a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
379 lines
19 KiB
Markdown
379 lines
19 KiB
Markdown
# METHYL PARATHION 25 W.P.
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- EPA Reg No: **279-2669**
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- Registrant: FMC CORPORATION
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- Signal word: Danger
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- Active ingredients: Methyl parathion (25%)
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- Label accepted: 1987-11-05
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000279-02669-19871105.pdf
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---
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(
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(
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.-
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Code 30392
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I -
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'"
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Net Weight
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RESTRICTED USE PESTICIDE
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Due 10 very high acute toxicity to Humans and Birds
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For relail sale 10 and i.I_ !.>:tly by certified applicator or pefsons under their dire:!. s~sk>n and
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only lor those uses covered ::-v the certified appIieator's certilicalion. Direct Sl. -pervision for this
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prodUC1 is defined as the cert1.1Od applicator being physically present durinq IfDlication. nixing.
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loading. repair and cleaning of application equipment Commercial cerliflf otppli:am must also
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ensure (hat all persons invotvod in lhese activities are infocrnecJ 01 the precautiOfU rv slilements.
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Methyl Parathion 25 w.P.
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Insecticide
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EPA Reg. No. 279-2669 ZA EPA Est.. 279-
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Actl.o IlIlIredlenlo: By WI.
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Methyl Parathion- ..................................... 23.7&%
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Related Compounds .• _. _. . • . . .. . .. . . . . . . . .. . ... . . . .. 1.25%
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Inert Ingredients: ....•.................................. 75.00%
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100.00%
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O(O,O-dimethyl·O-4·nilrophenyi phosphorothioale)
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STOP! READ THE LABEL
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CAN KILL YOU
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DANGER
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Keep out 01 reach
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01 children
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POISON
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See side panels
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lor antidote
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and precaullons
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PELIGRO
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PRECAUCION AL USUARIO: Si usled no lee ingles. no use esle pro·
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ducto hasta que la etiqueta Ie haya sido explicado ampliamenle.
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ACCEPTED
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NOV 5 1987
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Under the Federol Insecticid.,
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Fungicide. ond Rodentioid'3 Aot.
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as amended. for the p •• t1c:ide
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registered under / .....
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~
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SWAllOW
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DO NOT TOUCH
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DANGER-POlSON-PRECAUTIONS
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POISONOUS IF SWALLOWED
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ThIS product can kill you if swallowed even in
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small amounts. spray mist or dust may be .
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latal if swallowed
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POISONOUS BY SKIN CONTACT
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POisonous II louched by hands or spilled or
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splas'1ed on skm. in eyes or on clolhing (liquid
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goes Ihrough clothes"
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POISONOUS IF BREATHED
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Brealhing vapots. spray miSI or dust may be
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lalal.
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USE ONLY WHEN WEARING THE FOLLOWING PROTECTIVE
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CLOTHING AND EQUIPMENT DURING MIXINGILOADING. APPt.I·
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CATION. REPAIR, AND CLEANING OF APPLICATION EQUIPMENT.
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DISPOSAL OF PESTICIDE AND EARLY REENTRY INTO TREATED
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AREAS: protective suit of one or two pi~s =.:9 all parts of ~
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body except Ihe head. hands. and feel; chemical r glows; chemical
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resistant shoes (or chemical resistant shoe coveri"9s or chemical r8-"
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sistant boots); 90ggtes or face shield; hood or wide bnmmed hat; NIOSH
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approved reSpirator.
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POISONOUS TO FISH AND WlLDLIFf
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POISON SIGNS (S,mploml)
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METHYL PARATHION is a .ery dangorous poison. II rapidly orllers the
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body on contact with all skin surfaces and eyes. Clothing wet with this
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material must be removed Immediately. Exposed persons must receive
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prompt medical treatment or they may die.
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Some of the signs and symptoms 01 POIsoning are: HeadaGI1e. nausoa.
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vomiling. cramps, weakness. blurred vision, Pin·poIni pupils. lightness
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in chest, labored breathing, nervousness, sweating, w.tr.ing of eyes.
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drooling or frolhing of mouth and nose, muscle spasrr .. and coma.
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WORK SAFETY RULES .
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The National Pesticide Te1ecommuniccllion Netwoc1c: is available for ree·
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ommendations regarding poisonir"!9 management. emergency treat·
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ment. and other inlormatlon r~ardlng the toxicity 01 methYl parathion.
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The toll free number for the NallOl1al Pesticide TelecommunJcalion Net·
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work is 1·800·858·7378.
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EPA Beg. No. ::l.. 79'--d. t,6 '1 If handled indoors provide mechanJcaI exhaust ventilation. Keep all un·
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~
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protected pblSOnS, ch!!dren, livestock, and pets away from treated area
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~
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I or where there Is danger of drift. Do not rub eyes or mouth with hands.
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"---... ' II you feel sick in any way. STOP work and gel help rlghl away, See
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I . __ I First Aid (Practical Treatment) section .
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.r. HANDLE THE CONCENTRATE ONLY WHEN WEARING THE FOl·
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'-. i::',: . I 4 )987 :::.-:,. LOWINGPROTECTIVE CLOTHING AND EQUIPMENT:
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FMG Corporation
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Agricultural Chemical Group
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Philadelphia PA 19103
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Ml7
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. • J • Wear a prolocli.e suil 01 one or two pieces thai co .... all parts of !he
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,/ body excspllhe head, hands. and fool. WtaJ chemIcoI resistant ~_,
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chamleel reslslanl apron. and chemleel roslstantlhooo, ohoe = or DOOtS. Wear goggles or a lace shiekl. We., • pestic:ide r
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approved by tha· National InsIiM. for Occupalionaf SoMty and
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under lhe provisions of 30 CFR part It.
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--------- ---
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.-
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II' MIXINGlLOAriNG IS PERFORMED USING A CLOSED SYSTEM.
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THE FOLLOWING PROTECTIVE CLOTHING AND EQUIPMENT MAY
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BE WORN AS AN ALTERNATIVE: long·sleeve shirt; long·legged pants;
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chemical resistant ~roves; chemical resistant apron: shoes and socks.
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Goggles or (ace shIeld must be wom when lila system is under pres
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sure. All other protective clothing and equipment required for use with
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open systems must be available nearby.
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IF APPLICATION IS PERFORMED USING AN ENCLOSED CAB OR
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COCKPIT. THE FOLLOWING PROTECTIVE CLOTHING AND EQUIP
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MENT MAY BE WORN AS AN ALTERNATIVE: long·sleeve shirt and
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1?I'l!f-legged pants: shoos and socks. Chemical resistant gloves must
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be ava~able In the cab or cockpit and must be 'Nom during entry to and
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exit from the application vetlicle. An other protective clothing and equip
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ment required for use during application milsl be available in the cab
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and must be worn when exiting the cab into (reated area. When used
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for this purpose, contaminated clothing may not be brought back into
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the r.ab unless in an enclosure such as a plastic bag. REMEMBER
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THIS CLOTHING IS INADEQUATE TO PROTECT YOU DURING RE·
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PAIR AND CLEANING OF APPLICATION EQUIPMENT AND EARLY
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REENTRY TO TREATED AREAS! REFER TO PROTECTIVE CLOTH·
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ING AND EQUIPMENT REQUIREMENTS ABOVE.
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IMPORTANT! If pesticide comes in contact with skin. wash oft with soap
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and waler and contact a physician immediately. A!ways wash hands.
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face, and ar:ns with soap and water before smoking. eating. drinking,
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or tDileting.
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ArTER WORK: before remQ\;ng gkr,es. wash them with soap and wider.
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Take oft all work clothes and shoes. Shower using soap and water.
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Wear only clean clothes when leaving job---do not wear contaminated
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dolhing. Personal clothing worn during work must be stored and laun
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dered separalely from protective clothing and househoid art;cles. Store
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protective clothing separately from personal clothing. Clean or launder
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(
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""'teClive clothing after each use. Respirators must be cleaned and
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rs replaced according to illstructions included wilh the respirators.
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,otective cfothing and protective equipment heavily contaminated or
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drenched with methyl pcsrathion must be destroyed according to state
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and local regulations. HEAVILY CONTAMINATED OR DRENCHED
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CLOTHING CANNOT BE ADEQUATELY DECONTAMINATED. OUR·
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ING AERIAL APPLICATION. HUMAN FLAGGERS ARE PROHIBITED.
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FIRST AID TREATMENT
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Call a doctor (physician), clinic or hospital immediately. Explain that the
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victim has been exposed to methyl parathion and describe his condition.
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H breathing has stopped. start artificial respiration immediately and
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maintain until doctor sees victim.
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H Iwallowed, drink 1 or 2 91asses of water and induce vomiting by
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touching bc:.ck 01 throat with lInger. Do not i~duce vomiting Or givE: any
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thing by mouth to an unconscious person. Get medical atlention.
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In case of contact, immediately flush eyes or skin with plenty of water
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for at least 15 minutes while removing contaminated dothing and shoes.
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See doctor immediately.
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NOTE TO PHYSICIAN
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Antidole-administer alropine sulfate in large doses. TWO to FOUR
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mg. inlravenously or intramuSCUlarly as soon as cyanosis is overcome.
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Repeat at 5 to 10 minute intervals until signs of atropinization appear.
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(
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-PAM chloride is also antidotal and may be administered in conjunction
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1 atropine. DO NOT GIVE MORPHINE OR TRANQUILIZERS. Par·
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,tOn is a strong cholinesterase inhibitor aHecting the central and pe
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ripheral nervous systems and producing cardiac and respiratory depres-
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Sion. A: lirst sign of pulmonary edema. the patient should be given
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supplemental oxygen and treated symp!omatically. Continued absorp
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tion of the poison may occur and fatal relapses have been reported after
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initial improvemenl; VERY CLOSE SUPERVISION OF THE PATIENT
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!S INDICATED FOR AT LEAST 48 HOURS.
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FOR EMERGENCY ASSISTANCE CALL
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716-735-3765
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POST TREATED AREA
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Consult your Sidle AgricuburaJ Exlension Service or Experiment Slalion
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regarding posting treated areas.
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ENVIRONMENTAL HAZARDS
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This pesticide is highly toxic to aquatic invertebrates and wildlife. Birds
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In frealed areas may be killed. Do not apply djrectly to waler or wel/snds
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(swamps, marshes, bogs, and potholes). RunoH and drift (rom target
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areas may be hazardous to aquatic organisms in adjace~uatic sites.
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Do not contaminate water by deaning of equipment or di of wastes.
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This product is highly toxic to bees exposed to direct treatment or resi
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dues on blooming crops Dr '\Teeds. Do nof appJy this product or allow il
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(0 drift (0 blooming crops or weeds if bees ate visiting tho (realment
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area,
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DIRECTIONS FOR USE
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H is 8 V!OIation of Federar raw to use this product in a manner inoon
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$I$tenl with its labeling.
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Do not apply this product tiuO'Jgh any type of irrigation system.
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Do not apply this product in such a 1!'z,I'\Elr as to olrectly or througn
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drift expose workers 01 other persons. The scea being treated must be
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vacated by unprl)lected persons.
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Reentry into treated fields is prohibited for 48 hours after application,
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unless all protective clothing and ~,,:.,ment required for early reentry
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as describf.. j elsewhere on the label are worn.
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Because certain slates may require more restrictive reentry intervals for
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various crops treated With this product. consult your Stale Department
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of Agriculture (or further information.
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WriHen or oral warnings must be given to workers who are expected to
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be in a treated area or in an area about to be treated with this product.
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Inform workers of areas or fiekls that may not be entered without specific
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protective clolhing. period of time field must be '1acated and appropnate
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actions 10 take in case of accidental e)'posule. An example of such
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informatior. is given under writlen warnings. When oral warnings are
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given, warnings shall be given in a language customarily understood by
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wMers. Oral warnings must be given if there is reason to believe that
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written warnings cannot be understood by workers. Written warnings
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must ;xlude rhe 'ollowing information:
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DANGER
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Area trealed with Methyl Parathion 25 W.P. on (insert date). Do
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not enter without appropciate protective clothing (or 48 hours (in
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sert Stale Oepartme'1t of Agriculture's re·entry interval. if more
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restrictive).
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In case of accidental eXfX)sure to pesticide spray or dust. wash
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the skin thoroughly with soap and water. Remove contaminated
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clothing and wash before reuse. If in eyes, f1lJ3h with plenty 01
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water. If inhaled. go to an area where the pesticide has not been
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applied. Gel medICal aftention if needed.
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STORAGE AND DISPOSAL
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Pesticide Storage
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Keep out of reach of children and animal~. Store in original con
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tainers only. Store in a cool, dry place and avoid excess heat.
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Carefully open containers. After partial use, fold and roll back
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bags, clamp and close tightly. Do not put concentrate or dilute
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material into food or drink containers. Do not contaminate other
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peslicides. fettillzers, waler. food or teed by slorage or disposal.
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In case of spill. avoid contact, isolate area a.ld keep out animals
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and unprotected persons. Confine spills. Call FMC collect: (716)
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735·3765.
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To confine spill: If liquid, dike surrounding area or absorb with
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sand. cal lifter or commercial clay. If dry material, cover to pre·
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vent dispersal. Place damaged package in a holding container.
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Identify contents.
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Pesticide Disposal
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Pesticide wastes are acutely hazardous. Improper disposal of
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excess pesficide. speay miXture, or rinsate is a violation of Fed
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erallaw. If these wastes cannot be disposed of by use according
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to label instructions. contact your State Pestici<!'e or Environ
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mental Control Agency. or the Hazardous Waste representative
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at the nearest EPA Regional Office for guidance.
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Conltllner Dlsposa'
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Completely empty ba9 into application equipment. TI-.en dispose
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of empty bag in a sanitary landfill or by incineration, or. if allowed
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by State and Jocal authorities, by burning. It burned. stay out of
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smoke.
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ENDANGERED SPECIES RESTRICTIONS
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The following restrictions appty to use of this product after February 1.
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ISBB.
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Before using this pesticide on wheat, oals. andlor bar1ey in the counties
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IiSled below. y,," must obtain the PESTICIDE USE BULLETIN FOR
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PROTECTION OF ENDANGERED SPECIES 'or Ihe county in which
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the product is to be used. The bulletin is available (rom your CoUCity
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Extension fl.genl, Sfale Fish and Game Office, or your peslicide dealer.
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U ... 01 this product In I monner Inconslstont with the PESTICIDE
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USE BULLETIN FOR PROTECTION OF ENDANGERED SPECIES Is
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a violation of Federal law,.
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Allbama
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Colbert. Greene, Jackson, Lamar. Lauderdale, limestone, Madison,
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Marshall. Morgan, Pickens and Sumler
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Arkin ...
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Clay. Clall<. Cross. Lawrence. Lee. Poinsene. Randolph. Sharp and
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St. Francis
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call'ornl.
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Bun.. Colusa. Glenn. Inyo. Kern. Los Angeles. Merced. o.ange.
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Riverside. Sacramento, san Bernardino, San Diego, Santa Barbara,
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Solano. Stani$laus, Sutter, Tehama, Ventura a.ld YOlo
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c
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(
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.-
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Florid«
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Alachua. Baker, Bradford, Brevard. Broward, Charlotte. Citrus. Clay.
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Collier. Columbia, Dnde, De Soto. Dixie, Duval. Flagler, Gadsds!l.
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GiJctuesf. Sfades, Hardee, Hendri. Hernando. ~l9hrands. HiIIstxxougil,
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Indian River, Jefferson, Lafayette, lake. Lee, Leon, Levy, Madison,
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Manatee. Marion, Martin, Monroe. Nassau, Orange. Okeechobee.
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Osceola, Palm Beach. Pasco, Pinellas. Polk, Putnam, S1. Johns. SI.
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lucie, Sarasota. Seminole. Sumter, Suwannee, Tayfor, Union. Vofu.:;ia
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BndWakulia
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Georgll
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Bran~ey. Bryan. BllIIQch. Bllri<e. Camden. Candler. Chariton. Chatham.
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Effingham. Emanuel, Evans. Glascock. GIYIln, Jefferson, Jenkins,
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Johnson, libelty, Long. Mcintosh. l:lierce. Richmond. Screven. Ware.
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Washington and Wayne
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K.nu.
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Clark, Comanche, Meade and Stafford
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Kentuc"'l.
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Ballar ,Butler. Edmundson, Green. Hart. Jackson, laurel,livingston.
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Yarshall. McCracken. McCreary. Pulaski. Rockcaslle. Taylor, Warren
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and Wayne
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Mlululppl
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Itawamba, lowndes, Monroe and Noxubee
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Monana
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Garfield, McCone, Sheridan and Valley
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Nebraska
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Boyd. Brown, Buffalo, Butler, Cass, Cedar. Colfax, Dawson, Dodge,
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~Ias. Hall, Hamilton, Holt, Howard, Kearney, Keya Paha, Knox,
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Memck, Nance, Phelps, Plane, Polk, Rock, Sarpy and Saunders
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North Corollna
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Edge<:Offib<o. Nash and Pitt
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North Olkota
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Banson. Bonineau, Burke, Burleigh, Divide, Dunn, Eddy, Emmons,
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Foster, Kidder,logan, McHet1IJ, Mcintosh, McKenzie. Mclean. Mercer,
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Morton, Mountrail, Nelson. Oliver, Pierce, Ramsey. RanvitJe, Rolette,
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Sheridan, Sioux. Stutsman, Towner, Ward, Wells and Williams
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South Corollna
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Aiken, Barnwell. Beaufort, Berkely. Charleston. Coneton, Dorchester.
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Georgetown, Hampton. Horry, Jasper and Marion
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South Olkota
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Clay. H9~, Hughs. Poner, Stantey. Sully. Union, WaJworth, Yankton
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and Zie h
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Tennes.sr..
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Bedford, Blount, Clal:>arne. Decatur. Franklin, Hcmcock, Hardin
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Hickman, Knox. UnCC.ln, Loudon, Marshall, Maury. Meigs, Monroe,
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Rhea, Roane. Scott. Sequatchie, Smith. Sullivan, and Wayne
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Tex ••
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Aransas, Austin, Cameron, Colorado, Fort Bend, GOliad. Refugio and
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Victoria
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Virginia
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lee, Russell. Scott, Smyth, Tazewell. Washington and Wise
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Not for use or storage in or around the home.
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Apply when insects first appear and repeal as necessary. Apply rec
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ommended rates in sif,1icient water to thoroughly cover one a,;re. (With
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gr..:..und application eqliipment apply a minimum of 10 gals.; by air apply
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a minimum of 2 9al~ 01 fmished spray per acre. Apply with equipment
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with suHident agitation to keep this proouCl in solution at all times. 00
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not use in undiluted form. Observe days interval between last applica
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tion and harvest indicated by number In ( ) following the crop.
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AMalta (Seed and Hay). Clover (Seed and HlY) Ind Vetch: Spotted
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AIIaffa Aphid. Aphids. Armyworms (up to 3rd inslar). tealhopper-Use
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2-5 pcN!nds per acre. AI a rate of 4 pounds or less per acre do not ap'ply
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withIn 15 days of harvest. At a rate above 4 pounds do not apply Within
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20 days of harvest. In California do not apply more than % pounds per
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acre. Wildlife in treated areas may be killed. 00 not apply if the crop or
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weeds in the treatment aroa Bre In bloom.
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Artlchoka (7). Celery (15). Carrota (15). P.I. (15). Peppora (15):
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Aphids, Armyworms (up to 3rd instar), t=loabeetles, leafhopper-Use 4
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pounds per Bcre. 00 not use treated carrol tOSJS for food or feed. Col
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not apply if the crop or weeds in the treatment aroa Bre in bloom.
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eean. Dry (15) Green and lima (21). Tomlt_ (15). Broccoli (21).
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Bru.MI. Sproul. (21). Cabbage (21). COullno .... r (21): AphidS. Ar·
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myworms (up to 3rd instar), Fleaooetles, Leafhopper-Usc 4-6 pounds
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per acre. Do not apply if the crop or weeds in thO treatment area are in
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bloom.
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lettuce (21). Splnoch (21): Aphids. Armyworms (up 10 3rd instar). Flea
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Beetle, Leafhopper-use 3-4 pounds per acre.
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Smlll Groin. (15): (Birley, alt •• Whoat): Aphids-Use 2·3 pounds
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||
per acre. Armyworms (US; to 3rd instar), leafhoppers-Use 3 pounds
|
||
per acre.
|
||
Dealers Should Sell In Original Packages Only.
|
||
Term. 01 Sole n UN: On purchase 01 this proclucl buyer and user
|
||
agree to the frllowing conditions:
|
||
Warranty: FMC makes no warranty. expreSSed or ImptlOO. concerning
|
||
the use of this product other than indicated on the label. Except as so
|
||
warranted, the product is sokf as is. Buyer and user assume all risk of
|
||
l'se andlor handling andlor storage of this material when such use andl
|
||
Jr handling andlor storage is contrary to label instl1JCtiOns.
|
||
Dlrectlon'lnd Recommendations: Follow directions carefully. Timing
|
||
and method 01 application, weather and crop conditions, mixture with
|
||
other chemicals not specifically recommended and other influencing
|
||
factors in the use of this product are beyond the contrOl of the seller
|
||
and are assumed by the buyer al his own risk.
|
||
Use of Product: FMC's recommendations for the use of this ~uCl
|
||
are based upon tests believed to be reliable. The use of this product
|
||
being beyond 'he control of the manufacturer, no guarantee, exptessed
|
||
or implied, is made as to the eHects of such or the results to be obtained
|
||
if not used in accordance w:th directions or established safe pract~.
|
||
Oemlges: Buyer"s or user's exclusive remedy for damages for breach
|
||
of warranty or negligence shall be limited to direct damages not ex
|
||
ceeding the purchase price paid and shall not include incidental or con
|
||
sequential damages.
|
||
"'-FMC Trademark
|