a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
1461 lines
62 KiB
Markdown
1461 lines
62 KiB
Markdown
# ZIDUA PRO POWERED BY KIXOR HERBICIDE
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- EPA Reg No: **7969-365**
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- Registrant: BASF AGRICULTURAL SOLUTIONS US, LLC
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- Signal word: Caution
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- Active ingredients: Pyroxasulfone (23.06%); Saflufenacil (4.81%); Imazethapyr (13.45%)
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- Label accepted: 2017-12-28
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/007969-00365-20171228.pdf
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---
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
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WASHINGTON, DC 20460
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Fast Track Label Acceptable v.20150320
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OFFICE OF CHEMICAL SAFETY
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AND POLLUTION PREVENTION
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December 28, 2017
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Craig Kleppe
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Product Registration Manager
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BASF Corporation
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26 Davis Drive
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Research Triangle Park, NC 27709
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Subject: Label Amendment – minor changes
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Product Name: Zidua Pro Powered by Kixor Herbicide
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EPA Registration Number: 7969-365
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Application Date: 12/15/2017
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Decision Number: 532976
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Dear Craig Kleppe:
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The amended label referred to above, submitted in connection with registration under the Federal
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Insecticide, Fungicide and Rodenticide Act, as amended, is acceptable. This approval does not
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affect any conditions that were previously imposed on this registration. You continue to be
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subject to existing conditions on your registration and any deadlines connected with them.
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A stamped copy of your labeling is enclosed for your records. This labeling supersedes all
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previously accepted labeling. You must submit one copy of the final printed labeling before you
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release the product for shipment with the new labeling. In accordance with 40 CFR 152.130(c),
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you may distribute or sell this product under the previously approved labeling for 18 months
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from the date of this letter. After 18 months, you may only distribute or sell this product if it
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bears this new revised labeling or subsequently approved labeling. “To distribute or sell” is
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defined under FIFRA section 2(gg) and its implementing regulation at 40 CFR 152.3.
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Should you wish to add/retain a reference to the company’s website on your label, then please be
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aware that the website becomes labeling under the Federal Insecticide Fungicide and Rodenticide
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Act and is subject to review by the Agency. If the website is false or misleading, the product
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would be misbranded and unlawful to sell or distribute under FIFRA section 12(a)(1)(E). 40
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CFR 156.10(a)(5) list examples of statements EPA may consider false or misleading. In addition,
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regardless of whether a website is referenced on your product’s label, claims made on the
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website may not substantially differ from those claims approved through the registration process.
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Therefore, should the Agency find or if it is brought to our attention that a website contains false
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or misleading statements or claims substantially differing from the EPA approved registration,
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the website will be referred to the EPA’s Office of Enforcement and Compliance.
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Your release for shipment of the product constitutes acceptance of these conditions. If these
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conditions are not complied with, the registration will be subject to cancellation in accordance
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Page 2 of 2
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EPA Reg. No. 7969-365
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Decision No. 532976
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with FIFRA section 6. If you have any questions, please contact Erik Kraft by phone at 703-308-
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9358, or via email at kraft.erik@epa.gov
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attachment
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Sincerely,
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Erik Kraft, Product Manager 24
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Fungicide and Herbicide Branch
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Registration Division (7505P)
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Office of Pesticide Programs
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Group 2 14 15 Herbicide
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Premium Residual Option herbicide for use in soybean
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Active Ingredients:
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saflufenacil: N'-[2-chloro-4-fluoro-5-(3-methyl-2,6-dioxo-4-(trifluoromethyl)-3,
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6-dihydro-1(2H)-pyrimidinyl)benzoyl]-N-isopropyl-N-methylsulfamide. . . . . . . . . 4.81%
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imazethapyr: (±)-2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-
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oxo-1H-imidazol-2-yl]-5-ethyl-3-pyridinecarboxylic acid . . . . . . . . . . . . . . . . . . 13.45%
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pyroxasulfone: 3-[[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-
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1H-pyrazol-4-yl]methyl]sulfonyl]-4,5-dihydro-5,5-dimethylisoxazole . . . . . . . . . . 23.06%
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Other Ingredients: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58.68%
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Total: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100.00%
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Contains 2.28 lbs of pyroxasulfone, 1.33 lbs imazethaypr, and 0.48 lbs
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saflufenacil per gallon formulated as a water-based suspension concentrate
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EPA Reg. No. 7969-365 EPA Est. No.
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KEEP OUT OF REACH OF CHILDREN
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CAUTION/PRECAUCION
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See inside for complete Precautionary Statements, Directions For Use,
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Conditions of Sale and Warranty, and state-specific crop and/or use site restrictions.
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In case of an emergency endangering life or property involving this product,
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call day or night 1-800-832-HELP (4357).
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Net Contents:
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BASF Corporation
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26 Davis Drive, Research Triangle Park, NC 27709
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Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en
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detalle. (If you do not understand the label, find someone to explain it to you in detail.)
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12/28/2017
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7969-365
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2
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Precautionary Statements
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Hazards to Humans and Domestic Animals
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CAUTION. Harmful if swallowed. Wash thoroughly with
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soap and water after handling and before eating, drinking,
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chewing gum, using tobacco, or using the toilet.
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Personal Protective Equipment (PPE)
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Applicators and other handlers must wear:
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• Long-sleeved shirt and long pants
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• Chemical-resistant gloves made of any waterproof
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material including barrier laminate, butyl rubber ≥14 mils,
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nitrile rubber ≥14 mils, neoprene rubber ≥14 mils,
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natural rubber ≥14 mils, polyethylene, polyvinyl chloride
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≥14 mils, or viton ≥14 mils
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• Shoes plus socks
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• Protective eyewear (face shield, goggles, or safety
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glasses)
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For aerial application, mixers and loaders must also wear a
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minimum of a NIOSH approved filtering face piece respira-
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tor with any N filter (TC-84A). You can also use other
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NIOSH approved particulate respirator that offer more pro-
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tection, including a half face or full face respirator with any
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filter or a powered air purifying respirator with an HE filter.
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For more information,
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see www.epa.gov/pesticide-respirators.
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Follow manufacturer’s instructions for cleaning/maintaining
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PPE. If no such instructions exist for washables, use deter-
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gent and hot water. Keep and wash PPE separately from
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other laundry. Remove and wash contaminated clothing
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before reuse. Discard clothing and other absorbent materi-
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als that have been drenched or heavily contaminated with
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this product’s concentrate. DO NOT reuse them.
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Engineering Controls
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When handlers use closed systems, enclosed cabs, or air-
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craft in a manner that meets the requirements listed in the
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Worker Protection Standard (WPS) for agricultural
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pesticides [40 CFR 170.240(d)(4-6)], the handler PPE
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requirements may be reduced or modified as specified in
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the WPS.
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IMPORTANT:When reduced PPE is worn because a
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closed system is being used, handlers must be provided all
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PPE specified above for applicators and other handlers
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and have such PPE immediately for use in an emergency,
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including a spill or equipment breakdown.
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Environmental Hazards
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For terrestrial uses, DO NOT apply directly to water, areas
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where surface water is present, or intertidal areas below
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the mean high water mark. DO NOT contaminate water
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when disposing of equipment washwater or rinsate.
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DO NOT discharge effluent containing this product into
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lakes, streams, ponds, estuaries, oceans, or other waters
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unless in accordance with the requirements of a National
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Pollutant Discharge Elimination System (NPDES) permit
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and the permitting authority has been notified in writing
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prior to discharge. DO NOT discharge effluent containing
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this product to sewer systems without previously notifying
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USER SAFETY RECOMMENDATIONS
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Users should:
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• Remove clothing/PPE immediately if pesticide gets
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inside. Then wash thoroughly and put on clean clothing.
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• Remove PPE immediately after handling this product.
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Wash the outside of gloves before removing. As soon as
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possible, wash thoroughly and change into clean
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clothing.
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• Wash hands before eating, drinking, chewing gum,
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using tobacco, or using the toilet.
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FIRST AID
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If swallowed
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• Call a poison control center or doctor immediately for treatment advice.
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• DO NOT induce vomiting unless told to do so by a poison control center or doctor.
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• DO NOT give anything to an unconscious person.
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• Have person sip water if able to swallow.
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If on skin
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• Take off contaminated clothing.
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• Rinse skin immediately with plenty of water for 15 to 20 minutes.
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• Call a poison control center or doctor for treatment advice.
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If in eyes
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• Hold eye open and rinse slowly and gently with water for 15 to 20 minutes.
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• Remove contact lenses, if present, after the first 5 minutes; then continue rinsing.
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• Call a poison control center for treatment advice.
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If inhaled
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• Move person to fresh air.
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• If person is not breathing, call 911 or an ambulance; then give artificial respiration, preferably
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by mouth to mouth, if possible.
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• Call a poison control center or doctor for further treatment advice.
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HOTLINE NUMBER
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Have the product container or label with you when calling a poison control center or doctor or going for treatment.
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You may also contact BASF Corporation for emergency medical treatment information at 1-800-832-HELP (4357).
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3
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the local sewage treatment plant authority. For guidance,
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contact your State Water Board or Regional Office of the
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EPA.
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Drift and runoff may be hazardous to aquatic organisms in
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water adjacent to treated areas.
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Groundwater Advisory. This product has properties and
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characteristics associated with chemicals detected in
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groundwater. These chemicals may leach into groundwater
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if used in areas where soils are permeable, particularly
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where the water table is shallow.
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Surface Water Advisory. DO NOT apply directly to
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water, to areas where surface water is present, or to inter-
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tidal areas below the mean high water mark. Drift and
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runoff may be hazardous to aquatic organisms in water
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adjacent to treated areas. DO NOT contaminate water
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when disposing of equipment washwater or rinsate. This
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product may impact surface water due to runoff of
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rainwater. This is especially true for poorly draining soils
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and soils with shallow groundwater. This product is classi-
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fied as having high potential for reaching surface water via
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runoff for several weeks after application. A level, well-
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maintained buffer strip between areas to which this product
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is applied and surface water features including ponds,
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streams, and springs will reduce the potential loading of
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these chemicals and pyroxasulfone’s degradation product,
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[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-
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pyrazol-4-yl]methanesulfonic acid (M1), from runoff water
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and sediment. Runoff of this product will be reduced by
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avoiding application when rainfall is forecast to occur within
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48 hours.
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Proper Handling Instructions. This product may not be
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mixed or loaded within 50 feet of wells (including aban-
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doned wells and drainage wells), sinkholes, perennial or
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intermittent streams and rivers, and natural or impounded
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lakes and reservoirs. This setback does not apply to prop-
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erly capped or plugged abandoned wells and does not
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apply to impervious pad or properly diked mixing/loading
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areas.
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Operations that involve mixing, loading, rinsing, or washing
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of this product into or from pesticide handling or applica-
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tion equipment or containers within 50 feet of any well are
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prohibited unless conducted on an impervious pad con-
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structed to withstand the weight of the heaviest load that
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may be positioned on or moved across the pad. Such a
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pad must be designed and maintained to contain any
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product spills or equipment leaks, container or equipment
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rinse or washwater, and rainwater that may fall on the pad.
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Surface water shall not be allowed to either flow over or
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from the pad, which means the pad must be self-
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contained. The pad shall be sloped to facilitate material
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removal. An unroofed pad shall be of sufficient capacity to
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contain at a minimum 110% of the capacity of the largest
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pesticide container or application equipment on the pad. A
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pad that is covered by a roof of sufficient size to completely
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exclude precipitation from contact with the pad shall have a
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minimum containment capacity of 100% of the capacity of
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the largest pesticide container or application equipment on
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the pad. Containment capacities as described above shall
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be maintained at all times. The above specific minimum
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containment capacity DOES NOT apply to vehicles when
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delivering pesticide shipments to the mixing/loading site.
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States may have in effect additional requirements regarding
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wellhead setbacks and operational containment.
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This product must be used in a manner which will prevent
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back-siphoning in wells, spills, or improper disposal of
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excess pesticide spray mixture.
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Point-source Contamination. To prevent point-source
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contamination, DO NOT mix or load this or any other pesti-
|
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cide product within 50 feet of wells (including abandoned
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wells and drainage wells), sinkholes, perennial or intermit-
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tent streams and rivers, and natural or impounded lakes
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and reservoirs. This setback does not apply to properly
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capped or plugged abandoned wells and does not apply to
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impervious pad or dike mixing/loading areas as described
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below.
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Mixing, loading, rinsing, or washing operations performed
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within 50 feet of a well are allowed only when conducted
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on an impervious pad constructed to withstand the weight
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of the heaviest load that may be on or move across the
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pad. The pad must be self-contained to prevent surface
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water flow over or from the pad. The pad capacity must be
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maintained at 110% that of the largest pesticide container
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or application equipment used on the pad and have suffi-
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cient capacity to contain all product spills, equipment or
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container leaks, equipment washwater, and rainwater that
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may fall on the pad. The containment capacity does not
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apply to vehicles delivering pesticide shipments to the
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mixing/loading site. States may have in effect additional
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requirements regarding wellhead setbacks and operational
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containment.
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||
Care must be taken when using this product to prevent:
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• Back-siphoning into wells
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||
• Spills
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• Improper disposal of excess pesticide, spray mixes, or
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rinsates
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Check valves or anti-siphoning devices must be used on all
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mixing equipment.
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Physical or Chemical Hazards
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DO NOT mix or allow contact with oxidizing agents.
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Hazardous chemical reaction may occur.
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Endangered Species Protection
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Requirements
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||
This product may have effects on federally listed threatened
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||
or endangered plant species or their critical habitat. When
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using this product, you must follow the measures con-
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tained in the Endangered Species Protection Bulletin for
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the county or parish in which you are applying the pesti-
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cide. To determine whether your county or parish has a
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Bulletin, and to obtain that Bulletin, consult
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||
http://www.epa.gov/espp/, or call 1-844-447-3813 no
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||
more than 6 months before using this product. Applicators
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||
must use Bulletins that are in effect in the month in which
|
||
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4
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the pesticide will be applied. New Bulletins will generally be
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||
available from the above sources 6 months prior to their
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||
effective dates.
|
||
Directions For Use
|
||
It is a violation of federal law to use this product in a man-
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ner inconsistent with its labeling. This labeling must be in
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||
the possession of the user at time of herbicide application.
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||
Read the entire label. Use strictly in accordance with pre-
|
||
cautionary statements and directions and with applicable
|
||
state and federal regulations.
|
||
DO NOT apply this product in a way that will contact work-
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ers or other persons, either directly or through drift. Only
|
||
protected handlers may be in the area during application.
|
||
For any requirements specific to your state or tribe, consult
|
||
the agency responsible for pesticide regulation.
|
||
Observe all precautions and limitations in this label and the
|
||
labels of products used in combination with Zidua
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||
® PRO
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||
herbicide. The use of Zidua PRO not consistent with this
|
||
label can result in injury to crops, animals or persons, poor
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||
weed control, and/or illegal residues. Keep containers
|
||
closed to avoid spills and contamination.
|
||
Unless otherwise directed in supplemental labeling, all
|
||
applicable directions, restrictions, precautions and
|
||
Conditions of Sale and Warranty are to be followed.
|
||
BASF Corporation does not recommend or authorize the
|
||
use of this product in manufacturing, processing or prepar-
|
||
ing custom blends with other products for application in
|
||
crops.
|
||
(continued)
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(continued)
|
||
AGRICULTURAL USE REQUIREMENTS
|
||
Use this product only in accordance with its labeling and
|
||
with the Worker Protection Standard, 40 CFR Part 170.
|
||
This standard contains requirements for the protection of
|
||
agricultural workers on farms, forests, nurseries, and
|
||
greenhouses, and handlers of agricultural pesticides. It
|
||
contains requirements for training, decontamination, notifi-
|
||
cation, and emergency assistance. It also contains
|
||
specific instructions and exceptions pertaining to the
|
||
statements on this label about personal protective equip-
|
||
ment (PPE) and restricted-entry interval. The requirements
|
||
in this box only apply to uses of this product that are cov-
|
||
ered by the Worker Protection Standard.
|
||
DO NOT enter or allow worker entry into treated areas
|
||
during the restricted-entry interval (REI) of 12 hours.
|
||
EXCEPTION: If the product is soil injected or soil incor-
|
||
porated, the Worker Protection Standard, under certain
|
||
circumstances, allows workers to enter the treated area if
|
||
there will be no contact with anything that has been
|
||
treated.
|
||
AGRICULTURAL USE REQUIREMENTS
|
||
(continued)
|
||
PPE required for early entry to treated areas that is permit-
|
||
ted under the Worker Protection Standard and that
|
||
involves contact with anything that has been treated,
|
||
including plants, soil, or water, is:
|
||
• Coveralls
|
||
• Chemical-resistant gloves made of any waterproof
|
||
material including barrier laminate, butyl rubber
|
||
≥14 mils, nitrile rubber ≥14 mils, neoprene rubber
|
||
≥14 mils, natural rubber ≥14 mils, polyethylene,
|
||
polyvinyl chloride ≥14 mils, or viton ≥14 mils
|
||
• Shoes plus socks
|
||
• Protective eyewear
|
||
STORAGE AND DISPOSAL
|
||
DO NOT contaminate water, food, or feed by storage or
|
||
disposal. Open dumping is prohibited.
|
||
Pesticide Storage
|
||
DO NOT use or store near heat or open flame. Store in
|
||
original container in a well-ventilated area separately from
|
||
fertilizer, feed, or foodstuffs and away from other pesti-
|
||
cides. Avoid cross-contamination with other pesticides.
|
||
Groundwater contamination may be reduced by diking
|
||
and flooring of permanent liquid bulk storage sites with an
|
||
impermeable material.
|
||
Pesticide Disposal
|
||
Wastes resulting from this product must be disposed of
|
||
on-site or at an approved waste disposal facility. Improper
|
||
disposal of excess pesticide, spray mix, or rinsate is a vio-
|
||
lation of federal law. If these wastes cannot be disposed
|
||
of according to label instructions, contact the state
|
||
agency responsible for pesticide regulation or the
|
||
Hazardous Waste representative at the nearest EPA
|
||
Regional Office for guidance.
|
||
Container Handling
|
||
Nonrefillable Container. DO NOT reuse or refill this
|
||
container. Triple rinse or pressure rinse container (or
|
||
equivalent) promptly after emptying; then offer for recy-
|
||
cling, if available, or reconditioning, if appropriate, or
|
||
puncture and dispose of in a sanitary landfill, or by inciner-
|
||
ation, or by other procedures approved by state and local
|
||
authorities.
|
||
Triple rinse containers small enough to shake
|
||
(capacity
|
||
≤5 gallons) as follows: Empty the remaining
|
||
contents into application equipment or a mix tank and
|
||
drain for 10 seconds after the flow begins to drip. Fill the
|
||
container 1/4 full with water and recap. Shake for 10 sec-
|
||
onds. Pour rinsate into application equipment or a mix
|
||
tank, or store rinsate for later use or disposal. Drain for
|
||
10 seconds after the flow begins to drip. Repeat this pro-
|
||
cedure two more times.
|
||
|
||
5
|
||
In Case of Emergency
|
||
In case of large-scale spill of this product, call:
|
||
• CHEMTREC 1-800-424-9300
|
||
• BASF Corporation 1-800-832-HELP (4357)
|
||
In case of medical emergency regarding this product, call:
|
||
• Your local doctor for immediate treatment
|
||
• Your local poison control center (hospital)
|
||
• BASF Corporation 1-800-832-HELP (4357)
|
||
Steps to take if material is released or spilled:
|
||
• Dike and contain the spill with inert material (sand, earth,
|
||
etc.) and transfer liquid and solid diking material to sepa-
|
||
rate containers for disposal.
|
||
• Remove contaminated clothing and wash affected skin
|
||
areas with soap and water.
|
||
• Wash clothing before reuse.
|
||
• Keep the spill out of all sewers and open bodies of water.
|
||
Product Information
|
||
Zidua® PRO herbicide provides both contact burndown
|
||
and residual preemergence control of annual grass weeds
|
||
and annual broadleaf weeds (including biotypes resistant to
|
||
ACCase inhibitors, ALS inhibitors, triazine herbicides, and
|
||
glyphosate) (refer to Table 1 for lists of weeds controlled) in
|
||
soybean. Refer to Crop-specific Information section for
|
||
instructions on herbicide tank mixes.
|
||
Make burndown application of Zidua PRO when weeds
|
||
are small and actively growing. An adjuvant is required with
|
||
Zidua PRO for optimum burndown activity (refer to
|
||
Additives section for details). Burndown activity may be
|
||
slowed or reduced under cloudy and/or foggy or cooler
|
||
weather conditions or when weeds are growing under
|
||
drought or other stress conditions. When targeting dense
|
||
weed populations and/or larger broadleaf weeds, use high-
|
||
er spray volumes. Angling nozzles forward (to 45 degrees)
|
||
may improve penetration of denser weed canopies.
|
||
Periods of dry weather following application of Zidua PRO
|
||
may reduce herbicidal effectiveness. Residual
|
||
preemergence applications of Zidua PRO must be
|
||
activated by at least 1/2 inch of rainfall or sprinkler irrigation
|
||
prior to weed seedling emergence. When Zidua PRO is
|
||
not activated, a labeled postemergence herbicide or culti-
|
||
vation may be needed to control weed escapes.
|
||
STORAGE AND DISPOSAL (continued)
|
||
Container Handling (continued)
|
||
Triple rinse containers too large to shake
|
||
(capacity > 5 gallons) as follows: Empty the remaining
|
||
contents into application equipment or a mix tank. Fill the
|
||
container 1/4 full with water. Replace and tighten clo-
|
||
sures. Tip container on its side and roll it back and forth,
|
||
ensuring at least one complete revolution, for 30 seconds.
|
||
Stand the container on its end and tip it back and forth
|
||
several times. Turn the container over onto its other end
|
||
and tip it back and forth several times. Empty the rinsate
|
||
into application equipment or a mix tank, or store rinsate
|
||
for later use or disposal. Repeat this procedure two more
|
||
times.
|
||
Pressure rinse as follows: Empty the remaining
|
||
contents of all containers into application equipment or
|
||
mix tank and continue to drain for 10 seconds after the
|
||
flow begins to drip. Hold containers upside down over
|
||
application equipment or mix tank, or collect rinsate for
|
||
later use or disposal. Insert pressure rinsing nozzle in the
|
||
side of the containers and rinse at about 40 PSI for at
|
||
least 30 seconds. Drain for 10 seconds after the flow
|
||
begins to drip.
|
||
Refillable Container. Refill this container with pesticide
|
||
only. DO NOT reuse this container for any other purpose.
|
||
Triple rinsing the container before final disposal is the
|
||
responsibility of the person disposing of the container.
|
||
Cleaning before refilling is the responsibility of the refiller.
|
||
Triple rinse as follows: To clean the container before
|
||
final disposal, empty the remaining contents from this
|
||
container into application equipment or mix tank. Fill the
|
||
container about 10% full with water. Agitate vigorously or
|
||
recirculate water with the pump for 2 minutes. Pour or
|
||
pump rinsate into application equipment or rinsate collec-
|
||
tion system. Repeat this rinsing procedure two more
|
||
times.
|
||
When this container is empty, replace the cap and seal all
|
||
openings that have been opened during use; return the
|
||
container to the point of purchase or to a designated
|
||
location. This container must only be refilled with a pesti-
|
||
cide product. Prior to refilling, inspect carefully for damage
|
||
including cracks, punctures, abrasions, worn-out threads
|
||
and closure devices. Check for leaks after refilling and
|
||
before transport. DO NOT transport if this container is
|
||
damaged or leaking. If the container is damaged, or leak-
|
||
ing, or obsolete and not returned to the point of purchase
|
||
or to a designated location, triple rinse emptied container
|
||
and offer for recycling, if available, or dispose of container
|
||
in compliance with state and local regulations.
|
||
|
||
6
|
||
Table 1. Weeds Controlled by Zidua® PRO herbicide
|
||
(continued)
|
||
Level of Control
|
||
C = Control S = Suppression
|
||
Maximum
|
||
Height or
|
||
Diameter
|
||
(inches)
|
||
Common Name Scientific Name
|
||
Residual
|
||
Application
|
||
Burndown
|
||
Application
|
||
Burndown
|
||
Application
|
||
Broadleaf Weeds
|
||
Alligatorweed Alternanthera philoxeroides — C 4
|
||
Amaranth, Palmer1 Amaranthus palmeri C C 6
|
||
Amaranth, Powell Amaranthus powellii C C 6
|
||
Anoda, spurred Anoda cristata C C 2
|
||
Artichoke, Jerusalem Helianthus tuberosus — C 8
|
||
Bedstraw, catchweed Galium aparine — C 3
|
||
Beets, wild Beta vulgaris S C 5
|
||
Beggarticks, hairy Bidens pilosa — C 6
|
||
Beggarweed, Florida Desmodium tortuosum — C 6
|
||
Bindweed, field Convolvulus arvensis — S2 6
|
||
Buckwheat, wild Polygonum convolvulus C C 3
|
||
Buffalobur Solanum rostratum S S 3
|
||
Canola, volunteer (rapeseed) Brassica spp. C C 6
|
||
Carpetweed Mollugo verticillata C C 6
|
||
Chickweed, common Stellaria media S C 3
|
||
Chickweed, mouse-ear Cerastium vulgatum — C 3
|
||
Cocklebur, common Xanthium strumarium S C 8
|
||
Cowcockle Vaccaria pyramidata — C 4
|
||
Cress, hoary Cardaria draba — S 2
|
||
Dandelion Taraxacum officinale — S2 6
|
||
Evening primrose, cutleaf Oenothera laciniata — C 4
|
||
Falseflax, smallseed Camelina microcarpa — C 4
|
||
Filaree, redstem Erodium cicutarium — S 3
|
||
Filaree, whitestem Erodium moschatum — S 3
|
||
Fleabane, hairy Conyza bonariensis S C 6
|
||
Fleabane, rough Erigeron asper S C 3
|
||
Flixweed Descurainia sophia — C 6
|
||
Galinsoga Galinsoga parviflora C — —
|
||
Groundcherry, cutleaf Physalis angulata — C 6
|
||
Groundsel, common Senecio vulgaris S C 4
|
||
Henbit Lamium amplexicaule S S 3
|
||
Horseweed (marestail) Conyza canadensis S C 6
|
||
Jimsonweed Datura stramonium S C 3
|
||
Knotweed, prostrate Polygonum aviculare — C 3
|
||
Kochia1 Kochia scoparia C C 1 to 3
|
||
Suppression of
|
||
button/puffball
|
||
stage at < 1-inch tall
|
||
|
||
7
|
||
Table 1. Weeds Controlled by Zidua® PRO herbicide (continued)
|
||
(continued)
|
||
Level of Control
|
||
C = Control S = Suppression
|
||
Maximum
|
||
Height or
|
||
Diameter
|
||
(inches)
|
||
Common Name Scientific Name
|
||
Residual
|
||
Application
|
||
Burndown
|
||
Application
|
||
Burndown
|
||
Application
|
||
Broadleaf Weeds (continued)
|
||
Ladysthumb Polygonum persicaria C C 6
|
||
Lambsquarters, common Chenopodium album C C 6
|
||
Lambsquarters, narrowleaf Chenopodium pratericola S C 6
|
||
Lettuce, miner’s Claytonia perfoliata — C 3
|
||
Lettuce, prickly Lactuca serriola — C 6
|
||
Mallow, common Malva neglecta — C 6
|
||
Mallow, little (cheeseweed) Malva parviflora — C 6
|
||
Mallow, Venice Hibiscus trionum S C 6
|
||
Marestail (horseweed) Conyza canadensis S C 6
|
||
Marshelder Iva xanthifolia C C 4
|
||
Milkweed, common Asclepias syriaca — C 3
|
||
Morningglory, entireleaf Ipomoea hederacea var. integriuscula S C 6
|
||
Morningglory, ivyleaf Ipomoea hederacea S C 6
|
||
Morningglory, palmleaf Ipomoea wrightii S C 6
|
||
Morningglory, pitted Ipomoea lacunosa S C 6
|
||
Morningglory, smallflower Jacquemontia tamnifolia C C 3
|
||
Morningglory, tall Ipomoea purpurea S C 6
|
||
Mustard, black Brassica nigra C C 6
|
||
Mustard, tumble Sisymbrium altissimum — C 6
|
||
Mustard, wild Sinapis arvensis C C 6
|
||
Nettle, burning Urtica urens — C 4
|
||
Nightshade, black Solanum nigrum C C 6
|
||
Nightshade, cutleaf Solanum triflorum S C 6
|
||
Nightshade, Eastern black Solanum ptycanthum C C 6
|
||
Nightshade, hairy Solanum saccharoides C C 6
|
||
Pennycress, field Thlaspi arvense — C 6
|
||
Pepperweed, field Lepidium campestre — C 3
|
||
Pepperweed, Virginia Lepidium virginicum — C 3
|
||
Pigweed, prostrate Amaranthus blitoides C C 6
|
||
Pigweed, redroot Amaranthus retroflexus C C 6
|
||
Pigweed, smooth Amaranthus hybridus C C 6
|
||
Pigweed, spiny Amaranthus spinosus C C 6
|
||
Poinsettia, wild Euphorbia heterophylla C — —
|
||
Puncturevine Tribulus terrestris C C 6
|
||
Purslane, common Portulaca oleracea C C 3
|
||
Pusley, Florida Richardia scabra C S 3
|
||
|
||
8
|
||
Table 1. Weeds Controlled by Zidua® PRO herbicide (continued)
|
||
(continued)
|
||
Level of Control
|
||
C = Control S = Suppression
|
||
Maximum
|
||
Height or
|
||
Diameter
|
||
(inches)
|
||
Common Name Scientific Name
|
||
Residual
|
||
Application
|
||
Burndown
|
||
Application
|
||
Burndown
|
||
Application
|
||
Broadleaf Weeds (continued)
|
||
Radish, wild Raphanus raphanistrum S S 4
|
||
Ragweed, common1 Ambrosia artemisiifolia S C 6
|
||
Ragweed, giant1 Ambrosia trifida S C 6
|
||
Redmaids Calandrinia ciliata — C 3
|
||
Rocket, London Sisymbrium irio — C 4
|
||
Rocket, yellow Barbarea vulgaris — C 3
|
||
Sesbania, hemp Sesbania exaltata — C 4
|
||
Shepherd’s-purse Capsella bursa-pastoris C C 6
|
||
Sida, prickly Sida spinosa C C 6
|
||
Smartweed, Pennsylvania Polygonum pensylvanicum C C 6
|
||
Smartweed, swamp (seedling) Polygonum coccineum — C 3
|
||
Sowthistle, annual Sonchus oleraceus — C 6
|
||
Sowthistle, spiny Sonchus asper — C 6
|
||
Spurge, petty Euphorbia peplus — C 3
|
||
Spurge, prostrate Euphorbia supina — S 3
|
||
Spurge, spotted Euphorbia maculata C S 3
|
||
Spurry, corn Spergula arvensis — C 3
|
||
Starbur, bristly Acanthospermum hispidum — C 2
|
||
Sunflower, common Helianthus annuus S C 6
|
||
Swinecress Coronopus didymus — C 3
|
||
Tansymustard, green Descurainia incana — C 3
|
||
Tansymustard, pinnate Descurainia pinnata — C 6
|
||
Thistle, Canada Cirsium arvense — S2 6
|
||
Thistle, Russian Salsola kali C C 3
|
||
Velvetleaf Abutilon theophrasti S C 6
|
||
Watercress, creeping Coronopus squamatus — C 2
|
||
Watercress Nasturtium officinale — C 3
|
||
Waterhemp1 Amaranthus tuberculatus C C 6
|
||
Willowweed Epilobium adenocaulon — C 3
|
||
|
||
9
|
||
Table 1. Weeds Controlled by Zidua® PRO herbicide (continued)
|
||
1 Populations of noted weeds exist that are known to be resistant to Group 2/Group B, Group 14/Group E, and/or
|
||
Group 9/Group G (e.g. glyphosate) herbicides. Zidua PRO may not provide full-season control of these herbicide-
|
||
resistant biotypes. See the Resistance Management section for practices to manage and minimize the impact of
|
||
resistant weeds (e.g. tank mix or alternate with other herbicide modes of action, crop rotation, and mechanical control).
|
||
2 Control of seedling stage and suppression of perennial growth stage
|
||
Level of Control
|
||
C = Control S = Suppression
|
||
Maximum
|
||
Height or
|
||
Diameter
|
||
(inches)
|
||
Common Name Scientific Name
|
||
Residual
|
||
Application
|
||
Burndown
|
||
Application
|
||
Burndown
|
||
Application
|
||
Grass Weeds
|
||
Barley, volunteer Hordeum vulgare S S 2
|
||
Barnyardgrass Echinochloa crus-galli C S 3
|
||
Canarygrass Phalaris canariensis C — —
|
||
Canarygrass, littleseed Phalaris minor S S 2
|
||
Cheat Bromus secalinus S — —
|
||
Crabgrass, large Digitaria sanguinalis C S 3
|
||
Crabgrass, smooth Digitaria ischaemum C S 3
|
||
Crowsfootgrass Dactyloctenium aegyptium C — —
|
||
Cupgrass, Southeastern Eriochloa acuminata C — —
|
||
Cupgrass, woolly Eriochloa villosa S C 3
|
||
Foxtail, giant Setaria faberi C C 6
|
||
Foxtail, green Setaria viridis C C 3
|
||
Foxtail, yellow Setaria pumila C C 3
|
||
Goosegrass Eleusine indica C — —
|
||
Johnsongrass (rhizome) Sorghum vulgare — S 6
|
||
Johnsongrass (seedling) Sorghum vulgare C C 8
|
||
Millet, wild proso Panicum miliaceum S S 3
|
||
Oats, volunteer Avena sativa S S 2
|
||
Oats, wild Avena fatua S S 3
|
||
Panicum, fall Panicum dichotomiflorum C — —
|
||
Panicum, Texas Panicum texanum S — —
|
||
Rice, red Oryza rufipogon C C 3
|
||
Ryegrass, Italian Lolium perenne spp. multiflorum C — —
|
||
Ryegrass, rigid Lolium rigidum C — —
|
||
Sandbur Cenchrus spp. S — —
|
||
Shattercane Sorghum bicolor S C 8
|
||
Signalgrass, broadleaf Brachiaria platyphylla C C 8
|
||
Wheat, volunteer Triticum spp. S S 2
|
||
Sorghum, almum Sorghum almum S C 3
|
||
Sedge
|
||
Nutsedge, yellow Cyperus esculentus S2 S2 3
|
||
|
||
10
|
||
Mode of Action
|
||
Zidua® PRO herbicide contains three herbicide active
|
||
ingredients. Saflufenacil is a potent inhibitor of
|
||
protoporphyrinogen-oxidase, belonging to herbicide
|
||
mode-of-action Group 14 (WSSA)/Group E (HRAC).
|
||
Imazethapyr is a potent inhibitor of acetohydroxyacid
|
||
synthase, belonging to herbicide mode-of-action
|
||
Group 2 (WSSA)/Group B (HRAC). Pyroxasulfone is a
|
||
potent inhibitor of very long chain fatty acid (VLCFA)
|
||
synthesis, belonging to the mode-of-action
|
||
Group 15 (WSSA)/Group K3 (HRAC). The
|
||
Group 14/Group E and Group 2/Group B herbicides of
|
||
Zidua PRO are rapidly absorbed by roots and foliage.
|
||
Plant death is the result of membrane damage and inhibi-
|
||
tion of the production of branched chain amino acids.
|
||
Under active growing conditions, susceptible emerged
|
||
weeds usually develop chlorotic and necrotic injury
|
||
symptoms within hours and die within a few days.
|
||
Susceptible emerging weed seedlings will usually die as
|
||
they reach the soil surface or shortly after emergence. The
|
||
Group 15/Group K3 herbicide of Zidua PRO is absorbed
|
||
by roots and shoots of weeds following germination. Plant
|
||
death is the result of very long chain fatty acid synthesis
|
||
inhibition; susceptible weeds typically do not emerge.
|
||
Herbicide Resistance Management
|
||
While weed resistance to protoporphyrinogen-oxidase-
|
||
inhibiting herbicide is relatively infrequent, populations of
|
||
resistant biotypes to protoporphyrinogen-oxidase or
|
||
acetohydroxyacid-synthase-inhibiting herbicides are known
|
||
to exist. Weed resistance to VLCFA synthesis-inhibiting
|
||
herbicides is rare. Resistance management should be part
|
||
of a diversified weed control strategy that integrates chemi-
|
||
cal, cultural, and mechanical (tillage) control tactics.
|
||
Cultural control tactics include crop rotation, proper fertiliz-
|
||
er placement, and optimum seeding rate/row spacing.
|
||
Consult your local BASF representative, state cooperative
|
||
extension service, professional consultants, or other quali-
|
||
fied authority to determine appropriate actions if you
|
||
suspect resistant weeds. Herbicide resistance manage-
|
||
ment practices should be considered and include:
|
||
Chemical Control
|
||
1. Following labeled application rate and weed growth
|
||
stage instructions.
|
||
2. Avoiding repeated applications of herbicides with the
|
||
same mode of action.
|
||
3. The use of preemergence herbicides that provide soil
|
||
residual control of broadleaf and grass weeds to reduce
|
||
early season weed competition and allow for timely in-
|
||
crop postemergence herbicide applications.
|
||
4. Utilizing tank mixes and sequential applications with
|
||
other herbicides possessing different sites of action that
|
||
are also effective on the target weeds.
|
||
5. Using crop rotation so competition, tillage, or herbicides
|
||
with alternative modes of action can be used to control
|
||
weed escapes.
|
||
Scouting and Containment
|
||
1. Scouting fields after herbicide application to identify
|
||
areas where weed control was ineffective.
|
||
2. Controlling weed escapes with herbicides possessing a
|
||
different site of action or using a mechanical or cultural
|
||
control measure. Weed escapes should not be allowed
|
||
to reproduce by seed or to proliferate vegetatively.
|
||
3. Contacting your Zidua PRO supplier and/or your local
|
||
BASF representative to report weed escapes.
|
||
4. Cleaning equipment before moving to a different field to
|
||
avoid spread of resistant weeds.
|
||
Crop Tolerance
|
||
Soybeans are tolerant to Zidua PRO when applied
|
||
according to label directions as a preplant to
|
||
preemergence treatment and under normal environmental
|
||
conditions. Crop injury may occur under stressful growing
|
||
conditions (e.g. seedling disease, extreme hot or cold
|
||
weather, excessive moisture, high soil pH, high soil salt
|
||
concentration, or drought).
|
||
Severe crop injury will result if Zidua PRO is applied
|
||
postemergence (over the top) to soybeans.
|
||
Application Instructions
|
||
Apply Zidua PRO prior to crop emergence only.
|
||
Application Methods and Equipment
|
||
Zidua PRO may be applied by ground or air. DO NOT
|
||
apply through any type of irrigation system.
|
||
Thorough spray coverage is required for optimum weed
|
||
control and can be improved with proper adjuvant, nozzle,
|
||
and spray volume selection. Use and configure application
|
||
equipment to provide an adequate spray volume, an accu-
|
||
rate and uniform distribution of spray droplets over the
|
||
treated area, and to avoid spray drift to nontarget areas.
|
||
Equipment should be adjusted to maintain continuous
|
||
agitation during spraying with good mechanical or bypass
|
||
agitation. Avoid overlaps that will increase rates above the
|
||
use rates specified in this label.
|
||
Zidua PRO may only be applied using water as the spray
|
||
carrier.
|
||
Aerial Application Requirements
|
||
Water Volume. Use 3 or more gallons of water per acre.
|
||
The actual minimum spray volume per acre is determined
|
||
by the spray equipment used. Use adequate spray volume
|
||
to provide accurate and uniform distribution of spray parti-
|
||
cles over the treated area and to avoid spray drift.
|
||
The following measures must be followed to reduce the
|
||
potential of spray drift to nontarget areas from aerial
|
||
applications:
|
||
1. The distance of the outermost nozzles on the boom
|
||
must not exceed 3/4 the length of the fixed wingspan or
|
||
90% of rotor blade diameter.
|
||
2. Use low-drift nozzles (straight-stream nozzles, D-8 or
|
||
larger). DO NOT use nozzles producing a mist droplet
|
||
spray.
|
||
|
||
3. Nozzles must always point backward parallel with the
|
||
airstream and never be pointed downward more than
|
||
45 degrees.
|
||
4. Without compromising aircraft safety, make applications
|
||
at a height of 10 feet or less above the crop canopy or
|
||
tallest plants.
|
||
5. DO NOT apply during periods of temperature inversions
|
||
or stable atmospheric conditions.
|
||
6. Avoid potential adverse effects to nontarget areas by
|
||
maintaining a 30-feet buffer between the point of direct
|
||
application and the closest downwind edge of sensi-
|
||
tive terrestrial habitats (grasslands, forested areas,
|
||
shelter belts, woodlots, hedgerows, riparian areas, and
|
||
shrub lands).
|
||
Ground Application Requirements
|
||
Water Volume. Use 5 or more gallons of water per treated
|
||
acre for weed control applications. Thorough spray cover-
|
||
age is required for control of emerged broadleaf weeds.
|
||
High populations and/or variations in size can prevent ade-
|
||
quate spray coverage. Controlling fall-germinated weeds in
|
||
the spring (e.g. horseweed/marestail) will also require thor-
|
||
ough spray coverage. Use higher spray volumes (e.g. 15 to
|
||
20 gallons of water per acre) in these situations to increase
|
||
spray coverage and optimize burndown activity.
|
||
The following measures must be followed to reduce the
|
||
potential of spray drift to nontarget areas from ground
|
||
applications:
|
||
1. Apply this product using nozzles which deliver medium-
|
||
to-coarse spray droplets as defined by ASAE
|
||
standard S-572 and as shown in nozzle manufacturer’s
|
||
catalogs. Flat-fan nozzles are recommended for burn-
|
||
down applications while flood-jet type nozzles are
|
||
recommended for residual soil surface applications.
|
||
Nozzles that deliver coarse spray droplets may be used
|
||
to reduce spray drift provided spray volume per
|
||
acre (GPA) is increased to maintain coverage of target
|
||
(i.e. weeds or soil surface). DO NOT use nozzles that
|
||
produce fine (e.g. cone) spray droplets.
|
||
2. Apply this product only when the potential for drift to
|
||
adjacent nontarget areas is minimal (e.g. when the wind
|
||
is 10 MPH or less and is blowing away from sensitive
|
||
areas). DO NOT apply during periods of temperature
|
||
inversions or stable atmospheric conditions.
|
||
3. Avoid potential adverse effects to nontarget areas by
|
||
maintaining a 13-feet buffer between the application
|
||
area and the closest downwind edge of sensitive
|
||
terrestrial habitats (grasslands, forested areas, shelter
|
||
belts, woodlots, hedgerows, riparian areas, and shrub
|
||
lands).
|
||
Cleaning Spray Equipment
|
||
Clean application equipment thoroughly by using a strong
|
||
detergent or commercial sprayer cleaner according to the
|
||
manufacturer’s directions, followed by triple rinsing the
|
||
equipment before and after applying this product.
|
||
Spray Drift Management
|
||
It is the responsibility of the applicator to avoid spray drift at
|
||
the application site, especially onto nontarget areas. The
|
||
interaction of many equipment-related and weather-related
|
||
factors determines the potential for spray drift. The applica-
|
||
tor and the grower are responsible for considering all these
|
||
factors when making decisions.
|
||
The applicator must be familiar with and take into account
|
||
the information covered in the following spray drift reduc-
|
||
tion advisory information.
|
||
Controlling Droplet Size. The most effective way to
|
||
reduce drift potential is to apply the largest droplets that
|
||
provide sufficient coverage and control.
|
||
Volume. Use high flow rate nozzles to apply the highest
|
||
practical spray volume. Nozzles with higher rated flows
|
||
produce larger droplets.
|
||
Pressure. DO NOT exceed the nozzle manufacturer’s
|
||
specified pressures. For many nozzle types, lower pressure
|
||
produces larger droplets. When higher flow rates are need-
|
||
ed, use higher flow rate nozzles instead of increasing
|
||
pressure.
|
||
Number of Nozzles. Use the minimum number of nozzles
|
||
that provide uniform coverage.
|
||
Nozzle Type. Use a nozzle type that is designed for the
|
||
intended application. With most nozzle types, narrower
|
||
spray angles produce larger droplets.
|
||
Swath Adjustment. When applications are made with a
|
||
crosswind, the swath will be displaced downwind.
|
||
Therefore, on the upwind and downwind edges of the field,
|
||
the applicator must compensate for this displacement by
|
||
adjusting the path of the application equipment (e.g. air-
|
||
craft, ground) upwind. Swath adjustment distance should
|
||
increase with increasing drift potential (higher wind, smaller
|
||
droplets, etc.).
|
||
Wind. Drift potential is lowest between wind speeds of 3 to
|
||
10 mph. However, many factors, including droplet size and
|
||
equipment type, determine drift potential at any given
|
||
speed. If applying at wind speeds less than 3 mph, the
|
||
applicator must determine if:
|
||
1. Conditions of temperature inversion exist, or
|
||
2. Stable atmospheric conditions exist at or below nozzle
|
||
height.
|
||
DO NOT make applications into areas of temperature
|
||
inversions or stable atmospheric conditions.
|
||
NOTE: Local terrain can influence wind patterns. Every
|
||
applicator must be familiar with local wind patterns and
|
||
how they affect spray drift.
|
||
Wind Erosion. Avoid treating powdery, dry or light sandy
|
||
soils when conditions are favorable for wind erosion. Under
|
||
these conditions, the soil surface should first be settled by
|
||
rainfall or irrigation.
|
||
11
|
||
|
||
Additives
|
||
For optimum burndown activity of emerged weeds with
|
||
Zidua® PRO herbicide, an adjuvant system must be used
|
||
that includes the following:
|
||
1 MSO-based adjuvant MUST contain at least 60% methy-
|
||
lated seed oil. Poor performance may occur with
|
||
adjuvants containing less than 60% methylated seed oil.
|
||
2 DO NOT use less than 1 pint/A of MSO with low-volume
|
||
(< 12.5 gallons per acre) aerial or ground applications.
|
||
Use an AMS fertilizer when mixing Zidua PRO with
|
||
glyphosate-based herbicides.
|
||
DO NOT use nonionic surfactant (NIS) as a substitute for
|
||
MSO or poor performance on broadleaf weeds will occur.
|
||
When an adjuvant is to be used with this product, BASF
|
||
prefers the use of a Chemical Producers and Distributors
|
||
Association (CPDA) certified adjuvant.
|
||
Tank Mixing Information
|
||
Zidua PRO may be tank mixed with one or more regis-
|
||
tered herbicide products according to the specific tank
|
||
mixing instructions in this label and respective product
|
||
labels. Refer to Crop-specific Information section for
|
||
details. It is the pesticide user’s responsibility to ensure that
|
||
all products in the mixtures are registered for the intended
|
||
use. Read and follow the applicable restrictions and limita-
|
||
tions and directions for use on all product labels involved in
|
||
tank mixing. Users must follow the most restrictive direc-
|
||
tions for use and precautionary statements of each product
|
||
in the tank mixture.
|
||
Tank mixtures with contact herbicides (e.g. carfentrazone,
|
||
paraquat) may reduce the burndown activity of
|
||
Zidua PRO.
|
||
Compatibility Test for Mix Components
|
||
Before mixing components, always perform a compatibility
|
||
jar test.
|
||
1. For 20 gallons per acre spray volume, use 3.3 cups
|
||
(800 mL) of water. For other spray volumes, adjust rates
|
||
accordingly. Only use water from the intended source at
|
||
the source temperature.
|
||
2. Add components in the sequence indicated in the mix-
|
||
ing order using 2 teaspoons for each pound or
|
||
1 teaspoon for each pint of label rate per acre.
|
||
3. Always cap the jar and invert 10 cycles between compo-
|
||
nent additions.
|
||
4. When the components have all been added to the jar, let
|
||
the solution stand for 15 minutes.
|
||
5. Evaluate the solution for uniformity and stability. The
|
||
spray solution should not have free oil on the surface, or
|
||
fine particles that precipitate to the bottom, or thick
|
||
(clabbered) texture. If the spray solution is not
|
||
compatible, repeat the compatibility test with the addi-
|
||
tion of a suitable compatibility agent. If the solution is
|
||
then compatible, use the compatibility agent as directed
|
||
on its label. If the solution is still incompatible, DO NOT
|
||
mix the ingredients in the same tank.
|
||
Mixing Order
|
||
Shake Zidua PRO container well before use.
|
||
Maintain agitation throughout mixing and application until
|
||
spraying is completed.
|
||
1. Water - Fill tank 1/2 to 3/4 full with clean water and start
|
||
agitation.
|
||
2. Inductor - If an inductor is used, rinse it thoroughly after
|
||
each component has been added.
|
||
3. Products in PVA bags - Place any product contained
|
||
in water-soluble PVA bags into the mixing tank. Wait until
|
||
all water-soluble PVA bags have fully dissolved and the
|
||
product is evenly mixed in the spray tank before
|
||
continuing.
|
||
4. Water-soluble additives (including dry and liquid fertil-
|
||
izers ammonium sulfate or urea ammonium nitrate)
|
||
5. Water-dispersible products (dry flowables, wettable
|
||
powders, suspension concentrates, or suspo-emulsions)
|
||
- Add Zidua PRO at this point in the mixing process.
|
||
6. Water-soluble products (including glyphosate)
|
||
7. Emulsifiable concentrates (including methylated seed
|
||
oil adjuvants)
|
||
8. Remaining quantity of water
|
||
If the spray mixture is allowed to settle for any period of
|
||
time, thorough agitation is essential to resuspend the mix-
|
||
ture before spraying is resumed. Continue agitation while
|
||
spraying.
|
||
Use Restrictions
|
||
• DO NOT apply Zidua PRO after crop emergence or
|
||
severe crop injury will occur.
|
||
• DO NOT contaminate irrigation ditches or water used for
|
||
domestic purposes.
|
||
• DO NOT apply Zidua PRO through any type of irrigation
|
||
system (e.g. chemigation).
|
||
• Zidua PRO is not for sale, distribution, or use in
|
||
Nassau and Suffolk counties in New York State, or
|
||
in California.
|
||
Adjuvant Rate
|
||
methylated seed oil1 (MSO) 1 gal/100 gals2 (1% v/v)
|
||
PLUS PLUS
|
||
ammonium sulfate (AMS)
|
||
or
|
||
urea ammonium nitrate (UAN)
|
||
8.5 to 17 lbs/100 gals
|
||
(1% to 2% w/v)
|
||
or
|
||
1.25 to 2.5 gals/100 gals
|
||
(1.25% to 2.5% v/v)
|
||
12
|
||
|
||
13
|
||
Use Precautions
|
||
• Rainfastness - Zidua® PRO herbicide is rainfast
|
||
1 hour after application. Burndown activity may be
|
||
reduced if rain or irrigation occurs within 1 hour of
|
||
application.
|
||
• Full-rate application of products containing chlorimuron
|
||
ethyl, chloransulam-methyl, flumetsulam, or imazaquin in
|
||
the same year as Zidua PRO may increase the risk of
|
||
injury to sensitive follow crops. Consult the respective
|
||
labels of these products for specified uses of these prod-
|
||
ucts in combinations.
|
||
• When organophosphate or carbamate insecticides are
|
||
tank mixed with Zidua PRO, temporary injury may result
|
||
to the treated crops.
|
||
• Only rotational crops harvested at maturity may be used
|
||
for feed or food.
|
||
Rotational Crop Restrictions, Crop Rotation,
|
||
and Emergency Replanting Intervals
|
||
Use Table 2 and its exceptions in the paragraphs following
|
||
the table to determine the proper interval between
|
||
Zidua PRO application and rotational crop planting. This
|
||
interval can be used to determine the acceptable planting
|
||
interval for rotational crops as well as replanting after crop
|
||
failure (because of environmental factors including drought,
|
||
frost or hail, etc.). Be sure to determine the rotational crop
|
||
interval for tank mix products and utilize the most restrictive
|
||
interval of all products applied.
|
||
Table 2. Rotational Crop Planting and
|
||
Emergency Replanting Intervals after an
|
||
Application of Zidua PRO
|
||
a The planting interval for this crop and rates are further
|
||
defined in the respective Crop-specific Information
|
||
section of this label. Use the longer interval within listed
|
||
ranges for indicated crops grown on coarse-textured soils
|
||
with organic matter less than or equal to 2.0%.
|
||
b Following 40 months after a Zidua PRO application and
|
||
before planting any crop not listed elsewhere in the
|
||
Rotational Crop Restrictions, Crop Rotation, and
|
||
Emergency Replanting Intervals, a successful field
|
||
bioassay must be completed. The field bioassay consists
|
||
Crop Rotational Crop Interval
|
||
(months after application)
|
||
Clearfield® corn 0
|
||
Soybean 0 to 1a
|
||
Peas, field (dry) 1
|
||
Chickpea
|
||
Clearfield
|
||
® wheat
|
||
Lentil
|
||
Peanut
|
||
Wheat
|
||
4
|
||
Field corn
|
||
Field corn grown for seed
|
||
8.5
|
||
Peas, edible-podded and
|
||
succulent shelled 9
|
||
Clearfield® sunflower 9.5
|
||
Alfalfa 10
|
||
Barley
|
||
(except in North Dakota)
|
||
Beans, edible (dry, edible-
|
||
podded, and succulent
|
||
shelled)
|
||
Rye (except in North Dakota
|
||
and in Minnesota north of
|
||
Highway #210)
|
||
11
|
||
Clearfield® canola
|
||
Clearfield® rice 12
|
||
Barley
|
||
(grown in North Dakota)
|
||
Clover
|
||
Cotton
|
||
Lettuce
|
||
Oat
|
||
Popcorn
|
||
Rye (grown in North Dakota
|
||
and in Minnesota north of
|
||
Highway #210)
|
||
Safflower
|
||
Sorghum
|
||
Sunflower (non-Clearfield
|
||
®)
|
||
Sweet corn
|
||
Tobacco
|
||
18
|
||
Flax
|
||
Potato
|
||
26
|
||
Other crops 40b
|
||
|
||
14
|
||
of a test strip of the intended rotational crop planted
|
||
across the previously treated field and grown to maturity.
|
||
The test strip should include low areas and knolls and
|
||
include variations in soil including type and pH. If no crop
|
||
injury is evident in the test strip, the intended rotational
|
||
crop may be planted the following year. Sugar beet pro-
|
||
duction can be reduced when grown in soil conditions
|
||
with a pH less than 6.5. If the field is limed to adjust pH
|
||
prior to planting rotational crops not listed in Rotational
|
||
Crop Restrictions, Crop Rotation, and Emergency
|
||
Replanting Intervals, apply the lime at least 12 months
|
||
prior to planting the rotational crop.
|
||
Use of Zidua
|
||
® PRO herbicide in accordance with label
|
||
directions is expected to result in normal growth of rota-
|
||
tional crops in most situations. However, various
|
||
environmental and agronomic factors make it impossible to
|
||
eliminate all risks associated with the use of this product
|
||
and, therefore, rotational crop injury is always possible.
|
||
Exceptions to Crop Rotation Restrictions
|
||
Corn Inbred Lines
|
||
All corn inbred seed lines may be planted the year following
|
||
an application of Zidua PRO. Several seed companies
|
||
have tested a wide range of inbreds for sensitivity to
|
||
Zidua PRO soil residues and have reported good crop
|
||
safety. However, due to the proprietary nature of seed pro-
|
||
duction, BASF has not been given access to the inbred
|
||
data. Growers are directed to contact the seed company
|
||
for information regarding the planting of corn grown for
|
||
seed in fields treated with Zidua PRO the previous year.
|
||
Because growing conditions, environmental conditions,
|
||
and grower practices are beyond the control of BASF, to
|
||
the extent of applicable law all risks and consequences
|
||
associated with planting seed corn inbreds into fields treat-
|
||
ed previously with Zidua PRO shall be assumed by the
|
||
user.
|
||
Sweet Corn and Popcorn
|
||
(Illinois, Indiana, Iowa, Minnesota, Ohio, Tennessee,
|
||
and Wisconsin only)
|
||
Sweet corn and popcorn may be planted the year following
|
||
an application of Zidua PRO. Some sweet corn and pop-
|
||
corn may be injured when planted at less than 18 months
|
||
following an application of Zidua PRO. Before planting
|
||
sweet corn for processing, contact the processor company
|
||
for information regarding the tolerance of sweet corn
|
||
planned for fields treated with Zidua PRO the previous
|
||
year. DO NOT plant fresh market sweet corn prior to
|
||
18 months after Zidua PRO use. Before planting popcorn,
|
||
contact the popcorn company for information regarding the
|
||
tolerance of popcorn planned for fields treated with
|
||
Zidua PRO the previous year. Because growing condi-
|
||
tions, environmental conditions, and grower practices are
|
||
beyond the control of BASF, to the extent of applicable law
|
||
all risks and consequences associated with planting sweet
|
||
corn or popcorn into fields treated previously with
|
||
Zidua PRO shall be assumed by the user. Stunting and
|
||
maturity-delay or other adverse effects may result when
|
||
sweet corn or popcorn are planted following Zidua PRO
|
||
use.
|
||
Certain Vegetable Crops
|
||
(Alabama, Delaware, Florida, Georgia, Indiana,
|
||
Kentucky, Maryland, New Jersey, North Carolina,
|
||
Pennsylvania, South Carolina, and Virginia only)
|
||
The following crops may be planted 18 months following
|
||
the last application of Zidua PRO: Bahiagrass, cabbage,
|
||
cantaloupe, cucumber, Irish potato, onion, sweet pepper
|
||
transplants, sweet potato transplants, tomato transplants
|
||
and watermelon.
|
||
Field Corn and Field Corn Grown for Seed
|
||
(Arizona, Hawaii, Idaho, Montana, Nevada, Oregon,
|
||
Utah, Washington, and Wyoming)
|
||
Plant 9.5 months after Zidua PRO application.
|
||
Crop-specific Information
|
||
This section provides use directions for Zidua PRO. Be
|
||
sure to read about product information, mixing, application,
|
||
weeds controlled and adjuvant instructions in preceding
|
||
sections of the label.
|
||
Depending on specific application directions, Zidua PRO
|
||
may be applied for burndown control of emerged weeds
|
||
and/or residual control of germinating weeds (refer to
|
||
Table 1 for list of weeds controlled) before planting
|
||
(preplant/preseed) or after planting but before crop emer-
|
||
gence. Depending on the time between Zidua PRO
|
||
application and planting, a followup in-crop herbicide appli-
|
||
cation may be needed for complete weed control
|
||
throughout the growing season.
|
||
Thorough spray coverage is required for control of
|
||
emerged broadleaf weeds. High populations and/or
|
||
variations in size can prevent adequate spray coverage.
|
||
Controlling fall-germinated weeds in the spring
|
||
(e.g. horseweed/marestail) will also require thorough spray
|
||
coverage. Use higher spray volumes (e.g. 15 to 20 gallons
|
||
of water per acre) in these situations to increase spray cov-
|
||
erage and optimize burndown activity.
|
||
Fallow
|
||
Zidua PRO may be used as a burndown treatment to con-
|
||
trol listed weeds at any time of the year during the fallow
|
||
period following crop harvest and before the following crop
|
||
is planted (see paragraph below pertaining to rotational
|
||
planting intervals).
|
||
Application Rate and Timing
|
||
Apply Zidua PRO as a broadcast burndown spray at
|
||
6.0 fl ozs/A plus required adjuvants (refer to Additives sec-
|
||
tion for details). For best product performance, apply
|
||
Zidua PRO when broadleaf weeds are small and actively
|
||
growing (refer to Table 1 for list of weeds controlled).
|
||
Thorough coverage of existing weeds is essential and high-
|
||
er spray volumes may be needed for best performance.
|
||
Specific rotational crop planting intervals must be observed
|
||
between an application of Zidua PRO and planting of the
|
||
following crops (see Table 2 for rotational crop planting
|
||
intervals).
|
||
|
||
15
|
||
Tank Mixes
|
||
Broad-spectrum burndown control of grass weeds and/or
|
||
additional broadleaf weeds requires a tank mix with another
|
||
herbicide. Zidua
|
||
® PRO herbicide may be tank mixed or
|
||
applied sequentially with one or more of, but not limited to,
|
||
the following herbicide products:
|
||
• 2,4-D
|
||
• dicamba
|
||
• glyphosate
|
||
It is the pesticide user’s responsibility to ensure that all
|
||
products in the mixtures are registered for the intended
|
||
use. Read and follow the applicable restrictions and limita-
|
||
tions and directions for use on all product labels involved in
|
||
tank mixing. Users must follow the most restrictive direc-
|
||
tions for use and precautionary statements of each product
|
||
in the tank mixture.
|
||
Soybean
|
||
Zidua PRO may be applied in the fall and/or in the spring
|
||
as a preplant or preemergence burndown application in
|
||
conventional, reduced-till, or no-till soybean for weed con-
|
||
trol (refer to Table 1 for list of weeds controlled). An
|
||
adjuvant system (refer to Additives section for details) is
|
||
required for optimum burndown activity.
|
||
Application Rate
|
||
See Table 3 for application rates of Zidua PRO in soybean
|
||
when applied alone, in tank mix, or sequentially.
|
||
Table 3. Application Rate (in fl ozs/A) of Zidua PRO in
|
||
soybean.
|
||
aApply 6 fl ozs/A on fields with high weed pressure, resistant weed popu-
|
||
lations, or emerged weeds at the time of application. If less than
|
||
6 fl ozs/A is applied under these conditions, weed control may be
|
||
diminished.
|
||
State-specific Use in North Dakota and in Minnesota
|
||
north of Highway #210. Apply ZIDUA PRO at
|
||
4.5 fl ozs/A in the fall or in the spring (see Application
|
||
Timing section below for details) for burndown and/or
|
||
residual weed control in conventional, reduced-till, or no-till
|
||
soybean.
|
||
Application Timing
|
||
Fall Application
|
||
Apply Zidua PRO for burndown and/or residual weed con-
|
||
trol after the prior crop is harvested. Applications must be
|
||
made prior to first killing frost. Fall applications can be
|
||
made to all soil types.
|
||
Spring Application
|
||
Apply Zidua PRO early preplant through preemergence for
|
||
burndown and/or residual weed control prior to crop emer-
|
||
gence. A sequential application of Sharpen
|
||
® herbicide at
|
||
1.0 and 2.0 fl ozs/A may be made with a minimum of
|
||
30 and 60 days between applications, respectively.
|
||
Soybean Planting Interval
|
||
Depending on soil texture and organic matter, an interval
|
||
between Zidua PRO application and soybean planting
|
||
may be required (see Table 4 and Table 5). These intervals
|
||
must be observed prior to planting soybeans or crop injury
|
||
may occur.
|
||
Table 4. Minimum Soybean Planting Interval
|
||
Table 5. Minimum Soybean Planting Intervals when
|
||
Zidua PRO is Applied with other Group 14/Group E
|
||
Herbicides
|
||
1 Group 14/Group E herbicides including sulfentrazone or flumioxazin
|
||
*Interval for reduced-till and no-till soybean only. Interval for conventional-
|
||
till soybean is 30 days.
|
||
Application Tillage System
|
||
Burndown and
|
||
residual weed
|
||
control
|
||
Conventional Reduced-till No-till
|
||
4.5 to 6.0a 4.5 to 6.0a 6.0
|
||
Minimum Preplant Interval
|
||
(days)
|
||
Required between Zidua PRO
|
||
Application and Soybean Planting
|
||
Soil Texture
|
||
Organic Matter
|
||
≤2.0% > 2.0%
|
||
Coarse
|
||
(Sand, loamy sand,
|
||
and sandy loam)
|
||
30 None
|
||
Medium
|
||
(Silt, silt loam, loam,
|
||
and sandy clay loam)
|
||
None None
|
||
Fine
|
||
(Sandy clay, silty clay,
|
||
silty clay loam, clay
|
||
loam, and clay)
|
||
None None
|
||
Minimum Preplant Interval
|
||
(days)
|
||
Required between Zidua PRO Application and
|
||
Soybean Planting when Tank Mixed or Sequentially
|
||
Applied with a Group 14/Group E Herbicide1
|
||
Soil Texture
|
||
Organic Matter
|
||
≤2.0% >2.0%
|
||
Coarse
|
||
(Sand, loamy sand,
|
||
and sandy loam)
|
||
30 14*
|
||
Medium
|
||
(Silt, silt loam, loam,
|
||
and sandy clay loam)
|
||
14* 14*
|
||
Fine
|
||
(Sandy clay, silty clay,
|
||
silty clay loam, clay
|
||
loam, and clay)
|
||
14* 14*
|
||
|
||
16
|
||
Crop-specific Restrictions
|
||
• DO NOT apply more than 6.0 ozs/A of Zidua® PRO
|
||
herbicide in a single application or cumulatively in soy-
|
||
bean per year.
|
||
• DO NOT apply more than a maximum cumulative
|
||
amount of 0.089 lb ai/A of saflufenacil per year in soy-
|
||
bean from all product sources.
|
||
• DO NOT apply more than a maximum cumulative
|
||
amount of 0.112 lb ai/A of pyroxasulfone on coarse soils
|
||
per year in soybean from all product sources.
|
||
• DO NOT apply more than a maximum cumulative
|
||
amount of 0.186 lb ai/A of pyroxasulfone on all soils other
|
||
than coarse per year in soybean from all product
|
||
sources.
|
||
• DO NOT apply more than a maximum cumulative
|
||
amount of 0.063 lb ai/A of imazethapyr per year in soy-
|
||
bean from all product sources.
|
||
• DO NOT apply when soybeans have reached the crack-
|
||
ing stage or after emergence because severe crop injury
|
||
will result.
|
||
• DO NOT apply Zidua PRO on coarse soils with
|
||
≤2% organic matter within 30 days of planting.
|
||
• DO NOT apply Zidua PRO with other products contain-
|
||
ing Group 14/Group E herbicides (including
|
||
sulfentrazone or flumioxazin) as a tank mix or sequential
|
||
application within 14 days of planting because crop injury
|
||
may result.
|
||
• DO NOT graze or feed treated soybean forage, hay or
|
||
straw to livestock.
|
||
• There must be a Preharvest Interval of at least 85 days
|
||
between an application of Zidua PRO and soybean grain
|
||
harvest.
|
||
Use Precautions
|
||
• Ensure that the seed row is sufficiently covered with soil
|
||
to avoid washing and concentration of the herbicide in
|
||
the seed zone.
|
||
• Always use the most restrictive preplant interval of all
|
||
inclusive herbicides when applying Zidua PRO as part of
|
||
a tank mix.
|
||
• The use of Zidua PRO may result in temporary growth
|
||
suppression in soybean if extreme conditions of high rain-
|
||
fall and extended periods of water-saturated soil occur
|
||
during soybean germination or early seedling
|
||
development.
|
||
• Group 14/Group E herbicides labeled for
|
||
postemergence applications in soybean may be used
|
||
14 days after soybean emergence. Refer to other prod-
|
||
ucts’ labels for use directions.
|
||
Tank Mixes
|
||
Broad-spectrum burndown or enhanced residual control of
|
||
additional grasses or broadleaf weeds requires a tank mix.
|
||
Zidua PRO may be tank mixed or applied sequentially with
|
||
one or more of, but not limited to, the following herbicide
|
||
products:
|
||
• 2,4-D
|
||
• dicamba
|
||
• glyphosate
|
||
It is the pesticide user’s responsibility to ensure that all
|
||
products in the mixtures are registered for the intended
|
||
use. Read and follow the applicable restrictions and limita-
|
||
tions and directions for use on all product labels involved in
|
||
tank mixing. Users must follow the most restrictive direc-
|
||
tions for use and precautionary statements of each product
|
||
in the tank mixture.
|
||
|
||
17
|
||
Clearfield, Kixor, and Zidua are registered trademarks of
|
||
BASF.
|
||
The symbol is a registered trademark of Kumiai
|
||
Chemical Industry Co., Ltd.
|
||
© 2017 BASF Corporation
|
||
All rights reserved.
|
||
007969-00365.20170830c.NVA 2017-04-482-0139
|
||
Supersedes: NVA 2016-04-482-0216
|
||
Supplemental: NVA 2017-04-482-0145
|
||
BASF Corporation
|
||
26 Davis Drive
|
||
Research Triangle Park, NC 27709
|
||
Conditions of Sale and Warranty
|
||
The Directions For Use of this product reflect the
|
||
opinion of experts based on field use and tests. The
|
||
directions are believed to be reliable and must be followed
|
||
carefully. However, it is impossible to eliminate all risks
|
||
inherently associated with the use of this product. Crop
|
||
injury, ineffectiveness or other unintended consequences
|
||
may result because of such factors as weather conditions,
|
||
presence of other materials, or use of the product in a
|
||
manner inconsistent with its labeling, all of which are
|
||
beyond the control of BASF CORPORATION (“BASF”) or
|
||
the Seller. To the extent consistent with applicable law, all
|
||
such risks shall be assumed by the Buyer.
|
||
BASF warrants that this product conforms to the chemical
|
||
description on the label and is reasonably fit for the
|
||
purposes referred to in the Directions For Use, subject
|
||
to the inherent risks, referred to above.
|
||
TO THE EXTENT CONSISTENT WITH APPLICABLE
|
||
LAW, BASF MAKES NO OTHER EXPRESS OR
|
||
IMPLIED WARRANTY OF FITNESS OR
|
||
MERCHANTABILITY OR ANY OTHER EXPRESS OR
|
||
IMPLIED WARRANTY.
|
||
TO THE EXTENT CONSISTENT WITH APPLICABLE
|
||
LAW, BUYER’S EXCLUSIVE REMEDY AND BASF’S
|
||
EXCLUSIVE LIABILITY, WHETHER IN CONTRACT,
|
||
TORT, NEGLIGENCE, STRICT LIABILITY, OR
|
||
OTHERWISE, SHALL BE LIMITED TO REPAYMENT
|
||
OF THE PURCHASE PRICE OF THE PRODUCT.
|
||
TO THE EXTENT CONSISTENT WITH APPLICABLE
|
||
LAW, BASF AND THE SELLER DISCLAIM ANY
|
||
LIABILITY FOR CONSEQUENTIAL, EXEMPLARY,
|
||
SPECIAL OR INDIRECT DAMAGES RESULTING
|
||
FROM THE USE OR HANDLING OF THIS PRODUCT.
|
||
BASF and the Seller offer this product, and the Buyer and
|
||
User accept it, subject to the foregoing Conditions of
|
||
Sale and Warranty which may be varied only by
|
||
agreement in writing signed by a duly authorized
|
||
representative of BASF.
|
||
1108
|