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# THIOPHANATE-METHYL 4.1 SC FUNGICIDE
- EPA Reg No: **8033-129**
- Registrant: NIPPON SODA CO., LTD.
- Signal word: Caution
- Active ingredients: Thiophanate-methyl (41.3%)
- Label accepted: 2019-10-02
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/008033-00129-20191002.pdf
---
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
WASHINGTON, DC 20460
Fast Track Label Acceptable v.20150320
OFFICE OF CHEMICAL SAFETY
AND POLLUTION PREVENTION
October 2, 2019
John J. Wrubel
Director of Regulatory Affairs
Nippon Soda Co.
c/o Nisso America Inc.
88 Pine Street, 14th Floor
New York, NY 10005
Subject: Label Amendment Updating Resistance Management to comply with PRN
2017-1
Product Name: Thiophanate-methyl 4.1 SC Fungicide
EPA Registration Number: 8033-129
Application Date: 8/21/2018
Decision Number: 555693
Dear Mr Wrubel:
The amended label referred to above, submitted in connection with registration under the Federal
Insecticide, Fungicide and Rodenticide Act, as amended, is acceptable. This approval does not
affect any conditions that were previously imposed on this registration. You continue to be
subject to existing conditions on your registration and any deadlines connected with them.
A stamped copy of your labeling is enclosed for your records. This labeling supersedes all
previously accepted labeling. You must submit one copy of the final printed labeling before you
release the product for shipment with the new labeling. In accordance with 40 CFR 152.130(c),
you may distribute or sell this product under the previously approved labeling for 18 months
from the date of this letter. After 18 months, you may only distribute or sell this product if it
bears this new revised labeling or subsequently approved labeling. “To distribute or sell” is
defined under FIFRA section 2(gg) and its implementing regulation at 40 CFR 152.3.
Should you wish to add/retain a reference to the companys website on your label, then please be
aware that the website becomes labeling under the Federal Insecticide Fungicide and Rodenticide
Act and is subject to review by the Agency. If the website is false or misleading, the product
would be misbranded and unlawful to sell or distribute under FIFRA section 12(a)(1)(E). 40
CFR 156.10(a)(5) list examples of statements EPA may consider false or misleading. In addition,
regardless of whether a website is referenced on your products label, claims made on the
website may not substantially differ from those claims approved through the registration process.
Therefore, should the Agency find or if it is brought to our attention that a website contains false
or misleading statements or claims substantially differing from the EPA approved registration,
the website will be referred to the EPAs Office of Enforcement and Compliance.
Page 2 of 2
EPA Reg. No. 8033-129
Decision No. 555693
Your release for shipment of the product constitutes acceptance of these conditions. If these
conditions are not complied with, the registration will be subject to cancellation in accordance
with FIFRA section 6. If you have any questions, please contact Nathan Mellor by phone at 703-
347-8562, or via email at mellor.nathan@epa.gov.
Shaja B. Joyner, Product Manager 20
Fungicide-Herbicide Branch
Registration Division 7505P
Enclosure
1
Thiophanate-
methyl
GROUP 1 FUNGICIDE
Thiophanate-Methyl 4.1 SC
Fungicide
ACTIVE INGREDIENT:
Thiophanate-methyl (dimethyl[1,2-phenylene)-
bis(iminocarbonothioyl)]bis[carbamate])* . . . . . . . . . . . . . . . . . . . . . . . 41. 3%
OTHER INGREDIENTS: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58. 7%
TOTAL: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100.0%
Contains 4.11 pounds thiophanate-methyl per gallon.
*Also known as dimethyl 4,4-o-phenylenebis[3-thioallophanate]
KEEP OUT OF REACH OF CHILDREN
CAUTION
FIRST AID
If on skin or clothing:
x Take off contaminated clothing.
x Rinse skin immediately with plenty of water for 15-20 minutes.
x Call a poison control center or doctor for treatment advice.
If swallowed:
x Call a poison control center or doctor immediately for treatment advice.
x Have person sip a glass of water if able to swallow.
x Do not induce vomiting unless told to by a poison control center or doctor.
x Do not give anything by mouth to an unconscious person.
Have the product container or label with you when calling a poison control center or doctor or
going for treatment. Contact the Rocky Mountain Poison Control Center at 1-866-673-6671
for emergency medical treatment information.
**[See additional precautionary statements and directions for use inside booklet.]
**[Read the label carefully before opening the container.]
**[Peel back book here.]
**Note to EPA Product Manager: Text in brackets [ ] above is optional.
EPA Reg. No.8033-129 EPA Est. No.
NET CONTENTS: __________ Gallons Batch/Lot # ____________
Nippon Soda Co., Ltd. c/o Nisso America Inc.
88 Pine St., 14th floor, New York, NY 10005
Notification Resistance Management (PR Notice 2017-1) Revised 9-26-19
10/02/2019
8033-129
2
PRECAUTIONARY STATEMENTS
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
CAUTION
Harmful if absorbed through the skin or if swallowed. Avoid contact with skin, eyes or
clothing.
PERSONAL PROTECTIVE EQUIPMENT (PPE)
Some materials that are chemical-resistant to this product are barrier laminate, nitrile
UXEEHU •PLOV butyl rubber •PLOV , neoprene rubber •PLOV , polyvinyl
chloride (PVC) •PLOV , and Viton •PLOV .
Handlers mixing, loading, and applying the product as a dip (including application of
product in Kaolinite clay to conifer seedling roots) must wear:
x Coveralls over long-sleeved shirt and long pants,
x Chemical-resistant gloves,
x Chemical-resistant footwear plus socks,
x Chemical-resistant apron.
All other mixers, loaders, and applicators must wear:
x Long-sleeved shirt and long pants,
x Shoes plus socks,
x Chemical-resistant gloves,
x Chemical-resistant apron for mixers, loaders, and other handlers exposed to the
concentrate.
Seed treatment applicators and other seed treatment handlers must wear:
x Long-sleeved shirt and long pants,
x Shoes plus socks,
x Chemical-resistant gloves for all mixers and loaders and for applicators using
hand-held equipment,
x Chemical-resistant apron for mixers, loaders, and other handlers exposed to the
concentrate.
Note: Persons involved in bagging treated seed, sewing or moving bags of treated seed,
or cleaning up bagging areas or seed treatment equipment are pesticide handlers and must
wear the PPE required on this label for pesticide handlers.
3
User Safety Requirements
Follow manufacturers instructions for cleaning/maintaining PPE. If no such instructions
for washables exist, use detergent and hot water. Keep and wash PPE separately from
other laundry. Discard clothing and other absorbent materials that have been drenched or
heavily contaminated with this products concentrate. Do not reuse them.
ENGINEERING CONTROLS
When handlers use enclosed cabs in a manner that meets the requirements listed in the
Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)],
the handler PPE requirements may be reduced or modified as specified in the WPS.
USER SAFETY RECOMMENDATIONS
Users should wash hands before eating, drinking, chewing gum, using tobacco, or using
the toilet.
Users should remove clothing/PPE immediately if pesticide gets inside. Then wash
thoroughly and put on clean clothing.
Users should remove PPE immediately after handling this product. Wash the outside of
gloves before removing. As soon as possible, wash thoroughly and change into clean
clothing.
ENVIRONMENTAL HAZARDS
Do not apply directly to water, or to areas where surface water is present or to intertidal
areas below the mean high-water mark. Runoff from treated areas may be hazardous to
aquatic organisms in neighboring areas. Do not contaminate water when disposing of
equipment wash water or rinsate.
DIRECTIONS FOR USE
SHAKE WELL BEFORE USING
It is a violation of Federal law to use this product in a manner inconsistent with its
labeling.
Do not apply this product in a way that will contact workers or other persons, either
directly or through drift. Only protected handlers may be in the area during application.
For any requirements specific to your State or Tribe, consult the agency responsible for
pesticide regulation.
Do not apply when wind speed favors drift beyond the area intended for treatment.
4
AGRICULTURAL USE REQUIREMENTS
Use this product only in accordance with its labeling and with the Worker Protection Standard,
40 CFR part 170. This Standard contains requirements for the protection of agricultural
workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides.
It contains requirements for training, decontamination, notification, and emergency assistance.
It also contains specific instructions and exceptions pertaining to the statements on this label
about personal protective equipment (PPE), and restricted-entry interval. The requirements in
this box only apply to uses of this product that are covered by the Worker Protection Standard.
Do not enter or allow worker entry into treated areas during the restricted entry interval (REI).
Exemption: The Worker Protection Standard, under certain circumstances, allows workers to
enter the treated area if there will be no contact with anything that has been treated.
Do not enter or allow workers entry into treated areas during the restricted-entry interval
(REI). The REI for each crop is listed in the directions for use associated with that crop.
Exemption: If this product is applied by drenching or if treated seed is soil-injected or soil
incorporated, the Worker Protection Standard, under certain circumstances, allows workers to
enter the treated area if there will be no contact with anything that has been treated.
PPE required for early entry to treated areas that is permitted under the Worker Protection
Standard and that involves contact with anything that has been treated, including plants, soil,
or water, is:
x Coveralls over long-sleeved shirt and long pants,
x Chemical-resistant gloves made of any waterproof material,
x Chemical-resistant footwear plus socks,
x Chemical-resistant headgear for overhead exposures.
PRODUCT APPLICATION AND INSTRUCTIONS
RESISTANCE MANAGEMENT
For resistance management, Thiophanate-Methyl 4.1 SC contains a Group 1 fungicide.
Any fungal population may contain individuals naturally resistant to Thiophanate-Methyl
4.1 SC and other Group 1 fungicides. A gradual or total loss of pest control may occur
over time if these fungicides are used repeatedly in the same fields. Appropriate
resistance-management strategies should be followed.
To delay fungicide resistance, take one or more of the following steps:
• Rotate the use of Thiophanate-Methyl 4.1 SC Fungicide or other Group 1 fungicides
within a growing season sequence with different groups that control the same pathogens.
• Use tank mixtures with fungicides from a different group that are equally effective on
the target pest when such use is permitted. Use at least the minimum application rate as
labeled by the manufacturer.
5
• Adopt an integrated disease management program for fungicide use that includes
scouting, uses historical information related to pesticide use, and crop rotation, and which
considers host plant resistance, impact of environmental conditions on disease
development, disease thresholds, as well as cultural, biological and other chemical
control practices.
• Where possible, make use of predictive disease models to effectively time fungicide
applications. Note that using predictive models alone is not sufficient to manage
resistance.
• Monitor treated fungal populations for resistance development.
• Contact your local extension specialist or certified crop advisor for any additional
pesticide resistance-management and/or IPM directions for specific crops and pathogens.
• For further information or to report suspected resistance contact Nippon Soda Co., Ltd.
at 212-490-0350. You can also contact your pesticide distributor or university extension
specialist to report resistance."
INSTRUCTIONS
Apply Thiophanate-methyl 4.1 SC with ground or aerial equipment, using sufficient
volume of spray to provide thorough coverage. Continuous agitation is required to keep
the material in suspension. Nippon Soda Co., Ltd. does not advise tank mixes with
highly alkaline pesticides, including Bordeaux mixture or lime sulfur. No claim of
compatibility with other pesticides is implied. Use the higher rate under conditions of
severe disease pressure. Also, s ee local State Extension Service directions for application
schedules.
Use the fl. oz./Acre rate for concentrate sprays (less than 400 gallons on apples, less than
300 gallons on stone fruit). Use the fl. oz./100 gal. rate for dilute ground applications.
For aerial applications, use a minimum of 5 gallons/A for row crops, and a minimum of
10 gallons/A for tree crops. For ground applications use a minimum of 20 gallons/A for
row crops and 30 gallons/A for tree crops. Higher spray volume will generally result in
better coverage and better disease control. Lack of control when using below minimum
spray volumes is solely at the risk of the applicator/user, including use of electrostatic
sprayers.
Chemigation instructions follow. Do not apply through any irriga tion system unless
these instructions are followed.
For crops without labeled uses of thiophanate-methyl, observe a 30-day plantback
restriction.
Use on all labeled non-bearing tree fruit and tree nuts: Thiophanate-methyl 4.1 SC
may be used for control of the diseases listed on the label for these crops during the non-
6
bearing years of new plantings, and on nursery stock. All use directions and limitations
must be followed, except for the PHI, which is not applicable. Begin applications as
disease is first observed or expected. Tank mixing with a protectant fungicide is strongly
advised for resistance management.
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
Almonds
Do not enter or
allow worker
entry into
treated areas
during the
restricted
entry interval
(REI) of 3 days.
Brown Rot
Blossom Blight
(Monilinia)
Scab
(Cladosporium)
Jacket Rot
(Monilinia,
Sclerotinia, Botrytis)
Leaf Blight
(Seimatosporium)
21.8-32.7
(0.7
1.05)
Apply as needed at 10 to 14-day intervals
between pink bud and petal fall.
Thiophanate-methyl 4.1 SC may be
applied alone at pink bud for Brown Rot
control. For all other applications,
Thiophanate-methyl 4.1 SC needs to be
applied with a contact fungicide for broad
spectrum control and resistance
management.
Restrictions:
-Do not apply more than 32.7 fl. oz./A
(1.05 lb ai/A) per application.
-Do not apply more than a total of 65.4 fl.
oz. of product (2.1 lbs a.i.)/A/year.
-The minimum retreatment interval is ten
(10) days.
-Do not apply more than three (3)
applications per year.
Apples
Do not enter or
allow worker
entry into
treated areas
during the
restricted-
entry interval
(REI) of 2 days.
Apple Scab
(Venturia)
Black Pox***
(Helminthosporium
papulosum)
Flyspeck
(Zygophiala)
Powdery Mildew
(Podosphaera)
Sooty Blotch (Gloeodes)
Black Rot
(Botryosphaeria
obtusa)
Brooks Fruit Spot
(Mycosphaerella)
White Rot***
(Botryosphaeria
dothidia)
16.3-21.8
(0.52- 0.7)
[in CA use
32.7]
(1.1)
4.1-5.5
Apply at 5 to 10-day intervals from green
tip through petal fall; continue at 7 to
14-day intervals in cover sprays.
Restrictions:
-Do not apply more than 21.8 fl. oz./A
(0.7 lb. a.i./A) per application.
-In California, do not apply more than
32.7 fl. oz./A (1.1 lb. a.i./A) per
application.
-Do not apply more than a total of 87.2 fl.
oz. of product (2.8 lbs a.i.)/A/year.
-Pre-harvest interval: 1 day
7
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
-The minimum retreatment interval is
five (5) days.
-Do not apply more than five (5)
applications per year.
Follow resistance management guidelines
under Directions for Use.
Pre-Harvest use to control Post-Harvest Diseases on Apples
Storage Rot
Blue Mold
(Penicillium
expansum)
Gray Mold
(Botrytis cinerea)
Bulls-Eye Rot
(Neofabraea spp.)
16.321.8
(0.52-0.7)
4.1-5.5
Apply as a pre-harvest spray within 2
weeks to 3 days of harvest.
Thorough coverage of the fruit is
required. Application closer to harvest
may provide better efficacy.
For resistance management, do not use a
benzimidazole fungicide post-harvest
following Thiophanate-methyl 4.1 SC
pre-harvest application. Application of a
non-benzimidazole post-harvest
fungicide will provide additional
protection from post-harvest diseases.
Restrictions:
-Do not apply more than 21.8 fl. oz./A
(0.7 lb. a.i./A) per application.
-Do not apply more than a total of 87.2
fl.oz. of product (2.8 lbs a.i.)/A/year.
-The minimum retreatment interval is
five (5) days.
-Do not apply more than five (5)
8
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
applications per year.
-Pre-harvest interval: 1 day
Beans, dry and
succulent
Including:
Lima bean
Snap bean
Kidney bean
Mung bean
Navy bean
Pinto bean
Wax bean
Broad bean
Fava bean
Asparagus bean
Blackeyed pea
Cowpea
Sweet lupine
White lupine
White Sweet
lupine
Grain lupine
Chick pea
Garbanzo bean
Do not enter or
allow worker
entry into
treated areas
during the
restricted-
entry interval
(REI) of 24
hours for
succulent beans
and 3 days for
dry beans.
White Mold
(Sclerotinia)
Gray Mold
(Botrytis)
Anthracnose
(Colletotrichum)
32.7-43.6
(1.1-1.4)
OR
21.8-32.7
(0.7-1.1)
For one application: Apply when 100%
of plants have at least one open bloom or
when conditions are favorable for disease
development.
OR
For multiple applications: Make the first
application when 10% to 30% of plants
have at least one open bloom and follow
with sequential applications on a 4 to
7day interval. Apply prior to the
development of disease for best results.
Restrictions:
-Do not apply more than 43.6 fl.oz./A
(1.4 lb a.i./A per application.
-Do not apply more than 87.2 of product
(2.8 lbs a.i.)/A/year.
- The minimum retreatment interval is
four (4) days.
-Do not apply more than five (5)
applications per year.
-Pre-harvest interval: California only,
14 days for succulent beans, 28 days for
dry beans and lima beans.
-Pre-harvest interval: all other States,
14 days for succulent beans and lima
beans, 28 days for dry beans.
9
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
Cucurbits:
Cantaloupe,
Casaba,
Cucumbers,
Melons,
Pumpkins,
Summer and
Winter Squash,
and
Watermelons
Do not enter or
allow worker
entry into
treated areas
during the
restricted-
entry interval
(REI) of 24
hours
.
Thiophanate-methyl 4.1 SC can be used
in a tank mix with mancozeb or
chlorothalonil for additional disease
control and resistance management. It is
the pesticide users responsibility to
ensure that all products are registered for
the intended use. Read and follow the
applicable restrictions and limitations and
directions for use on all product labels
involved in tank mixing. Users must
follow the most restrictive directions for
use and precautionary statements of each
product in the tank mixture.
Follow resistance management guidelines
under Directions for Use.
Restrictions:
-Do not apply more than 10.9 fl. oz./A
(0.35 lb. a.i./A) per application.
-Do not apply more than 65.4 fl.oz. of
product (2.1 lbs a.i.)/A/year from any
combination of application timings.
-The minimum retreatment interval is
four (4) days.
-Do not apply more than five (5)
applications per year.
-Pre-harvest interval: 1 day
Acremonium/
Cephalosporium
Hypocotyl Rot
10.9
(0.35)
Apply in-furrow, on top of the seeds at
planting.
Restrictions:
-Do not use less than 10 gallons of water
per acre.
10
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
Anthracnose***
(Colletotrichum)
Gummy Stem Blight***
(Didymella)
Powdery Mildew
(Erysiphe,
Sphaerotheca)
Target Spot***
(Corynespora)
10.9
(0.35)
Begin applications when plants begin to
run or when disease first appears, and
repeat at 7-14 day intervals or as needed.
For Target Spot, use at 7-day intervals as
needed.
Restrictions:
-The minimum retreatment interval is
seven (7) days.
-Do not apply more than six (6)
applications per year.
Belly Rots***
(Rhizoctonia,
Fusarium)
10.9
(0.35)
Apply in sufficient volume to allow
runoff to the soil. Will not control
Pythium or Phytophthora.
Suppression of Vine
Decline
(Monosporascus)
Charcoal Rot
(Macrophomina)
10.9
(0.35)
Apply through buried drip irrigation
(chemigation) to the root zone. For
disease suppression, apply at 14-day
intervals, beginning at emergence and
continuing to harvest.
Applications weekly or biweekly,
beginning 4 to 6 weeks prior to harvest
will also offer suppression, but may not
be as effective as a season-long program.
Restrictions:
-The minimum retreatment interval is
fourteen (14) days.
-Do not apply more than six (6)
applications per year.
Garlic
(clove
treatment)
Penicillium Clove Rot
21.8
Completely immerse garlic cloves in
suspension for at least 5 minutes.
Continuously agitate the solution tank by
hydraulic or mechanical means.
After treatment, remove cloves from
solution and drain.
Dry cloves after treatment and prior to
planting.
11
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
Onions*
Garlic
(In furrow)
Do not enter or
allow worker
entry into
treated areas
during the
restricted entry
interval (REI)
of 3 days.
White Rot (Sclerotium
cepivorum) 43.6
(1.4)
broadcast
Spray directly into the open furrow at the
time of planting seed, sets or bulbs. Not
for this use through any type of irrigation
system.
Restrictions:
-Do not apply more than 43.6 fl. oz./A
(1.4 lb. a.i./A) per application.
-Do not apply more than 43.6 fl. oz. of
product (1.4 lbs a.i.)/A/year.
Do not apply more than one (1)
application per year.
Peanuts
Do not enter or
allow worker
entry into
treated areas
during the
restricted
entry interval
(REI) of 24
hours.
Early Leaf Spot
(Cercospora)
Late Leaf Spot
(Cercsoporidium)
Rust
(Puccinia)
Limb Rot (Rhizoctonia)
Web Blotch
(Ascochyta)
10.9
(0.35)
Begin applications when disease first
appears and repeat at 14-day intervals as
needed.
Restrictions:
-Do not apply more than 10 fl. oz./A
(0.35 lb. a.i./A) per application.
-Do not apply more than 43.6 fl.oz. of
product (1.4 lbs a.i.)/A/year.
-The minimum retreatment interval is
fourteen (14) days.
-Do not apply more than four (4)
applications per year.
-Pre-harvest interval: 14 days
-Thiophanate-methyl 4.1 SC must not be
used alone. Use only in combination
with a non-benzimidazole fungicide like
chlorothalonil.
-Follow resistance management
guidelines under Directions for Use.
Pecans
Do not enter or
allow worker
Brown Spot
(Cercospora)
Downy Spot
(Mycosphaerella)
Liver Spot
21.8
(0.7)
Begin applications when first leaves are
showing and repeat at 3 to 4-week
intervals until shuck split. Do not apply
after shuck split.
12
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
entry into
treated areas
during the
restricted
entry interval
(REI) of 3 days.
(Gnomonia)
Powdery Mildew
(Microsphaera)
Scab
(Fusicladium)
Stem End Blight
(Botryosphaeria)
Zonate Leaf Spot
(Cristulariella)
Restrictions:
-Do not apply more than 21.8 fl. oz./A
(0.7 lb. a.i./A) per application.
-Do not apply more than 65.4 fl. oz. of
product (2.1 lbs a.i.)/A/year.
-The minimum retreatment interval is
twenty one (21) days.
-Do not apply more than three (3)
applications per year.
-Pre-harvest interval: 1 day
-Follow resistance management
guidelines under Directions for Use.
Pistachios
Do not enter or
allow worker
entry into
treated areas
during the
restricted entry
interval (REI)
of 3 days.
Shoot Blight
(Botrytis, Botryosphaeria) 32.7-43.6
(1.1-1.4)
Apply at bloom.
Apply in a minimum of 100 gallons per
acre by ground or 20 gallons per acre by
air.
For aerial application, fly over every row
or center.
Restrictions:
-Do not apply more than 43.6 fl. oz./A
(1.4 lb. a.i./A) per application.
-Do not apply more than 43.6 fl. oz. of
product (1.4 lbs a.i.)/A/year.
Do not apply more than one (1)
application per year.
13
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
Potatoes
Do not enter or
allow worker
entry into
treated areas
during the
restricted
entry interval
(REI) of 2 days.
White Mold
(Sclerotinia sclerotiorum) 21.8-32.7
(0.7-1.1)
Make first application at row closure to
full bloom of the primary flower clusters
(prior to petal drop). Repeat the
application within 7-14 days and at 7-14
day intervals if conditions for disease
development are favorable.
Thorough coverage of the flowers, stems,
and branches is essential for disease
control.
Use a minimum of 6 gallons/A for aerial
application.
Apply prior to the development of
disease for the best results.
Restrictions:
-Do not apply more than 32.7 fl. oz./A
(1.1 lb. a.i./A) per application.
-Do not apply more than 87.2 fl. oz. of
product (2.8 lbs a.i.)/A/year.
-The minimum retreatment interval is
seven (7) days.
-Do not apply more than four (4)
applications per year.
-Pre-harvest interval: 21 days
-May be tank mixed with mancozeb for
Early and Late Blight control. It is the
pesticide users responsibility to ensure
that all products are registered for the
intended use. Read and follow the
applicable restrictions and limitations and
directions for use on all product labels
involved in tank mixing. Users must
follow the most restrictive directions for
use and precautionary statements of each
product in the tank mixture.
14
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
Soybeans
Do not enter or
allow worker
entry into
treated areas
during the
restricted
entry interval
(REI) of 24
hours.
Restrictions:
-Do not apply more than 21.8 fl. oz./A
(0.7 lb. a.i./A) per application.
-Do not apply more than 43.6 fl. oz. of
product (1.4 lbs a.i.)/A/year.
-The minimum retreatment interval is
seven (7) days.
-Do not apply more than two (2)
applications per year.
-Pre-harvest interval: 21 days
-Do not graze or feed treated vines or hay
to livestock.
Anthracnose
(Colletotrichum)
Brown Spot
(Septoria)
Frogeye Leaf Spot
(Cercospora)
Pod and Stem Blight
(Diaporthe, Phomopsis)
Purple Seed Stain
(Cercospora)
10.9-21.8
(0.35-0.7)
Apply from full bloom to when pods are
ǩ
WRó
LQOHQJWK0DNHDVHFRQG
application 14 to 21 days later. Do not
make the second application later than 14
days after pods average ¼'' in length or
when beans form in the pod. Use the high
rate under severe disease pressure.
21.8
(0.7)
FOR SEED BEANS ONLY
-For seed quality, make a single
application when beans form in the pod.
White Mold
(Sclerotinia) 16.3-21.8
(0.52-0.7)
Make one application at early bloom (R-1
to R-2 stage) followed by a second
application 7-14 days later if conditions
are favorable for continued disease
pressure.
Thorough coverage of the flowers, stems,
and branches is essential for disease
control.
Use a minimum of 5 gallons water/A by
air.
Aerial Blight
(suppression)
21.8
(0.7)
Make initial application when disease
threatens and repeat 14-21 days later if
needed.
15
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
Stone Fruit
Do not enter or
allow worker
entry into
treated areas
during the
restricted
entry interval
(REI) of 2 days.
Restrictions:
-Do not apply more than 32.7 fl. oz./A
(1.1 lb. a.i./A) per application.
-Do not apply more than 87.2 fl. oz. of
product (2.8 lbs a.i.)/A/year.
-The minimum retreatment interval is ten
(10) days.
Do not make more than four (4)
applications per year.
-Pre-harvest interval: 1 day
-Follow resistance management
guidelines under Directions for Use.
Apricots Brown Rot Blossom
Blight
Fruit Brown Rot
(Monilinia)
21.8-32.7
(0.7-1.1)
[in CA use
32.7]
(1.1)
7.3-10.9
Apply at early bloom (red bud). Make a
second application at full bloom.
If needed, under severe disease pressure,
apply additional sprays at 10 to 14-day
intervals between full bloom and final
pre-harvest sprays.
Cherries
Sweet and
Sour
Brown Rot
Blossom Blight
Fruit Brown Rot
(Monilinia)
21.8-32.7
(0.7-1.1)
[in CA use
32.7]
(1.1)
7.3-10.9
Apply at early bloom (early popcorn).
Make a second application at full bloom.
If needed under severe disease pressure,
apply additional sprays at 10 to 14-day
intervals between full bloom and final
pre-harvest sprays.
Cherry Leaf Spot
(Coccomyces) 25.0-32.7
(0.8-1.1)
8.2-10.9
Applications may be made at petal fall or
before (when leaves first unfold) and at
first, second, and third cover at 10 to
14-day intervals and one spray 14 to 21
days after harvest.
16
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
Powdery Mildew
(Podosphaera,
Sphaerotheca)
21.8-32.7
(0.7-1.1)
[in CA use
32.7]
(1.1)
PLUS
25.0-32.7
(0.8-1.1)
7.3-10.9
PLUS
8.2-10.9
Apply at early bloom (early popcorn).
Make a second application at full bloom.
PLUS
Apply at shuck fall and first cover.
Nectarines Brown Rot
Blossom Blight
Fruit Brown Rot
(Monilinia)
21.8-32.7
(0.7-1.1)
[in CA use
32.7]
(1.1)
7.3-10.9
Apply at early bloom (pink bud). Make a
second application at full bloom if
conditions favor disease development.
If needed under severe disease pressure,
apply additional sprays at 10 to 14-day
intervals between full bloom and final
pre-harvest sprays.
Peaches Brown Rot Blossom
Blight
Fruit Brown Rot
(Monilinia)
21.8-32.7
(0.7-1.1)
[in CA use
32.7]
7.3-10.9
Apply at early bloom (pink bud). Make a
second application at full bloom if
conditions favor disease development.
If needed under severe disease pressure,
apply additional sprays at 10 to 14-day
intervals between full bloom and final
pre-harvest sprays.
Peach Scab
(Cladosporium) 21.8-32.7
(0.7-1.1)
[in CA use
32.7]
(1.1)
PLUS
25.0-32.7
(0.8-1.1)
7.3-10.9
PLUS
8.2-10.9
Apply at early bloom (pink bud). Make a
second application at full bloom if
conditions favor disease development.
PLUS
Apply at shuck split and at first cover
sprays.
Plums and
Prunes
Brown Rot Blossom
Blight
Fruit Brown Rot
(Monilinia)
21.8-32.7
(0.7-1.1)
[in CA use
32.7]
(1.1)
7.3-10.9 Apply at early bloom (green tip). Make a
second application at full bloom.
If needed under severe disease pressure,
apply additional sprays at 10 to 14-day
intervals between full bloom and final
pre-harvest sprays.
17
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
Black Knot (Dibotryon)
21.8-32.7
(0.7-1.1)
[in CA use
32.7]
(1.1)
7.3-10.9
Apply at pre-bloom, petal fall, and at
first, second, or third cover sprays at 10
to 14-day intervals.
Leaf Spot (Coccomyces)
21.8-32.7
(0.7-1.1)
[in CA use
32.7]
(1.1)
7.3-10.9
Applications may be made at petal fall,
shuck split, and at first, second, and third
cover sprays at 10 to 14-day intervals and
1 spray 14 to 21 days after harvest.
Strawberries
Do not enter or
allow worker
entry into
treated areas
during the
restricted
entry interval
(REI) of 24
hours.
Restrictions:
-Do not apply more than 21.8 fl. oz./A
(0.7 lb. a.i./A) per application.
-Do not apply more than 87.2 fl. oz. of
product (2.8 lbs a.i.)/A/year.
-The minimum retreatment interval is
seven (7) days.
-Do not apply more than 4 applications
per year.
-Pre-harvest interval: 1 day
-Follow resistance management
guidelines under Directions for Use.
Crown Rot***
(Colletotrichum spp.)
Suppression only
16.3-21.8
(0.52-0.7)
Begin applications after establishment of
the transplants and continue through first
bloom at 10 to 14-day intervals. Use the
high rate if the fields have a history of
Colletotrichum crown rot and/or
conditions are favorable for development
of the disease. Will not control
Phytophthora species.
18
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
Fruit Rot
(Botrytis)
Leaf Blight
(Dendrophoma)
Leaf Scorch
(Diplocarpon)
Powdery Mildew
(Sphaerotheca)
16.3-21.8
(0.52-0.7)
Begin applications at early bloom and
continue at 7 to 10-day intervals. Use the
higher rate under conditions of severe
disease pressure.
Sugar Beets
Do not enter or
allow worker
entry into
treated areas
during the
restricted
entry interval
(REI) of 24
hours.
Restrictions:
-Do not apply more than 21.8 fl. oz./A
(0.7 lb. a.i./A) per application.
-Do not apply more than 65.4 fl. oz. of
product (2.1 lbs a.i.)/A/year.
-The minimum retreatment interval is
fourteen (14) days.
-Do not apply more than 3 applications
per year.
-Pre-harvest interval: 21 days
-Follow resistance management
guidelines under Directions for Use.
Cercospora Leaf Spot
(Cercospora) 10.9-21.8
(0.35-0.7)
Apply when conditions become favorable
for disease development before the
disease appears and follow with a non-
benzimidazole fungicide within 14 days
of application or as needed.
Thiophanate-methyl 4.1 SC must be tank
mixed with a protectant fungicide when
resistant strains of Cercospora are present
in the field.
For areas east of the Rocky Mountians:
Do not make more than one application
of Thiophanate-methyl 4.1 SC per season
for Cercospora Leaf Spot.
19
Crops/
REI Diseases
FL.
OZ./
Acre
(lb.
a.i./A)
FL.
OZ./
100 Gal
Application Instructions
Powdery Mildew
(Erysiphe) 10.9-21.8
(0.35-0.7)
Apply as soon as disease symptoms
appear and follow with a non-
benzimidazole fungicide at a 14-day
interval or as needed.
Thiophanate-methyl 4.1 SC can be tank
mixed with sulfur products for additional
disease control and resistance
management.
Triticale and
Fall-seeded
Wheat
For this use in
Idaho,
Oregon, and
Washington
ONLY
Do not enter or
allow worker
entry into
treated areas
during the
restricted
entry interval
(REI) of 24
hours.
Foot Rot, Strawbreaker,
Eye Spot
(Pseudocercosporella)
21.8
(0.7)
Apply Thiophanate-methyl 4.1 SC at the
rate indicated in a single application by
air or ground after tillering but before
stem elongation has begun.
Use sufficient water to obtain thorough
coverage.
Restrictions:
-Do not apply more than 21.8 fl. oz./A
(0.7 lb. a.i./A) per application.
-Do not apply more than 21.8 fl.oz. of
product (0.7 lb a.i.)/A/year.
-Do not cut for hay within 90 days of
application.
-Do not allow livestock to graze in
treated areas before harvest.
*** Not for this use in California
NOTE: Dilute sprays are not to exceed maximum rate per acre.
20
DIRECTIONS FOR USE ON CONIFERS
(Not for this use in California)
CROPS DISEASE RATE (fl. oz./A),
MINIMUM
GALLONAGE
APPLICATION INSTRUCTIONS AND
RESTRICTIONS
Conifers (Pine)
Austrian
Red
Scots
Christmas
Trees
Do not enter or
allow worker
entry into treated
areas during the
restricted entry
interval (REI) of
12 hours.
Tip Blight
(Diplodia)
21.8 fl. oz. per 100
gal./A
Apply at bud break. Repeat 10 to 14 days later, just
before needles emerge from sheath; repeat again 10 to
14 days after needle emergence.
Add a spreader/sticker to improve coverage.
- Use minimum gallonage with mist-blower types of
sprayers and higher gallonage with conventional
sprayers.
Restrictions:
-Do not apply more than 65.4 fl. oz. of product (2.1
lbs. a.i.)/A/year.
-The minimum retreatment interval is ten (10) days.
-Do not apply more than 3 applications per year.
-Do not graze livestock in treated areas.
Conifers
(Fir)
Douglas
Swiss Needle Cast
(Phaecryptopus)
Rhabdocline Needle
Cast
21.8 fl. oz. per
50 gal./A
Apply initially in early May. Repeat at 4-week
intervals.
Add a spreader/sticker to improve coverage.
- Use minimum gallonage with mist-blower types of
sprayers and higher gallonage with conventional
sprayers.
Restrictions:
-Do not apply more than 109 fl. oz. of product (3.5
lbs. a.i.)/A/year.
-The minimum retreatment interval is (28) days.
-Do not apply more than 5 applications per year.
Conifers
(seedling
treatment)
Longleaf
Brown Needle Blight
(Scirrhia)
1.4 fl. oz. product
per 9.5 oz. dry
Kaolinite clay for
seedling roots
Wet seedling roots in clean water, then apply
Thiophanate-methyl 4.1 SC/Kaolinite mixture to wet
roots.
Loblolly
Longleaf
Slash
Fusarium and
Rhizoctonia Root Rot
2.7 fl. oz. product
per 50 oz.
Kaolinite clay, plus
enough water to
make a slurry
Thoroughly cover seedling roots with Thiophanate-
methyl 4.1 SC/Kaolinite slurry.
Restrictions for Seedling Treatment:
-Do not apply mixture to seedling foliage.
-Avoid excess drying of roots or exposure to temperatures greater than 90° F or less than 32° F.
21
-Do not enter or allow workers to enter into treated areas during the restricted entry interval (REI) of 12 hours.
Note: Thiophanate Methyl 4.1 SC does not control Pythium or Phytophthora.
DIRECTIONS FOR USE THROUGH CHEMIGATION SYSTEMS
USE IN CALIFORNIA BY CHEMIGATION ONLY FOR BEANS, CUCURBITS
(CANTALOPE, CASABA, CUCUMBERS, MELONS, PUMPKINS, SQUASH,
WATERMELONS), PEANUTS, POTATOES, SOYBEANS, STRAWBERRIES, AND
SUGAR BEETS.
Apply this product only through sprinkler irrigation systems including center pivot, lateral move,
end tow, side (wheel) roll, traveler, solid set or hand move; or drip (mini-micro sprinklers, strip
tubing, trickle) irrigation systems. Do not apply this product through any other type of irrigation
system.
Crop injury, lack of effectiveness, or illegal pesticide residues in the crop can result from
nonuniform distribution of treated water.
If you have any questions about calibration, you must contact State Extension Service specialists,
equipment manufacturers or other experts.
A person knowledgeable of the chemigation system and responsible for its operation, or under the
supervision of the responsible person, shall shut the system down and make necessary
adjustments if needed. Do not connect chemigation system (including greenhouse systems) used
for pesticide irrigation to any public water system unless the pesticide label-prescribed safety
devices for public water systems are in place. Public water system means a system for the
provision of piped water for human consumption if such a system has at least 15 service
connections or regularly serves an average of at least 25 individuals daily at least 60 days out of
the year.
SYSTEM REQUIREMENTS
Chemigation systems connected to public water systems must contain a functional, reduced-
pressure zone, backflow preventer (RPZ) or the functional equivalent in the water supply line
upstream from the point of pesticide introduction. As an option to the RPZ, the water from the
public water system needs to be discharged into a reservoir tank prior to pesticide introduction.
There shall be a complete physical break (air gap) between the outlet end of the fill pipe and the
top or overflow rim of the reservoir tank of at least twice the inside diameter of the fill pipe.
Systems utilizing a pressurized water and pesticide injection system must meet the following
requirements:
The system must contain a functional check valve, vacuum relief valve, and low pressure drain
appropriately located on the irrigation pipeline to prevent water source contamination from
backflow.
The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve
to prevent the flow of fluid back toward the injection pump. The pesticide injection pipeline must
also contain a functional, normally closed, solenoid-operated valve located on the intake side of
the injection pump and connected to the system interlock to prevent fluid from being withdrawn
from the supply tank when the irrigation system is either automatically or manually shut down.
The system must contain functional interlocking controls to automatically shut off the pesticide
injection pump when the water pump motor stops.
The irrigation line or water pump must include a functional pressure switch which will stop the
22
water pump motor when the water pressure decreases to the point where pesticide distribution is
adversely affected.
Systems must use a metering pump (e.g., diaphragm pump) effectively designed and constructed
of materials that are compatible with pesticides and capable of being fitted with a system
interlock.
APPLICATION INSTRUCTIONS
Observe the requirements in the System Requirements section above.
Apply Thiophanate-methyl 4.1 SC only through systems containing anti-syphon and check valves
designed to prevent water source contamination or overflow of the mix tank and containing
interlocking controls between the metering device and the water pump to insure simultaneous
shut-off.
Maintain a gentle continuous agitation in mix tank during mixing and application to assure a
uniform suspension.
Greater accuracy in calibration and distribution will be achieved by injecting a larger volume of a
more dilute suspension per unit time.
Application of more than specified quantities of irrigation water per acre may result in decreased
product performance.
Where sprinkler distribution patterns do not overlap sufficiently, unacceptable disease control
may result.
Allow sufficient time for pesticide to be flushed through all lines and all nozzles before turning
off irrigation water.
Thiophanate-methyl 4.1 SC may be applied in conjunction with chemically neutral liquid
fertilizers. Application in conjunction with highly alkaline fertilizers, including aqueous
ammonia, is likely to cause a degradation of the pesticide, resulting in reduced performance and
needs to be avoided.
RESTRICTIONS:
Do not apply when wind speed favors drift, when system connections or fittings leak, when
nozzles do not provide uniform distribution or when lines containing the product cannot be
flushed and must be dismantled and drained. In a center pivot system, block the nozzle set nearest
the well/pivot/injection unit to prevent spray being applied to this area.
Do not apply when wind speed favors drift beyond the area intended for treatment.
SPRAY PREPARATION:
Remove scale, pesticide residues, and other foreign matter from the chemical tank and entire
injector system. Flush with clean water. Prepare a suspension of Thiophanate-methyl 4.1 SC in a
mix tank. Fill the tank with ½ or ¾ the desired amount of water. Start mechanical or hydraulic
agitation. Slowly add the required amount of Thiophanate-methyl 4.1 SC and then the remaining
volume of water.
Sprinkler Irrigation - Notes
Observe all System Requirements and Application Instructions above.
Set sprinkler system to deliver a maximum of 0.4 inch of water per acre. Volumes of water higher
than this may reduce efficacy. Start sprinkler and then uniformly inject the suspension of
Thiophanate-methyl 4.1 SC into the irrigation water line so as to deliver the desired rate per acre.
The suspension of Thiophanate-methyl 4.1 SC needs to be injected with a positive displacement
pump into the main line ahead of a right angle turn to ensure adequate mixing. When treatment
with Thiophanate-methyl 4.1 SC has been completed, do not irrigate the treated area for 24 to 48
hours to prevent washing the chemical off the crop.
23
Where sprinkler distributed patterns do not overlap sufficiently, unacceptable disease control may
result.
Check local restrictions and requirements regarding sprinkler irrigation applications, as they may
vary from state to state.
Drip (Mini-Micro Sprinklers, Strip Tubing, Trickle) Irrigation -N o t e s
Observe all System Requirements and Application Instructions above.
A pesticide supply tank is advised.
SEED TREATMENT USE
PRODUCT APPLICATION AND INSTRUCTIONS
Thiophanate-methyl 4.1 SC is an effective fungicide for seed treatment that provides
early season protection of seedlings against rhizoctonia. Seed needs to be sound and
well-cured before treatment.
Read and follow carefully all label directions of each combination product. When using
combinations of products, the most restrictive of label limitations and precautions must
be followed.
Seed Treatment Equipment: Thiophanate-methyl 4.1 SC may be used both for
commercial and for on-farm application. It can be applied with mechanical, slurry, or
mist-type seed treating equipment, as long as the equipment can be calibrated to
accurately and uniformly apply the product to seed without undue mechanical damage to
the seed. Uniform application to s eed is important for all seed treatment products.
Treatment of mechanically damaged seed or seed of low vigor or poor quality may result
in reduced germination. Treat and conduct germination tests on a small test sample of
seed before using this product on commercial quantities. Due to seed quality and seed
storage conditions beyond the control of Nippon Soda Co., Ltd. (Nisso), Nisso makes no
claims or guarantees as to germination of carry-over seed.
PRODUCT INSTRUCTIONS
Seed needs to be sound and well-cured before treatment. Refer to the label rates below.
Thiophanate-methyl 4.1 SC is typically diluted with water and/or mixed with other
products to attain an appropriate slurry application volume (fl. oz./cwt slurry rates) to
provide effective treating. The appropriate volume of slurry depends on crop, weather,
type of treater and other factors and needs to be adjusted as per normal treating practices
for the circumstances. Contact your local supplier or distributor representative for
specific directions.
TO ENSURE UNIFORMITY, MIX PRODUCT WELL BEFORE USE.
24
Thiophanate-methyl 4.1 SC plus water and/or other treatments need to be mixed
thoroughly prior to treating seed. Recalibrate treating equipment to compensate for the
required slurry rate to ensure all products are applied at the correct rate.
Restrictions:
Do not use Thiophanate-methyl 4.1 SC in combination with other seed treatment
products unless compatibility has been verified.
Crop(s) Application Rate
WHEAT, TRITICALE
For early season control of seed decay (Fusarium, Rhizoctonia)
and suppression of seedling blight (Fusarium, Rhizoctonia)
0.153 0.307 fl. oz/cwt
SOYBEANS
NOTE: Seed may be treated on a fl. oz./seed unit (to deliver a
target mg active ingredient/kernel) basis or and a per weight of
seed basis, as shown.
For early season control of seed decay (Phomopsis, Fusarium,
Rhizoctonia) and suppression of seedling blight (Fusarium,
Rhizoctonia)
Per Seed Unit:
0.072-0.144 fl. oz./seed unit
(140,000 seeds) (applies
0.0075-0.015 mg ai/seed)
OR
Per Seed Weight:
0.153 0.307 fl. oz./cwt
DRY BEANS and SNAP BEANS:
For early season control of seed decay (Phomopsis,
Rhizoctonia) and suppression of seedling blight (Fusarium,
Rhizoctonia)
0.153 0.307 fl. oz./cwt
Use higher rates for higher levels of seedling blight protection.
TREATED SEED LABELING
THE FEDERAL SEED ACT REQUIRES THAT BAGS CONTAINING TREATED
SEED MUST BE LABELED WITH THE FOLLOWING INFORMATION:
Ɣ7KLVbag contains seed treated with Thiophanate-methyl 4.1 SC containing
thiophanate-methyl. Do not use for food, feed, or oil purposes. Store away from feed
and food stuffs.”
ƔColoring Treated Seed
This product does not contain colorant. The purchaser of this product is responsible for
ensuring that all seed treated with this product are adequately dyed with a suitable color
to prevent its accidental use as food for man or feed for animals. Refer to 21CFR, part
25
2.25. Any colorant added to treated seed must be cleared for use under 40CFR, part
153.155. Alternatively, use in com bination with other colored seed treatment products
may provide adequate coloration.
LABELS FOR COMMERCIALLY TREATED SEED MUST ALSO INCLUDE THE
FOLLOWING ENVIRONMENTAL HAZARDS STATEMENTS:
Ɣ³(xposed treated seed may be hazardous to birds and wildlife. Dispose of all excess
treated seed and seed packaging or containers by burial away from bodies of water in
accordance with any local requirements. Cover, incorporate, or collect treated seeds
spilled during loading and planting. DO NOT contaminate bodies of water when
disposing of planting equipment wash water.”
THE U.S. ENVIRONMENTAL PROTECTION AGENCY REQUIRES THE
FOLLOWING STATEMENTS ON CONTAINERS CONTAINING TREATED SEED:
Ɣ³'2127DOOow children, pets or livestock to have access to treated seeds.”
Ɣ³'2127JUD]HRUIHHGOLYHVWRFNRQWUHDWHGDUHDVIRUGD\VDIWHUSODQWLQJ´
Ɣ³:HDUORQJSDQWVORQJ-sleeved shirt, shoes, socks and chemical-resistant gloves when
opening this bag or loading/pouring the treated seed.”
Ɣ³$IWHUWKHVHHGVKDYHEHHQSODQWHGGRQRWHQWHURUDOORZZRUNHUHQWU\LQWRWUHDWHG
areas during the restricted-entry interval (REI) of 12 hours. Exception: If the treated
seed is soil-injected or soil-incorporated, the Worker Protection Standard, under certain
circumstances, allows workers to enter the treated area if there will be no contact with
anything that has been treated. PPE required for early entry to treated areas that is
permitted under the Worker Protection Standard and that involves contact with anything
that has been treated, including plants, soil or water is: coveralls, chemical-resistant
gloves made of any waterproof material, and chemical-resistant footwear.”
USE RESTRICTIONS
Care must be exercised in the handling of treated seed. Augers used for handling treated
seed must not be used to move seed for feed, food or oil processing. Do not re-use bags
from treated seed to handle food or feed products.
STORAGE AND DISPOSAL
Do not contaminate water, food, or feed by storage and disposal.
STORAGE: Store in the original container in a dry area. Do not store in a manner where
cross-contamination with other pesticides, fertilizers, food or feed could occur. If spilled
during storage or handling, absorb with sand or other inert material and dispose of absorbent
in accordance with the Pesticide Disposal Instructions listed below.
DISPOSAL: Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture,
26
or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use
according to label instructions, contact your State Pesticide or Environmental Control Agency,
or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.
CONTAINER HANDLING
NON-REFILLABLE CONTAINERS
[For containers 5 gallons or less:]. Do not reuse or refill this container. Clean container
promptly after emptying. Triple rinse as follows: Empty the remaining contents into
application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill
the container ¼ full with water and recap. Shake for 10 seconds. Pour rinsate into application
equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after
the flow begins to drip. Repeat this procedure two more times. Then offer for recycling if
available, or puncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by
state and local authorities, by burning. If burned, stay out of smoke.
[For containers with a capacity > 5 gallons:]
Triple rinse or pressure rinse non-refillable containers too large to shake as follows:
Triple rinse as follows: Empty the remaining contents into application equipment or a mix
tank. Fill the container ¼ full with water. Replace and tighten closures. Tip container on its
side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand
the container on its end and tip it back and forth several times. Turn the container on its other
end and tip it back and forth several times. Empty the rinsate into application equipment or a
mix tank, or store rinsate for later use or disposal. Repeat this procedure two more times.
Pressure rinse as follows: Empty the remaining contents into application equipment or a mix
tank and continue to drain for 10 seconds after the flow begins to drip: Hold container upside
down over application equipment or mix tank and collect rinsate for later use or disposal.
Insert pressure rinsing nozzle in the side of the container, and rinse at about 40 PSI for at least
30 seconds. Drain for 10 seconds after the flow begins to drip.
Then offer for recycling if available, or puncture and dispose of in a sanitary landfill, or by
incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of
smoke.
REFILLABLE CONTAINERS
[Bulk Containers:] Refill this container with pesticide only. Do not reuse this container for
any other purpose. Cleaning the container before final disposal is the responsibility of the
person disposing of the container. Cleaning before refilling is the responsibility of the refiller.
To clean the container before final disposal, empty the remaining contents from this container
into application equipment or mix tank. Fill the container about 10 percent full with water.
Agitate vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into
application equipment or rinsate collection system. Repeat this rinsing procedure two more
times.
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When the container is empty, replace the cap and seal all openings that have been opened
during use; and return to the point of purchase, or to a designated location named at the time
of purchase of this product. Prior to refilling, inspect carefully for damage such as cracks,
punctures, abrasions, worn-out threads and closure devices. Check for leaks after refilling and
before transporting. Do not transport if this container is damaged or leaking. If the container is
damaged or leaking, call Chem-Trec. If the container is damaged and leaking or material has
been spilled, follow these procedures:
• Cover spill with absorbent material.
• Sweep into disposal container.
• Wash area with detergent and water and follow with clean water rinse.
• Do not allow to contaminate water supplies.
• Dispose of according to instructions.
If not returned to the point of purchase or to a designated location, clean empty container as
instructed above and offer for recycling. Disposal of this container must be in compliance with
state and local regulations.
IMPORTANT: READ BEFORE USE
Read the entire Directions for Use, Conditions, Disclaimer of Warranties and Limitations
of Liability before using this product. If terms are not acceptable, return the unopened
product container at once.
By using this product, user or buyer accepts the following Conditions, Disclaimer of
Warranties and Limitations of Liability.
CONDITIONS: The directions for use of this product are believed to be adequate and
must be followed carefully. However, it is impossible to eliminate all risks associated
with the use of this product. Crop injury, ineffectiveness or other unintended
consequences may result because of such factors as weather conditions, presence of other
materials, or the manner of use or application, all of which are beyond the control of
Nippon Soda Co., Ltd. All such risks shall be assumed by the user or buyer.
DISCLAIMER OF WARRANTIES: To the extent allowable by applicable laws Nippon
Soda Co., Ltd. makes no other warranties, express or implied, of merchantability or of
fitness for a particular purpose or otherwise, that extend beyond the statements made on
this label. No agent of Nippon Soda Co., Ltd. is authorized to make any warranties
beyond those contained herein or to modify the warranties contained herein. To the
extent allowable by applicable laws Nippon Soda Co., Ltd. disclaims any liability
whatsoever for special, incidental or consequential damages resulting from the use or
handling of this product.
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SEED TREATMENT: Treatment of seed, especially seed that is mechanically damaged
or seed known to be of low vigor and poor quality, may result in reduced germination
and/or reduction of seed and seedling vigor. Treat and conduct germination tests on a
small test sample of seed before treating commercial quantities with a selected chemical
treatment that includes this product. Due to seed quality and seed storage conditions
beyond the control of Nippon Soda Co., Ltd. (Nisso), Nisso makes no claims or
guarantees as to germination of carry-over seed.
LIMITATIONS OF LIABILITY: To the extent allowable by applicable laws the
exclusive remedy of the user or buyer for any and all losses, injuries or damages resulting
from the use or handling of this product, whether in contract, warranty, tort, negligence,
strict liability or otherwise, shall not exceed the purchase price paid, or at Nippon Soda
Co., Ltd.s election, the replacement of product.
Nippon Soda Co., Ltd.
c/o Nisso America Inc.
88 Pine St., 14
th FL.
New York, NY 10005