a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
322 lines
18 KiB
Markdown
322 lines
18 KiB
Markdown
# RIVERSIDE DITHON 63
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- EPA Reg No: **9779-125**
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- Registrant: WINFIELD SOLUTIONS, LLC
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- Signal word: Danger
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- Active ingredients: Methyl parathion (29.1%); Parathion (58.1%)
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- Label accepted: 1988-09-13
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/009779-00125-19880913.pdf
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---
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RESTRICTED USE PESTICIDE - 18 point
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Due to very high acute toxicity to humans and birda
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For retail sale to and use only by certified applicators or
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persons under their direct supervision and only for those
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us~s covereJ by the certified applicators' certification.
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Direct supervi.ion for this product is defined as the
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certified applicators' being physicall, present during
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application, aiIing, loading, repair and eleaning of
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application equipment. CO'-ercia1 certified applicators
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must also ensure that all persons involved in these
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activities are inforaed of the precautionary state_ents.
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Riverside Trademark-
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DITHON 63
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Contains 6 pound. parathion and 3 pound. methyl parathion per gallon
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ACTIVE INGREDIENTS
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O,O-diethyl O-p-nitrop~~ny1 pho.phorothioate* ••••• 58.1%
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O,D-dimethyl O-p ~itropheny1 phosphorothioate** ••• 29.1%
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INERT INGREDIENTS*** ••••••••.............•.•••.•.... 12.8%
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*Parathion (also known as ethyl parathion)
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**Kethy1 parathion
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***Contains 7.3% of aromatic petroleum solvent.
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TOTAL 100.0%
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Contains 6 pounds parathion and 3 pounds methyl parathion per gallon.
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ACCEPTED,
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f
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"
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• STOP-READ LABEL BEFORE USING.
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rEEP OUT OF REACH OF CHILDREN ~ 12 point
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DANGER - red - 18 point
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PELlGRO ~ re:i
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POISON
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VENENa
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Skull , Croaabonea - red
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Can Cauae Death
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PRECAUCION
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AL USUARIO
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Si uated no lee inglea,
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no use eate producto
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haata que la etiqueta
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Ie hay a aido explicada
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ampUament" •
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STATEMENT OF PRACTICAL TREATMENT
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FIRST AID TREATMENT + Call a doctor (phyaician), clinic or hoapital
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i.-ediately. Explain that the victim haa been "xposed to parathion
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methyl parathion and d"acribe hia condition.
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IF BREATHING HAS STOPPED: Start artificial reapiration i .. "diately
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and maintain until doctor a"". victi ••
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IF SWALLOWED: Call a phy.ician or poiaon control center. Drink 1
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or 2 glaa.ea of vater and induce vomiting by touching back of throat
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with finger, or, if available, by ad.ini8t"ring .yrup of ipecac. Do
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not induce vomiting or give anything by mouth to an unconacious person.
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IN CASE OF CONTACT: Immediately flu.h "y"a or akin with plenty of
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wat"r for at leaat 15 minute a vhile removing contaminated clothing
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and ahoe.. See doctor immediately.
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See additional PRECAUTIONARY STATEMENTS on left aide panel.
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EPA Reg. No. 9779 125
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Manufactured For
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RIVERSIDE/TERRA CORPORATION
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EPA Eat. No. 9779-TX-3
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NET CONTENTS
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___ GALLONS
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Terra Centre, 600 Fourth Street, Sioux City, Iowa 51101
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Riverside Serves Agriculture. Agriculture Serves Everyone.
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\,
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"
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PRECAUTIONARY STATEMENTS
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DANGER
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HAZARDS TO HUMANS AND DOMESTIC ANIMALS
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,........,-~=~---::I, _,.--", I ~(l~
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CAN KILL IF SWALLOWED
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Thi. product can kill
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you if' .. ,aUowed, even
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in ... 11 a.aunt •• pray
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mist may be fatal if
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.. wallowed.
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CAN KILL BY SKIN CONTACT
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This product can kill you
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if touched by hands or
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• pilled or spla.hed on
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akin, in eyes or on
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clothing (liquid goes
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through clothes).
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"
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~ ----
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CAN KILL IF BREATHED
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Thia product can kill
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you if vapora or .pray
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.iet are breathed •
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WORK SAFETY RULES: The National Pe.ticide Telecommunication Network is
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available for reco..endations regarding poi.oning .. nagement, emergency treat
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.ent, and other iofor.ation regarding the toxicity of parathion-.ethyl
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parathion. The toll free number for the National Pe.ticide Telecommunication
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Network is 1-800-858-7378. If handled indoors, provide mechanical exhauat ven
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tilation. Keep all unprotected persona, children, livestock, and pets away from
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treated area or where there is danger of drift. Do not rub eyes or mouth with
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handa. If you feel sick in any way, STOP work and get help right away. See
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Firat Aid (Practical Treatment) section. USE ONLY WHEN WEARING THE FOLLOWING
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PROTECTIVE CLOTHING AND EQUIPMENT DURING MIXING/LOADING, APPLICATION, REPAIR,
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AND CLEANING OF APPLICATION EQUIPMENT, DISPOSAL OF PESTICIDE AND EARLY REENTRY
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INTO TREATED AREAS: Waterproof auit of one or two piecea covering all parts of
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the body except the head, hands, and f~et; heavy-duty chemical resiatant gloves;
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chemical resistant shoes (or chemical resistant shoe coveringa or chemical
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reaiatant boots); gogglea or face ahield (a helmet with a visor .. y be subati
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tuted during aerial application in non-encloaed cockpits); hood or wide brimmed
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hat; NIOSH approved reapirator. In addition, mixer/loaders muat wear a chemical
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reaiatant apron when using the concentrate product. IMPORTANT I If peaticide
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comea in contact with skin, wash off with so~p and water and contact a phyaician
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immediately. Alwaya waah handa, face, and arma with aoap and water before
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amoking, eating, drinking, or toileting. AFTER WORK: Before removing glovea,
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waah them with eoap and water. Take off all work clothea and ahoea. Shower
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u~ing aoap and water. Wear only clean clothea when leaving the job. Do not
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wear contaminated clothing. Personal clothing worn during work muat be stored
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and laundered aeparately from protective clothing and household articles. Store
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protective Clothing separately from peraonal clothing. Clean or launder protec
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tive clothing after each uae. Reapiratora muat ~e cleaned and filter" r.placed
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according to instructions included with the respirators. rLcle:tiv~ clothing
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and protective equipment heavily contaminated or drenched wilh pacathion-methyl
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parathion muat be deatroyed according to atate and local reg~.~.i~na. HEAVILY
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CONTANINATED OR DRENCHED CLOTHING CANNOT BE ADEQUATELY DECONTAH"IATED. ')'JRING
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AERIAL APPLICATION, HUHAN FLAGGERS ARE PROHIBITED.
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L
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•
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•
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POISON SIGNS (Symptoms)
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Parathion-.ethyl parathion is • very dangeroul poison. It rapidly enters the
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body on contact vith all skin surfaces and eyes. Clothing vet with this
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material .uat be re.oved immediately. Exposed persona muat receive prompt medi
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cal treatment or they -ay die. So.e of the ailna and .y.pto •• of poiloning are
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headache, nausea, vomiting, cra.p., weaknee., blurred vision, pin-point pupil.,
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tightness in cheat, labored breathing, nervouane •• , .vesting, vatering of eyes,
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drooling or frothing of mouth and noae, mUlcle Ipasa, and coma.
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NOTE TO PHYSICIAN
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Antidote--ad.iniater atropine sulfate in large doses. TWO to FOUR mg. intrave
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nously or intr •• uBcular11 .a aoon .a cyanosis i. overcome. Repeat at 5 to 10
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minute interval. until signa of atropinization appear. 2-PAH chloride i. a1ao
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antidotal and .. y be administered in conjunction with atropine. DO NOT GIVE
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HORPHINE OR TRANQUILIZERS. Parathion-methyl parathion is a strong choli
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nesterase inhibitor affecting the central and peripheral nervous systems and
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producing cardiac and respiratory depression. At first sign of pulmonary edema.
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the patient should be given supplemental oxygen and treated symptomatically.
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Continued ablorption of the poieon -ay occur and fatal relapse. have been
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reported after initial improvement. VERY CLOSE SUPERVISION OF THE PATIENT IS
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INDICATED FOR AT LEAST 48 HOURS.
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POST TREATED AREAS
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Consult your State Agricultural Extension Service or Experiment Station
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regarding posting treated area.
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, '1
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ENVIRONHENTAL HAZARDS
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This pesticide is highly toxic to fish, aquatic inve~teb~ates, and wildlife.
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Bird. in treated are .... , be killed. Shri.p and other aquatic organi ••• may be
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killed at ~eco .. ended application ~ates. Do not apply di~ectly to wate~ o~
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wetlands (swamps, bogs, .. ~.hes, and potholes). Runoff and d~ift f~o. ta~get
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a~eas may be ha~a~dous to aquatic 0~ganis.8 in adjacent aquatic sites. Do not
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cont •• inate vater when dispoain, of equip.ent vashvatera. Thi. product is
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ext~e.ely toxic to bees exposed to di~ect t~eat.ent o~ ~esidues on blooming
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c~ops or weed.. Do not apply this p~oduct o~ allow it to drift to blooming
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crop. or weeds if bees are visiting the treat_ent area.
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~HEHICAL AND PHYSICAL HAZARDS
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Do not use, p~ur. spill, or store near heat or open fl •• e.
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DIRECTIONS FOR USE
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It i •• violation of Federal lav to use this product in a manner inconais.tent
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with its labeling.
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Do not apply this p~oduct through any type of i~rigation system.
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RE-ENTRY STATEHENTS: Reentry into treated fields befo~e expiration of the
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reentry interval specified on this label is prohibited, unless the protective
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clothing and equipment specified on this label are used. Unless advised other
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wise, do not reente~ t~eated fields for ) days after application. Becau"se
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certain states may require more restrictive reentry intervals for various crops
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treated with this p~oduct, consult your State Department of Agriculture for
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further information.
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NOTICE TO CROP OWNERS: Written o~ oral wa~nings must be given to worke~s who
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are expected to be in 8 treated area or in an area abo~t to be treated with this
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product. In case of accidental exp08ure follow the informa~ion given unde~
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STATEHENT OF PRACTICAL TREATMENT and have exposed person(s) c,e a physician.
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When oral warnings are given, varnings shall be given in a language customarily
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understood by workers. O~al warnings must be given if there is a reason to
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believe that written warnings cannot be understood by wo~kers. Written wafnings
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muot include the following information: DANGER. Area treated with pa~athion
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methyl parathion on (date). Do not enter without approp~iate protective
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clothing fo~ ) days, or as otherwise specified on this label. In caSe ~f ac
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cidental exp08ure immediately remove contaminated clothing, t/']~ the a~fected
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area, contact your supervisor, and have him take you to the ~oc~or.
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I
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'----
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,
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.. • .. 1 ...
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STORAGE AND DISPOSAL
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DO NO~ CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL.
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STORAGE
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Store in a dry location away from children, ani.als, foods, feeds, seeds, and
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other agricultural chemicals. Keep container clooed when not uoing. Do not
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allow wa~er into container as this may cause deterioration of product. Handle
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in accordance with information given under PRECAUTIONARY STATEMENTS. Do not
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store under conditions where temperature may exceed 12DoF or below 45°F. Keep
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.torage a~e. locked when not in use. In the event of spillage or leakage, aoak
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up .. teri.l with abaorbent clay, •• nd, aawdu.t or other absorbent material.
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Scrape up and dlopose of in accordance with information given under PESTICIDE
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DISPOSAL. Repackage and relabel useable product in a oound container of a type
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approved by the U.S. Department of Transportation. In case of fire or other
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emergency, report at once by toll-free telephone to 800-424-9300.
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DISPOSAL
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PESTICIDE DISPOSAL: Pesticide WBstes are acutely hazardous. Improper dtaposal
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of eXCess pesticide, spray mixture or rinsate ia a violation of Federal law. If
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theae wastes cannot be diaposed of by use according to label instructions, con
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tact your State Peatlcide or Environmental Control Agency or the Hazardoua Waste
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representative at the nearest EPA Regional Office for guidance.
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CONTAINER DISPOSAL: Plastic Containers--Triple rinse (or equivalent). Then
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offer for recycling or reconditioning, or puncture and dispose of in a sanitary
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landfill, or incineration, or, if allowed by state and local authoritied, by
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burning. If burned, otay out of smoke. Metal Containers--Triple rinse (or
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equivalent). Then offer for recycling or reconditioning, or puncture and
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dispose of in a sanitary landfill, )r by other procedures approved by state a~d
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local authorities.
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General Warnings and Limitationa: Do not plant any food or feed crop in
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parathion treated 8011s other than those with regiotered parathion usea.
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Consult your State Agricultural Extension Service or Experiment Station
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regarding posting treated areas. If crop is intended for canning, consult your
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~annery fieldman prior to application.
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I
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'.
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i
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GENERAL INFORMATION
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DlTRON 63 may be applied by ground .prayer. or by airplane., mixing DITHON 63 in
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water to fora an emul.ion .pray aolution. To .. ke the spray .olution, half fill
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the spray tank with water while still agitating. Continue to agitate during
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use.
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When applying with ground Rprayers calibrate 00 as to apply the recoamended
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amount of DlTRON 63 in not Ie •• than 3 gallono of water per acre. Airplane.
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should apply the recommended a.ount of DITRON 63 in not leo. than 1 gallon of
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water per acre. Always use sufficient water for adequate coverage of the crop
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foliage.
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Where a dosage range is given, use the lower rate on s.all or young plants or
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with light insect infeotations; use the higher rate on large or .. ture ,lants or
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with heavy insect infestations.
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The hazards and precautions for handling DITRON 63 in this container are equally
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ap~licable to it after dilution with water for spray application.
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Use of this product in a .. nner not in accordance with the information on' this
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label .. y injure or kill humans, domestic animals, wildlife, aquatic life,
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desirable plants, create excessive and unlawful chemical residup.s or produce
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other undesirable resulto.
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ALFALFA, CLOVER, GRASS AND VETCR: For control of aphids (greenbugs), spotted
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alfalfa aphid. alfalfa weevil larvae, alfalfa caterpillars, armyworms (up to
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third instar), climbing cutworm. and grasshoppero, use 1/3 to 2/3 pint per acre.
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For blister beetles, ~ebworms and spider aites, USe 1/2 pint per acre. For
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trotricid moths and clover leaf weevilo, use 2/3 pint per acre. For alfalfa, do
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not apply if the crop or weeds in the treatment area are in bloom.
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CABBAGE AND COLE CROPS (Broccoli, Brus.els Sprout., Cauliflower, Kohltabi): For
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control or aphids, imported cabbage wor •• and diamond-back mo' h., use 1/4 to 1/2
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pint per acre. For loopers, armyworm. (up to 3rd instar), flea beetles, and
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vegetable weevils, use 1/2 to 1 pint per acre. Do not apply DITRON 63 within 21
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days of harvest.
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CARROTS: For c~ntrol of aphids, leafhoppero, petrobia mites, and vegetable
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weevilo, ule 1/3 to 1/2 pint per 100 ,allono of water. Apply 300 gallons per
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acre. Do not use treated tops for food o~ feed. Do not apply DITHON 63 within
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15 days of harvest.
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CORN (Field, Hybrid, Pop and Sweet): For control of rootworm ~Jults, use'l/3
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pint pe;: acre. For aphido, armyworms up to third instar, fal', ar .. yworms, bud
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worms, opider mites, and climbing cutwor.s, use 1/2 pint per ~::!. For .tink bugs
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USe 3/4 pint per acre. For European corn borer control USe 3/5 pint per .~re.
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Apply firot opray when 75% of corn plant. ohow shot-hole feedinp, ~nd fullov with
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two additional opray. at 5 to 7 day intervMlo. Use sufficient ~.t~r per !cre to
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r~~yi~~ ~omp!ete coverage and b~ certAin whorls of plants ace weLL tr~a~!d. Do
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not apply to corn during the pollen ahed period. Do not apply DITRON 6~ t~ corn
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within 12 day. of ha~ve.t. cutting. or forage ulle. Do not reenter trea~~d
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fields for 6 dRYS.
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~.'
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COTTON: For control of cotton leafwor~s, fleahoppers, Lygus bugs, red spider
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mitea, thrips and garden webworms, use 1/2 pint ,er acre. For control of cabbage
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loopers and boll weevils. use 2/3 to I 1/3 pinta per acre. Foe bollwor •• and
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budworms use 1 1/3 pints per acre. For aphids, cotton leaf perforators,
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armyworms up to third instar, stink bugs and saltmarsh caterpillars, us~ I pint
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per acre. Application to cotton should be made at 4 to 5 day intervals until
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control is obtained. Workers entering fields within 24 hour. after application
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should wear protective clothing. Do not apply DITHON 63 within 1 days of har
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vest or of handpicking cotton.
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ONIONS: For control of onion thrip8, use 1/3 pint per acre. Do nol apply
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DITHON 63 within 15 days of harvest.
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POTATOES: For control of a~hid8, blister beetles, leafhoppers, leaf miners,
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plant bugs, potate psyllids, thrips, and vegetable weevils, use 1/2 to 1 1/3 pints
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per acre. Do n~t apply DITHO~ 63 within 5 days of harvest.
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SHALL GRAINS (Barley, Oats, Wheat): For co~trol of armyworms up to third
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instar, fall armyworms, winter grain mites and thrips, use 1/4 pint per acre. For
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aphids (greenb.tgs) use 1/3 pint per acre. For grasshoppers and brown wheat
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mites, use 1/2 pint per acre. For climbing cutworms, leafhoppers and Say's plant
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bugs, use 1/2 to 3/4 pint per acre. For chinch bugs and false chinch bugs, use 1
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pint per acre. Do not apply DITHON 63 to small grains within 15 days of har
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vest, pasturing, cutting, or forsge use.
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SORGHUH: For control of corn earworms, corn-leaf aphids, false chinch bugs and
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sorghum webworms, use 1/3 pint per acre. For sorghum midges, use 1/2 pint per
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acre. Leaf injury may Occur on some hybrid varieties of sorghum. Spray a few
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rows a week or so before booting to test effects upon plants. Do not apply
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DITHON 63 to sorghum within 21 days of harvest, cutting or forage use.
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SOYBEANS: For control of two-spotted mites, use 1/2 pint per acre. Fpr stink
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bugs use 2/3 pint per acre. For bollworms, fall armywo$ms, gleen cloverworms,
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velvet bean catp.r~illars and webworms, use 7/8 pint per acre. Do not apply more
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than 2 applications per growing season. Do not apply DITHO~ 63 to soybeans
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within 20 days of harvest or forage use.
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NOTICE: Seller warrants that the product conforms to its chemical description
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and is leasonably fit for the purposes stated on the label when used in accor
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dance with directions under normal conditions of use, hut neither this warranty
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nor any other warra~ty of merchantabJlity or fitness for a particular pUlr~se,
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express or implied, extends to the use of this product contracy t .. label
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instructions, or under abnormal conditions. or under conditions not reasunably
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foreseeable to Seller and Buyer assumeS the risk of any such u'e.
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