a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
321 lines
14 KiB
Markdown
321 lines
14 KiB
Markdown
# DUPONT EPN 5-EC
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- EPA Reg No: **352-405**
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- Registrant: CORTEVA AGRISCIENCE, LLC
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- Signal word: Danger
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- Active ingredients: O-Ethyl O-(p-nitrophenyl) phenylphosphonothioate (56%); Xylene range aromatic solvent (31.73%)
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- Label accepted: 1983-11-09
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000352-00405-19831109.pdf
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---
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" -,
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\ ,
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, ,
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\-
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'-j
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SI'I (:,,,n}.: IAIII:!.
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'11\.'\(;m, SHIU.
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-n~ ,\CllI.\1. SI:L flu ,\~·tu;d 1;1)'l'!.
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fi nl.IlSSBfl.\:l.s li 1l'1~1\" .Ifl' pl"illtt'll l~l"'l.
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RESTRICTEO USE PESTICIDE
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For retail sale to and use only by Certified ApP!lcators or persons IInder their direct
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supervision and only for those uses covered by Ihe Certified Applicato:'s certification,
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<[UJ~.N» EPN 5-EC
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INSECTICIDE EMULSIFIABLE Cm4CENTRATE
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1 Gallon Contains 5 Lbs, EPN
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87,73%
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EPN (O,Elhyl O,[p'nilrophenyll phenylphosphonolhioale) """"""" 56,00%
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Xylene Range Aromatic Solvent. ........ _ ............................. 31.73%
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INERT IfIGREOIENTS '" __ "','''",,, _'"''"",''''' __ """''''''""" 12,27% .....
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Keep oul of reach of children
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DA~~~ER :I: P~I"SON
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STATEMENT OF PRACTICI.L TREATMENT
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II swallowed: Call a ph~sl~.dn or Po,son Cootrol Cenle' O"n!. I (I' 2 glas~l'\ al
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... all" and ,"ojue .. '<am,l,ng by louChm8 bae!. ollh.a«1 .. 'It> f.n~,,' Dc nOI .nduCE'
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"em,l.og 01 g,ve aO)'lhm& by mouth 10 ao u""on~c'Ous r.e'~OIl
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II inhaled: Remo.e hOm e.pasuI,:> dnd hil.e pdl,enl Ite do ... " ana !.e.:!p QU'et I'
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oal,ent IS 001 brealntng, S\o31l ilrM,c,al reHhrallon ",'mea.alel)' I-/ever 8"e ilnr
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th,ng by mouth 10 an uncon~e.,ous person
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In cue 01 conl.ct: wa~h ~km .... 'Ih fl'enly Of ~oap ana ....ate. 101 e~es flush .... Ih
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..... iler '0' 15 m"'ules and get me(l"al al1enl'Oo. 1('1.'0 .... an,1 waSh conlam,na'E',1
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,IOlh,ng bQloce re ust'
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ATROPINE IS AN ANTIDDTE- SEEK MEDICAl ATTErntON
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AT ONCE IN All CASES OF SOSPECTED POISONING
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II warninl symptom1 'PPUI f~ee WARNING SyMPTOMSl K\'I ml'd.cal all(,nl.or
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,,& .,.', ,.: ~-..
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-. /
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STORAGE AND DISPOSAL
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Not 10' use o. Slorage 'Il 0' around the
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hOOle Do not conlam,n':lIe .... ater.loodOI
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feed by ,>IOlagt" or disposal Open dump
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,ng IS prOhibIted P&;llc.de. spray mu
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lure 0' ""se ... ale' Iha\ cannol be used
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ac(o.d.ng 10 label II1SltuCllqns must be
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dISPOsed of accoldmR to' federal or
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appro· .. {'d State procedures under Sub·
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t,Ue C of the Resource ConservatIon anu
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Reco~ery ACI 00 not reuse conla,"er.
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Inplt" r,"se (01 eQuIvalent). punctulE'.
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and d.'J,pos(' of '" a sanItary landfill. 01
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by olher approved Slale ilnd focal pro
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c('dures
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'''"''''-< ',' 1f.3 NET 5 GALLONS ...•.•
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E. L DU PONT DE NEMOURS & CO, (INC,). BIOCHEMICALS DEPARTMENT. WILMINGTON. DE
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PRECAUTIONARY STIITEMENTS
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HAZARDS TO HUMANS AND
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DOMESTIC ANIMALS
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DANGER ~ POISON
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MAY BE FATAl IF SWALLOWED. POISONOUS IF
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INHALED. EXTREMElY HAZARDOUS BY SKIN CON.
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TACT. RAPIDLY ABSORBED THROUGH SKIN. RE·
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PEATED EXPOSURE MAY. WITHOUt SYMPTOMS. BE.
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tNCREASINGLY HAZARDOUS.
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Do not brUlhe npor 01 Spr.,y misl.
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00 nol gel in eyt'S. on 1kin. or on clothing.
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WARNING SYMPTOMS - EPN pOlson,ng p,Qduces
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e!lects assoc.ate(l ",tn antIcholinesterase ae.hvlly
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whICh mol)' u'CI"df< ""t'aknE'Ss. blultt'd vls.on. head
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ache. naUSE'a. abdo.mnal cramps. dIscomfort en the
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chest. conSlllclloo 01 pupIls. s ..... eatlll& slow pulse.
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muscle tremOIS
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NOTE TO PHYSICIAN
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TREATMENT - AI'Ofl,ne sulfale Should be used for
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trealment Admln.ster lepealed dOSes. I 2 to 2 0 mg
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,"lravenouSly e~t'.y 101030 mlr.utes unl,llulla(.op,n,
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lal.on IS achlt',l'd \Ia.nlall1 alroplrltlal,Oll unt,llhE'
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Pdl,ent reco·,e.s AII.f,(.al resp,rat.on 0' o_rgt'n rna)'
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be necessary AllO., no further E'lPOSUle 10 any choh·
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nesterast' mh,t/:!o. unl,1 re;:o"ery IS assuled 2·PAI,\
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may be used as 'eQ,med to supplelTlE'nlthe airoplne
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sulfate Ilealmeni 00 nol use morphllle
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ENVIRONMENTAL HAZARDS
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Th.s product IS 10ilC 10 IrSh. birds. ;Jnd olner wltdllfe
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00 not ilPply d"ectty to water 00 not apply ..... here
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lunoff IS Iokely to occur 00 not apply when ..... eatMr
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condl\lons favOI (111ft Irom areas t'(lated 00 not COI'l·
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lamInate walel by cit'ilnmg 01 eQulpmeot or dIsposal
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01 wastes
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ThIS product .s tughly tOllC 10 bees t"IPQsed to duet!
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I," _ .. :.,bppZ,calion 001101 <lpply thiS product while bees are
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.; aCtIvely vlSII,ng Itlt' ,.ealfl1enl '1rea TIme apploe.at,ons
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to co,oe..de wllh oeflods 01 minImum bee actlvlly
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PHYSICAL AND CHEMICAL HAZARDS
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Keep awa~ hom "t'~t. sparks. ana open llan1t' KE'ep
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conla,nei clos .. .:! U~t' .... ,\h adeQualE' \e"lolallon
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.• . ' ... ~
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,., .,
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.', .
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; -.
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.:.
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, ..
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i,
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/..::J USE 0 Y WHE THE FOlb..lYflt~G
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PROT CliVE AND CLOTHING
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Wtd dtln, htnr duty. n ,,,,I cub l'Ons,.) Iprool pints. COIL hit lubbu boots or lubber
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onrshl)tS .nd s.af!ty 110 !es .htn ,n!lr,na. m ,ni or app!Yil1& "liS product Ww I pestiCIde
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Itspintor p)inHy IPprOY byille M 111& Enforce tnl.1Id Slltly Adlllin,stutlon(lormtrlllM U. S
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8uruu 01 Mmes) Ind It:.! Nil ,llnslrtute I Occup.OOnll SdelJ tnd Hulill
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~ -7 . WORK SAFETY RULES
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,'1101 Should nCoI.wst t11l11lullllRd Ioltlllli opellbon Ktep .nilllils Ind 111 unprotected ptlS(lns out
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01 oper.tlDlul lieu dUnJllllulmenl.nd IIh1lt Ihelt IS d,RiU 01 dllrt
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Donal tub eres Of l!Iolllh _«h hinds-II you led sIck In ,ny JUY STOP Rori Ind It!helprli~,II.aJ
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c.n • phr5ici.n, dll1!' or·llosjltll IIllIlIed,,!eIJ. bplJIR I~!I Itt .,cbm hIS bun upned to
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[PH ,rid dmrrbe ills" ~Ibon.lltu I,ulllt! IS llTfen (lee SllIemenl 01 Prlttl,,1 lrnlment (ronl
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plneQ .1Id il .-doctor Ci'.'\01 tome. lale Ylcbm 10 clinic or lIo-sp.1,1
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IIPOlTUn Before rem01'mi. I'oves ... 1$11 them *!ttl !.O.lp I nd Wiler. A1wl)"s -..ulllllnds. lice ,rod
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Irl!\$ ,ulll so.!) Ind .116 belO1e smokln£, ubnl 01 dllAkln1-
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Ami WOII. like off.D dotlles 1M shoes. Shower uSina SOIf!lnd .'Itl. Wur onlJ tlunclctlles
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.lItII fufinl feb 00 not .ur contln ... ultd c1othrnl. Wuh prolectsve clolllrni Ind pro(ectlve
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equipment with SOIf! Ind .ller Iher nch USI!. Resll'ulor should be cltlned .nd litter replied
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Kcotdinllo instruclloM intludtd II'lth resPlntor.
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.--:c::-:--==::-:-:cc: NOTICE OF WARRANTY -------,---, 'OIlI.-mlnls Ihll thIS ""rovel conlotms 10 Ihe chemalducnp(oon on It.e libel Ihert\l' uld IS
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.rtIlbIr Irt lor tht purposes sliltdon such l,belonlJ .t.tn ustdl/liccordllltt ""lithe dllulrons
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.U 1lOl/!lll' II1t eond.w.ns.1t IS Imp)SSrble to tI,mlnlte I~ IlSU ,nhtlentlJ u~lIled .rlll Ihe ust ~t
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U'IIS ""odvcl CrotlIRIUIJ.lIIlIIHll1lnes\. Of othel unrntelld"ed CClIstquenCH m'J IH~II. ronst 01
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SlIch IKIM II .-tlther C«I~lbOns. ""mnce of OU'.tl m'ltflll1. or the mlMn 01 use C( IppfrClI.Oll. ,II
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of .-l\Jch Ife be}ond I~.e t«I!J~ ol!hl POIIL In 110 U~! shl~ Du PO/Ilbe h,t>!e let" unstquenb,l steer"
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Of I~utd (flmliU ltsulbftllrom Iht use Of htn(fhnt 01 thl$ pfodrxL AU su,h lIS" st·11I bI! mumro
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by tht buJU. DUPONt MAKES HD WARRAIiTlES Of MERCH.lJ(lABIIITYOR flTHESS fOR A PJJlIIC·
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UUR pullroS[ NOR ANY OTHER [[PRESS OR I,",PUEO WAJlIWHY oem M SUTlO ABOYf
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OIRECTlONS FOR USE
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II is. riohtion of ftdmllillto use thrs plooutl In • mlnn~1 intonm(enl wrth lis "tot::ng.
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Du Ponl EPH S-EC InSKI>cide shO'J'd be used only In IttoldlnCt .i(lIletomm~ndJlrons on thIS
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libel ot in ~,,",rlle putfuhtd DuPont recommendlbons ."dlllle Ihrou,h locl1 dulels
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Du Ponl Will not be responsIble 10f louts Of d,mlits resultrnllrom use ollhls prM •.• In In,
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mlnner nol SPtCrfiull, Itcommendtd by OuPont Uur luumes.1I mUI$SOCIJte::l IIrlli such
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fIOnrecommerdi!d us.!.
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SPlAY PU,AlATlOI!i-Pcur specrlltd amounl ollhtS ""oduct mlo nwly Irlled sprl, link.. Add
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bllince of w.lel 10 lin IInl P;eep .,illlor runnrnl durinl'lI!Jnllnd spurina optralron1. ()o) nil'
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combine Ilth .ettatie po.den un!eu previous useoflhe midulebu prOYenph{SIClllrCOollf!llIb!e
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I~ Slie to pllnb.. Alu)1lhoroui,hly emukrtr IhrS proouct .dh .1 lent hili 0 IOllllU!U belOl"e
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Jddinl .-ettlble poII'd"
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UPLICAJIOJl-EPH S·EC ma, be applred bJ ,round or UnJllppllCltroll by I",ntd pelsonnelnnl,
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usinl.pprovtd proledlYe fQurpmenl Do not JPpir II'I\h hind equIpment
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lIapplJed by a!rmll. Ihe mlnrmum .mounl 01111:1\e1 pel Icrt should be If!prOllmate:y 1 to 10
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JIOon1. consn'tn'wdh CIOf! llGlI"\h and t(oOd CGler'it IIlppl:td IIdll ,round equrpmenllhrs ul~
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should be IpPlollmllt[, 5 10 10 llllons pel ICie
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Where a dos'lt IIn!~ IS ,.ytn. use Ihe 10_" Illes on smlD. JOUnrP"IIISOI .. hutlnstclr:r.l~stalron
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fS blh!; use tht Itrl tl lites on 11Ii:~ 01 mllure pllnls Of IIhtre rns~ct InltsllllOtI ,s /lUl'
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~L·..... I[(KTn STAn.UIl -¥itd." IAII' PI tfU t e4.I ... lds lilt! ill U t CUI. 01 e~~1 (114 J'.cu!dwtu T-- ,-.~dI:iUwtrI
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• JA"'Ug" fl em It j6¥l Stetr~ljrtUhUni ftk'IlO" '1",.......-i.,..I'f"ofAt.St~1OR
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'"I"d ill posb ,,( hilled 1I:M40
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tAlllllnUl( fOI conON-Thls produCI mlr be lint r.ttled _rth Mlth}1 Pmlhrcn. G.~(({on'
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~[I. fUMII. tECI. Fund.l. 4SPI. DuPonl lInnlte". OuPont hnnlle-p. NudllnfJ J S' 01"
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Hudlin- 90'. WI'.tn uSlRllhese products rn I tlni mil. obsm·e 11I11~!lll1ons Ind pr~Clullons
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whith 'Pf)('1f onl~e !abe:s. Uv. Iht IlIe Itcommendllrons I~.d Ipphutoon l.ml"ls 101 the Instel
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pest Ihrl IS 10 be conltVlI(d IS silled on 'hen libels
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"'*""· ••• t_ ...... (o~t+-t1(.oo.
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:t::=.'l!.'t:.!~; :~t~~'f.TI r ~';:'I': ~~r ... ""· 0"4 ,,~ .... '>! 1'I.,...-.IIi 14"<O ..... ,.~.d ....
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"""'" IS .... __ c'" r. to: ....... <I s.-.. (>.O .... ~ '-"
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1
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"'" .I.Wu
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PUJs
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JptlC~ts
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Ct.efllU
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Htdlltl'.U
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PUtl'lts
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Plum!
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Bur.s
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Corn (Frtl-1)
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(0,
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tern (S.ttll
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"""'
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IPtU .1
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!
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SGrt>e'!I
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S~iI't>l:tts
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1~lIt·n
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RATE OF EPN 5·EC
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.... "" h"d 5-EC/Acn
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~~l!~~ 16·2' '. ""' (0-(.06
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" fltf 100 ~S.I
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" ..
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O,,!ftlll ft~.IIrIOI.b. hUll!um Sull. Obt Sule • '. Orr~J\III h~rl: Moth. fl~'" CUJ(ut.o 16·2.1 '. ptf~~:iO,6~~ ,.
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lt$Slf Pt,chtree Borer. PUCMlte f«er 11·2'
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" per'ltI :1h,C.: .,
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" JlU>tIIl Bun Stel!e •• 01·(18 .. ,
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00
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hrcpun tern Borer ,.
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0t.(18 H,
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"' 6 ,.
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00
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toen Ro(J(lorms (Adults) 04-08 ,.
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Swt~.Htern .. .. r.
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'" /, ~
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{urGp(ln tern Boru O.(.()8 , .
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tern Roct.orlll!o (ld~:u) •• " .. " 01-(18
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" " '1
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,...." " ~
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E\;)'Wetd OHS ,.
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::f.~:~~~~:~m.CoItOIl ." " " eo:.OI"m. TO"NtcG Bu4.OI"Ill ~
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" PI~\ 8Gh:ofm • " " " " " • • ,.,....:, .,
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Pf(I!Io NIII CUfb.wu 'i 2«-31 .. (06-08 • per 100 Ill" • • Corn hraOlm {&Il.orml
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" " .. • · SUIubtel Wtt-.orm
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" .' • SttI.l.!ml-'COfJII. 're""wslrrptd .i.Jm,..Ofm. • 10."11110 flu·r.QlIl' ,C,rn EJr.et"t:lI. tomlto 0(.12 • R~nIM.te I, ,
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non-permeable, non-cloth material covering the body
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from ankles to wrists; lightweight, unlined, natural
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rubber boots at least mid-calf in length; full-face
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respirators are recommended; half-face respirators and
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goggles are required.
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Aerial applicators in positive pressure cockpits and
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other applicators in comparable ground equipment with
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appropriate filters at all 5ir intakes need not comply
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with these protective clothing requirements.
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2. Human flagger prohibited unless in totally enclosed
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vehicles.
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3. Do not apply this product when weather conditions favor
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drift from treated areas.
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4. REENTRY STATEMENT - Do not enter tre~ted areas for 24
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hours unless appropriate protective clothing is worn.
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Because certain statef· may require more restrictive
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reentry intervals for various crops treated with this
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product, consult you State Department of Agriculture
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for further information.
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S.
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6.
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Written or oral warnings must be given to workers who
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are expected to be in a treated area or in an area
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about to be treated with this product. When oral
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~arnings are given, warnings shall be given in a
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language customarily understood by workers. Oral
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warnings must be given; f there is reason to believe
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that written warnings cannot be understood by workers.
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Written (or oral) warnings must include the following
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information: "DANGER-POISON". Area treated with EPN SEC
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on (date of application). Do not enter treated area~
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without appropriate protective clothing for 24 hours.
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If warning symptoms appear, refer to Statement of
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Practical Treatment on front panel of label and seek
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medical attention at once.
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Do not apply when trees or a
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substantial number of weeds
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in the orchard are in bloom.
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Do not apply to corn during
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the pollen-shed period if
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bees are visiting the treatment
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area.
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ACCEPTED
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NOV 091983
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U"\~'." :hll Federal InsecUd e,
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r ..... l:li .i:;e. and Rodenticldll Act.
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as olOloJuded. 10: the ptllticld.
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'egitl.,od undo. >1,.., _,ldl::'
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BfA a.". No. .:J~.. 'I' JI
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" ...
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l
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7.
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8.
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9.
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Do not apply to blooming
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cotton if bees are visiting
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th~ treatment area.
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PELIGRO
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Precaucion al uSLario: Si
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usted no lee ingles, no use este
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producto hasta que la etiqueta
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haya sido explicado ampliamente.
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STORAGE
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Store ~roduct in original
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container only, away from
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other pesticides, fertilizer,
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food, or feed.
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DISPOSAL
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Do not cont~minate water, food,
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or feed by storage or
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disposal. Pesticide wastes are
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acutely hazardous. Improper
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disposal of excess pesticide,
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spray mixture, or rinsate is a
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violation of Federal Law. If
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these wastes cannot be disposed
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of ty use according to label
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instructions, contact you~
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State Pesticide or Environmental
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Control Agency, or the
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Hazardous Waste Representative
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at the nearest EPA Regional
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Office for guidance. Triple
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rinse (ur equivalent) the
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container. Then offer for
|
|
recy~ling or reconditioning,
|
|
or puncture and dispose of in
|
|
a sanitary landfill, or, if
|
|
allowed by state and locdl
|
|
authorities, by burning.
|
|
If burned, stay out of smoke.
|
|
10. Do not apply this product in such a
|
|
manner as to direc~ly or through
|
|
drift expose workers, other persons,
|
|
or animals. The area being treated
|
|
must be vacated by unprotected persons.
|
|
11. This product is highly toxic to
|
|
hees exposed to direct treatment
|
|
Or residues on blooming cropf.
|
|
or weeds. Do not apply this
|
|
product or allow it to drift to
|
|
blooming crops or weeds if bees
|
|
are visiting the treatment area.
|