a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
333 lines
19 KiB
Markdown
333 lines
19 KiB
Markdown
# BUTYL ESTER 6 2,4-D WEED KILLER
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- EPA Reg No: **1381-99**
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- Registrant: WINFIELD SOLUTIONS, LLC
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- Signal word: Caution
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- Active ingredients: 2,4-dichlorophenoxyacetic acid, butyl ester (74.4%)
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- Label accepted: 1987-06-15
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/001381-00099-19870615.pdf
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---
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\ c--.I I
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'-0 ' ...
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( June 1, 1987 .
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(Front Panel) f-t-'1 ;:' :,
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1::.-8 1- '11
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CEtlEX/LAl1D 0' LAKES
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BOTIL ESTER 6
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2,4-D HEED KILLER
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~'\..'9 \
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~. ;,
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<. (. "
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1'>.. C, , ~'O1" '."
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.PO . \. <0 ",.r' ' .•
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\~~ "~\ . .J 'i' . ~.
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ACTIVE INGREDIENT: \ ' ' ... '
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Butyl. Ester of 2, 4-Dichlorophenoxyacetic acid···· .. ~ ••••• ~ •• ..... : • .1r .•
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'. . - ~ .... \O',J
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ItJERT InGREDIENTS: ••••••••••••••••••••••••••••••• •.• ::.. ..... jl;.~'l .... "" ••••• , '1", '\'\/
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Total .................................. ~ •.••. ~ ••.•...•.
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• Isomer Specific by AOAC Method No. 6.275 13th Edition 1980
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e2,4-Dichlorophenoxyacetic acid equivalent ••• 59.5J
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Contains 5.6 lb. 2,4-Dichlorophenoxyaoetic acid per gallon
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74.4J
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25.61
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100.0~
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KEEP OUT OF REACII OF CHILDREII (12 pt. type size)
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"" "u) ) CAUTION (18 pt.
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SEE SIDE PANELS FOR ADDITIONAL PRECAUTIONARY STAT~~lTS
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ePA Reg. 110. 1381-99
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EPA Est. No. 407-IA-1S, 407-Mll-IA
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Superscript used corresponds to
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letter in lot number
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NET COli TENTS
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Manufactured For
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CEllEX/LAIID O'LAKES AGROIlOHY CO.
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St. Paul, H1l 551611
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D-87-84-1
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, , ,
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.. , ... ,
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...... , ,
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( <"
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PRECAUTIONARY STATDlEHTS
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HAZARDS TO IIUMAIIS AIID DotIESTIC AllnlALS
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CAUTIOII
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Harmful if swallowed. Do not got
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contact, wash with soap and water.
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contact with eyes wash with plenty
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in-·eyes, on skin or clothing.
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Avoid inhaling spray or mist.
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of water.
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(Side Panel)
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-In oase-of
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In oase of
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Do not forage or graze treated grain fields within 2 weeks after treatment with
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2,4-D. Do not feed treated straw to livestock. Do not graze pastures to dairy
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animals within seven days after treatment.
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ENVIROllMEtlTAL HAZARDS
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This produot is toxic to fish. Do not apply direotly to water.
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oontaminate water by rleaning of equipment or disposal of wastes.
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contaminate waters used for irrigation or dOQestic purposes.
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Do not
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Do not
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DOII'T OVER1)OSE! Follow directions carefully. Do not let spray drift to
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sensitive plants such as vegetables, legumes, grapes, flo~ers or other 2,4-D
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susceptible plants. Use coarse spray to reduce "wind drift". Local spray
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conditions will vary. Check local recommendations first. Use separate spray
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equipment for insecticides and fungicides. Do not make aerial applioation near
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cotton or sensitive plants. Under certain high temperature oonditions, vapors
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from this product will injure nearby susoeptible plants.
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DIRECTIONS FOR USE
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It is a violation of Federal law to use this produot in a manner inconsistent
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with its labeling.
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RE-EIITRY STATEHENT
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Do not apply this product in such a manner as to directly or through drift
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expose workers or other persons. The area being treated must be vacated by
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unprotected persons. Do not enter treated areas without protective clothing
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until sprays have dried.
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Beoause oertain states may require more restrictive reentry intervals for
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various crops treated with this product, oonsult your State Department of
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Agriculture for further information.
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Written or oral warnings must be given to workers who are expected to be in a
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treated area or in an area about to be treated with this produot. The
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PRECAUTIOIIARY STATEI-lEUTS shOUld be read to workers as well sa the instruotion
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not to enter until sprays have dried. When oral warnings are given, warnings
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shall be given in a language oustomarily understood by workers. Oral warnings
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must be given if there is reason to believe that written warnings oBpnot be
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understood by workers. Written warnings must inolude the-follOWing information:
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"CAUTION: Area treated with 2,4-D on (date of application). Do not enter
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without ap~ropriate protective clothing until sprays have dried."
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)
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STORAGE AND DISPOSAL (12 pt. typ~ .size): "
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STORAGE: Store in a secure area, in original oontainer only, aw~.~ from' ,
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fertilizers, food, or feed. Do not store near inseotioides or fungioides., , .. ":
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PESTICIDE DISPOSAL: Pestioide wastes are toxic. Improper disposal of excess "
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pesticide, spray mixture, or rinsate is a violation of Federal Law. If these:::::'
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wastes cannot be disposed of according to label instructions, oontact ynu~'state ,
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Pesticide or Environmental Control Agency, or the Hazardous Waste rep.~sentative"" ••
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at the nearest EPA Regional Offioe for guidance. Do not oontaminatl!. Wilter, ' •
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food, or feed by storage or disposal. ":' .•
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CONTAIIlER DISPOSAL: Triple rinse (or equivalent). Then offer ,'01' reoy,03illl.l or"
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reoonditioning, or puncture and dispose of" in a sanitary landfill, or by' n:ther
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procedures approved by state and local authorities.
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;
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.-.;;.'" J
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When stored at tempera(~res below freezing, it may be n~dSSary to warm contents
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to 450 F and mix thoroughly bef~ e using.
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This produot will control the listed plants and other 2,4-D susceptible speoies:
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Alligatorweed, artiohoke, bindweeds (h~dge, field, and European), tall and
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devil's beggarticks, blueweed (Texas), boxelder, broomweed, buokbrush, buokhorn
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plantain, buckwheat (wild), burdock, burhead, butteroup. oarpetweed, catnip,
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chamise, chickweed, chicory, cooklebur, ooffeeweed, common mullein, cornflower,
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ooyotebrush, oreeping jenny, oroton, cUl'ly indigo, dandelion, docks, dog fennel,
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oommon duckweed, elderberry, annual fleabane, fanweed, galinsoga, wild garlio,
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goatsbeard, goldenrod, ground ivy, halogeton, hemp, henbit, jewelweed,
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jimsonweed, kochia, lambsquarters, loooweed, mallow (Venioe), manzanita,
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marshelder, milkvetoh, climbing milkweed, morning-glory (annual), nettles,
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nutgrass, onion (wild), Parrot feather, pennyoress, pepperweed (field), redroot
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and amooth pigweed, plantain, poor joe , poison ivy, pokeweed, priokly lettuce,
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punoturevine, common purslane, rabbitbrush, radish (wild), ragweed (common and
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giant), rape (wild), redstem, rush, sagebrush (costal, big, sand), salsify, sand
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shinnery oak, sheep sorrel, shepherdspurse, sioklepod, smartweed, sneezeweed
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(bitter), sowthistle (annual), Spanishneedles, stinkweed, sumac, sunflower,
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sweetclover, tansymustard, tansy ragwort, thistle (bull, Canadian, musk, and
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Russian), tumbleweed, velvetleaf, Virginia oreeper, Waterprimrose, Willow, wild
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sweet potato, witohweed, wormwood, yellow rocket, yellow starthistle. Deep
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rooted perennials such as Canadian thistle and field bindweed and woody plants
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may require repeat applioations,
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Apply when weather is warm and plants are rapidly growing. Cold weather or dry )
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oonditions may cause poor results. DO Nor apply if rain is expected within two
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hours.
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Consult your Extension Service or Agricultural Experiment Station for local use
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and crop tolerance situations.
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This product may be applied as a water, 011, or adjuvant based sp.ray. Use
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coarse sprays to minimize drift. DO Nor apply where spray may come in contact
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with any desirable plants or susceptible crops other than those listed on this
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label.
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DO NOT apply this product through any type of irrigation system.
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When using ground eqUipment, keep boom or nozzles close to crop, apply 20
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gallons or more of spray per acre using flooding or flat fan nozzles with 20
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pounds or less of pressure. If wind exceeds 7 miles per hour, sprayinE should
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stop. DO Nor apply with hollow cone or any other mist producing nozzle.
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When using aerial eqUipment, apply a minimum of 3 to 5 gallons of spray per acre
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at 20 pounds or less nozzle pressure using nozzles that produoe a ooarse spray
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pattern. Spray only when wind is blowing less than 5 miles per hour.
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Apply the recommended amount of 2,4-D per acre regardless of the amount of
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diluent used.
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Applicatioa by any !Deana should take place only vbea there is ao danger :cit' ~pra": . :
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drift. Do aot apply aear cottoa, grapes, tomatoes, or other 2,_-D susceptibl~':":
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crops or 'Iqetables. Ill) aot apply vbea the wiacl is blowing toward these crops •• or plants. . ..•.
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HnIHG IISTJ!UCTIOHS: WATER-BASED SPRAY -- Fill the equipment half' ru'l'l of ... : ..
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water, agitate while adding this product, then add rest of water. . ..•
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~IATER AND SOYBEAII OIL OR PETROLEUM OIL-BASED SPR'Y -- First mix this . ",.'Q1uct ... , ..
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with the oil then add to water. If vigorous aEitation is possible, the' oil. oan .. · .. •
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be added last. DO Nor ADD OIL FIRSTI
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(
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Page II
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SOYBEAN OIL OR PETROLE~I OIL-BASED SPRAY -- Add this product to straight oil to
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form a solution. Do not allow water to get into this mixture, if it docs an
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invert emulsion will occur.
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NITROGEN FERTILIZER -- The compatability of this product must be tested with the
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fertilizer before its use· in application· equipment. This is done by means of a
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quart jar test as follows: The amount of this product to add to one pint of
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liquid nitroge~ fertilizer is determined by using this table --
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AHOUllT OF
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2,4-D
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PER ACRE
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1/2 pint
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1 pint
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2 pints
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4 pints
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GALLONS OF FERTILIZER PER ACRE
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10 20 30 40 50
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TEASPoolIS OF 2,4-D PER PIIIT OF FERTILT""R
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2~ 1n 1/3 1/4 1ffl
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1 114 1 3/4 1/2 1111
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2 112 2 1 1/2 1 112
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5 4 3 2 1
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The amount in the table is based on gallons of finished spray per aore.
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Different spray volumes will require appropriate changes in the amount of this
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product added to one pint of fertilizer. Actd the required amount of this
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product to one pint of fertilizer in a quart jar and shake to mix well. Let the
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mixtl!re stand and examine it after 5 minutes and again after 30 minutes. The
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product is incompatible if it balls up, forms flakes, sludges, gels, oily films,
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layers, or other precipitates. If the precipitate can be suspended with /
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agitation the oombination can be used if the equipment has vigorous agitation
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throughout mixing and spraying operations.
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In some cases, when incompatibility occurs, the addition of 1/4 teaspoon of a
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oompatibility agent to the jar before adding this product ~ay solve the problem
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(1/4 teaspoon is equal to 2 pints per 100 gallons of fertilizer). IF THIS DOES
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1I0T WORK, DO NOT ATTEMPT THE ADDITION OF THIS PRODUCT TO THE FERTILIZER.
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-- Fertilizer Mixing Sequenoe: Add this product to liquid fertilizer for weed
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and feed applications at the rates specified on this label. Fill the equipment
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half full of fertilizer, make a pre-mix of 1 part this product and 4 parts water
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and add to fertilizer with agitation 011. Tilen add balance of fertilizer and
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apply immediately with agitation ON. DO Il0T leave spray mixture in tank
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overnight.
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CORM -- Use the lower rate for small annual weeds. Use the higher rate for
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perennial or hard to kill weeds. To avoid injury, do not use with atrazine,
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oil, or other adjuvants. --Preemergenoe: Appl!,' 1 1/3 - 2 213 pints pel' aore
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after planting but before corn emerges. DO Il0T apply to sandy so11s.
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--Emergence: Apply 2/3 pint per acre just as corn plants are breaking ground.
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--rostemergenoe: Apply 1/3 pint per lcre after oorn is up. If oorn is ove~ 8
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inohes tall, use drop nozzles to !reep spray off oorn foliage as much all
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possible. 2/3 pint per acre may be needed to control some weeds, but this rate
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may injure the corn. DO !lOT apply from tasseling to dough stage. DO !lOT apply
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to open whorls. High m~isture and temperature oonditions may cause injury or
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brittleness. DO llOT cultivate for a week to 10 days after treatment.
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--Late Season Weed Control (To reduce weeds that interfere with harvest and
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reduce weed seed production): After silks are completely brown apply ,3/1 - 1:":':
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1/3 pints per acre. ,.. : .... :
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, ,
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SHALL GRAINS (!lot underseeded with a legume) -- 1I0TE: Do not let dairy animals"",
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or animals being finished for slaughter forage or graze treated fields within 2,,: ,,'
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weeks after treat~ent. Use the lower dose rate for small annual or biannual
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weeds. Use the higher dose rate for perennial or hard J kill weeds. ":' ...... , ,
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--Spring I1heat, Barley, and Rye: Apply 1/3 pint per _~re when grain is ,~n, full
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tiller stage (4 to 8 inohes high) but before dough stage when weeds ane'small":":
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and aotively growing. 1 1/3 pint per acre may be used to control difficu~t ~eed" "
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problems, but do not use unless some crop damage is aoceptable. ',:
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I (
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--Winter Wheat and Rye: Apply 113 - 1/2 pint per acre only in spring before
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grain is in boot to doueh stage.
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--Spring-seeded Oats: Apply 1/3 - 1/2 pint per acre at full tiller, but before
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early dough staee.
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--Fall-seeded Oats Orown For Ora in (Southern): Apply 1/2 - 1 pint per acre at
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full tiller, but before early doUSh. stage. Difficult weeds may require hisher
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rate, but some injury may occur since oats are less tolerant to 2,4-D than wheat
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or barley. DO flot spray durilll: or just after cold Weather.
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--Preharvest Treatment: Apply 2/3 - 1 1/3 pints per acre when grain is in hard
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dough stage to control weeds that ~ill interfere with harvest. Apply when soil
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moisture is p,dequate for weed growth for best results. IIOTE: DO 1I0T feed
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treated otraw to livestook.
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MILO (ORAIII SOnOHllH) - MOTE: Some varieties and ~.ybrids are 2,1I-D sensitive.
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Crop injury may also be increased by high moisture and temperature conditions.
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Check with your seed cocpany and Ex.tension Service for advice. Apply 1/3 pint
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per acre when plants are 5 to 15 in.ches tall. A higher rate of 1/2 - 2/3 pint
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per ~~"e may be needed for some we£ds, but chances of crop injury may increase.
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DO IIOT use oil. DO IIOT treat crop less than 5 inches tall or from boot to early
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dough stage. Use drop nozzles when crop is over 8 inches tall.
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a.SBIVAfIOI RUBnE PIOGRAMS lJfD SET-ASIDB ACRES - HaTE: DO 1.1T ulle on
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alfalfa, clover, other legwoes or newly seeded areas.
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-Broadleaf Weeds: Apply 1 1/2 qunrts per acre in sufficient water for good
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coverage. Deep-rooted perennial w(Jeds may require a higher rate or repented
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treatments.
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-Brush: Apply 2 1/4 - 3 quarts in 5 to 10 sallons of water plus 1 gallon of
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oil or the labeled amount of CIMBX/Land O'Lakes 17J Concentrate or other
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adjUYant per acre for Buckbrush, Rabbitbrush, Sagebrush, Coyotebrush and other
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Chaparrel Speoies. Apply 2 1/4 - 3 quarts in 5 gallons of oil or 4 gallons of
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water plus 1 gallon of oil per acre for Sand Shinnery Oak. /
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FOR SET-ASIDE ACRES - Onoe the grazing allowance time has been reached, do not .
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allow dairy animals or animals being finished for slaughter to forage or graze
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treated fields within 2 weeks aftel,~ treatment. DO 1I0T feed treated straw to
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livestock.
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FOR 'CONSERVATIOH RESERVE PROOr.»1S - DO 1I0T harvest or graze at IDI time.
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PASTURES OIl RAHOE LAND - IIOTE: DO HOT apply after heads form or when grass io
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in boot to milk stage when a seed crop is desired. DO 1I0T use on alfalfa,
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clover, other legumes, or newly seeded pastures. DO 1I0T allow dairy animals to
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gr~ze treated areas within 7 days of anplication.
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--Broadleaf Weeds: Apply 1 1/2 - 3 p~nts per acre in sufficient water for sood
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coverage. Deep-rooted perennial weeds may require a higher rate or repeated
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treatments.
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--Brush: Apply -t 112 - 2 quarts in. 5-to. 10, gallo\1s of water plus 1 gallon of
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oil or the labeled amount of CIMEX/Land O'Lakes 17J Concentrate or other
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adjuvant per acre for Buckbrush, Rabbitbrush, Sagebrush, Coyotebrush and other
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Chaparral Species. Apply' 1/2 - 2 quarts in 5 gallons of oil,or 4 gallons o~ .•.••
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water plus 1 gallon of oil per acre for Sand Shin~e~y Oak. ";'.' : . '0 ••••
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HON-CROP AREAS -- To control plants susceptible t, 2,4-D in drainage ditcfibanks, ...•
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fenoerows, roadsides, and riGhts-of-way apply 4 pints for woody plants or 2 2/~· ...
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pints for broadleaf weeds in 100 gallons of Hater. CEHIX/Land O'l,ak.e.s 17~';'"
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Coacentrate or other adjuvant may be added to increase effectiveness,; .• Spray
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woody plants to run-off when fully leafed out and growinG. Avoid sprayinc when';":
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plants are not actively grmling such as mid-summer. Reseeding the treausd·areas ..
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should be delayed until the following season. Deep-rooted perenniul''s may,::::;
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require repeated treatments. . . '. . ..
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I ( Page 6
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SPOT TREA1KERT - For weeds in non-crop areas, use 1/6 pint to 3 gallons of
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water, mix thoroughly, and spray to run-ofr. This high dosage rate may only be
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used where injury can be tolerated.
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ROTICE OF VAlRlNTY: Duyer assumes all risk or use, storage, ur handling of this
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product when not in strict accordance with directions given herewith.
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Reter to produot labeling tor un restriotiolls to proteat ENDANGERED SPECIFS.
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EHpAlIGEREll SPECIES RESTRICTIONS
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The fallOWing restrictions apply to use of this product after February 1, 1988.
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Betore use or this pestiaide on ranee and/or pastureland in the counties listed
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below, you must obtain the PESTICIDE USE BULLETIN FOR PROTECTION OF ENDANGERED
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SPECIES for the aounty in which the product is to be used. The bulletill is
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aYailnble rrom your County Extension Agent, State Fish and Game Office, or yo~~
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pesticide dealer. Use or this product in a manner inconsistent with the /
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PESTICIDE USE BULLEUN FOR PROTECTIOn OF EnDANGERED SPECIES is a violation or
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Federal laws.
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'!'PNKA: Cherokee, DeKalb, Etowah, Jacksoll and Harshall. ARIZONl: Cochise,
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COOOllinO, Gila, Grahao, ~Iaricopa, Hohave, lIavajo, Pima, Pinal, and Yavapai.
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CILIrOBBIA: Alameda, Dutte, Colusa, Contra Costa, Frasno, Glenn, Inyo, Lake,
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Los Angeles, tlendooino, Heroed, Nevada, Orange, Saoramento, San Benito, San
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Bernardino, San Cleaente Island, San Diego, San FranCisco, San Joaquin, San Luis
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Obispo, San Hateo, Santa Darbara, Santa Barbara Island, Solano, Sutter, Tehema,
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Velltura, and Yolo. ca.oRlDO: Delta, Jaokson, La Plata, Hesa, Hontezuma and
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Hootrose. FLORIDl: Charlotte, Franklin, Jefterson, Lee, Liberty, alld Oranee.
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GEOIGIl: Brantley, Towns, and lIayne. BlVlII: Islands or Hawaii and Haui and
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the District of Lahaina. IDABO: Idaho. w.IJIOIS: DuPage, Lee, McHenry, Ogle,
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and Winnebago. IOWl: Butler, Clarke, Dickinson, Emmet, Howard, KQssuth, Luoas,
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Oscocola, Story, and Jl1nneshieic. n:NiUCU: Fleaing, lIicholas, and Robertson.
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MIIIRESOTl: Cottonwood, Goodhue, Jackson, and Renville. HISSOUBI: Christian,
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Dade, and Greene. I1F"RlS"': Cherry, Garden, and Hooker. IOlDl: Nye. REV
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HElICO: Catron, Chaves, Dona Ana, Eddy, Linoolll, McKinley, Otero, San Juan, and
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Sierra. IOITH ClIOLIIl: Hellderson. OIEGOR: Harney and "allowa. SOUTS
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·-~l: . Greenville· and--MoCoraiok •. TERRESSEE~. Davidson,._ Rutherror.d,_.and. __ .
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lIilson. TEllS: Bandera, Brazos, Brewster, Burleson, Culberson, Edwards, El
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Paso, Gril!les, HarriS, Hays, Hudspeth, Jim Wells, terr, lCimble, neburg, I!ueoea,
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Peoos, PresidiO, Real, RefugiO, Robertson, Rur.nels, San Augustine, Starr, •••••
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Terrell, Uvalde, Val Verde, and Zapata. UTlB: Beaver, Caohe, Carbon, .lJUIJ\\e~me; • :
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F.aery .. Garfield, Grand, II'on, Kane, Piute, San Juan, Sanpete, $I!vier,' ·Uihtah •...••
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Utah, VasbingtOll, and Wa)'lle. VISCOrISD: Dane, Pieroe, Rook,· and Sauk. • ' •••
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. . . . .
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. . . . . . . .
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' ..... .. , ,.
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It • I
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