a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
339 lines
19 KiB
Markdown
339 lines
19 KiB
Markdown
# BUTYL ESTER 4 2,4-D WEED KILLER
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- EPA Reg No: **1381-100**
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- Registrant: WINFIELD SOLUTIONS, LLC
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- Signal word: Caution
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- Active ingredients: 2,4-dichlorophenoxyacetic acid, butyl ester (55.6%)
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- Label accepted: 1987-06-15
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/001381-00100-19870615.pdf
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---
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. .--
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ACTIVE IIIGREDIEIIT:
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1?"tI-IOO
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(
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CEt/llX/LAlill O'LAKES
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BOTJL rsrBR ~
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2,4-D HEED KILLER
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,,\,
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C~{( ;
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June 1, 1987
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(Front Panel)
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'£'.. C ':> \<1,'0:
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:0\\ \ . ". 0 ~ ~.,. . \,,0
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\l<. ,' ... , \'a0
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Dutyl Ester of 2,4-Dichlorophenoxyacetic acid' nPv~ .••• " ..... 55.6~
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IHERT IUGREDIEUTS: ........................... ; ........... ~il................. 41.1.4S
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Total .......................................... ~. ~ • . . . . . . . .. . .. '00. oS
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'Isomer Specific by AOAC Hethod 110. 6.275 13th Edition 1980
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'2,4-Dichlorophenoxyacetic acid equivalent ••• 44.5~
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Contains 3.8 lb. 2,~-Dichlorophenoxyacetic acid per gallon
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KEEP OUT OF REACH OF CHILDREII (12 pt. type size)
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C1UTIOI (18 pt. type size)
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SEE SIDE PAIIELS FOR ADDITIOIlAL PRECAUTlOIIARY STATEr'IEIITS
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EPA Reg. 110. 1381..;100
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EPA Est. 110. 1I07-IA_1S, 407-11II-1A
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Superscript used corresponds to
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letter in lot number
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NET COli TENTS _
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Manufactured For
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CFNEX/LAND O'LAKES AGRONOUY CO.
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St. Paul, WI 55164
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/
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• ••• I •
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. . •
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• , •• I •
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. . .. .... .
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•••• I
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• ••• I •
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, .
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· ..... . . ., ..
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I
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(
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Page 2
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(Side Panell
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PRECAUTIOllARY STATEHEllTS
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HAZARDS TO HUHAllS AlID DOHESTIC AIlWALS
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CAUTION
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Harmful if swallowed. Do not get
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contact, wBsh with ~oap and water.
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contaot with eyes wash with plenty
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in eyes, on skin or clothing •. -In oaee of
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Avoid inhaling spray or mist. In oase of
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of water.
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Do not forage or grde treated grain fields within 2 weeks after treatment with
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2,~-D. Do not feed treated straw to livestock. Do not graze pastures to dairy
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animals within seven days after treatment.
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ENVIRONMENTAL HAZARDS
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This produot is toxio to fish. Do not apply direotly to water.
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oontaminate water by oleaning of equipment or disposal of wastes.
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oontaminate waters used for irrigation or domestio purposes.
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Do not
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Do not
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DON'T OVERDOSEI Follow direotions oarefully. Do not let spray drift to
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sensitive plants such as vegetables, legumes, grapes, flowers or other 2,~-D
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susceptible plants. Use ooarse spray to reduoe "wind drift·. Looal spray
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oonditions will vary. Cheok local recommendations first. Use separate spray
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equipment for insectioides and fungicides. Do not make eerial applioation near
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cotton or se~sitive plants. Under oertain high temperature conditions, vapors
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frca this product will injure nearby susceptible plants.
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DIRECTIOnS FOR USE /
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It is a violation of Federal law to use this product in a manner inconsistent
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with its labeling.
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RE-EIlTRY STATEMENT
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Do not apply this product in suoh a manner as to direotly or through drift
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expose workers or other persons. The area being treated must be vaoated by
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unproteoted persons. Do not enter treated areas without proteotive clothing
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until sprays have dried.
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Beoause certain states may require more restriotive reentry intervals for
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various oropstreated with this produot, oonsult your State Department of
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Agrioulture for further information.
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Written or oral warnings must be given to workers who are expeoted to be in a
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treated area or in an area about to be treated with this produot. The
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PRECAUTIOIlARY STATEHENTS should be read to workers as well as the instruotion
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not to enter until sprays have dried. When oral warnings are given, warnings
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shall be given in a language customarily understood by workers. Oral warnings
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must be given if there is reason to believe that written warnings oannot be
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understood by workers. Written warnings must inolude the following information: .•••••
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"CAUTION: Area treated with 2,~-D on (date of applioation). Do nrlt:enter: .:
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without appropriate proteotive olothing until sprays have dried." ..•••• . . ..
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STORAGE AND DISPOSAL (12 pt. type size)":".
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STORAGE: Store in a secure area, in original container only, alley .. frcm" ".
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fertilizers, rood, cr feed. Do not store near inseoticides cr fungioid~ •.. · .
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PESTICIDE DISPOSAL: Pesticide wastes are toxio. Improper disposal of excess":":
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pestioide, spray mixture, or rinsate is a violation of Federal Law. ,If, ~)lese, .. ::.
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wastes oannot be disposed of according to label instructions, contact your ·State .....•
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Pesticide or Environmental Control Agenoy, or the Hazardous Waste reprel,fentaUve
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at the nearest EPA Regional Oftioe for guidanoe. Do not oontaminate wa'ter,
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food, or feed by storage or disposal.
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COnTAIIlER DISPOSAL: Triple rinse (or equivalent). Then offer for reoyoling or
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reoonditionins, or puncture and dispose of in a sanitary landfill, or by other
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procedures approved by state and local authorities.
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I When stored at tempera~ures below freezing,
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to ~5° F and mix thoroughly before usiDG.
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(
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it may be neuessary to warm contents
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This produot will control the listed plants and other 2,~-D susoeptible species:
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All1gatorweed, artichoke, bindweeds (hedge, field, and European.)·.···tall and
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davil's besgarticks, blueweed (Texas), boxelder, broomweed, buckbrush, buokhorn
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plantain, buckwheat (wild), burdook, burhead, buttercup, oarpetweed, oatnip,
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chamise, chickweed, ohicory, cocklebur, coffeeweed, common mullein, cornflcwer,
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coyotebrush, creeping jenny, crcton, curly indigo, dandelion, docks, dog fennel,
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common duckweed, elderberry, annual fleabane, fanweed, galinsoga, wild garlic,
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goatsbeard, goldenrod, ground ivy, halogeton, hemp, henbit, jewelweed,
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jimsonweed, kochia, lambsquarters, locoweed, mallow (Venice), manzanita,
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marshelder, milkvetch, climbing milkweed, mo~ning-glory (annual), nettles,
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nutgrass, onion (wild), Parrot feather, pennicress, pepperweed (field), redroot
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and smooth pib~eed, plantain, poorjoe, poison ivy, pokeweed, prickly lettuce,
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puncturevine, common purslane, rabbitbrush, radish (wild), ragweed (common and
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giant), rape (wild), redstem, rush, sagebrush (costal, big, a1nd), salsify, aand
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shinnery oak, sheep sorrel, shepherdspurse, uicklepod, smartweed, sneezeweed
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(bitter), sowthistle (annual), Spanishneedles, stinkweed, sumac, sunflower,
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sweetclover, tansymustard, tansy ragwort, thistle (bull, Canadian, musk, and
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. Russian), tumbleweed, velvetleaf, Virginia creeper, Waterprimrose, Willow, wild
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sweet potato, witchweed, wormwood, yellow rocket, yellow starthistle. Deep
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rooted perennials such as Canadian thistle and field bindweed and woody plants
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may requ~re repeat applications.
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Apply when weather is warm and plants are rapidly growing. Cold weather or dry
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conditions may cause poor results. DO HOT apply if rain is expected within two
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hourn.
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/
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Consult your Extension 3ervice or Agricultural Experiment Station for lccal use
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and crop toleranoe situations.
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This product may be applied as a water, oil, or adjuvant based spray. Use
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coarse sprays to minimize drift. DO IIOT apply where spl'ay may cOlbe in contact
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with any desirable plants or susceptible cropa other than those l~sted on this
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label.
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DO NOT apply th~s product through any type of irrigation system.
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When using ground squipment, keep boom or nozzles close to crop, apply 2U
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gallons o~ more of spray per acre using flooding or flat fan nozzles with 20
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pounds or less of pressure. If wind exceeds 7 miles per hour, spraying should
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stop. DO HOT· apply. with hollow cone or any other mist producing nozzle.
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When using aerial equipment, apply a minimum of 3 to 5 gallons of spray per acre
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at 20 pounds or less nozzle pressure using nozzles that produce a coarse spray
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pattern. Spray only when w~nd is blowing less than 5 miles per hour.
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I •••••
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I • • • I..
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Apply the recommended amount of 2, 4-D per acre regardless of the Bllo'unt o~" •• :
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diluent used. ., ••••
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, ••• I
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Appllcatloa bJ aDJ.eans should take place onlJ when there is DO danger of spraJ':'"
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drift. Do Dot applJ Dear cottca, grapes, tomatoes, or other ~,_-D su£coptible
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crops or ncetables. Do Dot applJ when the wind is blowiDg t.:lval'd theise: 'crops' : ' .:
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or plaDtll. ' • ..... .
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HIXDIG DSIROCTIO.S: HATER-BASED SPRAY -- Fill the eqUipment half· ·!'ull ot' .,
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water, agitate while adding this product, then add rest of water.
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\lATER AND SOYBEAN OIL OR PETROLEUH OIL-BASED SPRAY -- F'irst mix this product
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with th. oil then add to water. If vigorous agitation is possible, the oil can
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ue adde!.. last. DO IIOT ADD OIL FIRSTI
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•
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I
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i. "'bw ...
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SOYBEAN OIL OR PETIlOLE~" OIL-BASED SPRAY -- Add thi~ pr~uct to straight cll to
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fol'll a solution. Dc not allow water to get into this lIIixture, if it does an
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invert emulsion will occur.
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NITROGEN FERTILIZER -- The compatability of this product lIIust be te~ted with the
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fertilizer'before-its use ·in epplicatio~ equipment. This is done by lIIean&·ot--a
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quart jar test as follows: The amount of this product to add to one pint of
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liquid nitrogen fertilizer is determined by using this table --
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-'KOIJNT OF
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2,~-D
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PER ACRE
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112 pint
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1 pint
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2 pints
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4 pints
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GALLCi:1S OF FERTILIZER PER ACRE
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10 20 30 40 50
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TEASPoollS OF 2, 4-D PER PIIIT OF FERTILIZER
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213 112 113 1/4 1/8
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1 11~ 1 3/4 112 1/4
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2 1/2 2 1 1/2 1 112
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5 4 3 2 1
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The amount in the table is based on galions of finished spray per acre.
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Different spray volllllles will require appropriate changes in the amount of this
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produot added to one pint of fertilizer. Add the required alliount of this
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produot to one pint of fertilizer in a quart jar and shake to lIIix well. Let the
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mixture stand and examine it after 5 lIIinutes and again after 30 lIIinutes. The
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produot is incompatible if it balls up, fol'lls flakes, sludges, gels, oily films,
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layers, or other precipitates. If the precipitate oan be suspended with
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agitation the combination can be used if the equiPlilent has vigorous agitation
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throughout mixing and spraying operations. .
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In some cases, wb .. n incompatibility occurs, the addition of 11" teaspoon o:r a
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compatibility agent to the jar before adding this produot may solve the problelll
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(11" teaspoon is equal to 2 pints per 100 gallons of fertilizer). IF THIS DOES
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nOT \laRK, DO IIOT ATTEMPT THE ADDITION OF THIS PRODUCT TO THE FERTILIZER.
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--Fertilizer Mixing Sequenoe: If a oompatibility agent is not required, add
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half the fertilizer to the tank, ~ake a prelilix of 1 part this product and "
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parts water and add prelilix to tank with agitatian all. Then add balance of
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fertilizer. Apply at once with l18itation all. --If a compatibility agent is
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required add it to half full tank before premix addition. Then proceed as
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above. HAKE SURE TO FOLLOW ALL DIRECTIOIlS ON THIS AUD THE FERTILIZER AIID
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COMPATIBILITY ACEIlT LABELING.
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CORM -!lse the lower rate for small annual weeds. Use the higher rate for
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perennial or hard to kill weeds. To avoid injury, do not use with atrazine,
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011, or cther adjuvants. --Preemersenoe: Apply 1 - 2 quarts per acre after
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planting but before corn emerces. DO 1I0T apply to sandy soils.
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--Emergence: Appl~ 1/2 pint per acre just as corn plants are breaking ground.
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--Postemergence: Apply 1/2 pint per acre after corn is up. If corn is over 8
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/
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inches tall, use drop nozzles to keep spray off corn foliage as much as
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possible. 3/" pint per aore may be needed to control some weeds, but this rate . -.. , ..... may injure the corn. DO IIOT apply frolll tasseling to dough stage. DO ~aT: a,pply: ._:
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to open whorls. High moisture and temperature condi tiono lIIay cause in~ury or", •••
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brittleness. DO IIOT cultivate for a week to 10 days after treatment. . .••
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--Late Season Weed Control (To reduoe weeds that interfere with harvest and", ••
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reduce weeCi seed production): Arter silks are oOllipletely brown apply 1 - 2 .. : .• ' pints per aore. ' .. . ..... , .
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SHALL GWNS (tlot underseeded with a legume) - IIOTE: Do not let dairy. p.n:lmals ' .
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or animals being finished for slaughter forage or graze treated fields '"Hnin 2":":
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weeks after treatment. Use the lower dose rate for slilall annual or ,t,ia"nual" .,
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weeds. Use the higher dose rate for perennial Oi' hard to kill weeds.
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--Spring IIheat, Barley, and Rye: Apply 1/2 pint per acre when r,rain is in full
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tiller stage (4 to 8 inohes high) but before dough s tace when '-leeds are small
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and actively growing. 2/3 pint ~er kcre may be u~ed to oontrol difficult weed
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proble~s, bu~ do not use unless some crop damage is acceptable.
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·1
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( Page 5
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-llinter Wheat and Rye: Apply 112 - 1 pint per acre only in spring before grain
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is in boot to dough stage.
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--Spring-seeded Oats: Apply 1/2 - 2/3 pint per acre at full tiller, but before
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early dougl) !\tage. . "
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--Fall-seeded Oats Grown For Grain (Southern): Apply 2/3 - 1 1/2 pints per acre
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at fun tiller, but· before early dou(lh stage. Diffioult weeds may require
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higher rate, but lIorle injury may ocour lIinoe oats are lellll tolerant to 2,4-0
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than wheat ai' bal'ley. DO .10T liP ray during or just after cold weather.
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--Preharvest 1reatment: Apply 1 - 1 2/3 pints per aore when grain ill in hard
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dough IItage to control weeds that will interfere with harvest. Apply when soil
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moisture is adequate for weed Growth for best results. nOTE: 110 NOT feed
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treated straw to livestock.
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KILO (GRAIN SORGHUm - nOTE: . Some varieties and hybrids are 2,4-0 sensitive.
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Crop injury may also be increased by high moisture and temperature conditions.
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Check with your seed compwlY and Extension Service for advice. Apply 1/2 pint
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per aore when plants are 5 to 15 inches tall. A higher rate of 2/3 - 1 pint per
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acre may be needed for some weeds, but chances of crop injury may increase. DO
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NOT use oil. DO NOT treat crop less than 5 inches tall or from boot to early
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dough stage. Use drop nozzles when crop io over 8 inches tall •.
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COISlIYA'rIOI IESBln PIOCRlHS AID SET-ASIDB ACRES· Ii!!TE: DO NOT use on
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alfalfa, clover, other l~gumes or newly seeded areas.
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-Broadleaf Heeds: Apply 1 1/2 quartll per acre in suffioient water for good
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coverage. Deep-rooted perennial weeds may require a higher rate or repeated
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treatments.
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-Brueh: Apply 2 1/4 - 3 quarts in 5 to 10 gallons of water plus 1 gallon of
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oil or the labeled amount of CBNEX/Land O'Lakes lTJ Conoentrate or other
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adjuvant per acre for Buckbrush, Rabbitbrush, SaGebrush, Coyotebrush and other
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Chaparral Species. Apply 2 1/4 - 3 quarts in 5 gallons of oil or 4 gallons of
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wate~ plus 1 gallon of oil p&r acre for Sand Shinnery Oak.
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FOR SET-ASIDE ACRES - Once the grazing allowance tice has been reached, do not /
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allow dairy animals or animals being finished for slaughter to forage or graze
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treated fields within 2 weeks after treatment. DO 1I0T feed tre9.tlJd straw to
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livestock.
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FOR CONSERVATION RESERVE PROGRAMS - DO IlOT harvest or graze at IYII time.
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PASTURES AND RANGE LAND - 1I0TE: DO nOT apply after heads form or when &!Iss is
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in boot to milk stage when a seed crop is desired. DO 1I0T use on alfalfa,
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clover, other legumes, or newly seeded pastures. DO 1I0T allow dairy animals to
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graze treated areas within 7 days of applioation.
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--Broadleaf Weeds: Apply 1 1/2 quarts per acre in sufficient water for good
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coverage. Deep-rootod perennial weeds may require a higher rate or repeated
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treatlJlents.
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-Brush: Apply 2 1/4 - 3 quarts in 5 t.o 10 gallons of water plus 1 gallon of .•.••••
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011 or the labeled amount of CBMEX/Land O'Laleell lTJ Conoentrate or :o':.her .:
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adjuvant per acre for Buckbrush, Rabbitbrush, Sagebrush, Coyotebrullh and. other':":
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Chaparral Speoies. Apply 2 1/4 - 3 quarts in 5 gallons of oil or 4 gallons of ••
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water plus' 1 gallon of 011 per acre for Sand 'Shinnery Oak. . ...• .... .
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NOI-CROP AREAS - To control plants susceptible to 2,4-0 in drainage d1bciht.ankc, ... : ..
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fence rows , roadaides, and rights-of-way apply 3 quarts for woody plantij or 1 ..••
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quart for broadleaf weedll in 100 gallons of water'. CBNEX/Land O'Lakl'l'1I lTJ .....
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COIIoentrate or other adjuvant cay be added to increalle effeotiveness;' ·Spray .. · .. •
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woody plants to run-off when fully leafed out and crowinG. Avoid spraY1nl:. :whon
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plants are not actively growing such as mid-Du~er. Reseeding the treated arean
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should be delayed until the followinG season. Deep-rooted perennials may
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require repeated treatcents.
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I
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(
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SPOr TREATHEIT -- For weeds in non-orop areas, use 4 ounces to 3 gallons of
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water, mix thoroughly, and spray to run-off. This high dosage rate may only be
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ufted where injury can be tolerated.
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NOfICB OF VlBRJHTY: Buyer assumes all risk of use, storage, or handling of this
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produot when not in striot aocordanoe with direotions given herewith. .
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------ .. --- -- .... --
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Refer to produot labeling tor use restrictions to proteot ElIDANGEIIED SPECIES.
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EHDNIOIIRED SPECIES RESTRICTIOnS
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;.-
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~e following restrictions apply to use of this product after February 1, 1986.
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Before use of this pesticide on ran~~ and/or pastureland in the oounties listed
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below, you must obtain the PESTICIDE USE BULLETIN FOR PROTECTION OF ENDANGERED
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SPECIES for the county in which the product is to be used· •. The ·bulletin is
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available from your County Extension Agent, State Fish and Game Offioe, or your
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pestioide dealer. Use of this product in a l'U!I1ner inconsistent with the
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PESTlCIM USE BULLETIN FOR PROTECTIOn OF ElIDAHGERED SPECIES is a violation of
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Federal lawp •
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. A'"AKA: Cherokee, DeKalb, Etowah, Jackson and Harshall. ARIZONA: Coohise,
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Coconino, G11a, Graham, Haricopa, Hohave, Navajo, Pima, Pinal, and Yavapai.
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CILIFOBDIA: Alameda, Dutte, Colusa, Contra Costa, Fresno, Glenn, Inyo, Lake,
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Loa Angeles, MendOCino, Herced, Nevada, Orange, Sacramento, San Benito, San
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Bernardino, San Clemente Island, San Diego, San Franoisco, San Joaquin, San Luis
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Obiapo, San Mateo, Santa Barbara, Santa Barbara Islan6, Solano, sutter, Tehema,
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Ventura, and Yolo. COLOPJWO: Delta, Jaokson, La Plata, Mesa, Hontezuma and
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Hontrnse. FLORIDA: Charlotte, Franklin, Jefferson, Lee, Liberty, ond Orange.
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GEOIIGIl: Brantley, Towns, and \layne. 1Wl1II: Islands of liawa11 and I-Iaui and
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the District of Lahaina. IDAHO: Idaho. lLLIROIS: DuPage, Lee, MoHenry, OGle,
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and \l1nnebago. IOWA: Butler, Clarke, Dickinson, Emmet, Howard, Kossuth, Luoas,
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Osoocola, Story, and Hinneshiek. mrruCIY: Fl=ing, lIioholas, and Robertson.
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HIMNtSOTA: Cottonllood, Goodhue, Jaokson, and Renville. HISSOUNI: Christian,
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Dade, and Greene. HEBRASl:A: Cherry, Garden,and !looker. RBVlDA: lIye. JlEW
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/
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HElTCO;.,._Catron, -Chaves, Dona. Ana, Eddy·,. Lincoln,· MoKinley,. oter-o-,- San-Juan, -and ............ .
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Sierra. HOJITB CAROLINA: Henderson. OREGON: Harney and \Jal1owl.~:: 'liOUTd .:
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CIJIOLllIl: Greenville and McCoraiak, tEIlllESSEl'!: Davidson, Rutherfor,d, and':";
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Wilson. TEXAS: Bandera, Brazos, Brewster, Burleson, Culberson, Edwards, El "
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PUo, Grimes, HarriS, Hays, Hudspeth, Jim Wells, Kerr, Kimble, Kleburg, llueoes,":".
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P i ••••• eoon, Pres dio, Real, Refugio, Robertson, Runnels, San Augustine, ~tarr,
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I' I •
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Terrell, Uvalde, Val Verde, and Zapata, UTAH: Beaver, Cache, Carbon, tLl.hesne., ....
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Emery, Garfield, Orand, Iron, Kane, Piute,·San Juan, Sanpete, SeVier, Ulntah, ' •• '
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Utah, Washington, and Wayne. VISCOrISIH: D!IIIe, Pieroe,· Rook. and Sauk. . . . . . , , , , •• , . ,. I'
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