a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
329 lines
19 KiB
Markdown
329 lines
19 KiB
Markdown
# PCNB 2-E LIQUID EMULSIFIABLE CONCENTRATE
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- EPA Reg No: **5481-212**
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- Registrant: AMVAC CHEMICAL CORPORATION
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- Signal word: Warning
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- Active ingredients: Pentachloronitrobenzene (24%)
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- Label accepted: 2003-11-28
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/005481-00212-20031128.pdf
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---
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
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WASHINGTON, D.C. 20460
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NOV 2 B 2003
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111
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Mr. Darryl E, Brock
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AMV AC Chemical Corporation
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4695 MacArthur Court, Suite 1250
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Newport Beach, CA 92660
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OFFICE OF
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PREVENTION, PESTICIDES AND
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TOXIC SUBSTANCES
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Subject: PCNB 2-E UQUID Emulsifiable Concentrate
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EPA Registration Number 5481-212
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Your Amendment dated August 15, 2003
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Dear Mr. Brock:
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The amendment referred to above, submitted in connection with registration under
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the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA), as amended, is accepted
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provided the following changes are made:
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1. On page 4, in the third paragraph, change "caution" to "precautionary".
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2. On page 4, change the statement "Treated Seed" to "Treated Seed must be labeled
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with the following information":
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Also in the next sentence, add quotation marks as follows: "This seed has been
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treated with Pentachloronitrobenzene (PCNB) FUNGICIDE. Do not use for Food,
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Feed or Oil Purposes."
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3. On page 4, in the Storage and Disposal Box, change the subheading "Storage" to
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"Pesticide Storage".
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When making future labeling amendments, please use a larger font for your draft
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labels. The Agency must ensure that it has reproducible documents in its files.
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Inlernet Address (URl). http://www.epagov
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Recycled/Recyclable. Printed wHh Vegetable Oil Based Inks on Recvcled Paper (Minimum 25% Postconsumer)
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---
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=~=~ .. = .. -= ... --~ .......... -.~~--~---------
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..
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".)-.
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- 2-
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A stamped copy of the label is enclosed for your files. You must submit one copy of
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the final printed label prior to releasing the product for shipment. If you have questions
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about this letter, please contact Summer GardnercJenkins of my staff at (703) 308-9353.
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Enclosure: stamped label
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Sincerely,
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Mary L. Waller
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Product Manager 21
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Fungicide Branch
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Registration Division (7505C)
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..J~~ 3/7
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In EPA Letter Dated
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NOV 28 axl3
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PCNB 2-E LIQUID
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EMULSIFIABLE CONCENTRATE
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Vader doe F .......... "'dehIe,
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Fandlotrle.adRDdlJ , .. +hAd
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.. _ ..... d. , ... doe peedIIde
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np ............ ..," ... " •.
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SW/~2te __
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A SOIL FUNGICIDE FOR CONTROL OF SOIL-BORNE DISEASES AS LISTED ON
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COTTON, BEANS, GARLIC, PEANUTS, POTATOES AND FOR SEED TREATMENT.
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ACTIVE INGREDIENT:
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Pentachloronitrobenzene (peNB) ................................................................... 24.0%
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INERT INGREDIENTS:· ....................................................................................... 76.0%
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TOTAL: .................................................................................................................. 100.0%
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Contains 2 pounds of PCNB per Gallon
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'Contains Aromatic Petroleum Solvent
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KEEP OUT OF REACH OF CHILDREN
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WARNING
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Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle.
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(If you do not understand the label. find someone to explain it to you in detail.)
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FIRST AID
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If in eyes: · Hold eye open and rinse slowly and gently with water for 15-20 minutes.
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· Remove contact lenses, if present, after the first 5 minutes, then continue
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rinsing eye.
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· Call a poison control center or doctor for treatment advice.
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If swallowed: · .Call a poison control center or doctor immediately for treatment advice.
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· Have a person sip a glass of water if able to swallow.
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· Do not induce vomiting unless told to do so by a poison control center or
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doctor.
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· Do not give anything by mouth to an unconscious person.
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If on skin or · Take off contaminated clothing.
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clothing: · Rinse skin immediately with plenty of water for 15-20 minutes.
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· Call a poison control center or doctor for treatment advice.
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If inhaled: · Move person to fresh air.
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· If person is not breathing, call 911 or an ambulance, then give artificial
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respiration, preferably mouth-to-mouth if possible.
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· Call a poison control center or doctor for further treatment advice.
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EMERGENCY INFORMATION
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Have the product container or label with you when calling a poison control center or doctor, or going for
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treatment.
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FOR THE FOLLOWfNG EMERGENCIES, PHONE 24 HOURS A DAY:
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'I Transportation: CHEMTREC ..................................................................... 1-800-424-9300
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Other: AMVAC ..................................................................................... 1-323-264-3910 I
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SEE SIDEIBACK PANEL FOR ADDITIONAL PRECAUTIONARY STATEMENTS AND DIRECTIONS FOR liSE.
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EPA Reg. No. 5481-212 Net Weight:
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EPA Est. No. 5481-CA-I As Marked on Container
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212-030815r3
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ATAMVAC
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4100 E. Washington Blvd.
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Los Angeles, CA 90023 U.S.A
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1-323-264-3910. www.amvac-chemical.com
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., t.
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, , .
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I, ~.
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Page 1 of5
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, ~ r , • I
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, ,
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PRECAUTIONARY STATEMENTS
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HAZARDS TO HUMANS AND DOMESTIC ANIMALS
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WARNING: May be fatal if swallowed, inhaled, or absorbed though the skin. Causes eye and skin irritation. Do not
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get in eyes, on skin, or on clothing, Do not breathe vapors. Avoid breathing vapors or spray mist. Use with adequate
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ventilation. Do not contaminate feed or foodstuffs.
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PERSONAL PROTECTIVE EQUIPMENT (PPE)
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Some materials that are chemical-resistant to this product are listed below. If you want more options, follow the
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instructions for category (G) on an EPA chemical-resistance category selection chart.
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Applicators and other handlers must wear:
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Coveralls over tong-sleeved shirt and long pants,
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Chemical-resistant gloves such as barrier laminate or Viton
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Chemical-resistant footwear plus socks
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Protective eyewear
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Chemical-resistant headgear for overhead exposure
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For exposures outdoors: DustIMist filtering respirator (MSHAINIOSH approval number prefix TC-21 C), or a
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NIOSH approved respirator with any N. R, P or HE filter.
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For exposures in enclosed areas: A respirator with either an organic vapor-removing cartridge with a prefilter
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approved for pesticides (MSHAINIOSH approval number prefix TC-23C). or a canister approved for pesticides
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(MSHAJNIOSH approval number prefix TC-14G). or a NIOSH approved respirator with an organic vapor (OV)
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cartridge or canister with any N, R, P or HE prefilter.
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USER SAFETY REQUIREMENTS
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Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent
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and hot water. Keep and wash PPE separately from other laundry.
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USER SAFETY RECOMMENDATIONS
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Users should:
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Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet.
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Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing.
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Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as
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possible, wash thoroughly and change into clean clothing.
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ENVIRONMENTAL HAZARDS
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This pesticide is toxic to fish and aquatic organisms. Drift and runoff from treated areas may be hazardous to fish and
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aquatic organisms in adjacent aquatic sites. Do not apply directly to water. to areas where surface water is present or to
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intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of
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equipment washwaters. Do not apply directly adjacent to potable water supplies.
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PHYSICAL OR CHEMICAL HAZARDS
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Flammable. Keep away from heat and open flame.
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DIRECTIONS FOR USE
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It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
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Do not apply this product in a way that will contact workers or other persons. either directly or through drift. Only
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protected handlers may be in the area during application. Do not plant root crops in peNS treated fields within 12
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months of broadcast and banding applications unless PCNS is registered for use on those crops. Do not apply,. thiS;.
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product through any type of irrigation system. For any requirements specific to your State or Tribe, consult the Cl8rvw" •
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responsible for pesticide regulation. . , ... , . ,
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< •
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••
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• •
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.' ... ~. f
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• •• • •
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~& • .. ........
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. ~ ~ .. • • ~ ... \O
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212-030815r3 Page 2 of5
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AGRICULTURAL USE REQUIREMENTS
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Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This
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Standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, greenhouses, and
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handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency
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assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal
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protective equipment (PPE) and restricted entry interval. The requirements in this box only apply to uses of this
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product that are covered by the Worker Protection Standard.
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Do not enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 12 hours.
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PPE required for early entry to treated areas that is pennitted under the Worker Protection Standard and that involves
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contact with anything that has been treated, such as plants, soil, or water, is:
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• Coveralls over long-sleeved shirt and long pants
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• Chemical-resistant gloves such as barrier laminate or Viton
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• Chemical-resistant footwear plus socks
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• Protective eyewear.
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COTTON
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For Damping-off caused by Rhizoc/onia solani: As a row treatment use lh gallon for sandy soil and I gallon for organic
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soils per acre in a minimum of 15 gallons of water for 13,000 linear feet ofrow based on a 40 inch spacing. Direct the
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spray toward the seed and surrounding soil at planting time. Do not allow livestock to graze or feed on cotton foliage
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in peNB treated fields.
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BEANS
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For Root and Stem Rot caused by Rhizoctonia solani: As a furrow treatment apply 2 to 3 quarts mixed in 8 to to
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gallons of water and apply to 14,500 linear feet of bush beans or 8,340 linear feet of pole beans. Direct the spray to the
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base of planting furrow in front of seed drop and to the covering soil at planting time. Do not directly spray bare seed
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since delayed emergence may result. In California and Ariwna use 3 to 4 pints in 8 to 10 gallons of water and apply to
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the same linear feet as above indicated for bush and pole beans. Direct the spray to the furrow and to the covering soil
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at planting time. Use the lower rates for sandy and light soils. Do not apply to bare seed.
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SNAP & DRY BEANS·
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For White Mold caused by Sclero/inia sclerotiorum: Apply as a band row treatment in an 8 inch wide band centered on
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the row, immediately after or at the time of planting by using 1 gallon mixed in 8 to 10 gallons of water to treat 14,500
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linear feet of row for bush beans or 8,340 linear feet for pole beans. ·Not for use in California
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Avoid application directly to seed since delayed emergence may occur. When Dinitro type pre-emergence herbicides are
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used, add I gallon of this product to the final spray mix of the herbicide and apply simultaneously. lfdisease is severe
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additional appHcations may be made at 2 to 3 week intervals using I or 2 nozzles per row and directing the spray to the
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soil at the base of the plants. Apply at the same rate using I gallon in 8 to 10 gallons of water to treat 14,500 linear feet of
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row. Do not apply after the first blooms appear. Do not feed treated vines to livestock.
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GARLIC·
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For White Rot caused by Sclerotium cepivorum: As a fUl!ow treatment use 10 gallons of this product mixed in tOO
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gallons of water and apply at planting time 21,800 linear row feet per acre when crop row spacing is 24 inches. This rate
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is equivalent to 58.7 oz. ofPCNB 2-E LIQUID per 1, 000 linear feet of row. Utilize an appropriate spray rig attached to
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the planter and spray 8 to 12 inch wide bands using 2 nozzles per planting furrow. Direct the front nozzle to treat the
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bottom of the open furrow and the seed as it is dropped from the planter and the rear nozzle to treat the soil as the seed is
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covered. *Notfor use in California
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PEANUTS ....
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For Damping-offcaused by Rhizoctonia solani: As a row treatment in sandy soils use Y, gallon ofPeNB 2-E LI<:!WIDar:d
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in organic soils use 1 gallons PCNB 2-E LIQUID per acre in a minimum of 15 gallons of water for 13,000 linea: I1:eJ, of
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row based on a 40 inch row spacing. Direct the spray toward the seed and surrounding soil at planting time. Do n~~alJow
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livestock to graze or feed in peNB treated fields.
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POTATOES •
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. " For Rhizoctonia solani as a pre-planting broadcast soil treatment use 9 to 12 Y:! gallons per acre mixed with sufficiepf ..
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waterto total 25 gallons of finished spray. Apply to the soil surface prior to planting and thoroughly disc to a de~tp.of ••
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4 inches by cross discing. Attach a harrow on the last discing. It is desirable to make this treatment when the soil is •
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slightly moist. As a furrow treatment use 5 gallons mixed in 15 gallons of water per 12,400 linear feet of row. Using
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three nozzles per row place the front '"Fan" type nozzle ahe~d of the furrow opening disc with two "Cone" type n.ules· •
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placed above and slightly ahead of the closing discs in the rear. Select nozzles that will deliver about 1/3 of the spmy·"
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mix per acre through each nozzle at the desired planting speed and pressure. ." .. :
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••••
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212-030815r3 Page 3 of5
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I't , ....
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'II 1..
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• • · ... ,. " . · . ~, ... · .......
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AS A SEED TREATMENT FUNGICIDE
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For Barley, Beans, Com, Cotton, Peas, Sorghum, Soybeans, Rice, Oats, Safflower, Sugar Beets and Wheat. For
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Control of listed Smut diseases and Damping-off caused by Rhizoctonia.
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Seed Treatment
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Use PCNB 2-E LIQUID with suitable liquid or slurry type seed treating equipment such as Panogen or Mist-O-Matic
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and apply at the rates as indicated below. Seed to be used for planting should be sound, fully cured, cleaned and have
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an excellent gennination record. Use the following seed treatment rates per 100 Ibs. of seed.
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Important
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The "Seed Treater" is responsible for the use of an approved seed treater dye in the discoloration of seed that is to be
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treated and sold for further sales in Interstate commerce. The Federal Government and most States have seed laws or
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regulations that require treated seed to be "tagged" with an appropriate caution statement such as the following and as
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found at the bottom of this column for treated seed. Check with such Agencies before release of treated seed.
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How to Apply
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Apply PCNB 2-E LIQUID undiluted to the seed directly from the drum at recommended rates. If desirable add one
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part water to five parts PCNS 2~E LIQUID. Make sure to recalibrate equipment to deliver the recommended rate of
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PCNB 2-E LIQUID per 100 Ibs. of seed. Refer to the following chart. "Use highest rate for pathologically infected
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seed and when conditions are known to favor the development of soil~bome diseases. ···For Cotton use the lower rate
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for acid delinted; the higher rate for mechanically delinted. ··.·Not for use on Com, Rice or Saffiower in California.
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Seeds to be Treated Rates per 100 Ibs_ of Seed (0_ oz-) Seedling Dis .... Compl ..
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** Controlled
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Barley 4.20 to 8.40 Covered Smut
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Beans 3.35 Rhizoctonia & Fusarium
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Com···· 3.35
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Cotton··· 12.0 to 16.20
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Peas 3.35 to 6.70
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Sorldlum 1.95
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Soybeans 3.35 to 6.70
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Rice···· 4.45 to 8.90
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Oats 6.13 to 12.26 Oat Smut
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Safflower···· 1.95 to 3.90 Seed~bome rust.
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Rhizoctonia & Fusarium
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Sugar Beets 6.13 to 12.0 Rhizoctonia & Fusarium
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Wheat 3.35 Common Smut or Bunt
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Rhizoctonia & Fusarium
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TREATED SEED: This seed has been treated with Pentachloronitrobenzene (peNB) FUNGICIDE. Do not use for
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Food, Feed or Oil Purposes.
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STORAGE AND DISPOSAL
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Do not contaminate water, food or feed by storage or disposal.
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STORAGE: Store product in its original labeled container in a cool. dry, locked place out of reach of children. ~N)'«X:\?
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from temperatures below 32" F.·' " . ,
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PESTICIDE DISPOSAL: Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rb.~t&
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is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact. Y''i)U~'
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State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA regiolllli
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office for guidance. ..' "
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CONTAINER DISPOSAL: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or punctu,e And
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dispose of in a sanitary landfill, or by other procedures approved by tate and local authorities. ,., •
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212-030815r3
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" .. ~ . • ,. ....
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• • • • • •• ••
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Page40f5
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. ~ " .
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I'
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Limited Warranty Notice - Read Carefully
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The treatment of poor quality or mechanically damaged seed, except for the curative control of existing diseases, may
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result in reduced gennination andlor reduction of seed or seedling vigor. To avoid these results, first conduct
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gennination tests on small portions of such treated seed before treating the entire lot. Due to seed conditions beyond
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our control no claims can be made to guarantee the gennination of "carry~over" of such "damaged or low vigor" treated
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seed.
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LIMITED WARRANTY AND DISCLAIMER
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The manufacturer warrants (a) that this product coofonn to the chemical description on the label; (b) that this product is reasonably fit
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for the purposes set forth in the directions for use, subject to the inherent risks referred to herein. when it is used in accordance with
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such directions; and (c) that the directions, warnings, and other statements on this label are based upon responsible ex.perts' evaluations
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of reasonable tests of effectiveness, of toxicity to laboratory animals and to plants and residues on food crops, and upon reports of
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field experience. Tests have not been made on all varieties of food crops and plants, or in all states or under aU conditions.
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THERE ARE NO EXPRESS WARRANTIES OTHER THAN THOSE SET FORTH HEREIN. THE MANUFACTIJRER
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NEITIIER MAKES NOR INfENDS, NOR DOES IT AUTHORIZE ANY AGENT OR REPRESENTATIVE, TO MAKE
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ANY OTHER WARRANTIES, EXPRESS OR IMPLIED, AND IT EXPRESSLY EXCLUDES AND DISCLAIMS ALL
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IMPLIED WARRANTIES OF MERCHANTABILITY OF FITNESS FOR A PARTICULAR PURPOSE, OR ANY
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WARRANTY OF QUALITY OR PERFORMANCE. THIS WARRANTY DOES NOT EXTEND TO, AND THE BUYER
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SHALL BE SOLELY RESPONSIBLE FOR, ANY AND ALL LOSS OR DAMAGE WHICH RESULTS FROM THE USE OF
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THIS PRODUCT IN ANY MANNER WHICH IS INCONSISTENT WITH THE LABEL DIRECTIONS, WARNINGS OR
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CAUTIONS. •
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BUYER'S EXCLUSIVE REMEDY AND MANUFACTIJRER'S OR SELLER'S EXCLUSIVE LIABILITY FOR ANY AND
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ALL CLAIMS, LOSSES, DAMAGES, OR INJURIES RESULTING FROM THE USE OR HANDLING OF THIS
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PRODUCT, WHETHER OR NOT BASED IN CONTRACT, NEGLIGENCE, STRICT LIABILITY IN TORT OR
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OTHERWISE, SHAll BE LIMITED, AT THE MANUFACTURER'S OPTION, TO REPLACEMENT OF, OR THE
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REPAYMENT OF THE PURCHASE PRICE FOR, THE QUANTITY OF PRODUCT WITH RESPECT TO WHICH
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DAMAGES ARE CLAIMED. IN NO EVENT, SHALL MANUFACTIJRER OR SELLER BE LIABLE FOR SPECIAL,
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INDIRECT OR CONSEQUENTIAL DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT.
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AMVAC offers this product, and Buyer accepts it, subject to the foregoing Limited Warranty which may be varied only by agreement
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in writing signed by an authorized representative of AMV AC.
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Amvac Chemical Corporation
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4100 E, Washington Blvd,
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Los Angeles, CA 90023 U,S,A,
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1·323·264·3910
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www.amvac-chemical.com
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•
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-,.>
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•
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to '- ~ •
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.. , ..
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• •
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•
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• • .. ..
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212·030815,3 Page 5 of5
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711
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• or ... ~ • , , • • • .... , ..... • • ••
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" , ..... • • •••••
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