Files
crop-chem-docs/corpus/epa_ppls/19713-325.md
T
justin a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
docker: production image + Gitea Actions for monthly refresh
Dockerfile: self-contained image with corpus + Chroma + BM25 baked
in. Drawbar's compose pulls + runs without volume mounts. Built from
sources.json (labels schema), PRODUCT_NAME=crop_chem by default,
HYBRID_SEARCH=true (always-on for production quality). RERANK_URL +
OLLAMA_URL get set at compose time.

.gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does
full scrape → reindex → image push. Scrapes Bayer (~30 min) +
EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus
diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>.

.gitea/workflows/image-only.yml: on-demand or auto on code-only
pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt,
Dockerfile, sources.json). Reindexes from committed corpus, builds
image, pushes. ~10 min vs ~9h full refresh.

.gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md +
sidecars). Lets image-only.yml rebuild indexes without re-scraping.
chroma/ + bm25/ still gitignored (regenerable binary indexes).

.dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md,
deploy/, .git/ — keeps the image lean. corpus + chroma + bm25
explicitly NOT in dockerignore (those go INTO the image).

Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
2026-05-24 12:32:41 -04:00

745 lines
38 KiB
Markdown
Raw Blame History

This file contains invisible Unicode characters
This file contains invisible Unicode characters that are indistinguishable to humans but may be processed differently by a computer. If you think that this is intentional, you can safely ignore this warning. Use the Escape button to reveal them.
# DREXEL PARATHION 4 EC.
- EPA Reg No: **19713-325**
- Registrant: DREXEL CHEMICAL COMPANY
- Signal word: Danger
- Active ingredients: Parathion (45.3%)
- Label accepted: 1994-10-03
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/019713-00325-19941003.pdf
---
(
(
Ms. Barbara Brown
Drexel Chemical Company
P.O. Box 9306
Memphis, Tennessee 38190
Dear Ms. Brown:
Subject: Corrected Labeling
Drexel Parathion 4 EC
oel
EPA Registration No. 19713-325
Your Application Dated July 29, 1994
I.
The labeling referred to above, submitted in connection with
registration under the Federal Insecticide, Fungicide, and
Rodenticide Act, as amended, is acceptable, subject to the comments
listed below.
1. Throughout the use directions, the symbol ";",, is missing,
replaced on the label copies with a slanted plus sign.
We believe this is a word processing error, rather than
a change to the directions for use, therefore, in order
to accept this labeling, we have manually corrected the
errors. This must be corrected on your final printed
labels.
2. In the "Agr icul tural Use Requirements," page 8, the
symbol for the distance of "%" is also missing due to a
word processing error. We have also manually corrected
this error. Please ensure that this is corrected on your
final printed labeling.
3 . In the last sentence on page 9, the word "quipped" should
be "equipped."
4. In the directions for use on sorghum, change the word
"completed" to "completely."
5. The instructions for storage of this product should read
" ... may exceed 120°F or below 45°F." Please ensure that
the final printed labeling includes the degree sign,
rather than an "x".
I 'J -, ' I' I 1 . l ,
)
6. As a reminder, the
labeling for this
crossbones symbol.
front panel of the final printed
product must bear the skull and
A stamped copy of the label which we have corrected is
enclosed for your records. Before you release the product for
shipment bearing the amended labeling, you must make the
corrections we have indicated. Additionally, please submit five
copies of your final printed labeling for our files.
Enclosure
Sincerely,
DAnnis H. Edwards, Jr.
Product Manager 19
Insecticide-Rodenticide Branch
Registration Division (7505C)
RESTRICTED USE PESTICIDE
Due to very high acute toxicity to
Humans and Birds
1
+---------------------------------------------------------------------+ For retail sale only to certif1ed commercial aer1al applicators or
persons under their d1rect supervision. For use only by certified
commerc1al aerial applicators. Direct supervis!on for this product
is def1ned as the certified commercial applicator being physically
present during m1xing, loading, repair and cleaning of application
equipment. Cert1fied commercial applicators must also ensure that
all persons involved in these activities are informed of the
precautionary statements.
+---------------------------------------------------------------------+
ACTIVE INGREDIENTS:
DREXEL
PARATHION 4 EC
Parathion~ (O,O-diethyl O-p-nitrophenyl phosphorothioate) .
Related Compounds
INERT INGREDIENTS:
TOTAL:
~Also known as Ethyl Par3th10n
43.91%
1.39%
54.70%
.100.00%
Product contalns 4 pounds of Parath10n per gallon.
KEEP OUT
DANGER
PELIGRO
OF REACH OF CHILDREN
POISON
CAN CAUSE DEATH
Si usted no entiende la etiqueta, busque a alguien para que se la
explique a usted en detalle. (If you do not understand the label. find
someone to expla1n lt to you in de:ail).
EPA REG. NO. 19713-325
EPA EST. NO. 19713-MS-l
tltI'i..!>J lh< "f'lCtt:ru,' a,..·. 1'-,' \
Fr"JlIIII(i. .... ...,. i ft .... ,.",. ,
fJII ... 'on"~ '. :'". ,t-.. ,,' ..
ft~,'e"" J <!o~~~ ",',_ ",~.
j < I 7 I ~ 3: :;1. ~
,
•••••• • •• • •• • •
•••••• • • • • ••
••••• • • • • •••••
•• • • •• •••
• • • • •• • •••
• • • ••••• •
• •• •• • ••••
•••• • ••••
2
STATEMENT OF PRACTICAL TREATMENT
This product is an organophosphate insecticide/miticlde.
FIRST AID TREATMENT: Call a doctor (phys1clan). clinic or hospital
immedlately. Explain that the victim has been exposed to parathion and
describe his condition.
IF BREATHING HAS STOPPED: Start artificial respiration immediately and
maintain until doctor sees victim.
IF SWALLOWED: Call a physician or pOlson control center. Drink 1 or 2
glasses of water and induce vomiting by touching back of throat with
finger, cr. ~f available. by administering syrup of ipecac. Do not
induce vom1ting or glve anything by mouth to an unconSCJ.ous ~erson.
IN CASE OF CONTACT: Immediately flush eyes or skin w1th pienty of
water for at least 15 minutes. See doctor lm~ediately.
NOTE TO PHYSICIAN
Antidote: Administer atropine sulfate in large doses two to four mg .
intravenously or 1ntramuscularly as soon as cyanos1s 1S overcome.
Repeat at 5 to 10 m1nute 1ntervals ~nt11 signs of atropini=ation
appea~. 2-PAM chloride is also antidotal and may be adminlstered in
con;unction w1th at~opine. DO NOT GIVE MORPHINE OR TRANQUILIZERS.
Par3th10n 1S a strong chollneSterase 1nhibltcr affecting the central
and perlpheral nervous systems anc produc:ng cardiac and resp1rator
depress:on. At flrst s:gn of pu~monary edema the patient should be
glven supplemental oxygen and treated symptomatlcally.
Continued absorpt10n of the pOlson may occur and fatal relapses have
been reported after 1n1t1al improvement. VERY CLO~E SUPERVISION OF THE
PATIENT IS INDICATED FOR AT LEAST 48 HOURS .
( IlST AYlIUBLE CIPI )
•••••• • •• • •• • •
•••••• • • • • ••
••••• • • • • •••••
••• • •• •••
• • • • •• • •••
• • •••••• •
• •• •• • ••••
•••• • ••••
3
+---------------------------------------------------------------------+
PRECAUTIONARY STATEMENTS
DANGER
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
POlsonous if swallowed. inhaled. or absorbed through skin or eyes.
Rapldly absorbed through skln. Do not breathe vapors. Do not get ~n
eyes or on skln or clothing.
CAN KILL IF SWALLOWED: This product can kill you if swallowed. Even
in small amounts spray mlst may be fatal If swallowed.
CAN KILL BY SKIN CONTACT: This product can klll you if touched by
hands or spilled or splashed on skln. In ~yes or on clothing (llquid
,goes through clothes).
:CAN KILL IF BREATHED: ThlS prOQUCL can k~ll you if vapors or spray
:mlst are breathed.
:PERSONAL PROTECTIVE EQUIPMENT
:Some materials that are chenl1cai-reslstant to th1S product are
:llsted below. If you want more options. follow the instructions for
:category G on an EP~ chem1cal res1stant category selection chart.
:M1xers and Loader3 (who must use the closed s~stem described
:elsewhere on th1S label) must wear: Coveralls over loeg-sleeved
:shlrt a~d long pants. ChemIcal-res1stant gloves. such as Barr1er
Lam1nate or V1toe. Chem1cal-res1staet footwear plus s~cks. Chemical­
reSls:ant a~ron. Protectlve eyewe\r. 1~ the closed system 1S
pressurl:ed. and Chemlca~-resistant headJear for cverheac exposure
Applicators !pllots In enclosed cockpits! ~ust wear:
Long-sleeved sh1rt and long pants. and Shoes plus socks
In add1:10n. pllots must wear chemical-reslstant gloves. such as
BarrIer Laminate or Viton when enterlng or leaving an a1rcraft
contam:nated w1th pestlc1de residues. If taken into the COCkP1t. the
gloves m~st be kept in an enclosed container to prevent
contamlnation of the ins1de of the COCkP1t.
:All other hdndlers. Includ1ng persons who (1) repair. clean. or
:~alnta1n the p!rts of mlx1ng. loadIng. or appllcat10n eqUIpment that
;mai' ccnLu:1 resldues. (2~ clean up sp1lls. (3) handle open
:contalners. cr (4) dlspcse of thlS pesticide. must wear: Chemical­
:reslstant prOLect:ve SUlt. Chemlcal reSIstant gleves. such as
:3arrler Lamlnate or Viton. Chemlcal-reslstant IooLwear plus socks.
:ProtecLlve eyewear. Chemlcal-resistant headgear for overhead
:exposur~. and a respirator wlth elther an organic vapor removing
:car~rIdge WILh 3 prefilter approved fer pestlcldes IMSHA/NIOSH
:approval number pref1x TC-23C). or a canlster approved for
;pestlcldes (MSHA/NIOSH approval number preflx TC-14GI.
+---------------------------------------------------------------------+
•••••• • •• • •• • •
•••••• • • • • ••
••••• • • • • •••••
••• • •• •• •
• • • • •• • •••
• • • ••••• •
• •• •• • ••••
•••• • ••••
4
+--------------------------------_._-----------------------------------+ User Safety Requirements
Users must:
Provide mechanical exhaust ventllation, if product is handled
indoors.
Discard clothlng and other absorbent materlals that have been
drenched or heavily contaminated with this product's concentrate. Do
not reuse them.
Clean respirators and replace cartridges or canlsters according to
instructions included with the resplrators.
Replace gloves frequently.
Keep and wash PPE (coveralls, gloves, footwear, a?rons, protecti'fe
eyewear, etc.) separately from all ether laund~y. Wash FPE after
eac~ day's use, following the manc£acturer's directions. If no such
instructlons, use detergent and hot wate~. Store PPE separately from
personal clothing.
Keep personal worK clothlng (long-sleev&d shirts,' long pants, and
socks) worn while perform1ng mixing, loadlng, application, and other
handl1ng and early entry tasks separate from hcusehold articles.
,After ear:h d:W of use, ' ... ash work cloth:ng separately from household
:art1cles.
+---------------------------------------------------------------------+
+_uu_uu __ uuu ___________________________ lIUT AVAIlABLE eM]
User Safety Recommendat10ns
Users should:
Not rub eyes or mouth with hands.
STOP work and get help r1ght away, if yeu feel sick ln any W37· See
F1rst A1j (Pract1cal Treatment) sectlon of th1S latel. Call a doctor
(phys1c1an;. Cl1~lC, or hOspltal 1mmediately. Explain that the
V1Ctl~ has tee~ e:'posed to parathlon and descrlbe h1S condltio~.
Aiter flr~t a1d 1S glven (3ee F1rst Ald Treatment Seetlon) and If a
doctor cannot come. take vlctlm to cl:nlc or hospltal .
:Wash hands before eatlng, drink1ng, cnewlng gum, uSlng tobacco. or
:uslng the tOllet.
:Remove cloth:ng lmmedlately 1f pest1clee gets lDside. Then wash
:thoroughly and put on clean clothing.
:P&move PP3. all w~r~ clothlng, and footwear lmmediately after
:handllng thlS product. Wash the outslee of gloves with soap and
'water befere removlng, Shower using soat· a~d w~ter. Wear only clean
clothlng when leavlng Job--do not wear contaminated clothing.
The Nat lonal Pes tlC lde Te lecommunica t l0n Network (NPTN) is .<1vpi lable
for recommendatlons regarding pOlsonlDg hlanagement •• M~rge!'.<;'.·
trea:ment, and o::her ~ni::lrmation regardlng the tox::ci!'t! of •
parathlon. The toll-free number for NPTN ~s 1-800-~58-'378.. • . ef!.. ••• • ••
Repeated exposures to Chollnesterase Inhlbltors sucn:at ar~ • ••
contained in this product may. w::.tr.cut warning, causeo·prolM~
susceptiblll::Y to very small doses ot any chollnes~~~ie lhhibitor.
Persons worklng wlth thls product should have freque~~·blood·tests
:of thelr chollnesterase levels. Ii the cholineste~ase leve~ :(~lls
:below a critical pOlnt. no further exposure should be allow~Q.~ntil
:it has been determined by means of blood tests that the •• :.
:cholinesterase level has returned to normal. Before using this
:product, consult the Agricultural Extension SerVlce or Experlmental
:Station for specific recommendations regarding such blood tests.
+
+---------------_._------------------------------------_._--------------+
5
POISON SIGNS (Symptoms)
Parat~ion is a very dangerous poison. It rapidly ~nters the body on
contact wIth all skin surfaces and eyes. Clothing wet with this
material must be removed immediately. Exposed persons must receive
prompt medical treatment or they may die.
Some of the SIgns and symptoms of poisonlng are: Headache, nausea,
vom1ting, cramps, weakness, blurred vision, pin-point pupils,
tight~ess in chest, labored breathing, nervousness, sweating, watering
of eyes, drooling or frothing of mouth and nose, muscle spasms and
coma.
ENVIRONMENT~L HAZARDS
This pesticide is highly toxic to figh, aquatic invertebrates, and
wildlife. Birds in treated area may be kIlled. ShrImps and other
aquatIc o~ganisms may be killed at recommended appllcation ratea. For
terrestrial uses, do not apply directly to water, to areas where the
su~face water is present, or to intertidal areas below the mean high
water mar~. Runoff and drift from target areas may be hazardous to
~quatlc organisms in adjacent aquatic SItes. Do no~ contaminate water
when disposiag of eqUIpment washwaters. ThlS product is extremely
tO~lC to bees exposed to direct treatment or residues on blooming
crops or weeds. Do not apply th1S product or allow It to dri~t to
bloom~ng crop or weeds 1f bees are v~s~:lng the treatment area.
PHYSICAL AND CHEMICAL HAZARDS
Do not use or store near heat or open flame.
DIRECTIONS FOR USE
It is a viol at 1011 of Federal :aw to use :hlS product in a manner
lncons13t3nt wl~h ItS labellng.
For any requlr~ments speciflc t: your State or ~ri~e. c~~s~lt the
age~c1 r~spcnslble for P03tlc~de regulat!cn.
APPL:CATION RESTRICTIONS
Aerlal Appllca:ion Only: Et~yl parathioc may only Cd applled aerlal 1.
and only by a certlfled commerclal appllcator as deflned In FlFRA
2(e)[3). HUMAN FLAGGERS ARE STRICTLY PROHIBITED DURING AERIAL
A?PLICATICN.
No Spray or Drlft Cn Any Person: Do not apply this produ:t :n a way
that will contact any perso~, elther dlrectly or throug~ drlft. Durlng
applicatlon keep ALL persJns out oi (1: the treated area plus any area
withln 100 feet of the treated area, and (2) any additional area where
there is a dang~r of drift. Keep all llvestock and pets away from
treated area and where there IS danger of drift.
Areas Where _ Appllcatlon Is PrOhlbIted: Do not apP\I •• ~~lS i'::~~ct
wlthln 100 teet of bUlldlngs. putil ~ r,oads, or boctl~ :of water. Do no:
apply wlthin 100 feet of property lines, unless tne owner pt ~he
adjacent property has given prlor wrltten consent ·t~·'he ~~~cation
and has been informed of the tlmlng of the appllcat·~h and t~e
appropr late entry restr lctlons. ••••• : ••••• • • Crop LimItatlons: ThlS product must not be applle~.~~·any c£op other
than alfalfa, barley, cern, cotton, sorghum. soybeans, s~t1~wer, and
wheat. Any treated crop \nust b8 harvested only by mechani~'~ means.
Hand harvesting of treated crop IS prohlbi ted. : •••
Chemigation Prohibited: Do not apply thIS product through'any type of
irrigatlon system.
[BEST AVAIlABLE c.d]
6
Drift Reduction Measures: Do not apply thlS product if the wind
exceeds 10 miles per hour. Apply only from nozzles located not more
than 75% of the distance from the center of the aircraft to the wing
tip of helicopter rotor tip .
• ••••• • •• • •• • •
•••••• • • • • ••
••••• • • • • •••••
• •• • •• •• •
• • • •• • •••
• • •••••• •
• •• •• • ••••
•••• • ••••
• I
7
+---------------------------------------------------------------------+
AGRICULTURAL USE REQUIREMENTS
Use this product only in accordance w1th 1tS label1ng and with the
Worker Protection Standard, 40 CFR 170. Th1S Standard conta1ns
requ1rements for the protection of agricultural workers on farms,
forests, nurser1es, and greenhou3es, and handlers of agricultural
pesticides. It contains requirements for tralnir.g, decontamination,
,notification, and emergency assistance. It also contains specific
:instruct1ons pertaining to the statements 1n this labeling about
:personal protective equ1pment, restricted-entry intervals, and
:notificat1on to workers. The requirements in this box only apply to
:uses of th1S product that are covered by the Worker Protection
'Standard (WPS)
IMPORTANT: The except10ns 1n the WPS pertaining to personal
protective equipment, restricted-entry intervals. and notification
to workers do NOT apply when this product is used.
Restrictions on En:ry to Treated Areas:
Do not enter or allow any person to enter into entry-restri~ted
areas (treated areas plus areas within 100 feet of treated areas)
:dur~ng tie restr1cted entry 1nterval IRSI) of 3 days (6 days for
:oornl and dur:ng ar.y longer per10d of time prescribed by State law
:or regulatlcn. Entry lnto entry-restricted are,s i 1nc:ud:ng e~rly
:entry that would otierWlse be permitted under the W?S) by any person
. 13 ~ROHIBITSD. except for per30ns wto are (11 handlers performing
;crop-advlscr tasks or 12 workers ~erformlng :rrigation-related
;tasks.
:Restr:ctlona for All Persons Who Enter Entry-Restrlcted
:~hen any person enters the treated areas or within 10C feet of the
:trea:ed area before the explrat:on of REI all of the followlng
:requlrements must be complied wlth:
:1' ~c entry 15 per~ltted. except for persons whc are performing
: ·:rcp-ad'lls::r tasks or 1rr1g.3.tlon-related task3.
:. ~o ~er£on ~s a~lcwed to ente~ or remal~ 1n entry-restrl~t~d ar~as
: jurlng ap~i:catlon and untll ~eur (4) hcur3 a~ter appl1cat1on :s
:c')mploate .
:3) No persen 15 allcwed to rema~n 1n 3ny entrl-rest~lcted area for a
~tot~l of mc~e than ~ne (I) hour In any 24-hour ~ariod,
:4\ Eac~ p~r30n must wear th~ par3~nal prJtectlve ~qulpment 3peClfied
:foc ~arl! entry on thIS label.
:5 Each p~r30n must be prOVIded the p[ote~t1ons In the WPS and in
:t~1S label:ng. :i the two reqUirements are not Identlcal, the
:=~qulr~~en~s t~a~ ar~ t~e mcst restrlctive must be f~llowed.
:6i Each per30n. except owners of the farm and members of their
:lmmedlate fam:ly. must have rece1ved tra1ning as follows:
: a' Currently cert1f1ed as an appl1~ator of restr1cted-use.··.·.
P~3t1.Cld-?:;, OR : •• :-: •••
d . • •• - • : (b i Cucrent:y tr:H:1e as a nandler ur.der the requlI'emellts 0;' tpe
: 'f'.-J?S. CR •••••• • •• •• •••• : l·c \ ::'-l~rentli' tra:ned as a 'Nor~er und~r the requ1reftlAr1t3 Qf the WPS
: an·j. ~n a·!dlt:C:1. 15 ::..nfcrmec: (L how t.o P'.lt on. us.~_ •• and t·cr~~· off
:P?~ ~orrectiv. (I:) about t~e Importance of Washlna th&rouoh}y after
~.... -:remo·/lr.g PFE. and ,1:1: ho'" to prevent. recognIze, and glv~.e!).rrect
: fIrs: ald for heat Illness. • •••
I ••••
• •
+----------------------------------------------------- -----~~~--------+
(lEST AlAlUILE eM]
8
+---------------------------------------------------------------------+
:AGRICULTURAL USE REQUIREMENTS (Continued)
(7) Before entering the entry-restricted area, each person must have
read the product labeling or been infermed ln a manner the person
can unders~and 0: all the requlrements of all labellng requlrements
related to safe use of the pest1c1de, includ1ng signal word. human
hazard precautions, first a1d instruct1ons, symptoms of poisonlng,
and personal protect1ve equ1pment requirements for early entry.
(3) Appropriate measures to prevent heat illness must be taken for
each person.
(9) Each person must be provided a decontamination site that is
reasonably access:ble and is withln ~mile of that persen.
(Exception: if the site where the person is working lS more than ~
mile from tne nearest p01nt reachable by vehicle, the
decontamlnation slte may be at the access pClnt.) Each
decontam1nation Sl~e must conta1n an adequate supply of soap and
s:ngle-use towels and an adequate amount of water fer routine
washlng, emergency eyeflush1ng, and emergency whole body washing .
The ~ater mU3t be cf a quality and temperature that w111 not cause
.11lness or in~ur7 when it centacts the skin or eyes or 1f 1t lS
:s~al10wed. The s:te must also contain a clean chanoe of clothing,
':0) Each pers:~ mus: carry an ~yefl'!sh d13penser ~c~taini~g ~t
least one pint of water that meets the 1uallty and tem~erature
~riter1a llst@d for de:ontamlnat10n water 1n (9) abeve.
Ill) After the actlvity 1n tne entry-restricted area, scap, clean
,tQwels. and an adequate amount of water for thorough wash1ng must be I
: ~vallable at the place where the person removes the PPE. The water
:must meet the quallty and temperature cr1teria listed fer
:decontamination water ln (9 1 above.
: ( 12) Each per,·=r. :nust wash the-roughly aite:' rem':Vlnc; ?PE.
: 1131 P~rscnal p~ot~ctlve equlpm·!nt worn during early entry must not
:b~ W0r~ hJme. :IC perscn. other :han J~ne~s ot the fa=~ an~ members
:of t~e~= Imm~d13te f3~11y, may t3~a hcm~--b~fore It is cleaned--PPE
~wcrn j~rl~g ~a=:'l e~try .
:Personal ?:,ctec:~':e Eq~lpment f~r Early Entry: PPE requI:'ed for
:ear1y entry to treated areas that lS permItted on this label is:
:Coveralis over long-sleeved shirt a~d long pants
:ChemIcal-resls:a~t glcves, such as E3rrier Lamlnate and Viton
:?~ct~ctlve eyewear
:Chemloal-resistant heaj~ear for overhead exposure
:Notl~lcatlon About Applicat:on And Entry Restrlctlons:
:Notify workers (Jther than wor~ers who are members of the farm
:owners' immedlate famlly) of the applIcatIon by wa~Qh~~ th~~.~allY
:If they w:ll be WithIn, mlla ot the treated area. :I~ ~ddltlgn,
:traated areas must be posted With WPS signs at (or'100'fee~ o~tside'
: all US'.la':' pCInts of entry or at (lGO feet outside) '~'!: the·..,5t)ners
:of the treat~d areas affordIng maXImum visitility. •••• • • ••••••
+--------------------------------------------------~~~.---~----------+
•• • ••••• • •• •• • ••••
IIIST .IIILABLE eM J .. ::"
9
NOTIFICATION TO FARM OWNER/OPERATOR
A certIfIed commercial applicator must not apply this parathion
product on a farm until he or she makes sure the owner of the farm (or
person responsIble for managing the farm) has the followIng
InformatIon in wrIting: (1) specific location and descri~tion of area
to be treated. (2) time and date of application. (3) product name. EPA
registration number. and active ingredients, (4) the entry
restrIctions including the restricted-entry interval. (5) the
requirement for both oral warnIngs to workers and posting of t~eated
areas. (6) the requirement that crops treated with parathion be
harvested mechanically and the prohibitIon on hand ha~vesting, (7) the
IncIdent reportIng requirements set forth on thIS label. and workers
or other persons during or after applIcation. This requirement is
satisfied if the owner/operato~ of the farm has a copy of this
labelIng.
PROTECTION OF APPLICATORS AND MIXER/LOADERS
Applicato~ ProtectIon: The CCCk~lt of the aircraft used to apply thIS
product must be fully enclosed whIle this product IS being applied. No
pl!ot may apply thIS product if the pilot has earlier durIng the 6ay
ot ap91lcatIJn performed any mix:ngiloadlng activitIes (othar than
ac~:ng as a~ observer' involvIng any pestlcide product contaInIng
parathlO~. Human flaggers are prohIbited.
Mixer/Loader Protection: An observer must be present durIng all
miXIng/loadIng actIVIties in order to f';rnlsh assistance ln the event
of an accIdent. The observer must not act as a mixer/loader and need
not wear personal protective eqUIpment.
ThIS product must be mixed and loaded in a closed system. as described
below:
When handlers uae closed systems. enclosed cabs. or a:rcraft In a
manner that meets t~e reqUIrement IlsLed In the Worker ProtectIon
Standard (WPS) for agricultural pestICIdes [40C?R 17r.2~O·d)(4-6)1,
the handler PPE reqUIrements may be reduced or ~0dified as specified
in the WPS.
The lIquid pesticide must be ~erJved from l~S original shIPPIng
container and transfQ:red t~reugh ccnnectlng hoses. pipes. and/or
couplIngs that ~re sufficiently tlght tJ prevent handlers or other
perscns from contactIng th~ pa:ath:oc concentrate. use d:lu:ion. or
rlnsate solutIon. A complete seal by d~y break or screw-on couplIng to
the openIng of the orIgInal containe: sha~l be req~l~ed.
All hoses. pIpIng. tanks. and conneC~lons used In the system shall be
of a type appropriate for the produc: beIng used and the pressure and
vaC'lum lev"!ls lnvolv"!d. The svstem ahall be desloned and ooe·; .. t.ed so -~ . - ....!..!.... . •••
~hat the concentrated form 0: th12 pr~duct IS not ul~eJ:more ~han 25
pSl or pressure at any pOInt in the syst"!m beyond or do~nstr~a~ from a
pu;np prcduclng poslt:ve pressure. The closed system "I1Io.!>"1: be·adQ1Juate
LO make ner:essar'[ measurements of Lhe product beIng uW. E.:tecrlal . h l' t :l h ••••••. slgnt '1auges s a J. e q'...l1pper WIL '!alves se that ttM:(o~ow ef
pestlc:de to tte SIght gauge can be shut off In caa~.~~·breakage or
leakage from the gauge. : ••••
( IlST AflfUBl£ co;o
••••
• ••• • ••••
10
Shut-off devlces ~ust be installed on the e:~it end of all hoses and at
all disconnect points to prevent leakage of parathion when the
transfer is stopped and the hose is removed or disconnected. If a hose
carried parathion concentrate and has not been rlnsed In accordance
with the Instructions In thlS section, a dry ccuple shutoff device
that will mlnimi=e parathIon drippage to not more than 2 mI. per
disconnect must be Installed at the disconnect point. If the hose
carried diluted-for-use parathion or r~nsate solution, a reversing
ac:ion pump or a si~ilar system that wlll empty the hose and eliminate
drlpplng of liquid from the end of the hose may be used as an
alternative to a shut-off devlce.
In mIxlng/loading operations do not pour this product fr~m Its
container. Before opening the ccntainer. make sure that the container
IS restlng securely on the grollnd or a sturdy support, wlth the top
(opening) end up and approxlmately level.
Remove the product from the contalner only by use of a vacuum­
producing pump system connected to a probe system that IS llsted by
t~e State of CalIfornia under that 3tate's program establlshlng
cr:teria for closed-system handlIng of TOXlcity Category I pestlcides.
Sxa~ples of Callfornla Ilsted systems are the Chemprobei~! Model II
syst~m 501·j by Charlor ~fg. Co., Inc .. P. O. Box 2174. SalInas, CA
93 Q 02. telephone 402-422-5477 or the Pr~tect-O-Loader Mode~ XM-l
sy3t~m soLd by Protec~c Mig. C2 .. 20~39 ~lrerock Road, Bend. Or.
97701: telephone 503/382-6386. The probe system shall be screwed into
the threaded openlng In the top 0: the contalner to ferm a watertlght
connectlon. uSlng approprlate adaptors provlded by the probe
manufacturer as necessary. The Instructlons provlded by tne seller of
the probe system shall be followed. except that a removable probe may
not be removed frem the contaIner until tne contaIner IS empty and the
contaIner and probe have been thoroughl? rlnsed as requlred by thls
se·::tlon.
T~e cJo3~d-system must pr~v:de for adEq~at? rins:ng ci an~' r~mcv~bl~
probe a~d of all ccnt31ne=s that are net lajeled for =et~rn to the
reglstra~t. Rlns~ng must ~e done us:~g a l!qUld tha: con~alns no
pestlclde. ~he rlns:ng system m~s: be capable cf spr3y-rlnslng the
Inner surface of tte contalner. The rlnse Solutlon snaIl De r~mcved
from the pes:lclde ccnta:ner c~nc~rrent wlth tje l~tr~d~ct~on of the
rlnse medium. The rl~se Solutlon sha~l go Into tre pest::lce mlX tank
cr appl:cator ~ehicle Vla the closed system.
rh~ syst~m shall be ::~sed ac=ordl~g tc the 3p~c:i:~3tl,:n3 0~ t~e
man~fact~rer of the probe system. or. in the absence of such
speclflcatlcns. by movlng at least one half of the c~ntalDer volume
through the system. A mInlmum pressure of i5 PSl shall be used for the
spray rlnse. Parathlon contalners shall be pr~tected agaIns~.~:cesslve
pressure .jurlng the contaIner rlnse operatlon. Meas\Hf~.sha'V.·~ taken
t·::> pre'lent the spr"!y rlnse procedure fr.)m caLs:ng ail J!n;rea.~e.ln
pre:;sure on the IDs:de of tl:e contalner wal':'s of mote tnan :. ~s.:..
Elther the operatDr of the closed system m~st ha'/e ~t-~·rt1ble..a~: the
tlme of operatl:n 3 compl",te set of W:-ltten Instr~ctlOO.3 fOf."f'pper
operatlon of the sys:em. c·r tne ce::-tlf led app;'lcatol"'~'~t ,:t>cu;nent In
·.n1tlng bef'Jre an :!Jeratcr uses che cl'::>sed s'!stem t:wt..the )p~rator
h'l.s been adeql,ately traIned In the pr)per operatlon cf the i;:!~!:oa'l\'
llUT InlUBlE elif]
•••• • ••••
11
INCIDENT REPORTING
A telephone notltlcation must be made lf mixing. loading. or use of a
product contalnlng parathion results in inadvertent or unexpected
human exposure to the product or liiness resulting from exposure to
the product. splll of the product, an investigatlon by Federal, State
or local authorltles of allegatlons lnvolving drift of the product, or
the deaths of blrds or other wildlife. The certified applicator or the
owner of the treated land must notlfy by telephone the Chlef.
Compliance Branch. Office of Compliance Monitoring, U.S. EPA. at 202-
260-33 7 5 wlthln seven days of becomlng aware of the lncldent.
GENERAL INFORMATION
Mix Paratjlon 4EC ln water to form an emulsion spray solution. To make
the spray Solutlon. flll the spray tank half full with water. agitate,
add the proper amount of Parathion 4EC and then fill the spray tank
witt water whlle still agitating. Continue to agitate during use.
Aircraft should apply the recommended amount of Parathion 4EC in not
less than 1 gallon of water per acre. Always use suff:clent water for
ade~uate coverage of the crop follage.
~her~ a dosage range :s glven, use the lower rate on small cr young
p:ants or wlth Ilght lnsect lnf3statlons. Use the hlg~er rat~ on
mat~r~ pla~ts or Wl:~ heavy Ins~c: lni~statlon.
Th~ lffioun: gl'/~~ tJ use are the 3mc~n~s of ?3rat~lon ~Z~ :0 apply per
acre per appllcat:cn. The hazard; and precautio~s for handllng
Parathion 4EC are equally appllcabl~ to it after d:lut:on With water
for spray applicatlon.
ALFALFA: For three-cornered alfa:fa hoppers. alfalfa caterpillars. and
spittlebugs. use ~pint per acre. Fer aphIds. alfa:fa weevll larvae
~nd adult weevlls. armyworms up to thlrd lnstar. clover leaf weevlls.
cll:nblng :utwcr~3. wetworms, grasshoppers. crlckets, s~ctt~d alfalfa
aphIds. leafhoppers. Lygus bugs. thrlps. and tortlc:d ~oths. use ~to
1 plnt pe: acre. Fe: alfali3 s~ed c~alc:ds centrel en a!falfa grcwn
for soeed. use 1ft. to 1 pint per acre. Callfornla and Ne"/ada regt.:latlons
:Iml~ the use of thls material to not mere than 3/4 pInt per acre. For
=lcver w~e~:ls. spljer mltes. blIster beetles. ASlatl= garden ~eetles.
sw~et clover weeVils. and green June beetles. use 1 pint per acre. For
teet armyworms anc corn earwor';lS use 1 to 1 '12. pint per '\cre. [:0 net
s~ray alfalfa durIng bleom rerled to avold lnJury to heney bees. Do
not apply wlthln 15 days of harvest. cuttIng or forage t.:se. Do not
aprly lf the srep or weeds ln tje treatment area are ln bloom. The
restrlcted-entry interval is 3 days.
CORN: Fo;:- centrol of European corn borers, use 1 plnt ~er a(i~·~~.APply
• • ••• •• • •• tne first spray when 75% ot the corn plants show sh~:- .~le fe~dlng and
i''Jllow With two additional sprays at 5 to 7 day inte=rva~s. !J~e •
sufflclent water per acre to provvle complete cever~t'"<Snd ~e.·o:~r,:ain
whorls of plants are woell treated. F·)[ corn leaf aphl~io" USQ 'j..nint - '"1 d 1 •••••• poer acre. r or t11 . ar:nyworms .:orn rc·otworm a u ts. ~!I!lo'"wcr:.ls up to
third lns':ar, -::11;r.D1WI cutworms. grClssnoppers and Ja.fa~.E!"s~ cee-tles.
use 3/~ pint per acre. To control stink bugs and spider mlt~~~·~se 1
plnt poer acre. ':'0 control corn ean/orm. use 1 plnt per acre ~'1M apply
to Silks as soon as they appear. Make 3 to 4 appllcatlons a~.~·to 3
day lntoervals as lnfestatlon warrants. Re-apply lmmedlately after
rain.
{ BESl AYlIUBffcOFl)
12
To control chinch bugs, use 1 'h,pint per acre. Do not apply within 12
days of harvest, cuttlng or forage use. The restricted-entry inlerval
lS 6 days.
CORN (Sweet): 1'e, contr·:)l fall armyworms, a~hlds and sllkflies. use 'b­
plnt per acre. To control sap beetles and spider mi:es, use 1 pint per
acre. To control corn ear~orm apply to sllks as soon as they appear.
Make 3 to 4 applications at 2 to 3 day lntervals as infestation
warrants. Reapply immediately after ra:n. To control chinch bugs, use
1 In. pln t per acre. : f crop is intended for canning, consult your
cannery fleldmen prlor to applicatlon. Do not apply withln 12 days of
harvest. The restrlcted-entry interval is 6 days.
COTTON: To centrol aphids, mltes. cotton leaf~orms. cotten
f!eahoppers, garden webworms and thrlps, use + pint per acre. For
cabbage loopers. use 3/4 to l plnt per a~re. For boll weevlls and
sti~k bugs, use l to 1~ plnt per acre. For salt-marsh caterpillars,
use 1 to ~ plnts per acre. For bollworms. cottae leaf perforators,
Lyg~s bug3, fa:se chlach bugs, serpentl~e leaf m1ners and seuthern
garden leaihoppers. use 2 plnts per acre. Make f:rst appl1~at:on whe~
l~SeCt appear and repeat at 7 day intervals 1i required. I~ deslred,
:hlS f~rmtlllt:0~ may b~ c2mtlnEd Wlt~ ~ther !nSectlcld~E ~n a complete
,:c::cn Sp:3Y ;r0g~3m. Do nc: feed c~tton ~rash ~o da~ry an:mals or
a~l~als being r:nisned for s:aughter wlthln 15 jays or appl~:atlcn. JO
not har~est ~lthl~ 7 days after appl:cation. The restri:ted-entry
ln~erval 13 3 days.
8MALL GRA!NS '~heat. Barley): To con~rol arm?wcrms up to thlrd lnStar,
api1lds (:;reenbugz) and w1~ter t;'ra1n ml tes. use 'n. plnt per acre. For
tr.r:9s. use ¥Lto:) 3 4 pint per acra. For Say's pl"nt Dugs. use 3/4 r:nt
per acre. ?or b~ack g~ass bugs. s:lnk bugs. whlte splder mites.
leafho9gers. cllmtlng cut~or~s. grasshoppars and ~rQwn wtaat rnltes.
U5~ 1 p:~t per acre. ?or chin:h bugs. false chlnch but;'s and Banks
gr3.SS mltes. us-= l~t:l~t per acr'~. Do no: apply w:thln ~5 days of
jar~est. cuttlng. or forage use. The restrlcted-entry :nterval 15 3
daiS.
30RSHUH: 7c control sorghum mldge. apply at a rate of 1 to = plnts per
acre. ~ak2 2 3.?pi::at1cns 3 to 5 days apart wnen a~prox:mately 90' of
the heads nay! c:mple:ed emergej frcill t~e coot or not later than start
cf D:i.com.:.ng. For a;:nlds (9ree~bu<;:s) and mltes. use 'ir-p:nt per a·:r8.
For sorghum webworms. fall armyworms, armyworms up to thlrd lnstar and
cern earwcrms. use 3/4 to 1 plnt per acre. Leaf injury may occur on
some hybr:d varletles of sorghum. Spray a few rows a week o~~~ before •••••• •• ¥
boct:ng tc test e:fects cn pLmt.;;. Do n'Jt apply witlt.:.n:.t2 day~ of
har·/est. ·::utt:ng or ferage use. The restrlcted-entr'! lnrer-/a.L 10'5 3
day.:. •• : •• : ••••• :
• • •• •• 1/- ••••••
30YB~ANS: To con:ro: webwor~s. use nPlnt per acre. q~'~onttJl velvet
bean cat'3rplL.ar. green cloverworms. two-spotted ml~'.o1nd s:tnk bugs,
use 1 plnt per acre. To control corn ean/orms an:i fall army·~c.f~. use
1 tJ llL p:nt per ac~e. Do not apply wlth1n 20 days of harvest";·cutt1ng ~ ~ .... or rorage use. The restr1cted-entry lnterval 1S 3 days. ..:.
\ BUT ,"IUILE tift]
13
SUNFLOWERS: To control sunflower moth, use 1 to 2 pints per acre on a
schedule of 2 to 3 appl1cations at 5 day intervals. Hybr1d sunflowers
completely bloom in 12 to 15 days; thus the initial application should
be made when 10 - 20% of the plant have begun to flower and moths and
young larvae are present. Do not apply later than 30 days before
harvest. The restr1cted-entry interval is 3 days.
STORAGE AND DISPOSAL
DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL
3TORAGE: Store in a dry location away from children, an1mals, foods,
feeds, seeds, and other agricultural chemicals. Keep corrtainer closed
when not uS1ng. Do not allow water into container as th1s may cause
deter10ration of product. Personnel must wear the personal protective
equ1pment spec1fied for "ALL Other Handlers" Ilsted 1n the Hazards to
Humans section of this label when handl1ng open containers or cleaning
up sp1lls. Do not store under conditions where temperature may exceed
120xF or below 45xF. Keep storage area looked when not in use. In the
event of sp1llage or leakage, soak up material w1th absorbent clay,
s~nd, sawdust, or other absorbent mater1als wh1le wear1ng appropriate
protective equipment. Scrape up and d~spose of in accordance with
information glven under PESTICIDE rIS?OSAL. In case of fire or other
emergency. report at once by toll-free telephone to aOO-~21-9300.
DI3POSAL:
P~STICID~ DISPOSAL: Fastl0lde wastes are acutely nazardous. Improper
dIspcsal oI e:{cess pesticlde. sFray m:xt~re. or rlnsate 1S a v:olation
of Federal :aw. If these wastes cannot be d1sposed of by use according
to label instruct1ons, contact your State Pest1cide or Environmental
Control Agency or the Hazardous Waste representatlve at the nearest
EPA Reg10nal Office for gUIdance.
CONTAINER DISPOSAL: Metal Contalners - Tr1p:e r:nze (or equ1valent).
Then cfier fer recycling or recondltiOTIing, or puncture and dispose of
ln a sanItary :ana£1:1. or oy ot~er prccedures approved by s~ate and
ll:ca: author:tles .
WARRANTY - CONDITION OF SALE
OU? R2COMME:IDAT:ONS FOR USE of thIS product are based upon tests
belleved reliable. Follow directions carEfully. Timing and method of
"!::>r,ll··ati,)tl. ·".."U-,..,r and ~r<)p r:; 'ndl.tic:ls. mlxt:.lreS WIt.l I)ther
~hemicais no~ spec:flcally reccmmended. and cther influencIng Iactors
In the use of thiS product are ceyonc the control or the seller. Buyer
a3su~es 311 r:sks of use, storage and handl1ng of thls materIal not in
strlet accordance w1th d1rectlons gIven herewith.
In no case shall Drexel or the Seller be iiable for consequential.
speclal or indlrect damages resulting from the use or handl~tt'i·~f this
product when such use and/or ha::dling 1S r.ot in str!~~·:cccr·cf3.flce ',ollth
directlons given herewIth. The f:ngoH.g 15 a conditlkn· ~f sa).e Py
Drexel ChemIcal C.,m,:an·{ 3nd IS lc·::epted as such by t!Jo\:-·~uyet •.• ·.:
• • •• • • •••••• ".... . • • •• • •••••
t BUT AVAIlABLE con)
• •• •• • ••••
•••• • ••••
\
,
\