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crop-chem-docs/corpus/epa_ppls/5905-527.md
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# CHLOROTHALONIL 90 D
- EPA Reg No: **5905-527**
- Registrant: HELENA AGRI-ENTERPRISES, LLC, D/B/A HELENA CHEMICAL COMP
- Signal word: Danger
- Active ingredients: Chlorothalonil (90%)
- Label accepted: 2010-08-19
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/005905-00527-20100819.pdf
---
(,-
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
WASHINGTON, D.C. 20460
OFFICE OF CHE;\'llCAL SAFETY
AND POLLUTION PREVENTION
AUG 1 9 2010
Ms Cheryl Wagner
Helena Chemical Company
C/O Wagner Regulatory Associates, Inc
P.O Box 640
Hockessin, DE 19707
Subject: Label Notification(s) for Pesticide Registration Notice 2007-4
Dear Registrant:
The Agency is in receipt of your Application(s) for Pesticide Notification under
Pesticide Registration Notice (PRN) 2007-4 dated August 6,2010 for:
EPA Registration 5905-527 Chlorothalonil 90 D
The Registration Division (RD) has conducted a review of this request for applicability
under PRN 2007-4 and finds that the label change(s) requested falls within the scope ofPRN-
2007-4. The label has been date-stamped "Notification" and will be placed in our records.
Please be reminded that 40 CFR Part 156.140(a)(4) requires that a batch code, lot number,
or other code identifying the batch of the pesticide distributed and sold be placed on nonrefillable
containers. The code may appear either on the label (and can be added by non-notificationlPR
Notice 98-10) or durably marked on the container itself.
If you have any questions, please contact me directly at 703-305-5335 or Banza Djapao of
my staff at 703-305-7269.
Sincerely,
~a<~
Paul Mastradone, Acting Leader 4,1J1 .. _
Notifications & Minor Formulation'ne~eader
Registration Division (7505P)
Office of Pesticide Programs
Please read instructions on reverse before comp'-"'1g form. Form Appro f'- . OMB No. 2070-0060. Approval ex ires 0 1-
\. -. X '· ... eg istration OPP Identifier Number
United States I--
&EPA Environmental Protection Agency Amendment
Washington, DC 20460 I--
Other
Application for Pesticide - Section I
1. Company/Product Number 2. EPA Product Manager 3. Proposed Classification
5905-527 Tony Kish
4. Company/Product (Name) PM#
[8] None Restricted
Chlorothalonil 900 22
5. Name and Address of Applicant (Include Zip Code) 6. Expedited Review. In accordance with FIFRA Section 3(c)(3)
Helena Chemical Company
(b)(I), my product is similar or identical in composition and labeling
to:
c/o Wagner Regulatory Associates, Inc. EPA Reg. No.
P.O. Box 640 Product Name
Hockessin, DE 19707
D Check if this is a new address
Section - II
D Amendment - Explain below. D Final printed labels in response to
Agency letter dated
NOTifiCATION D Resubmission in response to Agency letter dated D "Me Too" Application.
~ Notification - Explain below. D Other - Explain below.
AUG 1 ~ 2010
Explanation: Use additional page(s) if necessary. (For Section I and Section II.)
Notification of label change per PR Notice 2007-4. This notification is consistent with the provisions of PR Notice 2007-4 and EPA Regulations at 40 CFR
156.10, 154.140, 156.144, 156.146, and 156.156. No other changes have been made to the labeling or the confidential statement of formula of this product.
I understand that it is a violation of 18 U.S.C. Sec. 1001 to willfully make any false statement to EPA. I further understand that if this notification is not
consistent with the requirements 40 CFR 156.10, 156.140, 156.144, 156.146, and 156.156, this product may be in violation of FIFRA and I may be subject to
enforcement action and penalties under Sections 12 and 14 of FIFRA.
Section - III
1. Material This Product Will Be Packaged In:
Chll~S~;~!aCkaging U~ckaging W~Soluble Packaging 2. Type of Container
Yes Yes Metal
X No X No X No X Plastic
If "Yes" No. per If "Yes" No. per Glass
* Certification must Unit Packaging wgt. container Package wgt container Paper
be submitted
I
Other (Specify) HOPE lined bags
3. Location of Net Contents Information l1I("Sfz'e(§)lllR-etailr~orjjtaif:1ijrl 5. Location of Label Directions
[]] Label D Container 2.5 gal., 5 gal., 30 gal., 55 gal. ~ On Label
On Labeling accompanying product
6. Manner in Which Label is Affixed to Product ~ Lithograph CJ Other _adhesive backed label
X Paper glued
Stenciled
Section - IV
0
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1. Contact Point (Complete items directly below for identification of individual to be contacted, if necessary, to process thIs application.)
Name I Title I Telephone No. (InCIl.(d~eAe:a Code)
Cheryl Wagner Agent for Helena Chemical Company (302) 2sqc&,g5;;1 0
Certification :;. 6. °Dflte Applicajion
I certify that the statements I have made on this form and all attachments thereto are true, accurate and complete. , 0 c d?eceived
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I acknowledge that any knowingly false or misleading statement may be punishable by fine or imprisonment or
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'~A .9-. '-".. ~ Agent for Helena Chemical Company c. L L ( (
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Cheryl Wagner August 6,2010
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.. ThiS IS a reproduction of EPA Form 8570-1 (Rev. 8-94) PrevIous editions are obsolete.
HELENA CHEMICAL COMPANY
225 Schilling Blvd., Suite 300
Collierville, Tennessee 38017
Phone: (901) 761-0050
May 3, 2010
US Environmental Protection Agency
Office of Pesticide Programs
1200 Pennsylvania Ave. NW
Washington, D.C. 20460
Re: Designation of Agent for:
Helena Chemical Company (EPA Company no. 5905)
664 Moore Road
Memphis, TN 38120
Dear Sir or Madam:
This letter serves as notification that our company has appointed Wagner Regulatory Associates,
Inc. ("WRA") to serve as Agent on our company's behalf regarding US EPA regulatory matters
relative to Helena's existing registered products, products pending registration and future
registration applications. WRA is based at 7460 Lancaster Pike, Suite 9, Hockessin, Delaware'
19707.
Helena requests the EPA to accept registration submissions and inquiries from WRA for Helena
products and authorizes the EPA to provide registration correspondence to WRA for Helena
products.
Thank you for your time and assistance. Please feel free to call me at if you have any questions.
This appointment will remain in effect until such time as it is revoked in writing by Helena.
Respectfully submitted,
[)a--J~-
Dave Thomas
Vice President - Marketing
cc: WRAlnc.
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August 6, 2010
Document Processing Desk (NOTIF)
ATTN: Mr. Tony Kish PM 22
Registration Division (7504P)
U.S. Environmental Protection Agency
Room S-4900, One Potomac Yard
2777 South Crystal Drive
Arlington, Virginia 22202-4501
Dear Mr. Kish:
Re: Chlorothalonil 90D
EPA Registration Number 5905-527
Notice of Revised Storage & Disposal Label Language
WRA
Wagner Regulatory Associates, Inc.
P.O. Box 640
7460 Lancaster Pike, Suite 9
Hockessin, Delaware 19707
Wagner Regulatory Associates, Inc., on behalf of Helena Chemical Company, hereby
notifies the Agency that the storage and disposal section of the subject label as been
revised in accordance with PR Notice 2007-4. Enclosed for the Agency's file is:
Letter from Helena Chemical Company authorizing Wagner Regulatory to
serve as Agent
EPA Notification form (EPA Form 8570-1)
One copy of revised labeling
Please feel free to contact me at (302) 234-8551 if you have any questions or require
additional information.
Respectfully submitted,
\ \) . 0 "" ~.\...A..)~~
Cheryl Wagner
Agent for Helena Chemical Company
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CHLOROTHALONIL 900
AGRICULTURAL FUNGICIDE
(90% Water Dispersible Granules)
NOTIFICATION
AUG 1 9 2010
ACTIVE INGREDIENT:
Chlorothalonil (tetrachloroisophthalonitrile) ....... ............................... ..................................... 90.0%
INERT INGREDIENTS: ......................................................................................................................... 10.00/0
TOTAL ........................................................................................................................ 100.00/0
KEEP OUT OF REACH OF CHILDREN
DANGER • PELIGRO
Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle.
(If you Do not understand the label, find someone to explain it to you in detail.)
FIRST AID
IF IN EYES: · Hold eye open and rinse slowly and gently with water for 15-20 minutes.
· Remove contact lenses, if present, after the first 5 minutes, then continue
rinsing eye.
· Call a poison control center or doctor immediately for advice.
IF ON SKIN OR CLOTHING: · Take off contaminated clothing.
· Rinse immediately with plenty of water for 15- 20 minutes.
· Call a poison control center or doctor for treatment advice.
IF INHALED: · Move victim to fresh air.
· If person is not breathing, call 911 or an ambulance, then give artificial respiration preferably
mouth-ta-mouth if possible.
· Call a poison control center or doctor immediately for further treatment advice.
HOT LINE NUMBER
Have the product container or label with you when calling a poison control center or doctor, or going for treatment.
For emergency assistance call toll-free, 1-800-424-9300 (ChemTrec).
NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage.
EPA REG. NO. 5905-527
EPA EST. NO.
NET CONTENTS:
MANUFACTURED FOR
HELENA CHEMICAL COMPANY
225 SCHILLING BOULEVARD, SUITE 300
COLLIERVILLE, TN 38017
Disclaimer: Always refer to the label on the product before using Helena or any other product.
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PRECAUTIONARY STATEMENTS
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
DANGER
Corrosive. Causes irreversible eye damage. May be fatal if inhaled. Do not get in eyes or on clothing. Avoid contact with skin. Do not breathe
dust. Prolonged or frequently repeated skin contact may cause allergic reaction in some individuals.
PERSONAL PROTECTIVE EQUIPMENT (PPE)
Some materials that are chemical resistant to this product are made of waterproof material. If you want more options, follow the instructions for
category A on EPA chemical-resistant category selection chart.
Mixers, loaders, applicators and all other handlers must wear:
long-sleeved shirt and long pants
shoes plus socks
chemical resistant gloves such as or made of any waterproof material, such as polyethlene or polyvinyl chloride
goggles or faceshield, and
a respirator with an organic-vapor removing cartridge with a prefilter approved for pesticides (MSHAINIOSH approval number prefix TC-23C), or
a canister approved for pestiCides (MSHAINIOSH approval number prefix TC-14G), or a NIOSH approved respirator with any N, R, P, or HE
filter.
Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and
wash PPE separately from other laundry.
ENGINEERING CONTROLS STATEMENT
When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard
(WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS.
USER SAFETY RECOMMENDATIONS
Users should:
Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately if pesticide gets inside. Then
wash thoroughly and put on clean clothing. Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As
soon as possible, wash thoroughly and change into clean clothing.
ENVIRONMENTAL HAZARDS
This product is toxic to fish, aquatic invertebrates and wildlife. Do not apply directly to water or to areas where surface water is present or to intertidal
areas below the mean high-water mark. Drift and runoff may be hazardous to aquatic organisms in neighboring areas. Do not contaminate water
when disposing of equipment washwater or rinsate.
This chemical is known to leach through soil into groundwater under certain conditions as a result of label use. Use of this chemical in areas where
soils are permeable, particularly where the water table is shallow, may result in groundwater contaminate.
This chemical can contaminate surface water through spray drift. Under some conditions, it may also have a high potential for runoff into surface
water for several days to weeks after application. These include poorly draining or wet soils with readily visible slopes toward adjacent surface
waters, frequently flooded areas, areas overlaying extremely shallow ground water, areas with infield canals or ditches that drain to surface water,
areas not separated from adjacent surface waters with vegetated filter strips, and areas over-laying tile drainage systems that drain to surface water.
DIRECTIONS FOR USE
It is a violation of Federal law to use this product in a manner inconsistent with its labeling. 0 ~ ()
Do not apply this product in a way that will contact workers or other persons, or pets, either directly or through drift. Only protectecfhandlers may
be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesti«i6e' (egulation.
Disclaimer: Always refer to the label on the product before using Helena or any other product.
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r--------------------------A~G~R~IC~U~LT=U~RA~L~US~E~R~E~QU~I~RE=M=E-NT~S--------------------------~
Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard contains
requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It
contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions
pertaining to statements on this label about personal protective equipment (PPE) and restricted-entry interval. The requirements in this box only
apply to uses of this product that are covered by the Worker Protection Standard.
Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours.
PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has
been treated, such as plants, soil, or water is:
coveralls
chemical resistant gloves such as or made of any waterproof material
shoes plus socks, and
protective eyewear
Special Eye Irritation Provisions: This product is a severe eye irritant. Although the restricted-entry interval expires after 12 hours, for the next 6-1/2
days entry is permitted only when the following safety measures are provided:
(1) At least one container designed specifically for flushing eyes must be available in operating condition at the WPS-required decontamination site
intended for workers entering the treated area.
(2) Workers must be informed, in a manner they can understand:
-- that residues in the treated area may be highly irritating to their eyes,
-- that they should take precautions, such as refraining from rubbing their eyes, to keep the residues out of their
eyes.
- that if they do get residues in their eyes, they should immediately flush their eyes using the eyeflush container
that is located at the decontamination site or using other readily available clean water, and
-- how to operate the eyeflush container.
STORAGE AND DISPOSAL
Do not contaminate water, food, or feed by storage or disposal. Open dumping is prohibited.
PESTICIDE STORAGE: Store in a dry place.
PESTICIDE DISPOSAL: Pesticide wastes are toxic. Improper disposal of excess pesticide, pesticide spray, or rinsate is a violation of Federal law. If
these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the
Hazardous Waste representative at the nearest EPA Regional Office for guidance.
CONTAINER DISPOSAL: Nonrefillable container. Do not refill or reuse this container. Offer for recycling, if available, or, dispose of empty bag in a
sanitary landfill or by incineration, or if allowed by state and local authorities, by burning. If burned, stay out of smoke.
CHEMIGATION
Apply this product only through center pivot, motorized lateral move, traveling gun, solid set or portable (wheel move, side roll, end tow, or hand
move) irrigation system(s). Do not apply this product through any other type of irrigation system.
Crop injury, lack of effectiveness, or illegal pesticide residues in the crop can result from non-uniform distribution of treated water.
If you have questions about calibration, you should contact State Extension Service specialists, equipment manufacturers, or other(s~perts.
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Do not apply this product through irrigation systems connected to a public water system. Public water system means a system for, ,!h-e"provision to
the public of piped water for human consumption if such system has at least 15 service connections or regularly serveG °a~ average ot at least 25
individuals daily at least 60 days per year. g u ~ c
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Posting of areas to be chemigated is required when 1) any part of a treated area is within 300 feet of sensitive areas 8UQ,h~as residential areas, labor
camps, businesses, day care centers, hospitals, in-patient clinics, nursing homes, or any public areas such as schgglB:Rarks, playgbJods, or other
public facilities not including public roads, or 2) when the chemigated area is open to the public such as golf courses 6r ref3i1 greenho~ses.
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Posting must conform to the following requirements. Treated areas shall be posted with signs at all usual points of entry and alon£) likely routes of
approach from the listed sensitive areas. When there are no usual points of entry, signs must be posted in the corners of the treateo afe"as and in
any other location affording maximum visibility to sensitive areas. The printed side of the sign should face away from the treated areiftowards the
sensitive area. The signs shall be printed in English. Signs must be posted prior to application and must remain posted until foliage has dried and soil
Disclaimer: Always refer to the label on the product before using Helena or any other product.
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surface water has disappeared. Signs may ~main in place indefinitely as long as they are composed of materials to prevent deterioration and
maintain legibility for the duration of the posting period.
,
Posting required for chemigation does not replace other posting and re-entry interval requirements for farmworker safety, including those posted to
comply with the Worker Protection Standard.
All words shall consist of letters at least 2-1/2 inches tall, and all letters and the symbol shall be a color which sharply contrasts with their immediate
background. At the top of the sign shall be the words KEEP OUT, followed by an octagonal stop sign symbol at least 8 inches in diameter containing
the word STOP. Below the symbol shall be the words PESTICIDES IN IRRIGATION WATER.
For Sprinkler Chemigation:
The system must contain a functional check valve, vacuum relief valve, and low-pressure drain appropriately located on the irrigation pipeline to
prevent water source contamination from backflow.
The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection
pump.
The pesticide injection pipeline must also contain a functional, normally closed, solenoid-operated valve located on the intake side of the injection
pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation system is either
automatically or manually shut down.
The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops.
The irrigation line or water pump must include a functional pressure switch which will stop the water pump motor when the water pressure decreases
to the point where pesticide distribution is adversely affected.
Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump) effectively designed and constructed of
materials that are compatible with pesticides and capable of being fitted with a system interlock.
Do not apply when wind favors drift beyond the area intended for treatment.
GENERAL INFORMATION
CHLOROTHALONIL 900 is an excellent fungicide when used according to label directions for control of a broad spectrum of plant diseases.
CHLOROTHALONIL 900 can be used effectively in dilute or concentrate sprays. Thorough, uniform coverage is essential for disease control.
Coverage may be enhanced by adding SURFIX® spreader-sticker spray adjuvant.
GENERAL PRECAUTIONS AND RESTRICTIONS
This product must not be applied within 150 feet (for aerial and air-blast application) or 25 feet (for ground applications) of marine/estuarine water
bodies unless tIlat there is an untreated buffer area of that width between the area to be treated and the water body.
Avoiding spray drift at the application site is the responsibility of the applicator. The interaction of many equipment-and-weather-related factors
determine the potential for spray drift. The applicator and the grower are responsible for considering all these factors when making decisions.
The following drift management requirements must be followed to avoid off-target drift movement from aerial applications to agricultural field crops.
These requirements Do not apply to forestry applications, public health uses or to applications using dry formulations.
1. The distance of the outer most nozzles on the boom must not exceed 3/4 the length of the wingspan or rotor.
2. Nozzles must always pOint backward parallel with the air stream and never be pointed downwards more than 45 degrees.
Where states have more stringent regulations, they should be observed. o OL:('CO
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The applicator should be familiar with and take into account the information covered in the Aerial Drift Reduction AOvisory IhformatiolJ.~ Co
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AERIAL DRIFT REDUCTION ADVISORY INFORMATION
[This section is advisory in nature and does not supersede the mandatory label requirements.]
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INFORMATION ON DROPLET SIZE ( l. < C L : ( L L~' u
The most effective way to reduce drift potential is to apply large droplets. The best drift management strategy is to apply the largestdSQRJets that
provide sufficient coverage and control. Applying larger droplets reduces drift potential but will not prevent drift if applications are m~cleJm!)?operly, or
under unfavorable conditions (see Wind, Temperature).
Disclaimer: Always refer to the label on the product before using Helena or any other product.
6Aug2010 revised storage & disposal .
CONTROLLING DROPLET SIZE
., Volume -'Use high flow rate nozzles to apply the highest practical spray volume, Nozzles with higher rated flows produce larger droplets.
• Pressure - Do not exceed the nozzle manufacturer's recommended pressures. For many nozzle types lower pressure produces larger droplets.
When higher flow rates are needed, use higher flow rate nozzles instead of increasing pressure.
• Number of nozzles - Use the minimum number of nozzles that provide uniform coverage.
• Nozzle Orientation - Orienting nozzles so that the spray is released parallel to the airstream produces larger droplets than other orientations and is
the recommended practice. Significant deflection from horizontal will reduce droplet size and increase drift potential.
• Nozzle Type - Use a nozzle type that is designed for the intended application. With most nozzle types, narrower spray angles produce larger
droplets. Consider using low-drift nozzles. Solid stream nozzles oriented straight back produce the largest droplets and the lowest drip potential.
BOOM LENGTH
For some use patterns, reducing the effective boom length to less than 3/4 of the wingspan or rotor length may further reduce drift without reducing
swath width.
APPLICA nON HEIGHT
Applications should not be made at a height greater than 10 feet above the top of the largest plants unless a greater height is required for aircraft
safety. Making applications at the lowest height that is safe reduces exposure of droplets to evaporation and wind.
SWATH ADJUSTMENT
When applications are made with crosswind, the swath will be displaced downwind. Therefore, on the up and downwind edges of the field, the
applicator must compensate for this displacement by adjusting the path of the aircraft upwind. Swath adjustment distance should increase, with
increasing drift potential (higher wind, small drops, etc.).
WIND
Drift potential is lowest between wind speeds of 2-10 mph. However, many factors, including droplet size and equipment type determine drift
potential at any given speed. Application should be avoided below 2 mph due to variable wind direction and high inversion potential. NOTE: Local
terrain can influence wind patterns. Every applicator should be familiar with local wind patterns and how they affect spray drift.
TEMPERATURE AND HUMIDITY
When making applications in low relative humidity, set up equipment to produce larger droplets to compensate for evaporation. Droplet evaporation
is most severe when conditions are both hot and dry.
TEMPERATURE INVERSIONS
Applications should not occur during a temperature inversion because drift potential is high. Temperature inversions restrict vertical air mixing, which
causes small suspended droplets to remain in concentrated cloud. This cloud can move in unpredictable directions due to the light variable winds
common during inversions. Temperature inversions are characterized by increasing temperatures with altitude and are common on nights with
limited cloud cover and light to no wind. They begin to form as the sun sets and often continue into the morning. Their presence can be indicated by
ground fog; however, if fog is not present, inversions can also be identified by the movement of smoke from a ground source or an aircraft smoke
generator. Smoke that layers and moves laterally in a concentrated cloud (under low wind conditions) indicates an inversion, while smoke that
moves upward and rapidly dissipates indicates good vertical air mixing.
Sensitive Areas:
The pesticide should only be applied when the potential for drift to adjacent sensitive areas (e.g., residential areas, bodies of water, known for habitat
for threatened or endangered species, non-target crops) in minimal (e.g., when wind is blowing away from sensitive areas). (
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Do not combine in the spray tank with pesticides, surfactants, or fertilizers, unless your prior use has shown the cQmbBaron physical;y compatible,
effective, and non-injurious under your conditions of use. When combining with pesticides, surfactants, or fertilizers, refet to the lab,e~Qg on the
product that CHLOROTHALONIL 900 is being mixed with for specific tank mix instructions. C c, t (> ( ~ '-
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Do not combine with Dipel® 4L, Triton® AG-98, or Triton® 8-1956 as phytotoxiCity may result from the combinatioo CNc1c1l "applied toCsome crops on
this label. c L ~. L Co I.) (L (
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Dosage rates on this label indicate pounds of CHLOROTHALONIL 900 per acre, unless otherwise stated. Under conditions favoring .9Ls8ase
development, the high rate speCified and shortest application interval should be used. ( v CO" 0 0
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6Au~2010 revised storaqe & disposal
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The required amount of product should be adCled slowly into the spray tank during filling. With concentrate sprays, pre-mix the required amount in a
clean container and add to the spray tank as it is being filled. Keep agitator running when filling spray tank and during spray operations.
APPLICATION INSTRUCTIONS
FIELD AND ROW CROPS
Apply in sufficient water to obtain adequate coverage of foliage. Gallonage to be used will vary with crop and amount of plant growth. Spray volume
usually will range from 20 to 150 gallons per acre (200 to 1400 liters per hectare) for dilute sprays and 5 to 10 gallons per acre (50 to 100 liters per
hectare) for concentrate ground sprays and aircraft applications. Both ground and aircraft methods of application are recommended unless specific
directions are given for a crop. Application through sprinkler irrigation systems is not recommended unless specific directions are given for a crop.
S r f d I'b r . t fbi ee appllca Ion an ca I ra Ion inS ruc Ion eow:
Crop Pre· Harvest Interval (PHI)
Beans (Snap) 7 days
Beans (Dry)· Navy, 6 weeks
Pinto, Kidney, Lima,
Blackeye
I
i
Cabbage, Chinese 7 days - for Chinese Broccoli or
Cabbage (tight Chinese Cabbage only
headed varieties
only), Cauliflower,
Broccoli, Chinese
Broccoli, Brussels I
Sprouts
Carrot
Disease Rate/Acre Special Directions
Rust 1x.-2Yt Ibs. Use in sufficient water to obtain adequate coverage.
Begin applications during early bloom stage or when disease first
threatens and repeat at 7 day intervals.
Botry1is blight(grey mold) 2)1, Ibs. Same as above.
Limitations:
- Do not re-apply this product within 7 days of last treatment.
- Do not apply more than 10 Ibs. of this product (9 Ibs. a.i.) per acre per season.
Grazing Restrictions:
Do not graze treated areas or feed treated plant parts to livestock.
Rust 1x.-1o/. lbs. Use in sufficient water to obtain adequate coverage.
Anthracnose
Downy Mildew Cercospora leaf Begin applications during early bloom stage or when disease first
spot threatens and repeat at 7 to 10 day intervals.
(Blackeye only)
For use on beans harvested only with pods removed.
Limitations:
- Do not re-apply this product within 7 days of last treatment.
- Do not apply more than 6 ~ Ibs. of this product (6 Ibs. a.i.) per acre per season.
Grazing Restrictions:
Do not graze treated areas or feed treated jJlant jlCIrts to livestock.
Altemaria leaf spot 1%lbs. Use in sufficient water to obtain adequate coverage.
Downy mildew
Begin applications after transplants are set in field, or shortly after
emergence of field-seeded crop, or when condnions favor disease
development.
Repeat at 7 to 10 day intervals.
Ring spot (California only) 1)1, Ibs. For field-seeded brussels sprouts, begin applications at time of early
sprout development or when condnions favor disease development.
Repeat at 7 to 10 Day intervals.
Limitations:
- Do not apply more than 13a Ibs. of this product (12Ibs. a.i.) per acre per season.
Cercospora (ear1y) blight 1 %-1)1, Ibs. Use in sufficient water to obtain adequate coverage.
Altemaria (late) blight
Start applications when disease threatens and repeat at 7 to 10 day
intervals.
May be applied through sprinkler irrigation equipment. See
calibration section following this table for directions.
Limitations:
- Do not re-apply this product within 7 days of last treatment.
- Do not apply more than 16131bs. of this product (15Ibs. a.i.) per acre per season.
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6Aua2D1D revised storaae & disDosal
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Crop Pre-Harvest Interval (PHI) Disease Rate/Acre Special Directions
Ce'lery . 7 days Cercospora (early) blight cjl-1%lbs. Use cjl-2% Ibs. per acre on a 7 day schedule.
Setporia (late) blight
Start applications when transplants are set in the field.
Apply in sufficient water to obtain adequate coverage.
May be applied through sprinkler irrigation equipment. See
calibration section following this table for directions.
Basal stalk rot 10/.-2% Ibs. Same as above
(Rhizoctonia so/ani)
Pink rot (suppression) 2% Ibs. Same as above
Early blight, Late blight 1 % -1% Ibs. per For celery seed beds, apply 125 gallons per acre.
100 gallons
Start applications shortly after crop emergence.
Use higher rate under severe disease conditions.
Limitations:
- Do not re-apply this product within 7 days of last treatment.
- Do not apply more than 17 7/91bs. of this product (18Ibs. a.i.) per acre per season.
Corn (sweet), Corn 14 days Helminthosporium leaf e-1% Ibs. Use in sufficient water to obtain adequate coverage.
grown for seed blights
Rust Begin applications when conditions favor disease development.
Under severe disease conditions, use 1 %-1% Ibs. per acre.
Limitations:
- Do not re-apply this product within 7 days of last treatment
- Do not apply more than 10 Ibs. of this product (9 Ibs. a.i.) per acre per season.
- Do not apply to sweet com to be processed.
Grazing Restrictions:
- Do not allow livestock to graze in treated fields.
- Do not ensile treated com or use as livestock forage.
Cranberry 50 days Fruit rots 3%-5% Ibs. Apply at early bloom and repeat at 10 to 14 day intervals.
Lophodermium
leafltwig blight Under severe disease conditions, use the 5% Ibs. per acre rate on a
10 day schedule.
May be applied through sprinkler irrigation equipment. Use 300
gallons of water per acre through solid set systems only. See
calibration section foliowinQ this table for directions.
Limitations:
- Do not apply more than 16~ Ibs. of this product (15Ibs. a.i.) per acre per season.
Do not apply to bogs when flooded or allow release of irrigation water from bogs for at least 3 days followinQ aQQIication.
Cucurbils - - Anthracnose 1 %-1% Ibs. Use in sufficient water to obtain adequate coverage.
Cucumber, Downy mildew
Cantelope, Target spot Begin applications when plants are in first true leaf stage or when
Muskmelon, condHions are favorable for disease development.
Honeydew melon,
Watermelon, Repeat applications at 7 day intervals.
Squash, Pumpkin
Under severe conditions, shorten spray interval.
May be applied through sprinkler irrigation equipment (solid set,
portable wheel move, or center pivot systems only). See calibration
direction following this table.
Cercospora leaf spot 1 %-2% Ibs. Same as above.
Gummy stem blight (black rot)
Altemaria leaf blight
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Cucumber belly rot 7lbs. Use in sufficient watet ill 'i.lltairu runoff to sOil sc~rface.
(Rhizocatonia so/ani) o '-' 0
Make a single application wheno vines begin tl)~f~!TTl.
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May be applied through s~'riDIild'r irrigation. Se.3(~ibration section
following this table for directions. " ( ~. c v
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6AuQ2010 revised storaqe & disposal
12
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Crop Pre-Harvest Interval (PHI) Disease Rate/Acre ~cial Directions
G~asses groYJll for 14 days Stem rust cp-1f3lbs. Use sufficient coverage to obtain adequate coverage.
seed Leaf rust
Stripe rust Begin applications during stem elongation when conditions favor
Septoria leaf spot disease development.
Glume blotch
Bipolaris leaf spot Re-apply at flag (top) leaf emergence and repeat applications at 14
Drechslera leaf spot day intervals.
Selenophoma (eyes pot) cp-1f3lbs. Same as above.
Limitations:
- Do not apply more than 5 Ibs. of this product (4.5 Ibs. a.i.) per acre per season.
Grazing Restrictions:
- Do not allow livestock to raze in treated areas or feed treated plants to livestock.
Mint 80 days Rust 1xlbs. Use sufficient coverage to obtain adequate coverage.
(For use ONLY in Septoria leaf spot
Indiana, Michigan, Begin applications when emerging plants are 4-8 inches high.
and Wisconsin)
Repeat applications at 7 to 10 day intervals.
Limitations:
- Do not re-apply within 7 days of last treatment.
- Do not apply more than 3 times per season
- Do not feed fresh or extracted mint hay from treated fields to livestock.
Onion (dry bulb) 7 days Botrytis leaf blight/blast CP-1%lbs. Apply in sufficient water to obtain thorough coverage of tops.
Botrytris neck rot
(suppression) Low Disease This product is recommended for use with disease monitOring
Purple blotch Hazard & Prior to systems, which adjust fungicide rates and frequency of application
Infection: cP Ibs. according to disease hazard. See application rates in Rate/Acre
(Every 10 days) section under these conditions.
Low Disease For suppression of neck rot (Botrytis spp) during storage, a minimum
Hazard & Some of three weekly applications prior to lifting, using 1 X -1 % Ibs. per acre
Disease Present: is recommended.
1 X Ibs. (Every 7 to
10 days)
High Disease
Hazard: 1%lbs.
(Every 7 days)
Limitations:
- Do not apply more than 16[3lbs. of this product (15Ibs. a.i.) per acre per season.
Onion (green 14 Days Botrytis leaf blight/blast 1X·2%lbs. Use sufficient water to obtain thorough coverage of tops.
bunching), Leeks, Downy mildew
Shallots, Onion (suppression) Begin applications prior to favorable infection periods, and repeat at
grown for seed Purple blotch 7 to 10 day intervals as long as conditions favor disease.
Use the high rate and a 7 day schedule of applications when heavy
Garlic 7 days dew or rain persists.
, If additional disease control is needed before harvest, use another
registered fungicide.
Limitations:
- Do not apply more than 3 times per season for green bunching onions, leeks, and shallots.
papaya - Altemaria fruit spot 1% -2Y, Ibs. Apply with ground equipment only, in sufficient water to obtain
Antracnose adequate coverage on fruit and leaves.
Stem end rot
Begin treatment when conditions favor development of disease and
continue treatments at 14 day intervals until weather conditions no
longer favor disease development. Co
Limitations:
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. Do not apply more than 7Yz Ibs. of this product (6.75Ibs. a.i.) per acre per season. cc. G
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- Do not graze livestock in treated area or feed processing by-products to IiveS;()'(;f(:;~: (. ~
Parsnip 10 days Altemaria leaf spot 1X-1[3lbs. Apply in sufficient water to (,~taEl adequate coverage.
Antracnose o L
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Downy mildew Make the first applicatiOn' €t'th'il drst sign of disl:iase or when
Botrytis blight(grey mold) i conditions are favorable fdi' iDftjctions. 0 c.c
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Continue applications dn'iltT'to 1.';) day schedul~.
Limitations: ': v
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. Do not apply more than 4 times per season . ,
Grazing restrictions: c <. (. L
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- Do not feed treated plant parts to livestock. l.t-. (, v
Disclaimer: Always refer to the label on the product before using Helena or any other product.
6AuQ2010 revised storaQe & disposal
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Crop Pre-Harvest Interval (PHI)~ Disease Rate/Acre Special Directions
Passion Fruit - Alternaria fruit and leaf 1 liz Ibs. Apply with ground equipment only, in sufficient water to obtain
(Hilwaii Only). spot (passion fruit adequate coverage on fruit and leaves.
brown spot)
Peanut 14 days
Soybean -
Determinate
(Southern) Varieties
Soybean
Indeterminate
(Northern) Varieties
Limitations:
Begin treatment when fruit spots appear (April to July) and continue
treatments at 14 day intervals until weather conditions no longer
favor disease development.
- Do not apply more than 8Y. Ibs. of this product (7.5 Ibs. aJ.) per acre per season.
Grazing restrictions:
- Do not graze livestock in treated area or feed P!ocessing.b}'j)l'oducts to livestock.
Cecospora (early)leaf l-lY.lbs. Apply in sufficient water for adequate coverage when leaf wetness
spot first occurs and before disease symptoms appear, generally 30 to 40
Cercosporidium (late) days after planting.
leaf spot
Rust lY.lbs.
Web blotch
Limitations:
- Do not re-apply within 14 days of last treatment
When late leaf spot prevails or when rust or web blotch occur, apply
1X Ibs. per acre.
May be applied through sprinkler irrigation equipment. See
calibration section foliowinrL this table for directions.
Same as above.
- Do not apply more than 10 Ibs. of this product (9 Ibs. a.i.) per acre per season.
Grazing restrictions:
- Do not graze livestock in treated area.
- Do not feed hay or threshings from treated fields to livestock.
Anthracnose 1 X- 2 Ibs. Apply in sufficient water to obtain oomplete ooverage, using at least
Diaporthe pod and stem (2 application five gallons of water per acre for aerial application.
blight program)
Frogeye leaf spot or
(Cercospora sojina) -
Purple seed stain cjl-l liz Ibs.
Cercospora leaf blight (3 application
(Cercospora kikuchii) program)
Septora brown
Stem canker (Diaporthe
phase%rum var.caulivora)
Limitations:
cjllbs.
- Do not re-apply within 14 days of last treatment
Use three application program in areas having a history of moderate
to severe disease intenSity.
May be applied through sprinkler irrigation equipment. See
calibration section following this table for directions.
Two application program: Make the first application at early pod
sel (R3) slage, when majority of pods are X to /) inch in length and
the seoond at beginning of seed formation (R5) which occurs about
14 days later.
Three application program: Make the first application at the
~inni~ of flowering (R1), and the second at seed formation (R5).
Apply in 10 to 20 gallons of water per acre, as a band treatment
directing spray to provide coverage of entire plant.
Make one application at emergence of second trifoliate leaves (V2).
If conditions favor continued infection, make additional applications
at 14 day intervals.
- Do not apply more than 5 Ibs. of this product (4.5 Ibs. a.i.) per acre per season.
Grazing restrictions:
Do not feed treated plant parts to livestock or allow grazing in treated fields.
Anthracnose lX- 2lbs. Apply in sufficient waler to obtain oomplete ooverage, using alleast
Diaporthe pod and stem (2 application five gallons of water per acre for aerial application.
blight program)
F rogeye leaf spot Q[
(Cercospora sojina)
Purple seed stain
Ceroospora leaf blight
(Cercospora kikuchii)
Septora brown
Limitations:
cjl-ll1z Ibs.
(3 application
program)
- Do not re-apply wilhin 14 days of last treatment.
Use three application program in areas havioQ;~ history of moderate
to severe disease intensity. c.
May be applied through sprinkler irrigatio'i\ ;u~p~~nt See
calibration section foliQyJin'9 thls~table for direc!Lons. .
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Two application prog~aOE (M,a~e the first all;>~:oJtion at early pod
set (R3) stage, when maJor.ty of?,ods are X to Ii inch in length and
the second at beginning of'S6'.sd 10rmatior1~(R~lrwr\ich occurs about
14 days later. 00 C (, Ll (. ( 00
Three application prograrw M~ke the first apl1~ication at the
beginning of flowering (Pvtl,{3:\(Mhe second at see!! formation (R51.
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- Do not apply more than 5 Ibs. of this product (4.5 Ibs. a.i.) per acre per season.
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Grazing restrictions:
Do not feed treated plant parts to liveslock or allow grazing in treated fields.
Disclaimer: Amays refer to the label on the product before using Helena or any other product.
6Aug2010 revised storage & disposal
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Crop Pre·Harvest Interval (PHI) Disease Rate/Acre Special Directions
Tomato - Foliage - Early blight 1x -lXlbs. Apply in sufficient water to obtain adequate coverage.
Late blight
Gray leaf spot Begin applications when dew or rain occur and disease threatens.
Gray leaf mold
Septoria leaf spot Use highest and shortest interval specified when disease conditions
Target spot are severe.
May be combined with EPA-registered products that claim copper as
the active ingredient and are labeled for control of bacterial diseases
of tomatoes: Check the manufacturer's label for specific
instructions, precautions, and limitations prior to mixing.
May be applied through sprinkler irrigation equipment (solid set or
portable wheel move systems only). See calibration section
following this table for directions.
Tomato· - Anthracnose 1X -2Y..lbs. Same as above.
Fruit Alternaria fruit spot
(black mold)
Rhizoctonia fruit rot
Late blight fruit rot
BotrytisgrCl}' mold
Limitations:
- Do not apply more than 16-719lbs. of this product (15.1 Ibs. a.i.) per acre per season.
- Do not use with Copper Count® N in concentrated spray suspensions.
Grazing restrictions:
- Do not graze livestock in treated area or feed processi~by-products to livestock.
CALIBRATION TECHNIQUES FOR SPRINKLER IRRIGATION
CHLOROTHALONIL 900 may be used through two basic types of sprinkler irrigation systems as outlined in Sections A and B below. Determine
which type of system is in place, then refer to the appropriate directions provided for each type.
Always inject CHLOROTHALONIL 900 into irrigation water after it discharges from the irrigation pump and after it passes through the
check valve. Never inject pesticides into the intake line on the suction side of the pump.
A. Center Pivot, Motorized Lateral Move, and Traveling Gun Irrigation Equipment
For injection of pesticides, these continuously moving systems must use a positive displacement injection pump, of either diaphragm or piston
type, constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock and capable of injection at
pressures approximately 2-3 times those encountered within the irrigation water line. Venturi applicator units cannot be used on these systems.
Fill chemical supply tank of injection equipment with water. Operate system for one complete revolution or run across the field, measuring time
required, amount of water injected, and acreage covered. Thoroughly mix recommended amount of CHLOROTHALONIL 900 for acreage to be
covered into the same amount of water used during calibration and inject into system continuously for one revolution or run. Mixture in the
chemical supply tank must be continuously agitated during the injection run. Shut off injection equipment after one revolution or run, but
continue to operate irrigation system until product has been cleared from last sprinkler head.
B. Solid Set and Portable (Wheel Move, Side Roll, End Tow, or Hand Move) Irrigation Equipment
With stationary systems, an effectively designed in-line venturi applicator unit is preferred which is constructed of materials that are compatible
with pesticides; however, a positive-displacement pump can also be used.
Determine acreage covered by sprinkler. Fill tank of injection equipment with water and adjust flow to use contents over a thirty to forty-five
minute period. Mix desired amount of product for acreage to be covered with water so that the total mixture plus water in the injeqtion tank is
equal to the quantity of water used during calibration and operate entire system at normal pressures recommended by the manllfB6turer of
injection equipment used for amount of time established during calibration. Agitation is recommended. CHLOROTHALONIL 9Q,Q ccn be
injected at the beginning or end of the irrigation cycle or as a separate application. Stop injection equipment after treatment is''C(,Qr,fipleted and
continue to operate irrigation system until product as been cleared from last sprinkler head. ~ (J c ~ c ~ c
TREE AND ORCHARD CROPS
oLe
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Apply CHLOROTHALONIL 90 in sufficient water and with proper calibration to obtain uniform coverage of tree canopy.".A,:p.r51icationcwith-fjrpund
eqUipment is preferable to aerial application, because ground applications generally give better coverage of the tree G8~QPY. (0 l l l G
Disclaimer: Amays refer to the label on the product before using Helena or any other product.
6Aug20 1 0 revised storaqe & disposal
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Crop Pre-Harvest "-.:.o15ease Rate/Acre Rate/ - Special Directions
Interval (PHI) 100 gallons
Peach Leaf curl 2%-3% Ibs. ~-1x Ibs. For best control of both diseases, apply at leaf fall in late
Nestarine ,\pticot COIyneum blight autumn, using sufficient water and proper sprayer calibration
Tart Cherry Plum (shothole) to obtain uniform coverage.
Prune
When conditions favor high disease levels, use the high rate of
application and apply once or twice more in mid to late winter
before budswell.
If the leaf fall application is not practical, application for control
of leaf curl may be made at any time prior to budswell the
following spring.
Where Corneum blight (shothole) occurs, apply at budbreak to
proted newly emerging leaves and at shuck split to prevent
fruit infections.
Brown rot blossom blight 2%-4% Ibs. ~-1X Ibs. Use 3%-4% per acre on trees taller than 20 ft. and 2%-3% per
Lacy (russet) scab acre on smaller trees.
(plum/prune)
Make one application at popcom (pink, red, or early white bud)
and a second application at full bloom.
If weather conditions favor disease development, make an
additional application at petal fall.
Limitations:
- Do not re-apply this product within 7 days of last treatment.
- Do not apply more than 10 Ibs. of this product (9 Ibs. a.i.) per acre per season.
Grazing Restrictions:
Do not graze treated areas or feed treatedplant parts to livestock.
If application with ground equipment is not feasible, product may be applied with aircraft using at least 20 gallons per acre.
When concentrate sprays are used or when treating non-bearing or immature trees, the lower rate listed may be used. Do
not allow livestock to graze in treated areas.
The following spray volumes are recommended as gallons of spray per acre:
CROP SPRAY VOLUME (Gallons per acre)
Peach 20 (concentrate - 300 (Full Dilute
Nectarine 20 (concentrate - 300 Full Dilute
Apricot 20 concentrate) - 300 (Full Dilute
Tart Cherry 20 concentrate -300 Full Dilute
Plum 20 concentrate -300 Full Dilute
Prune 20 concentrate -300 Full Dilute
SWeet Cherry 20 concentrate -300 Full Dilute
CONDITIONS OF SALE· LIMITED WARRANTY
AND LIMITATIONS OF LIABILITY AND REMEDIES
Read the Conditions of Sale· Warranty and Limitations of Liability and Remedies before using this product. If the terms are not
acceptable, return the product, unopened, and the full purchase price will be refunded.
The directions on this label are believed to be reliable and should be followed carefully. Insufficient control of pests and/or injury to the crop to which
the product is applied may result from the occurrence of extraordinary or unusual weather conditions or the failure to follow the label directions or
good application practices, all of which are beyond the control of Helena Chemical Company (the "Company") or seller. In addition, failure to follow
label directions may cause injury to crops, animals, man or the environment. The Company warrants that this product conforms to th~~Qemical
description on the label and is reasonably fit for the purpose referred to in the directions for use subject to the factors noted above whicn are beyond
the control of the Company. The Company makes no other warranties or representations of any kind, express or implied, concerni'lg'~~f."pSoduct,
including no implied warranty of merchantability or fitness for any particular purpose, and no such warranty shall be iUlr')tied,by law. 0 L' "
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The exclusive remedy against the Company for any cause of action relating to the handling or use of this product sha11 P~Ji,rruted to, at H~13na
Chemical Company's election, one of the following: ~ ~ l" L
1.
2.
Refund of the purchase price paid by buyer or user for product bought, or
Replacement of the product used
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To the eX!,!",t allowed by 12"/, the Company shall not be liable and any and all claims against the Company are waived for special, indirecctrincidental,
or consequential damages or expense of any nature, including, but not limited to, 1055 of prOfits or income. The Company and the seller,aff3;1 this
product and the buyer and lIser accept it, subject to the foregoing conditions of sale and limitation of warranty, liability and remedies.
Disclaimer: Always refer to the label on the product before using Helena or any other product.
6Aug2010 revised storage & disposal
© Copyri<;ht ~elena Holding Company, 2010.
r ;.
*SURFIXTM is a trademark of Helena Holding Company.
**DIPE® is a registered trademark of Abbott Laboratories.
***TRITON AG·98™ and TRITON B·1956™ are trademarks of Rohm and Haas Company.
·COPPER·C OUNT® is a registered trademark of Mineral Research and Development Co.
Disclaimer: Always refer to the label on the product before using Helena or any other product.
6Aug2010 revised storage & disposal
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