a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
454 lines
20 KiB
Markdown
454 lines
20 KiB
Markdown
# BAS 516 ST SEED TREATMENT FUNGICIDE
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- EPA Reg No: **7969-248**
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- Registrant: BASF AGRICULTURAL SOLUTIONS US, LLC
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- Signal word: Caution
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- Active ingredients: Pyraclostrobin (12.8%); boscalid (25.2%)
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- Label accepted: 2009-08-07
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/007969-00248-20090807.pdf
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---
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
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WASHINGTON, D.C. 20460
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Attention: Khalid Akkari
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BASF Corporation
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P.O. Box 13528
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26 Davis Drive
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Research Triangle Park, NC 27709
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Subject: BAS 516 ST Fungicide
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EPA Registration No. 7969-248
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AUG 7 ,.. 2009
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OFFICE OF
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PREVENTION, PESTICIDES
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AND TOXIC SUBSTANCES
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Your amended label associated with Decision #408618 adding the previously approved
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cotton use, product application dated December 15,2008
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Dear Dr. Akarri,
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The amendment referred to above, submitted in connection with registration under FIFRA, as amended
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has been reviewed and is acceP!3-ble upon the following changes:
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1. On page 2, add the title "User Safety Requirements," above "Follow the manufacturer's
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instructions for cleaning ........ " In addition, add the word "exists," after "washables."
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2. On page 3, place the "Storage and Disposal" section inside a text box.
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3. On page 4, second column, under "DO NOT" delete the last sentence "Use with an EPA
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approved dye that imparts an unnatural color to the seed." The seed should already be dyed
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prior to bagging, and is therefore unnecessary. .
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A copy of the label stamped "Accepted with Comments" is enclosed for your records. Please submit one
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copy of the final printed label incorporating these changes before the product is released for shipping.
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If you have any questions, please contact Bryant Crowe by phone at (703) 305-0025 or via email.at
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crowe. bryant@epa.gov.
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L
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'6
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Enclosure
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Sincerely,
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fl· f(~
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Shajatyner
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Product 11anager20
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Fungicide Branch
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Registration Branch (7505P)
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ai?_
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~BASF
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The Chemical Company
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Group
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ACCEPtED
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wkb COMMENTS
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In EPA LeiteI' Dated
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AUG 7 2009 u .... the Fet!flI'IIl ............... ,
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....... de. ad ReM'" MeAei
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SAl amended, f.,. I£w, pt/IIIt&Iide
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..... 1eNJ~~ ~.~l:tiP.ur .. No. IJ q t; 9 - ,~'f' g'"
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--ASP 5E a g
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BAS 5i6SY
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seed treatment fungicide
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For use in brassicas, bulb vegetables, cotton, cucurbits, legume
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vegetables, soybean and sunflower
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Active Ingredients:
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pyraclostrobin: (carbamic acid, [2-[[[1-(4-chlorophenyl)-1 H-pyrazol-
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3-yl]oxy]methyl)phenyl)methoxy-, methyl ester) ........................ 12.8%
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boscalid: 3-pyridinecarboxamide,2-chloro-N-(4-chloro(1, 1 '-biphenyl)-2-yl) ... 25.2%
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Other Ingredients: ............................................ 62.0%
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Total: ....................................................... 100.0%
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EPA Reg. No. 7969-248 EPA Est. No.
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KEEP OUT OF REACH OF CHILDREN
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CAUTION/PRECAUCION
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Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en
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detalle. (If you do not understand the label, find someone to explain it to you in detail.)
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See inside booklet for complete First Aid, Precautionary Statements,
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Directions For Use, and Conditions of Sale and Warranty.
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In case of an emergency endangering life or property involving this product,
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call day or night 1-800-832-HELP (4357).
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Net Contents:
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BASF Corporation
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26 Davis Drive, Research Triangle Park, NC 27709
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". I,
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3 -'b
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Fungicide
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?
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FIRST AID
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• Take off contaminated clothing.
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If on skin or clothing • Rinse skin immediately with plenty of water for 15 to 20 minutes.
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• Call a poison control center or doctor for treatment advice.
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• Call a poison control center or doctor immediately for treatment advice.
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If swallowed • Have person sip a glass of water if able to swallow.
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• DO NOT induce vomiting unless told to do so by a poison control center or doctor.
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• DO NOT give anything by mouth to an unconscious person.
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• Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes.
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If in eyes • Remove contact lenses, if present, after first 5 minutes; then continue rinsing eyes.
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o Call a poison control center or doctor for treatment advice.
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• Move person to fresh air.
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If inhaled • If person is not breathing, call 911 or an ambulance; then give artificial respiration,
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preferably by mouth to mouth, if possible.
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• Call a poison control center or doctor for further treatment advice.
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HOT LINE NUMBER
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Have the product container or label with you when calling a poison control center or doctor or going for treatment. You may also
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contact BASF Corporation for emergency medical treatment-information: 1-800-832-HELP (4357).
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PRECAUTIONARY STATEMENTS
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HAZARDS TO HUMANS
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AND DOMESTIC ANIMALS
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CAUTION
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Harmful if swallowed or absorbed through the skin.
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Causes moderate eye irritation. Avoid contact with
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skin, eyes, or clothing. Prolonged or frequently
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repeated skin contact may cause allergic reactions
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in some individuals.
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Personal Protective Equipment (PPE)
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Some materials that are chemically resistant to this prod
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uct are listed below. For more options, refer to Category
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A on an EPA chemical-resistance category selection chart.
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Applicators and other handlers must wear:
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• Long-sleeved shirt and long pants
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• Chemical-resistant gloves made of any waterproof
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material (such as nitrile, butyl, neoprene and/or barrier
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laminate)
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• Shoes plus socks
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Follow the manufacturer's instructions for cleaning and
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maintaining PPE. If no such instructions for washables,
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use detergent and hot water. Keep and wash PPE sepa
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rately from other laundry.
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2
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User Safety Recommendations
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Users should:
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• Wash hands before eating, drinking, chewing gum,
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using tobacco or using the toilet.
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• Remove clothing immediately if pesticide gets inside.
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Then wash thoroughly and put on clean clothing.
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• Remove PPE immediately after handling this product.
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Wash the outside of gloves before removing. As soon
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as possible, wash thoroughly and change into Clean
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clothing.
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Environmental Hazards
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This pesticide is toxic to fish and aquatic invertebrates.
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DO NOT discharge effluent containing this product into
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lakes, streams, ponds, estuaries, oceans, or other waters
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unless in accordance with the requirements of a National
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Pollutant Discharge Elimination System (NPDES) permit
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and the permitting authority has been notified in writing
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prior to discharge. DO NOT discharge effluent containing
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this product into sewer systems without previ0usly, notify
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ing the local sewage treatment plant authority 'Fu', \;j'Llid
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ance, contact your State Water Board or RegiQnal,Office
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of the EPA. ' ,
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DO NOT contaminate water Wh3h 2isposing of equipment
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washwaters or rinsate. ., ,
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------------- -.--- -- -.--
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Directions F.':'t; Use -------
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It is a violation of federal law to ~~e 'this product i'n a man-
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ner inconsistent with its labeling. ' , . ,
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DO NOT apply this product in a way that will 00ntdpt
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workers or other persons. Only protected hanUIi,)rs may be
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in the area during application. For any requirements spe
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cific to your state or tribe, consult the agency responsible
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for pesticide regulation.
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Storage and Disposal
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DO NOT contaminate water, food, or feed by storage or
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disposal.
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Pesticide Storage. Store in original containers only. Keep
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container closed when not in use. DO NOT store near
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food or feed. In case of spill on floor or paved surfaces,
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mop and remove to chemical waste storage area until
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proper disposal can be made if product cannot be used
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according to label.
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Pesticide Disposal. Wastes resulting from using this
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product may be disposed of on-site or at an approved
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waste disposal facility. If these wastes cannot be disposed
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of according to label instructions, contact your State
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Pesticide or Environmental Control Agency, or the
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Hazardous Waste representative at the nearest EPA
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Regional Office for guidance.
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CONTAINER DISPOSAL
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Nonrefillable Container. DO NOT reuse or refill this
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container. Triple rinse or pressure rinse container (or
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equivalent) promptly after emptying; then offer for recy
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cling, if available, or reconditioning, if appropriate, or punc
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ture and dispose of in a sanitary landfill, or by incineration,
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or by other procedures approved by state and local
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authorities.
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Triple rinse containers small enough to shake
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(capacity S; 50 pounds) as follows: Empty the remain
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ing contents into application equipment or a mix tank.
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Fill the container 1/4 full with water and recap. Shake for
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10 seconds. Pour rinsate into application equipment or a
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mix tank, or store rinsate for later use or disposal. Drain
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for 10 seconds after the flow begins to drip. Repeat this
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procedure two more times.
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Triple rinse containers too large to shake (capacity
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> 50 pounds) as follows: Empty the remaining con
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tents into application equipment or a mix tank. Fill the
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container 1/4 full with water. Replace and tighten clo
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sures. Tip container on its side and roll it back and forth,
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ensuring at least one complete revolution, for 30 sec
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onds. Stand the container on its end and tip it back and
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forth several times. Turn the container over onto its other
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end and tip it back and forth several times. Empty the
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rinsate into application equipment or a mix tank, or store
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rinsate for later use or disposal. Repeat this procedure
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two more times.
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Pressure rinse as follows: Empty the remaining con
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tents into application equipment or mix tank. Hold con
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tainer upside down over application equipment or mix
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tank, or collect rinsate for later use or disposal. Insert
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pressure rinsing nozzle in the side of the container and
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rinse at about 40 PSI for at least 30 seconds. Drain for
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10 seconds after the flow begins to drip.
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In Case of Spill
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In case of large-scale spillage regarding this product, call:
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CHEMTREC 1-800-424-9300
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BASF Corporation 1-800-832-HELP (4357)
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3
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Steps to be taken in case this material is released or
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spilled:
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Dike and contain spill with inert material (sand, earth, etc.)
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and transfer liquid and solid diking material to separate
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containers for disposal. Remove contaminated clothing
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and wash affected skin areas with water. Wash clothing
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before reuse. Keep spill out of all sewers and open bodies
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of water.
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General Information
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This package contains BAS 516 ST seed treatment
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fungicide, a water-dispersible granule (WG). BAS 516 ST
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is a broad-spectrum fungicide that provides preventive
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seed and seedling protection against seed borne fungi
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causing seed decay and the soilborne pathogens
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Rhizoctonia so/ani, Penicillium spp. and Fusarium spp.
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BAS 516 ST may be applied in conjunction with applica
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tions of other registered seed treatment and crop protec
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tion products. Make all applications according to the use
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directions in this label. Use the higher rates of
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BAS 516 STwhen disease pressure is expected to be
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high.
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Resistance Management
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The active ingredients in BAS 516 ST, boscalid and
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pyrac!ostrobin, belong to the groups of respiration
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inhibitors classified by the EPA as Carboxamides and
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Quinone Outside Inhibitors (001) or Target Site of
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Action Group 7 and Target Site of Action Group 11
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fungicides, respectively. Due to the minimal amounts of
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active ingredient in BAS 516 ST applied to the seed that
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relocate to the upper parts of the plant, the potential for
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development of resistance to both fungicides is extremely
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low. Seed treatments of BAS 516 ST can, therefore, be
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followed by foliar use and resistance management
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guidelines of foliar use fungicides containing boscalid,
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pyraclostrobin, or both (Cabrio~ EG fungicide, Endura~
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fungicide, Headline~ fungicide, or Pristine~ fungicide)
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as specified on the respective labels.
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Application Instructions
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For use on "crop" seed at commercial treatmAnt far;ilities.
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Not for use on farm. ' ; . \ , ,
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Apply BAS 516 ST asa water-based slurry UGi'nd standard
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slurry or mist-type seed treatment fl.pplication' eq~ipment.
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The exact amount of water nee(;ed 'LO provid~ the ~Iurry
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rate (mll100 kg or ozlcwt of se~d' /('\r, 0ptimu[ (I (;(;I,,6(age
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is difficult to predict since weather 'w!1uitions, (~0t o( cold),
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seed type and surface, and equ;pfTlAr,t used all h'a)/f., a
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bearing on coverage, Consult a,s3'-;rj,treatment s::Jecialist
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,regarding slurry rates for the crop seed to be t~E'9~pd with
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BAS 516 ST. The required amount of BAS 51-5 5T'should
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then be mixed with the specified amount of wc::t:r .~hat will
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provide uniform and complete coverage on th£, GeOd sur
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face. Uniform application on seed and complete seed cov
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erage are necessary for seed safety and best disease pro
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tection.
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s ---~
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Seed must be sound and well cleaned prior t6 treatment.
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The purchaser of BAS 516 ST seed treatment fungicide
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is responsible for ensuring that all seed treated with this
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product are adequately dyed with a suitable color to pre
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vent its accidental use as food for man or feed for animals.
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Refer to 21 CFR, Part 2.25 and 40CFR 153.155(b)(1). Use
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an EPA-approved dye or colorant that imparts an unnatur
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al color to the seed. Any dye or colorant added to treated
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seed must be cleared for use under 40CFR, Part 180.900,
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. "Exemptions from the requirement of a tolerance".
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Federal regulations have established official tolerances or
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exemptions from tolerances for residues on food and for
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age crops that should not be exceeded when the product
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(dye or colorant) is used at labeled rates.
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Consult the seed treatment specialist for calibration and
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operation procedures of the seed treatment equipment
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being used. Mechanical agitation is required for proper
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mixing of BAS 516 ST. Prepare no more mixture of
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BAS 516 ST than is needed for immediate treating. Add
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3/4 of the required volume of water to the mix tank. With
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agitation running, add the required amount of BAS 516 ST
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in the tank along with other seed treatment components.
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Add the remaining 1/4 of the required water. Follow the
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mixing sequence listed below. Agitate thoroughly before
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and during application.
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BAS 516 ST With Tank Mix Partners
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BAS 516 ST mixes easily with water and other water
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based seed treatments manufactured by BASF
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Corporation. When using BAS 516 ST in a tank mixture
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with other seed treatment products, observe all directions
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for use, crops/sites, use rates, dilution ratios, precautions,
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and limitations that appear on the tank mix partner label.
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No label dosage or application rate should be exceeded,
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and the most restrictive label precautions and limitations
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should be followed. BAS 516 ST should not be mixed
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with any product that prohibits such mixing. All
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applications should be made according to the use
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directions.
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When mixing BAS 516 ST with products from other
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manufacturers, the compatibility should be tested prior to
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use by conducting a jar test as follows:
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1 . Mix all intended seed treatments with the appropriate
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amount of water in a clear glass container.
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2. Mix well and allow to sit for one hour.
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3. Remix and observe for incompatibility.
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Physical compatibility is only part of compatibility. Testing
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also needs to be done with the seed to make sure the
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combination of products does not have detrimental effects
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on the seed.
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Tank Mixing Instructions
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1. Add 3/4 of the required amount of water to the mix tank
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and turn on the agitation. Mechanical agitation is pre
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ferred.
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2. Follow the following mixing sequence: dye or colorant,
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wettable powders, soluble powders, flowable formula
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tions, emulsifiable concentrates, and remaining 1/4 of
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the required water. The 1/4 of the required water as the
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last item for addition to the premix tank can be used as
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rinsate for the chemical container or to adjust the total
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slurry to compensate for water displacement by pow
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dered products.
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3. Maintain agitation until the entire slurry mixture has been
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used.
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4. Ensure that seed is dry prior to bagging.
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NOTE: Federal law requires that bags of treated seeds
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shall be labeled with the following: "This seed has been
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treated with boscalid and pyraclostrobin fungicides.
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DO NOT use for food, feed or oil purposes. Store away
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from food and feedstuffs. Use with an EPA-approved dye
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that imparts an unnatural color to the seed."
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4
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Crop-specific Use Directions
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Product Use Rate in
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Crop Target Disease ozs/100 Ibs seed
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(Ib ai/100 Ibs seed)
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Brassica vegetables Seed and seedling disease (damping- 2.5 to 5
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off) caused by Rhizoctonia so/ani, (0.06 to 0.12)
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Phoma /ingam and other seed borne
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fungi causing seed decay, seedling
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damping-off, including Cladosporium
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spp., Penicillium spp.
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. Bulb vegetables Seed and seedling disease (damping- 2.5 to 5
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off) caused by seed borne fungi (0.06 to 0.12)
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(Botrytis, Aspergillus and Penicillium
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spp.) causing seed decay, seedling
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damping-off
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Cotton 1
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Seed and seedling disease (damping- 2.5 to 5
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off) caused by Rhizoctonia so/ani, (0.06 to 0.12)
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seed borne fungi causing seed decay,
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and seedling damping-off
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Cucurbits Seed and seedling disease (damping- 0.63 to 5
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off) caused by Rhizoctonia so/ani, (0.015 to 0.12)
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seed borne fungi causing seed decay,
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and seedling damping-off
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Legume vegetables Seed and seedling disease (damping- 0.63 to 2.52
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(dried shelled peas and beans, off) caused by Rhizoctonia so/ani, (0.015 to 0.06)
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except cowpea, field pea, and seedborne fungi causing seed decay,
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grain lupin) seedling damping-off
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Broad bean, Chickpea, Fava bean,
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Guar, Lablab bean, Lentil, Pigeon pea
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Lupinus spp.: Sweet lupin, White
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lupin, White sweet lupin
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Phaseo/us spp.: Black bean, Field
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bean, Kidney bean, Lima bean, Navy
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bean, Pink bean, Pinto bean, Tepary
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bean
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Vigna spp.: Adzuki bean, Black-eyed (' \
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pea, Catjang, Crowder pea, Moth
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bean, Mung bean, Rice bean, , ,
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Southern pea, Urd bean , -_._---
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Soybean Seed and seedling disease (damping- 0.63 to 2.52' , , '
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\., '- '.', 1
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(Glycine spp.) off) caused by Rhizoctonia so/ani, (O.G 1 t? \.0 O.OEi) ,
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seed borne fungi causing seed decay,
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seedling damping-off
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Sunflower Seed and seedling disease (damping- 1.25 to 2.5,
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off) caused by Rhizoctonia so/ani, (0.03 to 0.06)
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seed borne fungi causing seed decay,
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seedling damping-off
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lFor control of seed and seedling disease (damping-off) caused by pythium spp., use BAS 516 ST seed treatment fungicide only in
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conjunction with labeled rates of mefenoxam- or metalaxyl-containing seed treatment products.
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5
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Conditions of Sale and Warranty
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The Directions For Use of this product reflect the opin
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ion of experts based on field use and tests. The direc
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tions are believed to be reliable and must be followed
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carefully. However, it is impossible to eliminate all risks
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inherently associated with the use of this product. Crop
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injury, ineffectiveness or other unintended consequences
|
||
may result because of such factors as the presence of
|
||
other or untested or unapproved materials, seed of low
|
||
quality or low vigor or low germination, use of the prod
|
||
uct in a manner inconsistent with its labeling, misappli
|
||
cation of the product, or weather conditions at planting
|
||
or environmental conditions during seed storage,. all of
|
||
which are beyond the control of BASF CORPORATION
|
||
("BASF") or the Seller. To the extent consistent with
|
||
applicable law, all such risks shall be assumed by the
|
||
Buyer.
|
||
BASF warrants that this product conforms to the chemi
|
||
cal description on the label and is reasonably fit for the
|
||
purposes referred to in the Directions For Use, subject
|
||
to the inherent risks, referred to above.
|
||
TO THE EXTENT CONSISTENT WITH APPLICABLE
|
||
LAW, BASF MAKES NO OTHER EXPRESS OR IMPLIED
|
||
WARRANTY OF FITNESS OR MERCHANTABILITY OR
|
||
ANY OTHER EXPRESS OR IMPLIED WARRANTY. TO
|
||
THE EXTENT CONSISTENT WITH APPLICABLE LAW,
|
||
BUYER'S EXCLUSIVE REMEDY AND BASF'S EXCLU
|
||
SIVE LIABILITY, WHETHER IN CONTRACT, TORT, NEG
|
||
LIGENCE, STRICT LIABILITY, OR OTHERWISE, SHALL
|
||
BE LIMITED TO REPAYMENT OF THE PURCHASE
|
||
PRICE OF THE PRODUCT. TO THE EXTENT CONSIS
|
||
TENT WITH APPLICABLE LAW, BASF AND THE SELL
|
||
ER DISCLAIM ANY LIABILITY FOR CONSEQUENTIAL,
|
||
SPECIAL OR INDIRECT DAMAGES RESULTING FROM
|
||
THE USE OR HANDLING OF THIS PRODUCT. BASF
|
||
and the Seller offer this product, and the Buyer and User
|
||
accept it, subject to the foregoing Conditions of Sale
|
||
and Warranty which may be varied only by agreement
|
||
in writing signed by a duly authorized representative of
|
||
BASF. ST1107
|
||
6
|
||
Cabrio, Endura, Headline and Pristine are registered
|
||
trademarks of BASF.
|
||
© 2008 BAS':: G'orpration
|
||
< •• ' All rights: reserved.
|
||
007969-00248.20080317 o.NVA 20087q4-~fJ~-0097
|
||
Supersedes: ;'~vh 2007 L04-284-0147
|
||
BASF Corporation
|
||
26 Davis Drive
|
||
Research Triangle P&rk ,~k: 27709
|
||
"'~BASF
|
||
The Chemical Company
|