCK: Mites, Scale· 10/. ozs. in 10 gals. water. 
HOLLY (ENGLISH & AMERICAN) NOT BURFORD 
VARIETY: Leafminers, Mites, Soft Scale· 10/. ozs. in 
10 gals. water. For Leafminers, apply in spring when 
Leafminer Flies first appear, or in early summer, for 
control of larvae in infested leaves. 
IRIS: Aphids, Iris Borer, Thrips· 3% ozs. in 10 gals. 
water. For borer control, spray when new leaves are 5 to 
6 inches tall. 
JUNIPER: Aphids, Bagworms, Midges, Mites - 3% ozs. 
in 10 gals. water. 
OAK: Golden Oak Scale· 3% ozs. in 10 gals. water. 
POINSETTIA: Mites, Whitefly, Mealybug, Aphids - 1;y. 
ozs. in 10 gals. water. 
ROSES: Aphids, Leafhoppers, Mites, Thrips - 10/. OZS. 
in 10 gals. water.

T AXUS (upright or spreading yew): Fletcher Scale, 
Mealybug, Mites - 3% ozs. in 10 gals. water. 
TREES 
COTTONWOOD TREES GROWN FOR PULP: Leaf 
Beetle - Use 213 to 1 quart of DIMETHOA TE 4 EC in 10 
gallons of water per acre by air, or 213 to 1 quart per acre 
by dripline (see chemigation section of this label). 
Application may be repealed two more times (total of 
three applications.) Do not apply more than three times 
per season. 
DOUGLAS FIR SEED ORCHARDS AND BREEDING 
ORCHARDS: For control of Douglas Fir Seed and Cone 
Insects such as Contarinia, Megastigma, Dioryclria, 
Barbara, Henricus (midges, worms, moths, 
phaloniids) - Apply at leasl1.S gallons but not more than 
2.1 gallons of product (S.2Ibs. to B.3Ibs. a.i.) in 100 
gallons of water by ground equipment. Spray for thorough 
coverage of foliage and conelets. Application should be 
made aftElr conelet closure and when cones are in the 
process of turning down. Repeat as necessary at the 
proper timing. Spray with caution, especially at higher 
rates for fOliage (conifer needle) phytotoxicity is possible. 
Spraying should be under direction supervision of the 
Horticulturist in charge of the seed and breeding 
. orchards. Seed should be used strictly for forest tree 
propagation or breeding purposes only. Otherwise, the 
seed shall be destroyed in an environmentally acceptable 
method. . 
ORNAMENTAL SHADE AND NURSERY TREES: 
Aphids, Elm Leaf Beetle - Soil injections: 3.5 mls. of 
product p4~r inch of tree circumference measured at 
approximately 4.5 to 5 feet above ground level. 
Application should be made once per growing season 
(twice per season for elm leaf beetles; once shortly after 
trees leaf out and once S to 8 weeks later.) Some s~ies 
such as River Birch, Prunus, Ornamental Cherry, 
Hawthorne, Japanese Lace Maple and Aspens may 
show phytotoxiC effects at label rates. DO NOT USE ON 
BEARING FRUIT TREES. Use a Kiontz Injector with a 6-
inch probl:ltip or similar type equipment capable of 
delivering metered dosage. A common household funnel 
should be used to fill the injector, and chemical-resistant 
gloves (see Personal Protective Equipment section of this 
label) must be worn. Product should be inserted to a 4 to 
S inch levEl1 below ground surface. Injections should be 
distributed equally radially in the area around the tree 
trunk to drip line. Number of insertions should equal 
.incheS of tree circumference. Do not inject concentrate 
. \\J\'} 
directly into live root tissue. Water heavily after injection. 
At least 2 inches of water is recommended. 
CONDITIONS OF SALE· liMITED WARRANTY 
AND LIMITATIONS OF LIABiliTY AND REMEDIES 
Read the Conditions of Sale· Warranty and 
Limitations of Liability and Remedies before using 
this product. If the terms are not acceptable, return 
the product, unopened, and the full purchase price 
will be refunded. 
The directions on this label are believed to be reliable and 
should be followed carefully. Insufficient control of pests 
and/or injury to the crop to which the product is applied 
may result from the occurrence of extraordinary or 
unusual weather conditions, the failure to follow the label 
directions, or good application practices, all of which are 
beyond the control of Helena Chemical Company (the 
'Company') or seller. In addition, failure to follow label 
directions may cause injury to crops, animals, man or the 
environment. The Company warrants that this product 
conforms to the chemical description on the label and is 
reasonably fit for the purpose referred to in the directions 
for use subject to the factors noted above which are 
beyond the control of the Company. The Company 
makes no other warranties or representations of any kind, 
express or implied, concerning the product, including no 
implied warranty of merchantability or fitness for any -
particular purpose, C!nd no such warranty shall be implied 
bylaw. 
The exclusive remedy against the Company for any 
cause of action relating to the handling or use of this 
product shall be limited to, at Helena Chemical 
Company's election, one of the following: 
1. Refund of the purchase price paid by buyer or 
user for product bought, or 
2. Replacement of the product used 
To the extent allowed by law, the Company shall not be 
liable and any and all claims against the Company are 
waived for special, indirect, incidental, or consequential 
damages or expense of any nature, including, but not 
limited to, loss of profits or income. The Company and the 
seller offer this product and the buyer and user accept it, 
subject to the foregoing conditions of sale and limitation 
of warranty, liability and remedies. 
© Copyright Helena Holding Company, 2005.

December 8, 2005 
HELENA CHEMICAl COMPANY 
225 Schilling Blvd., Suite 300 
Collierville, Tennessee 38017 
Telephone: 9011761-0050 
U.S. Environmental ProteCtion Agency 
Document Processing Desk (NOTIF) 
Office of Pesticide Programs (7504C) 
1801 South Bell Street 
Crystal Mall tf2, Room 266A 
Arlington, VA 22202-4501 
RE: Notification to Change Other Revisions 
To Whom It May Concern, 
Enclosed, you will find Helena Chemical Company's Notification. for numerous products. 
Helena has changed the EPA Establishment Numbers from 82952-AR-1, 82952-CA-1, 82952-
GA-1, and 82952-IA-1 to 5905-AR-1, 5905-CA-1, 5905-GA-1, and 5905-IA-1. This has been 
done on the following products: 
Helena Brand 21b. Chlorate Defoliant Desiccant 5905-87 
Fyfanon The Premium Grade Malathion 5905-196 
4.8Ib. Diuron Flowable Herbicide 5905-482 
Dimethoate 4EC 5905-493 
51b. Dimethoate Systemic Insecticide 5905-497 
Trifluralin 4EC 5905-519 
Asset PGR 5905-540 
HM-2010 5905-542 
Empower 2 5905-548 
HardBall 5905-549 
Bayonet 2 5905-554 
First-Up RST 5905-558 
This should also be noted on all alternate brand names of the master labels. 
In support of these Notifications, you will.find the following: 
EPA Form 8570-1 
1 copy of the revised label highlighted 
If you have any questions, do not hesitate to call me at (901) 752-4420 or by fax at (901) 
758-1694. Thank you for your assistance in this matter. 
Sincerely, 
v;)pS6£ 
( 
. Mandy K. Styles 
Product Registration Supervisor 
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