a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
1713 lines
56 KiB
Markdown
1713 lines
56 KiB
Markdown
# THIOPHANATE-METHYL 4.1 SC FUNGICIDE
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- EPA Reg No: **8033-129**
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- Registrant: NIPPON SODA CO., LTD.
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- Signal word: Caution
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- Active ingredients: Thiophanate-methyl (41.3%)
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- Label accepted: 2019-10-02
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/008033-00129-20191002.pdf
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---
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
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WASHINGTON, DC 20460
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Fast Track Label Acceptable v.20150320
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OFFICE OF CHEMICAL SAFETY
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AND POLLUTION PREVENTION
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October 2, 2019
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John J. Wrubel
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Director of Regulatory Affairs
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Nippon Soda Co.
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c/o Nisso America Inc.
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88 Pine Street, 14th Floor
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New York, NY 10005
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Subject: Label Amendment – Updating Resistance Management to comply with PRN
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2017-1
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Product Name: Thiophanate-methyl 4.1 SC Fungicide
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EPA Registration Number: 8033-129
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Application Date: 8/21/2018
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Decision Number: 555693
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Dear Mr Wrubel:
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The amended label referred to above, submitted in connection with registration under the Federal
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Insecticide, Fungicide and Rodenticide Act, as amended, is acceptable. This approval does not
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affect any conditions that were previously imposed on this registration. You continue to be
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subject to existing conditions on your registration and any deadlines connected with them.
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A stamped copy of your labeling is enclosed for your records. This labeling supersedes all
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previously accepted labeling. You must submit one copy of the final printed labeling before you
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release the product for shipment with the new labeling. In accordance with 40 CFR 152.130(c),
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you may distribute or sell this product under the previously approved labeling for 18 months
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from the date of this letter. After 18 months, you may only distribute or sell this product if it
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bears this new revised labeling or subsequently approved labeling. “To distribute or sell” is
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defined under FIFRA section 2(gg) and its implementing regulation at 40 CFR 152.3.
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Should you wish to add/retain a reference to the company’s website on your label, then please be
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aware that the website becomes labeling under the Federal Insecticide Fungicide and Rodenticide
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Act and is subject to review by the Agency. If the website is false or misleading, the product
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would be misbranded and unlawful to sell or distribute under FIFRA section 12(a)(1)(E). 40
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CFR 156.10(a)(5) list examples of statements EPA may consider false or misleading. In addition,
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regardless of whether a website is referenced on your product’s label, claims made on the
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website may not substantially differ from those claims approved through the registration process.
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Therefore, should the Agency find or if it is brought to our attention that a website contains false
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or misleading statements or claims substantially differing from the EPA approved registration,
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the website will be referred to the EPA’s Office of Enforcement and Compliance.
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Page 2 of 2
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EPA Reg. No. 8033-129
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Decision No. 555693
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Your release for shipment of the product constitutes acceptance of these conditions. If these
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conditions are not complied with, the registration will be subject to cancellation in accordance
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with FIFRA section 6. If you have any questions, please contact Nathan Mellor by phone at 703-
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347-8562, or via email at mellor.nathan@epa.gov.
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Shaja B. Joyner, Product Manager 20
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Fungicide-Herbicide Branch
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Registration Division 7505P
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Enclosure
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1
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Thiophanate-
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methyl
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GROUP 1 FUNGICIDE
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Thiophanate-Methyl 4.1 SC
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Fungicide
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ACTIVE INGREDIENT:
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Thiophanate-methyl (dimethyl[1,2-phenylene)-
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bis(iminocarbonothioyl)]bis[carbamate])* . . . . . . . . . . . . . . . . . . . . . . . 41. 3%
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OTHER INGREDIENTS: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58. 7%
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TOTAL: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100.0%
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Contains 4.11 pounds thiophanate-methyl per gallon.
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*Also known as dimethyl 4,4’-o-phenylenebis[3-thioallophanate]
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KEEP OUT OF REACH OF CHILDREN
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CAUTION
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FIRST AID
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If on skin or clothing:
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x Take off contaminated clothing.
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x Rinse skin immediately with plenty of water for 15-20 minutes.
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x Call a poison control center or doctor for treatment advice.
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If swallowed:
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x Call a poison control center or doctor immediately for treatment advice.
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x Have person sip a glass of water if able to swallow.
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x Do not induce vomiting unless told to by a poison control center or doctor.
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x Do not give anything by mouth to an unconscious person.
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Have the product container or label with you when calling a poison control center or doctor or
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going for treatment. Contact the Rocky Mountain Poison Control Center at 1-866-673-6671
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for emergency medical treatment information.
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**[See additional precautionary statements and directions for use inside booklet.]
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**[Read the label carefully before opening the container.]
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**[Peel back book here.]
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**Note to EPA Product Manager: Text in brackets [ ] above is optional.
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EPA Reg. No.8033-129 EPA Est. No.
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NET CONTENTS: __________ Gallons Batch/Lot # ____________
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Nippon Soda Co., Ltd. c/o Nisso America Inc.
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88 Pine St., 14th floor, New York, NY 10005
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Notification – Resistance Management (PR Notice 2017-1) Revised 9-26-19
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10/02/2019
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8033-129
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2
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PRECAUTIONARY STATEMENTS
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HAZARDS TO HUMANS AND DOMESTIC ANIMALS
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CAUTION
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Harmful if absorbed through the skin or if swallowed. Avoid contact with skin, eyes or
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clothing.
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PERSONAL PROTECTIVE EQUIPMENT (PPE)
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Some materials that are chemical-resistant to this product are barrier laminate, nitrile
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UXEEHUPLOVbutyl rubber PLOV, neoprene rubber PLOV, polyvinyl
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chloride (PVC) PLOV, and Viton PLOV.
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Handlers mixing, loading, and applying the product as a dip (including application of
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product in Kaolinite clay to conifer seedling roots) must wear:
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x Coveralls over long-sleeved shirt and long pants,
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x Chemical-resistant gloves,
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x Chemical-resistant footwear plus socks,
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x Chemical-resistant apron.
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All other mixers, loaders, and applicators must wear:
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x Long-sleeved shirt and long pants,
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x Shoes plus socks,
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x Chemical-resistant gloves,
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x Chemical-resistant apron for mixers, loaders, and other handlers exposed to the
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concentrate.
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Seed treatment applicators and other seed treatment handlers must wear:
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x Long-sleeved shirt and long pants,
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x Shoes plus socks,
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x Chemical-resistant gloves for all mixers and loaders and for applicators using
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hand-held equipment,
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x Chemical-resistant apron for mixers, loaders, and other handlers exposed to the
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concentrate.
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Note: Persons involved in bagging treated seed, sewing or moving bags of treated seed,
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or cleaning up bagging areas or seed treatment equipment are pesticide handlers and must
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wear the PPE required on this label for pesticide handlers.
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3
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User Safety Requirements
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Follow manufacturer’s instructions for cleaning/maintaining PPE. If no such instructions
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for washables exist, use detergent and hot water. Keep and wash PPE separately from
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other laundry. Discard clothing and other absorbent materials that have been drenched or
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heavily contaminated with this product’s concentrate. Do not reuse them.
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ENGINEERING CONTROLS
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When handlers use enclosed cabs in a manner that meets the requirements listed in the
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Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)],
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the handler PPE requirements may be reduced or modified as specified in the WPS.
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USER SAFETY RECOMMENDATIONS
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Users should wash hands before eating, drinking, chewing gum, using tobacco, or using
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the toilet.
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Users should remove clothing/PPE immediately if pesticide gets inside. Then wash
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thoroughly and put on clean clothing.
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Users should remove PPE immediately after handling this product. Wash the outside of
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gloves before removing. As soon as possible, wash thoroughly and change into clean
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clothing.
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ENVIRONMENTAL HAZARDS
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Do not apply directly to water, or to areas where surface water is present or to intertidal
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areas below the mean high-water mark. Runoff from treated areas may be hazardous to
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aquatic organisms in neighboring areas. Do not contaminate water when disposing of
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equipment wash water or rinsate.
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DIRECTIONS FOR USE
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SHAKE WELL BEFORE USING
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It is a violation of Federal law to use this product in a manner inconsistent with its
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labeling.
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Do not apply this product in a way that will contact workers or other persons, either
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directly or through drift. Only protected handlers may be in the area during application.
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For any requirements specific to your State or Tribe, consult the agency responsible for
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pesticide regulation.
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Do not apply when wind speed favors drift beyond the area intended for treatment.
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4
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AGRICULTURAL USE REQUIREMENTS
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Use this product only in accordance with its labeling and with the Worker Protection Standard,
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40 CFR part 170. This Standard contains requirements for the protection of agricultural
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workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides.
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It contains requirements for training, decontamination, notification, and emergency assistance.
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It also contains specific instructions and exceptions pertaining to the statements on this label
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about personal protective equipment (PPE), and restricted-entry interval. The requirements in
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this box only apply to uses of this product that are covered by the Worker Protection Standard.
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Do not enter or allow worker entry into treated areas during the restricted entry interval (REI).
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Exemption: The Worker Protection Standard, under certain circumstances, allows workers to
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enter the treated area if there will be no contact with anything that has been treated.
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Do not enter or allow workers entry into treated areas during the restricted-entry interval
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(REI). The REI for each crop is listed in the directions for use associated with that crop.
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Exemption: If this product is applied by drenching or if treated seed is soil-injected or soil
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incorporated, the Worker Protection Standard, under certain circumstances, allows workers to
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enter the treated area if there will be no contact with anything that has been treated.
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PPE required for early entry to treated areas that is permitted under the Worker Protection
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Standard and that involves contact with anything that has been treated, including plants, soil,
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or water, is:
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x Coveralls over long-sleeved shirt and long pants,
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x Chemical-resistant gloves made of any waterproof material,
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x Chemical-resistant footwear plus socks,
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x Chemical-resistant headgear for overhead exposures.
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PRODUCT APPLICATION AND INSTRUCTIONS
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RESISTANCE MANAGEMENT
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For resistance management, Thiophanate-Methyl 4.1 SC contains a Group 1 fungicide.
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Any fungal population may contain individuals naturally resistant to Thiophanate-Methyl
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4.1 SC and other Group 1 fungicides. A gradual or total loss of pest control may occur
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over time if these fungicides are used repeatedly in the same fields. Appropriate
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resistance-management strategies should be followed.
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To delay fungicide resistance, take one or more of the following steps:
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• Rotate the use of Thiophanate-Methyl 4.1 SC Fungicide or other Group 1 fungicides
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within a growing season sequence with different groups that control the same pathogens.
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• Use tank mixtures with fungicides from a different group that are equally effective on
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the target pest when such use is permitted. Use at least the minimum application rate as
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labeled by the manufacturer.
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5
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• Adopt an integrated disease management program for fungicide use that includes
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scouting, uses historical information related to pesticide use, and crop rotation, and which
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considers host plant resistance, impact of environmental conditions on disease
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development, disease thresholds, as well as cultural, biological and other chemical
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control practices.
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• Where possible, make use of predictive disease models to effectively time fungicide
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applications. Note that using predictive models alone is not sufficient to manage
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resistance.
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• Monitor treated fungal populations for resistance development.
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• Contact your local extension specialist or certified crop advisor for any additional
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pesticide resistance-management and/or IPM directions for specific crops and pathogens.
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• For further information or to report suspected resistance contact Nippon Soda Co., Ltd.
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at 212-490-0350. You can also contact your pesticide distributor or university extension
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specialist to report resistance."
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INSTRUCTIONS
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Apply Thiophanate-methyl 4.1 SC with ground or aerial equipment, using sufficient
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volume of spray to provide thorough coverage. Continuous agitation is required to keep
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the material in suspension. Nippon Soda Co., Ltd. does not advise tank mixes with
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highly alkaline pesticides, including Bordeaux mixture or lime sulfur. No claim of
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compatibility with other pesticides is implied. Use the higher rate under conditions of
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severe disease pressure. Also, s ee local State Extension Service directions for application
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schedules.
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Use the fl. oz./Acre rate for concentrate sprays (less than 400 gallons on apples, less than
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300 gallons on stone fruit). Use the fl. oz./100 gal. rate for dilute ground applications.
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For aerial applications, use a minimum of 5 gallons/A for row crops, and a minimum of
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10 gallons/A for tree crops. For ground applications use a minimum of 20 gallons/A for
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row crops and 30 gallons/A for tree crops. Higher spray volume will generally result in
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better coverage and better disease control. Lack of control when using below minimum
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spray volumes is solely at the risk of the applicator/user, including use of electrostatic
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sprayers.
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Chemigation instructions follow. Do not apply through any irriga tion system unless
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these instructions are followed.
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For crops without labeled uses of thiophanate-methyl, observe a 30-day plantback
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restriction.
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Use on all labeled non-bearing tree fruit and tree nuts: Thiophanate-methyl 4.1 SC
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may be used for control of the diseases listed on the label for these crops during the non-
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6
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bearing years of new plantings, and on nursery stock. All use directions and limitations
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must be followed, except for the PHI, which is not applicable. Begin applications as
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disease is first observed or expected. Tank mixing with a protectant fungicide is strongly
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advised for resistance management.
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Crops/
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REI Diseases
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FL.
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OZ./
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Acre
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(lb.
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a.i./A)
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FL.
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OZ./
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100 Gal
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Application Instructions
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Almonds
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Do not enter or
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||
allow worker
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entry into
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treated areas
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during the
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restricted
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||
entry interval
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(REI) of 3 days.
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Brown Rot
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Blossom Blight
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(Monilinia)
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Scab
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(Cladosporium)
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Jacket Rot
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(Monilinia,
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Sclerotinia, Botrytis)
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Leaf Blight
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(Seimatosporium)
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21.8-32.7
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(0.7 –
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1.05)
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Apply as needed at 10 to 14-day intervals
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between pink bud and petal fall.
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Thiophanate-methyl 4.1 SC may be
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applied alone at pink bud for Brown Rot
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control. For all other applications,
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Thiophanate-methyl 4.1 SC needs to be
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applied with a contact fungicide for broad
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spectrum control and resistance
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management.
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Restrictions:
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||
-Do not apply more than 32.7 fl. oz./A
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||
(1.05 lb ai/A) per application.
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||
-Do not apply more than a total of 65.4 fl.
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||
oz. of product (2.1 lbs a.i.)/A/year.
|
||
-The minimum retreatment interval is ten
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||
(10) days.
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||
-Do not apply more than three (3)
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||
applications per year.
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||
Apples
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||
Do not enter or
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||
allow worker
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||
entry into
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treated areas
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during the
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restricted-
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entry interval
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(REI) of 2 days.
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Apple Scab
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(Venturia)
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Black Pox***
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(Helminthosporium
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papulosum)
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Flyspeck
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(Zygophiala)
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Powdery Mildew
|
||
(Podosphaera)
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||
Sooty Blotch (Gloeodes)
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||
Black Rot
|
||
(Botryosphaeria
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||
obtusa)
|
||
Brooks Fruit Spot
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||
(Mycosphaerella)
|
||
White Rot***
|
||
(Botryosphaeria
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dothidia)
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16.3-21.8
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(0.52- 0.7)
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||
[in CA use
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32.7]
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(1.1)
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4.1-5.5
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Apply at 5 to 10-day intervals from green
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||
tip through petal fall; continue at 7 to
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||
14-day intervals in cover sprays.
|
||
Restrictions:
|
||
-Do not apply more than 21.8 fl. oz./A
|
||
(0.7 lb. a.i./A) per application.
|
||
-In California, do not apply more than
|
||
32.7 fl. oz./A (1.1 lb. a.i./A) per
|
||
application.
|
||
-Do not apply more than a total of 87.2 fl.
|
||
oz. of product (2.8 lbs a.i.)/A/year.
|
||
-Pre-harvest interval: 1 day
|
||
|
||
7
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||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
-The minimum retreatment interval is
|
||
five (5) days.
|
||
-Do not apply more than five (5)
|
||
applications per year.
|
||
Follow resistance management guidelines
|
||
under Directions for Use.
|
||
Pre-Harvest use to control Post-Harvest Diseases on Apples
|
||
Storage Rot
|
||
Blue Mold
|
||
(Penicillium
|
||
expansum)
|
||
Gray Mold
|
||
(Botrytis cinerea)
|
||
Bulls-Eye Rot
|
||
(Neofabraea spp.)
|
||
16.3–21.8
|
||
(0.52-0.7)
|
||
4.1-5.5
|
||
Apply as a pre-harvest spray within 2
|
||
weeks to 3 days of harvest.
|
||
Thorough coverage of the fruit is
|
||
required. Application closer to harvest
|
||
may provide better efficacy.
|
||
For resistance management, do not use a
|
||
benzimidazole fungicide post-harvest
|
||
following Thiophanate-methyl 4.1 SC
|
||
pre-harvest application. Application of a
|
||
non-benzimidazole post-harvest
|
||
fungicide will provide additional
|
||
protection from post-harvest diseases.
|
||
Restrictions:
|
||
-Do not apply more than 21.8 fl. oz./A
|
||
(0.7 lb. a.i./A) per application.
|
||
-Do not apply more than a total of 87.2
|
||
fl.oz. of product (2.8 lbs a.i.)/A/year.
|
||
-The minimum retreatment interval is
|
||
five (5) days.
|
||
-Do not apply more than five (5)
|
||
|
||
8
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
applications per year.
|
||
-Pre-harvest interval: 1 day
|
||
Beans, dry and
|
||
succulent
|
||
Including:
|
||
Lima bean
|
||
Snap bean
|
||
Kidney bean
|
||
Mung bean
|
||
Navy bean
|
||
Pinto bean
|
||
Wax bean
|
||
Broad bean
|
||
Fava bean
|
||
Asparagus bean
|
||
Blackeyed pea
|
||
Cowpea
|
||
Sweet lupine
|
||
White lupine
|
||
White Sweet
|
||
lupine
|
||
Grain lupine
|
||
Chick pea
|
||
Garbanzo bean
|
||
Do not enter or
|
||
allow worker
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted-
|
||
entry interval
|
||
(REI) of 24
|
||
hours for
|
||
succulent beans
|
||
and 3 days for
|
||
dry beans.
|
||
White Mold
|
||
(Sclerotinia)
|
||
Gray Mold
|
||
(Botrytis)
|
||
Anthracnose
|
||
(Colletotrichum)
|
||
32.7-43.6
|
||
(1.1-1.4)
|
||
OR
|
||
21.8-32.7
|
||
(0.7-1.1)
|
||
For one application: Apply when 100%
|
||
of plants have at least one open bloom or
|
||
when conditions are favorable for disease
|
||
development.
|
||
OR
|
||
For multiple applications: Make the first
|
||
application when 10% to 30% of plants
|
||
have at least one open bloom and follow
|
||
with sequential applications on a 4 to
|
||
7day interval. Apply prior to the
|
||
development of disease for best results.
|
||
Restrictions:
|
||
-Do not apply more than 43.6 fl.oz./A
|
||
(1.4 lb a.i./A per application.
|
||
-Do not apply more than 87.2 of product
|
||
(2.8 lbs a.i.)/A/year.
|
||
- The minimum retreatment interval is
|
||
four (4) days.
|
||
-Do not apply more than five (5)
|
||
applications per year.
|
||
-Pre-harvest interval: California only,
|
||
14 days for succulent beans, 28 days for
|
||
dry beans and lima beans.
|
||
-Pre-harvest interval: all other States,
|
||
14 days for succulent beans and lima
|
||
beans, 28 days for dry beans.
|
||
|
||
9
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
Cucurbits:
|
||
Cantaloupe,
|
||
Casaba,
|
||
Cucumbers,
|
||
Melons,
|
||
Pumpkins,
|
||
Summer and
|
||
Winter Squash,
|
||
and
|
||
Watermelons
|
||
Do not enter or
|
||
allow worker
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted-
|
||
entry interval
|
||
(REI) of 24
|
||
hours
|
||
.
|
||
Thiophanate-methyl 4.1 SC can be used
|
||
in a tank mix with mancozeb or
|
||
chlorothalonil for additional disease
|
||
control and resistance management. It is
|
||
the pesticide user’s responsibility to
|
||
ensure that all products are registered for
|
||
the intended use. Read and follow the
|
||
applicable restrictions and limitations and
|
||
directions for use on all product labels
|
||
involved in tank mixing. Users must
|
||
follow the most restrictive directions for
|
||
use and precautionary statements of each
|
||
product in the tank mixture.
|
||
Follow resistance management guidelines
|
||
under Directions for Use.
|
||
Restrictions:
|
||
-Do not apply more than 10.9 fl. oz./A
|
||
(0.35 lb. a.i./A) per application.
|
||
-Do not apply more than 65.4 fl.oz. of
|
||
product (2.1 lbs a.i.)/A/year from any
|
||
combination of application timings.
|
||
-The minimum retreatment interval is
|
||
four (4) days.
|
||
-Do not apply more than five (5)
|
||
applications per year.
|
||
-Pre-harvest interval: 1 day
|
||
Acremonium/
|
||
Cephalosporium
|
||
Hypocotyl Rot
|
||
10.9
|
||
(0.35)
|
||
Apply in-furrow, on top of the seeds at
|
||
planting.
|
||
Restrictions:
|
||
-Do not use less than 10 gallons of water
|
||
per acre.
|
||
|
||
10
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
Anthracnose***
|
||
(Colletotrichum)
|
||
Gummy Stem Blight***
|
||
(Didymella)
|
||
Powdery Mildew
|
||
(Erysiphe,
|
||
Sphaerotheca)
|
||
Target Spot***
|
||
(Corynespora)
|
||
10.9
|
||
(0.35)
|
||
Begin applications when plants begin to
|
||
run or when disease first appears, and
|
||
repeat at 7-14 day intervals or as needed.
|
||
For Target Spot, use at 7-day intervals as
|
||
needed.
|
||
Restrictions:
|
||
-The minimum retreatment interval is
|
||
seven (7) days.
|
||
-Do not apply more than six (6)
|
||
applications per year.
|
||
Belly Rots***
|
||
(Rhizoctonia,
|
||
Fusarium)
|
||
10.9
|
||
(0.35)
|
||
Apply in sufficient volume to allow
|
||
runoff to the soil. Will not control
|
||
Pythium or Phytophthora.
|
||
Suppression of Vine
|
||
Decline
|
||
(Monosporascus)
|
||
Charcoal Rot
|
||
(Macrophomina)
|
||
10.9
|
||
(0.35)
|
||
Apply through buried drip irrigation
|
||
(chemigation) to the root zone. For
|
||
disease suppression, apply at 14-day
|
||
intervals, beginning at emergence and
|
||
continuing to harvest.
|
||
Applications weekly or biweekly,
|
||
beginning 4 to 6 weeks prior to harvest
|
||
will also offer suppression, but may not
|
||
be as effective as a season-long program.
|
||
Restrictions:
|
||
-The minimum retreatment interval is
|
||
fourteen (14) days.
|
||
-Do not apply more than six (6)
|
||
applications per year.
|
||
Garlic
|
||
(clove
|
||
treatment)
|
||
Penicillium Clove Rot
|
||
21.8
|
||
Completely immerse garlic cloves in
|
||
suspension for at least 5 minutes.
|
||
Continuously agitate the solution tank by
|
||
hydraulic or mechanical means.
|
||
After treatment, remove cloves from
|
||
solution and drain.
|
||
Dry cloves after treatment and prior to
|
||
planting.
|
||
|
||
11
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
Onions*
|
||
Garlic
|
||
(In furrow)
|
||
Do not enter or
|
||
allow worker
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted entry
|
||
interval (REI)
|
||
of 3 days.
|
||
White Rot (Sclerotium
|
||
cepivorum) 43.6
|
||
(1.4)
|
||
broadcast
|
||
Spray directly into the open furrow at the
|
||
time of planting seed, sets or bulbs. Not
|
||
for this use through any type of irrigation
|
||
system.
|
||
Restrictions:
|
||
-Do not apply more than 43.6 fl. oz./A
|
||
(1.4 lb. a.i./A) per application.
|
||
-Do not apply more than 43.6 fl. oz. of
|
||
product (1.4 lbs a.i.)/A/year.
|
||
Do not apply more than one (1)
|
||
application per year.
|
||
Peanuts
|
||
Do not enter or
|
||
allow worker
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted
|
||
entry interval
|
||
(REI) of 24
|
||
hours.
|
||
Early Leaf Spot
|
||
(Cercospora)
|
||
Late Leaf Spot
|
||
(Cercsoporidium)
|
||
Rust
|
||
(Puccinia)
|
||
Limb Rot (Rhizoctonia)
|
||
Web Blotch
|
||
(Ascochyta)
|
||
10.9
|
||
(0.35)
|
||
Begin applications when disease first
|
||
appears and repeat at 14-day intervals as
|
||
needed.
|
||
Restrictions:
|
||
-Do not apply more than 10 fl. oz./A
|
||
(0.35 lb. a.i./A) per application.
|
||
-Do not apply more than 43.6 fl.oz. of
|
||
product (1.4 lbs a.i.)/A/year.
|
||
-The minimum retreatment interval is
|
||
fourteen (14) days.
|
||
-Do not apply more than four (4)
|
||
applications per year.
|
||
-Pre-harvest interval: 14 days
|
||
-Thiophanate-methyl 4.1 SC must not be
|
||
used alone. Use only in combination
|
||
with a non-benzimidazole fungicide like
|
||
chlorothalonil.
|
||
-Follow resistance management
|
||
guidelines under Directions for Use.
|
||
Pecans
|
||
Do not enter or
|
||
allow worker
|
||
Brown Spot
|
||
(Cercospora)
|
||
Downy Spot
|
||
(Mycosphaerella)
|
||
Liver Spot
|
||
21.8
|
||
(0.7)
|
||
Begin applications when first leaves are
|
||
showing and repeat at 3 to 4-week
|
||
intervals until shuck split. Do not apply
|
||
after shuck split.
|
||
|
||
12
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted
|
||
entry interval
|
||
(REI) of 3 days.
|
||
(Gnomonia)
|
||
Powdery Mildew
|
||
(Microsphaera)
|
||
Scab
|
||
(Fusicladium)
|
||
Stem End Blight
|
||
(Botryosphaeria)
|
||
Zonate Leaf Spot
|
||
(Cristulariella)
|
||
Restrictions:
|
||
-Do not apply more than 21.8 fl. oz./A
|
||
(0.7 lb. a.i./A) per application.
|
||
-Do not apply more than 65.4 fl. oz. of
|
||
product (2.1 lbs a.i.)/A/year.
|
||
-The minimum retreatment interval is
|
||
twenty one (21) days.
|
||
-Do not apply more than three (3)
|
||
applications per year.
|
||
-Pre-harvest interval: 1 day
|
||
-Follow resistance management
|
||
guidelines under Directions for Use.
|
||
Pistachios
|
||
Do not enter or
|
||
allow worker
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted entry
|
||
interval (REI)
|
||
of 3 days.
|
||
Shoot Blight
|
||
(Botrytis, Botryosphaeria) 32.7-43.6
|
||
(1.1-1.4)
|
||
Apply at bloom.
|
||
Apply in a minimum of 100 gallons per
|
||
acre by ground or 20 gallons per acre by
|
||
air.
|
||
For aerial application, fly over every row
|
||
or center.
|
||
Restrictions:
|
||
-Do not apply more than 43.6 fl. oz./A
|
||
(1.4 lb. a.i./A) per application.
|
||
-Do not apply more than 43.6 fl. oz. of
|
||
product (1.4 lbs a.i.)/A/year.
|
||
Do not apply more than one (1)
|
||
application per year.
|
||
|
||
13
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
Potatoes
|
||
Do not enter or
|
||
allow worker
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted
|
||
entry interval
|
||
(REI) of 2 days.
|
||
White Mold
|
||
(Sclerotinia sclerotiorum) 21.8-32.7
|
||
(0.7-1.1)
|
||
Make first application at row closure to
|
||
full bloom of the primary flower clusters
|
||
(prior to petal drop). Repeat the
|
||
application within 7-14 days and at 7-14
|
||
day intervals if conditions for disease
|
||
development are favorable.
|
||
Thorough coverage of the flowers, stems,
|
||
and branches is essential for disease
|
||
control.
|
||
Use a minimum of 6 gallons/A for aerial
|
||
application.
|
||
Apply prior to the development of
|
||
disease for the best results.
|
||
Restrictions:
|
||
-Do not apply more than 32.7 fl. oz./A
|
||
(1.1 lb. a.i./A) per application.
|
||
-Do not apply more than 87.2 fl. oz. of
|
||
product (2.8 lbs a.i.)/A/year.
|
||
-The minimum retreatment interval is
|
||
seven (7) days.
|
||
-Do not apply more than four (4)
|
||
applications per year.
|
||
-Pre-harvest interval: 21 days
|
||
-May be tank mixed with mancozeb for
|
||
Early and Late Blight control. It is the
|
||
pesticide user’s responsibility to ensure
|
||
that all products are registered for the
|
||
intended use. Read and follow the
|
||
applicable restrictions and limitations and
|
||
directions for use on all product labels
|
||
involved in tank mixing. Users must
|
||
follow the most restrictive directions for
|
||
use and precautionary statements of each
|
||
product in the tank mixture.
|
||
|
||
14
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
Soybeans
|
||
Do not enter or
|
||
allow worker
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted
|
||
entry interval
|
||
(REI) of 24
|
||
hours.
|
||
Restrictions:
|
||
-Do not apply more than 21.8 fl. oz./A
|
||
(0.7 lb. a.i./A) per application.
|
||
-Do not apply more than 43.6 fl. oz. of
|
||
product (1.4 lbs a.i.)/A/year.
|
||
-The minimum retreatment interval is
|
||
seven (7) days.
|
||
-Do not apply more than two (2)
|
||
applications per year.
|
||
-Pre-harvest interval: 21 days
|
||
-Do not graze or feed treated vines or hay
|
||
to livestock.
|
||
Anthracnose
|
||
(Colletotrichum)
|
||
Brown Spot
|
||
(Septoria)
|
||
Frogeye Leaf Spot
|
||
(Cercospora)
|
||
Pod and Stem Blight
|
||
(Diaporthe, Phomopsis)
|
||
Purple Seed Stain
|
||
(Cercospora)
|
||
10.9-21.8
|
||
(0.35-0.7)
|
||
Apply from full bloom to when pods are
|
||
ǩ
|
||
|
||
WRó
|
||
|
||
LQOHQJWK0DNHDVHFRQG
|
||
application 14 to 21 days later. Do not
|
||
make the second application later than 14
|
||
days after pods average ¼'' in length or
|
||
when beans form in the pod. Use the high
|
||
rate under severe disease pressure.
|
||
21.8
|
||
(0.7)
|
||
FOR SEED BEANS ONLY
|
||
-For seed quality, make a single
|
||
application when beans form in the pod.
|
||
White Mold
|
||
(Sclerotinia) 16.3-21.8
|
||
(0.52-0.7)
|
||
Make one application at early bloom (R-1
|
||
to R-2 stage) followed by a second
|
||
application 7-14 days later if conditions
|
||
are favorable for continued disease
|
||
pressure.
|
||
Thorough coverage of the flowers, stems,
|
||
and branches is essential for disease
|
||
control.
|
||
Use a minimum of 5 gallons water/A by
|
||
air.
|
||
Aerial Blight
|
||
(suppression)
|
||
21.8
|
||
(0.7)
|
||
Make initial application when disease
|
||
threatens and repeat 14-21 days later if
|
||
needed.
|
||
|
||
15
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
Stone Fruit
|
||
Do not enter or
|
||
allow worker
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted
|
||
entry interval
|
||
(REI) of 2 days.
|
||
Restrictions:
|
||
-Do not apply more than 32.7 fl. oz./A
|
||
(1.1 lb. a.i./A) per application.
|
||
-Do not apply more than 87.2 fl. oz. of
|
||
product (2.8 lbs a.i.)/A/year.
|
||
-The minimum retreatment interval is ten
|
||
(10) days.
|
||
Do not make more than four (4)
|
||
applications per year.
|
||
-Pre-harvest interval: 1 day
|
||
-Follow resistance management
|
||
guidelines under Directions for Use.
|
||
Apricots Brown Rot Blossom
|
||
Blight
|
||
Fruit Brown Rot
|
||
(Monilinia)
|
||
21.8-32.7
|
||
(0.7-1.1)
|
||
[in CA use
|
||
32.7]
|
||
(1.1)
|
||
7.3-10.9
|
||
Apply at early bloom (red bud). Make a
|
||
second application at full bloom.
|
||
If needed, under severe disease pressure,
|
||
apply additional sprays at 10 to 14-day
|
||
intervals between full bloom and final
|
||
pre-harvest sprays.
|
||
Cherries
|
||
Sweet and
|
||
Sour
|
||
Brown Rot
|
||
Blossom Blight
|
||
Fruit Brown Rot
|
||
(Monilinia)
|
||
21.8-32.7
|
||
(0.7-1.1)
|
||
[in CA use
|
||
32.7]
|
||
(1.1)
|
||
7.3-10.9
|
||
Apply at early bloom (early popcorn).
|
||
Make a second application at full bloom.
|
||
If needed under severe disease pressure,
|
||
apply additional sprays at 10 to 14-day
|
||
intervals between full bloom and final
|
||
pre-harvest sprays.
|
||
Cherry Leaf Spot
|
||
(Coccomyces) 25.0-32.7
|
||
(0.8-1.1)
|
||
8.2-10.9
|
||
Applications may be made at petal fall or
|
||
before (when leaves first unfold) and at
|
||
first, second, and third cover at 10 to
|
||
14-day intervals and one spray 14 to 21
|
||
days after harvest.
|
||
|
||
16
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
Powdery Mildew
|
||
(Podosphaera,
|
||
Sphaerotheca)
|
||
21.8-32.7
|
||
(0.7-1.1)
|
||
[in CA use
|
||
32.7]
|
||
(1.1)
|
||
PLUS
|
||
25.0-32.7
|
||
(0.8-1.1)
|
||
7.3-10.9
|
||
PLUS
|
||
8.2-10.9
|
||
Apply at early bloom (early popcorn).
|
||
Make a second application at full bloom.
|
||
PLUS
|
||
Apply at shuck fall and first cover.
|
||
Nectarines Brown Rot
|
||
Blossom Blight
|
||
Fruit Brown Rot
|
||
(Monilinia)
|
||
21.8-32.7
|
||
(0.7-1.1)
|
||
[in CA use
|
||
32.7]
|
||
(1.1)
|
||
7.3-10.9
|
||
Apply at early bloom (pink bud). Make a
|
||
second application at full bloom if
|
||
conditions favor disease development.
|
||
If needed under severe disease pressure,
|
||
apply additional sprays at 10 to 14-day
|
||
intervals between full bloom and final
|
||
pre-harvest sprays.
|
||
Peaches Brown Rot Blossom
|
||
Blight
|
||
Fruit Brown Rot
|
||
(Monilinia)
|
||
21.8-32.7
|
||
(0.7-1.1)
|
||
[in CA use
|
||
32.7]
|
||
7.3-10.9
|
||
Apply at early bloom (pink bud). Make a
|
||
second application at full bloom if
|
||
conditions favor disease development.
|
||
If needed under severe disease pressure,
|
||
apply additional sprays at 10 to 14-day
|
||
intervals between full bloom and final
|
||
pre-harvest sprays.
|
||
Peach Scab
|
||
(Cladosporium) 21.8-32.7
|
||
(0.7-1.1)
|
||
[in CA use
|
||
32.7]
|
||
(1.1)
|
||
PLUS
|
||
25.0-32.7
|
||
(0.8-1.1)
|
||
7.3-10.9
|
||
PLUS
|
||
8.2-10.9
|
||
Apply at early bloom (pink bud). Make a
|
||
second application at full bloom if
|
||
conditions favor disease development.
|
||
PLUS
|
||
Apply at shuck split and at first cover
|
||
sprays.
|
||
Plums and
|
||
Prunes
|
||
Brown Rot Blossom
|
||
Blight
|
||
Fruit Brown Rot
|
||
(Monilinia)
|
||
21.8-32.7
|
||
(0.7-1.1)
|
||
[in CA use
|
||
32.7]
|
||
(1.1)
|
||
7.3-10.9 Apply at early bloom (green tip). Make a
|
||
second application at full bloom.
|
||
If needed under severe disease pressure,
|
||
apply additional sprays at 10 to 14-day
|
||
intervals between full bloom and final
|
||
pre-harvest sprays.
|
||
|
||
17
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
Black Knot (Dibotryon)
|
||
21.8-32.7
|
||
(0.7-1.1)
|
||
[in CA use
|
||
32.7]
|
||
(1.1)
|
||
7.3-10.9
|
||
Apply at pre-bloom, petal fall, and at
|
||
first, second, or third cover sprays at 10
|
||
to 14-day intervals.
|
||
Leaf Spot (Coccomyces)
|
||
21.8-32.7
|
||
(0.7-1.1)
|
||
[in CA use
|
||
32.7]
|
||
(1.1)
|
||
7.3-10.9
|
||
Applications may be made at petal fall,
|
||
shuck split, and at first, second, and third
|
||
cover sprays at 10 to 14-day intervals and
|
||
1 spray 14 to 21 days after harvest.
|
||
Strawberries
|
||
Do not enter or
|
||
allow worker
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted
|
||
entry interval
|
||
(REI) of 24
|
||
hours.
|
||
Restrictions:
|
||
-Do not apply more than 21.8 fl. oz./A
|
||
(0.7 lb. a.i./A) per application.
|
||
-Do not apply more than 87.2 fl. oz. of
|
||
product (2.8 lbs a.i.)/A/year.
|
||
-The minimum retreatment interval is
|
||
seven (7) days.
|
||
-Do not apply more than 4 applications
|
||
per year.
|
||
-Pre-harvest interval: 1 day
|
||
-Follow resistance management
|
||
guidelines under Directions for Use.
|
||
Crown Rot***
|
||
(Colletotrichum spp.)
|
||
Suppression only
|
||
16.3-21.8
|
||
(0.52-0.7)
|
||
Begin applications after establishment of
|
||
the transplants and continue through first
|
||
bloom at 10 to 14-day intervals. Use the
|
||
high rate if the fields have a history of
|
||
Colletotrichum crown rot and/or
|
||
conditions are favorable for development
|
||
of the disease. Will not control
|
||
Phytophthora species.
|
||
|
||
18
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
Fruit Rot
|
||
(Botrytis)
|
||
Leaf Blight
|
||
(Dendrophoma)
|
||
Leaf Scorch
|
||
(Diplocarpon)
|
||
Powdery Mildew
|
||
(Sphaerotheca)
|
||
16.3-21.8
|
||
(0.52-0.7)
|
||
Begin applications at early bloom and
|
||
continue at 7 to 10-day intervals. Use the
|
||
higher rate under conditions of severe
|
||
disease pressure.
|
||
Sugar Beets
|
||
Do not enter or
|
||
allow worker
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted
|
||
entry interval
|
||
(REI) of 24
|
||
hours.
|
||
Restrictions:
|
||
-Do not apply more than 21.8 fl. oz./A
|
||
(0.7 lb. a.i./A) per application.
|
||
-Do not apply more than 65.4 fl. oz. of
|
||
product (2.1 lbs a.i.)/A/year.
|
||
-The minimum retreatment interval is
|
||
fourteen (14) days.
|
||
-Do not apply more than 3 applications
|
||
per year.
|
||
-Pre-harvest interval: 21 days
|
||
-Follow resistance management
|
||
guidelines under Directions for Use.
|
||
Cercospora Leaf Spot
|
||
(Cercospora) 10.9-21.8
|
||
(0.35-0.7)
|
||
Apply when conditions become favorable
|
||
for disease development before the
|
||
disease appears and follow with a non-
|
||
benzimidazole fungicide within 14 days
|
||
of application or as needed.
|
||
Thiophanate-methyl 4.1 SC must be tank
|
||
mixed with a protectant fungicide when
|
||
resistant strains of Cercospora are present
|
||
in the field.
|
||
For areas east of the Rocky Mountians:
|
||
Do not make more than one application
|
||
of Thiophanate-methyl 4.1 SC per season
|
||
for Cercospora Leaf Spot.
|
||
|
||
19
|
||
Crops/
|
||
REI Diseases
|
||
FL.
|
||
OZ./
|
||
Acre
|
||
(lb.
|
||
a.i./A)
|
||
FL.
|
||
OZ./
|
||
100 Gal
|
||
Application Instructions
|
||
Powdery Mildew
|
||
(Erysiphe) 10.9-21.8
|
||
(0.35-0.7)
|
||
Apply as soon as disease symptoms
|
||
appear and follow with a non-
|
||
benzimidazole fungicide at a 14-day
|
||
interval or as needed.
|
||
Thiophanate-methyl 4.1 SC can be tank
|
||
mixed with sulfur products for additional
|
||
disease control and resistance
|
||
management.
|
||
Triticale and
|
||
Fall-seeded
|
||
Wheat
|
||
For this use in
|
||
Idaho,
|
||
Oregon, and
|
||
Washington
|
||
ONLY
|
||
Do not enter or
|
||
allow worker
|
||
entry into
|
||
treated areas
|
||
during the
|
||
restricted
|
||
entry interval
|
||
(REI) of 24
|
||
hours.
|
||
Foot Rot, Strawbreaker,
|
||
Eye Spot
|
||
(Pseudocercosporella)
|
||
21.8
|
||
(0.7)
|
||
Apply Thiophanate-methyl 4.1 SC at the
|
||
rate indicated in a single application by
|
||
air or ground after tillering but before
|
||
stem elongation has begun.
|
||
Use sufficient water to obtain thorough
|
||
coverage.
|
||
Restrictions:
|
||
-Do not apply more than 21.8 fl. oz./A
|
||
(0.7 lb. a.i./A) per application.
|
||
-Do not apply more than 21.8 fl.oz. of
|
||
product (0.7 lb a.i.)/A/year.
|
||
-Do not cut for hay within 90 days of
|
||
application.
|
||
-Do not allow livestock to graze in
|
||
treated areas before harvest.
|
||
*** Not for this use in California
|
||
NOTE: Dilute sprays are not to exceed maximum rate per acre.
|
||
|
||
20
|
||
DIRECTIONS FOR USE ON CONIFERS
|
||
(Not for this use in California)
|
||
CROPS DISEASE RATE (fl. oz./A),
|
||
MINIMUM
|
||
GALLONAGE
|
||
APPLICATION INSTRUCTIONS AND
|
||
RESTRICTIONS
|
||
Conifers (Pine)
|
||
Austrian
|
||
Red
|
||
Scots
|
||
Christmas
|
||
Trees
|
||
Do not enter or
|
||
allow worker
|
||
entry into treated
|
||
areas during the
|
||
restricted entry
|
||
interval (REI) of
|
||
12 hours.
|
||
Tip Blight
|
||
(Diplodia)
|
||
21.8 fl. oz. per 100
|
||
gal./A
|
||
Apply at bud break. Repeat 10 to 14 days later, just
|
||
before needles emerge from sheath; repeat again 10 to
|
||
14 days after needle emergence.
|
||
Add a spreader/sticker to improve coverage.
|
||
- Use minimum gallonage with mist-blower types of
|
||
sprayers and higher gallonage with conventional
|
||
sprayers.
|
||
Restrictions:
|
||
-Do not apply more than 65.4 fl. oz. of product (2.1
|
||
lbs. a.i.)/A/year.
|
||
-The minimum retreatment interval is ten (10) days.
|
||
-Do not apply more than 3 applications per year.
|
||
-Do not graze livestock in treated areas.
|
||
Conifers
|
||
(Fir)
|
||
Douglas
|
||
Swiss Needle Cast
|
||
(Phaecryptopus)
|
||
Rhabdocline Needle
|
||
Cast
|
||
21.8 fl. oz. per
|
||
50 gal./A
|
||
Apply initially in early May. Repeat at 4-week
|
||
intervals.
|
||
Add a spreader/sticker to improve coverage.
|
||
- Use minimum gallonage with mist-blower types of
|
||
sprayers and higher gallonage with conventional
|
||
sprayers.
|
||
Restrictions:
|
||
-Do not apply more than 109 fl. oz. of product (3.5
|
||
lbs. a.i.)/A/year.
|
||
-The minimum retreatment interval is (28) days.
|
||
-Do not apply more than 5 applications per year.
|
||
Conifers
|
||
(seedling
|
||
treatment)
|
||
Longleaf
|
||
Brown Needle Blight
|
||
(Scirrhia)
|
||
1.4 fl. oz. product
|
||
per 9.5 oz. dry
|
||
Kaolinite clay for
|
||
seedling roots
|
||
Wet seedling roots in clean water, then apply
|
||
Thiophanate-methyl 4.1 SC/Kaolinite mixture to wet
|
||
roots.
|
||
Loblolly
|
||
Longleaf
|
||
Slash
|
||
Fusarium and
|
||
Rhizoctonia Root Rot
|
||
2.7 fl. oz. product
|
||
per 50 oz.
|
||
Kaolinite clay, plus
|
||
enough water to
|
||
make a slurry
|
||
Thoroughly cover seedling roots with Thiophanate-
|
||
methyl 4.1 SC/Kaolinite slurry.
|
||
Restrictions for Seedling Treatment:
|
||
-Do not apply mixture to seedling foliage.
|
||
-Avoid excess drying of roots or exposure to temperatures greater than 90° F or less than 32° F.
|
||
|
||
21
|
||
-Do not enter or allow workers to enter into treated areas during the restricted entry interval (REI) of 12 hours.
|
||
Note: Thiophanate Methyl 4.1 SC does not control Pythium or Phytophthora.
|
||
DIRECTIONS FOR USE THROUGH CHEMIGATION SYSTEMS
|
||
USE IN CALIFORNIA BY CHEMIGATION ONLY FOR BEANS, CUCURBITS
|
||
(CANTALOPE, CASABA, CUCUMBERS, MELONS, PUMPKINS, SQUASH,
|
||
WATERMELONS), PEANUTS, POTATOES, SOYBEANS, STRAWBERRIES, AND
|
||
SUGAR BEETS.
|
||
Apply this product only through sprinkler irrigation systems including center pivot, lateral move,
|
||
end tow, side (wheel) roll, traveler, solid set or hand move; or drip (mini-micro sprinklers, strip
|
||
tubing, trickle) irrigation systems. Do not apply this product through any other type of irrigation
|
||
system.
|
||
Crop injury, lack of effectiveness, or illegal pesticide residues in the crop can result from
|
||
nonuniform distribution of treated water.
|
||
If you have any questions about calibration, you must contact State Extension Service specialists,
|
||
equipment manufacturers or other experts.
|
||
A person knowledgeable of the chemigation system and responsible for its operation, or under the
|
||
supervision of the responsible person, shall shut the system down and make necessary
|
||
adjustments if needed. Do not connect chemigation system (including greenhouse systems) used
|
||
for pesticide irrigation to any public water system unless the pesticide label-prescribed safety
|
||
devices for public water systems are in place. Public water system means a system for the
|
||
provision of piped water for human consumption if such a system has at least 15 service
|
||
connections or regularly serves an average of at least 25 individuals daily at least 60 days out of
|
||
the year.
|
||
SYSTEM REQUIREMENTS
|
||
Chemigation systems connected to public water systems must contain a functional, reduced-
|
||
pressure zone, backflow preventer (RPZ) or the functional equivalent in the water supply line
|
||
upstream from the point of pesticide introduction. As an option to the RPZ, the water from the
|
||
public water system needs to be discharged into a reservoir tank prior to pesticide introduction.
|
||
There shall be a complete physical break (air gap) between the outlet end of the fill pipe and the
|
||
top or overflow rim of the reservoir tank of at least twice the inside diameter of the fill pipe.
|
||
Systems utilizing a pressurized water and pesticide injection system must meet the following
|
||
requirements:
|
||
The system must contain a functional check valve, vacuum relief valve, and low pressure drain
|
||
appropriately located on the irrigation pipeline to prevent water source contamination from
|
||
backflow.
|
||
The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve
|
||
to prevent the flow of fluid back toward the injection pump. The pesticide injection pipeline must
|
||
also contain a functional, normally closed, solenoid-operated valve located on the intake side of
|
||
the injection pump and connected to the system interlock to prevent fluid from being withdrawn
|
||
from the supply tank when the irrigation system is either automatically or manually shut down.
|
||
The system must contain functional interlocking controls to automatically shut off the pesticide
|
||
injection pump when the water pump motor stops.
|
||
The irrigation line or water pump must include a functional pressure switch which will stop the
|
||
|
||
22
|
||
water pump motor when the water pressure decreases to the point where pesticide distribution is
|
||
adversely affected.
|
||
Systems must use a metering pump (e.g., diaphragm pump) effectively designed and constructed
|
||
of materials that are compatible with pesticides and capable of being fitted with a system
|
||
interlock.
|
||
APPLICATION INSTRUCTIONS
|
||
Observe the requirements in the System Requirements section above.
|
||
Apply Thiophanate-methyl 4.1 SC only through systems containing anti-syphon and check valves
|
||
designed to prevent water source contamination or overflow of the mix tank and containing
|
||
interlocking controls between the metering device and the water pump to insure simultaneous
|
||
shut-off.
|
||
Maintain a gentle continuous agitation in mix tank during mixing and application to assure a
|
||
uniform suspension.
|
||
Greater accuracy in calibration and distribution will be achieved by injecting a larger volume of a
|
||
more dilute suspension per unit time.
|
||
Application of more than specified quantities of irrigation water per acre may result in decreased
|
||
product performance.
|
||
Where sprinkler distribution patterns do not overlap sufficiently, unacceptable disease control
|
||
may result.
|
||
Allow sufficient time for pesticide to be flushed through all lines and all nozzles before turning
|
||
off irrigation water.
|
||
Thiophanate-methyl 4.1 SC may be applied in conjunction with chemically neutral liquid
|
||
fertilizers. Application in conjunction with highly alkaline fertilizers, including aqueous
|
||
ammonia, is likely to cause a degradation of the pesticide, resulting in reduced performance and
|
||
needs to be avoided.
|
||
RESTRICTIONS:
|
||
Do not apply when wind speed favors drift, when system connections or fittings leak, when
|
||
nozzles do not provide uniform distribution or when lines containing the product cannot be
|
||
flushed and must be dismantled and drained. In a center pivot system, block the nozzle set nearest
|
||
the well/pivot/injection unit to prevent spray being applied to this area.
|
||
Do not apply when wind speed favors drift beyond the area intended for treatment.
|
||
SPRAY PREPARATION:
|
||
Remove scale, pesticide residues, and other foreign matter from the chemical tank and entire
|
||
injector system. Flush with clean water. Prepare a suspension of Thiophanate-methyl 4.1 SC in a
|
||
mix tank. Fill the tank with ½ or ¾ the desired amount of water. Start mechanical or hydraulic
|
||
agitation. Slowly add the required amount of Thiophanate-methyl 4.1 SC and then the remaining
|
||
volume of water.
|
||
Sprinkler Irrigation - Notes
|
||
Observe all System Requirements and Application Instructions above.
|
||
Set sprinkler system to deliver a maximum of 0.4 inch of water per acre. Volumes of water higher
|
||
than this may reduce efficacy. Start sprinkler and then uniformly inject the suspension of
|
||
Thiophanate-methyl 4.1 SC into the irrigation water line so as to deliver the desired rate per acre.
|
||
The suspension of Thiophanate-methyl 4.1 SC needs to be injected with a positive displacement
|
||
pump into the main line ahead of a right angle turn to ensure adequate mixing. When treatment
|
||
with Thiophanate-methyl 4.1 SC has been completed, do not irrigate the treated area for 24 to 48
|
||
hours to prevent washing the chemical off the crop.
|
||
|
||
23
|
||
Where sprinkler distributed patterns do not overlap sufficiently, unacceptable disease control may
|
||
result.
|
||
Check local restrictions and requirements regarding sprinkler irrigation applications, as they may
|
||
vary from state to state.
|
||
Drip (Mini-Micro Sprinklers, Strip Tubing, Trickle) Irrigation -N o t e s
|
||
Observe all System Requirements and Application Instructions above.
|
||
A pesticide supply tank is advised.
|
||
SEED TREATMENT USE
|
||
PRODUCT APPLICATION AND INSTRUCTIONS
|
||
Thiophanate-methyl 4.1 SC is an effective fungicide for seed treatment that provides
|
||
early season protection of seedlings against rhizoctonia. Seed needs to be sound and
|
||
well-cured before treatment.
|
||
Read and follow carefully all label directions of each combination product. When using
|
||
combinations of products, the most restrictive of label limitations and precautions must
|
||
be followed.
|
||
Seed Treatment Equipment: Thiophanate-methyl 4.1 SC may be used both for
|
||
commercial and for on-farm application. It can be applied with mechanical, slurry, or
|
||
mist-type seed treating equipment, as long as the equipment can be calibrated to
|
||
accurately and uniformly apply the product to seed without undue mechanical damage to
|
||
the seed. Uniform application to s eed is important for all seed treatment products.
|
||
Treatment of mechanically damaged seed or seed of low vigor or poor quality may result
|
||
in reduced germination. Treat and conduct germination tests on a small test sample of
|
||
seed before using this product on commercial quantities. Due to seed quality and seed
|
||
storage conditions beyond the control of Nippon Soda Co., Ltd. (Nisso), Nisso makes no
|
||
claims or guarantees as to germination of carry-over seed.
|
||
PRODUCT INSTRUCTIONS
|
||
Seed needs to be sound and well-cured before treatment. Refer to the label rates below.
|
||
Thiophanate-methyl 4.1 SC is typically diluted with water and/or mixed with other
|
||
products to attain an appropriate slurry application volume (fl. oz./cwt slurry rates) to
|
||
provide effective treating. The appropriate volume of slurry depends on crop, weather,
|
||
type of treater and other factors and needs to be adjusted as per normal treating practices
|
||
for the circumstances. Contact your local supplier or distributor representative for
|
||
specific directions.
|
||
TO ENSURE UNIFORMITY, MIX PRODUCT WELL BEFORE USE.
|
||
|
||
24
|
||
Thiophanate-methyl 4.1 SC plus water and/or other treatments need to be mixed
|
||
thoroughly prior to treating seed. Recalibrate treating equipment to compensate for the
|
||
required slurry rate to ensure all products are applied at the correct rate.
|
||
Restrictions:
|
||
Do not use Thiophanate-methyl 4.1 SC in combination with other seed treatment
|
||
products unless compatibility has been verified.
|
||
Crop(s) Application Rate
|
||
WHEAT, TRITICALE
|
||
For early season control of seed decay (Fusarium, Rhizoctonia)
|
||
and suppression of seedling blight (Fusarium, Rhizoctonia)
|
||
0.153 – 0.307 fl. oz/cwt
|
||
SOYBEANS
|
||
NOTE: Seed may be treated on a fl. oz./seed unit (to deliver a
|
||
target mg active ingredient/kernel) basis or and a per weight of
|
||
seed basis, as shown.
|
||
For early season control of seed decay (Phomopsis, Fusarium,
|
||
Rhizoctonia) and suppression of seedling blight (Fusarium,
|
||
Rhizoctonia)
|
||
Per Seed Unit:
|
||
0.072-0.144 fl. oz./seed unit
|
||
(140,000 seeds) (applies
|
||
0.0075-0.015 mg ai/seed)
|
||
OR
|
||
Per Seed Weight:
|
||
0.153 – 0.307 fl. oz./cwt
|
||
DRY BEANS and SNAP BEANS:
|
||
For early season control of seed decay (Phomopsis,
|
||
Rhizoctonia) and suppression of seedling blight (Fusarium,
|
||
Rhizoctonia)
|
||
0.153 – 0.307 fl. oz./cwt
|
||
Use higher rates for higher levels of seedling blight protection.
|
||
TREATED SEED LABELING
|
||
THE FEDERAL SEED ACT REQUIRES THAT BAGS CONTAINING TREATED
|
||
SEED MUST BE LABELED WITH THE FOLLOWING INFORMATION:
|
||
Ɣ7KLVbag contains seed treated with Thiophanate-methyl 4.1 SC containing
|
||
thiophanate-methyl. Do not use for food, feed, or oil purposes. Store away from feed
|
||
and food stuffs.”
|
||
ƔColoring Treated Seed
|
||
|
||
This product does not contain colorant. The purchaser of this product is responsible for
|
||
ensuring that all seed treated with this product are adequately dyed with a suitable color
|
||
to prevent its accidental use as food for man or feed for animals. Refer to 21CFR, part
|
||
|
||
25
|
||
2.25. Any colorant added to treated seed must be cleared for use under 40CFR, part
|
||
153.155. Alternatively, use in com bination with other colored seed treatment products
|
||
may provide adequate coloration.
|
||
|
||
LABELS FOR COMMERCIALLY TREATED SEED MUST ALSO INCLUDE THE
|
||
FOLLOWING ENVIRONMENTAL HAZARDS STATEMENTS:
|
||
Ɣ³(xposed treated seed may be hazardous to birds and wildlife. Dispose of all excess
|
||
treated seed and seed packaging or containers by burial away from bodies of water in
|
||
accordance with any local requirements. Cover, incorporate, or collect treated seeds
|
||
spilled during loading and planting. DO NOT contaminate bodies of water when
|
||
disposing of planting equipment wash water.”
|
||
THE U.S. ENVIRONMENTAL PROTECTION AGENCY REQUIRES THE
|
||
FOLLOWING STATEMENTS ON CONTAINERS CONTAINING TREATED SEED:
|
||
Ɣ³'2127DOOow children, pets or livestock to have access to treated seeds.”
|
||
Ɣ³'2127JUD]HRUIHHGOLYHVWRFNRQWUHDWHGDUHDVIRUGD\VDIWHUSODQWLQJ´
|
||
Ɣ³:HDUORQJSDQWVORQJ-sleeved shirt, shoes, socks and chemical-resistant gloves when
|
||
opening this bag or loading/pouring the treated seed.”
|
||
Ɣ³$IWHUWKHVHHGVKDYHEHHQSODQWHGGRQRWHQWHURUDOORZZRUNHUHQWU\LQWRWUHDWHG
|
||
areas during the restricted-entry interval (REI) of 12 hours. Exception: If the treated
|
||
seed is soil-injected or soil-incorporated, the Worker Protection Standard, under certain
|
||
circumstances, allows workers to enter the treated area if there will be no contact with
|
||
anything that has been treated. PPE required for early entry to treated areas that is
|
||
permitted under the Worker Protection Standard and that involves contact with anything
|
||
that has been treated, including plants, soil or water is: coveralls, chemical-resistant
|
||
gloves made of any waterproof material, and chemical-resistant footwear.”
|
||
USE RESTRICTIONS
|
||
Care must be exercised in the handling of treated seed. Augers used for handling treated
|
||
seed must not be used to move seed for feed, food or oil processing. Do not re-use bags
|
||
from treated seed to handle food or feed products.
|
||
STORAGE AND DISPOSAL
|
||
Do not contaminate water, food, or feed by storage and disposal.
|
||
STORAGE: Store in the original container in a dry area. Do not store in a manner where
|
||
cross-contamination with other pesticides, fertilizers, food or feed could occur. If spilled
|
||
during storage or handling, absorb with sand or other inert material and dispose of absorbent
|
||
in accordance with the Pesticide Disposal Instructions listed below.
|
||
DISPOSAL: Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture,
|
||
|
||
26
|
||
or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use
|
||
according to label instructions, contact your State Pesticide or Environmental Control Agency,
|
||
or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.
|
||
CONTAINER HANDLING
|
||
NON-REFILLABLE CONTAINERS
|
||
[For containers 5 gallons or less:]. Do not reuse or refill this container. Clean container
|
||
promptly after emptying. Triple rinse as follows: Empty the remaining contents into
|
||
application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill
|
||
the container ¼ full with water and recap. Shake for 10 seconds. Pour rinsate into application
|
||
equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after
|
||
the flow begins to drip. Repeat this procedure two more times. Then offer for recycling if
|
||
available, or puncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by
|
||
state and local authorities, by burning. If burned, stay out of smoke.
|
||
[For containers with a capacity > 5 gallons:]
|
||
Triple rinse or pressure rinse non-refillable containers too large to shake as follows:
|
||
Triple rinse as follows: Empty the remaining contents into application equipment or a mix
|
||
tank. Fill the container ¼ full with water. Replace and tighten closures. Tip container on its
|
||
side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand
|
||
the container on its end and tip it back and forth several times. Turn the container on its other
|
||
end and tip it back and forth several times. Empty the rinsate into application equipment or a
|
||
mix tank, or store rinsate for later use or disposal. Repeat this procedure two more times.
|
||
Pressure rinse as follows: Empty the remaining contents into application equipment or a mix
|
||
tank and continue to drain for 10 seconds after the flow begins to drip: Hold container upside
|
||
down over application equipment or mix tank and collect rinsate for later use or disposal.
|
||
Insert pressure rinsing nozzle in the side of the container, and rinse at about 40 PSI for at least
|
||
30 seconds. Drain for 10 seconds after the flow begins to drip.
|
||
Then offer for recycling if available, or puncture and dispose of in a sanitary landfill, or by
|
||
incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of
|
||
smoke.
|
||
REFILLABLE CONTAINERS
|
||
[Bulk Containers:] Refill this container with pesticide only. Do not reuse this container for
|
||
any other purpose. Cleaning the container before final disposal is the responsibility of the
|
||
person disposing of the container. Cleaning before refilling is the responsibility of the refiller.
|
||
To clean the container before final disposal, empty the remaining contents from this container
|
||
into application equipment or mix tank. Fill the container about 10 percent full with water.
|
||
Agitate vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into
|
||
application equipment or rinsate collection system. Repeat this rinsing procedure two more
|
||
times.
|
||
|
||
27
|
||
When the container is empty, replace the cap and seal all openings that have been opened
|
||
during use; and return to the point of purchase, or to a designated location named at the time
|
||
of purchase of this product. Prior to refilling, inspect carefully for damage such as cracks,
|
||
punctures, abrasions, worn-out threads and closure devices. Check for leaks after refilling and
|
||
before transporting. Do not transport if this container is damaged or leaking. If the container is
|
||
damaged or leaking, call Chem-Trec. If the container is damaged and leaking or material has
|
||
been spilled, follow these procedures:
|
||
• Cover spill with absorbent material.
|
||
• Sweep into disposal container.
|
||
• Wash area with detergent and water and follow with clean water rinse.
|
||
• Do not allow to contaminate water supplies.
|
||
• Dispose of according to instructions.
|
||
If not returned to the point of purchase or to a designated location, clean empty container as
|
||
instructed above and offer for recycling. Disposal of this container must be in compliance with
|
||
state and local regulations.
|
||
IMPORTANT: READ BEFORE USE
|
||
Read the entire Directions for Use, Conditions, Disclaimer of Warranties and Limitations
|
||
of Liability before using this product. If terms are not acceptable, return the unopened
|
||
product container at once.
|
||
By using this product, user or buyer accepts the following Conditions, Disclaimer of
|
||
Warranties and Limitations of Liability.
|
||
CONDITIONS: The directions for use of this product are believed to be adequate and
|
||
must be followed carefully. However, it is impossible to eliminate all risks associated
|
||
with the use of this product. Crop injury, ineffectiveness or other unintended
|
||
consequences may result because of such factors as weather conditions, presence of other
|
||
materials, or the manner of use or application, all of which are beyond the control of
|
||
Nippon Soda Co., Ltd. All such risks shall be assumed by the user or buyer.
|
||
DISCLAIMER OF WARRANTIES: To the extent allowable by applicable laws Nippon
|
||
Soda Co., Ltd. makes no other warranties, express or implied, of merchantability or of
|
||
fitness for a particular purpose or otherwise, that extend beyond the statements made on
|
||
this label. No agent of Nippon Soda Co., Ltd. is authorized to make any warranties
|
||
beyond those contained herein or to modify the warranties contained herein. To the
|
||
extent allowable by applicable laws Nippon Soda Co., Ltd. disclaims any liability
|
||
whatsoever for special, incidental or consequential damages resulting from the use or
|
||
handling of this product.
|
||
|
||
28
|
||
SEED TREATMENT: Treatment of seed, especially seed that is mechanically damaged
|
||
or seed known to be of low vigor and poor quality, may result in reduced germination
|
||
and/or reduction of seed and seedling vigor. Treat and conduct germination tests on a
|
||
small test sample of seed before treating commercial quantities with a selected chemical
|
||
treatment that includes this product. Due to seed quality and seed storage conditions
|
||
beyond the control of Nippon Soda Co., Ltd. (Nisso), Nisso makes no claims or
|
||
guarantees as to germination of carry-over seed.
|
||
LIMITATIONS OF LIABILITY: To the extent allowable by applicable laws the
|
||
exclusive remedy of the user or buyer for any and all losses, injuries or damages resulting
|
||
from the use or handling of this product, whether in contract, warranty, tort, negligence,
|
||
strict liability or otherwise, shall not exceed the purchase price paid, or at Nippon Soda
|
||
Co., Ltd.’s election, the replacement of product.
|
||
Nippon Soda Co., Ltd.
|
||
c/o Nisso America Inc.
|
||
88 Pine St., 14
|
||
th FL.
|
||
New York, NY 10005
|