a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
365 lines
16 KiB
Markdown
365 lines
16 KiB
Markdown
# VALCO BRAND METHYL PARATHION EMULSIFIABLE NO. 4
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- EPA Reg No: **9779-288**
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- Registrant: WINFIELD SOLUTIONS, LLC
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- Signal word: Danger
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- Active ingredients: Chevron 100 (48.26%); Methyl parathion (45.49%)
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- Label accepted: 1985-01-14
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/001063-00104-19850114.pdf
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---
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til~II(1n.
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:U,1!~ .re. or
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klc: ill any way
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'Pnuii7al lrt'al~
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)WI:\G
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IIXG
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"r rubi'er "~'er'
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~Splnt'lr JIJJntly
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Admlr.lstfat!(m
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n.l II"IHIUH<' lor
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()f 30 erR part
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.... lIh Si)ap !>r.d
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p ;ttl.:! ",Uer t:.e-
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-". S!:<)'~"(~r •.. bmg
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","'E the Job Dc>
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.Qthmg and pro~
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,.lSe RI'~plrator
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.trurljUIlS mdud-
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re.·II)' ~r through
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'fig ueated cT'lut
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.reentc\' lntef\'al~
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~ )'our' State De:
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.. d;a are exp<!cted
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trNted 1,Iqth this
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, !leld.lo that may
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:Ici!lang ~pec:f:ffi
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O'..l.;,n,.:: \I"3Im!.'!)1
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Itl(; ~a\:d Hl ca~e
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ve'l 1f1 a [a:'"!>!.;as':
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'1'::~!~!, -:J~J'~~~~~1
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19 In [ormatIOn
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__ .d;,.te) __
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109 lOr -\6 houa
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this product label
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.)n ((lod or forage
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l" ~DirlX{inns (or
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.yl parathion ttH.)'
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ct. mhalation or
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Of under ..... ('athl'r
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reas 1"101 Jnlended
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protC'-Cte-d humans
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;lnd other ...... Jdhle
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",liN. Keep nut of
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. Shrimp .md crab
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Ibis lahel, Do flot
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apply '~'here fun
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er condltlor,$ favor
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;.er by deamrlg of
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t only as specified
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.::IirKt treatment or
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obtaine4 (rom )'OUf
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ARO
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heat or name.
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\
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RESTRICTED USE PESTICIDE
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For retail sa.le to and use only by Certified Applicators or persons und(>T their direct supeTvision, and only tor those
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uses covered by the Certiried Applicator's certiflcation.
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®
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\
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NET CONTENTS ______ GALLONS
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ALeo
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B R A N
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METHYL PARATHION
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EMULSIFIABLE NO. 4
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D
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(CONTAINS 4 LBS. METHYL PARATHION PER GALLON)
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ACTIVE INGREDIENTS: BY WEIGHT
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O,O-dimethy! O-p-nitrophenyl
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Related Compounds
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Thiophosphate' 13.22·-~
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Aromatic Petroleum Solvent
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I:-<ERT INGREDIENTS:
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TOTAL.
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'Methyl Parathion
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2.27%
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-18.26%
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6.25:0
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100.00%
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DANGER: BEFORE USING, READ THIS LABEL
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CAREFULLY
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~ POISON
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DANGER
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KEEP OUT OF REACH OF CHILDRSN
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SEE OTHER WARNINGS ON LEFT PANEL
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Manufactured By
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VALLEY CHEMICAL COMPAft'V
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GREENVILLE P. O. BOX 1317 MISSISSIPJ-.
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/
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I
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/
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/
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/
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(
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DANGER - POISON - PRECAunONS
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NOT FOR HOME USE
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r·~I~(t~
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_~Jl'P.i"'~'U'_
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.. ~ -.,. "'" ... ..,. ~ ---..... -~-... --. "' ..
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-- ........... 1 • ...-
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..Wt..MJ._et~'!I_~!...,,'1.
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.... .-...." .... ,.,. ....... -............. _ .. ,." ••• -0,..
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---_ .... ,-..... ........
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--,-
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... :ft~~~ • ... .. -....... -
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~ PQlSOK SIGHS (SymptomJ)
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~!ethyl ~arathion i5 a very danierous poison. It rapid!>" colen the
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budy Oil contact with aU ,kin sw-faces and ey~. Clothing wet v. lib
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this materia! mW;t be remO\'ed immediately. Exposed persons must re
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ceive prompt medical treatment or they may die.
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Some 01 the signs and .yrnptoms of po[~oning art headaches, nausea,
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\·omlt~ng. cramp$. \l.uknes:s, blurred vision, pin_point pupils, tightness
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In chest. labore..i bredthing, nef'''ousness. sweating, watering (If eyes,
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droohng or froll-ung of mouth and m:·se. muscle spasms and CQma.
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POISON
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ATROi>lNE IS AN ANTIDOTE.
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CONSULT PHYSICIAN FOR
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EMERGENCY SUPPLY.
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CALL A PHYSIClAS AT ONCE IN ALL CASES OF SUSPECTED
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~tETH\'L PAR.A.THlO:-i POISONING
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If symJltoms or signs of poisoning include blurted vision. abdominal
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cramps. and ngntn<:ss in the chest, do not \I.·<lit for a doctor but gi\'~
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t ..... o atropine t~blets :;each 11100 gnin of 0.65 milligrams) at once
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,r)n" tablet :0 ch!icren under {iv(o years of aie.)
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+ FIRST AID TREATMENT +
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STATEMENT OF PRACTICAL TREATMENT
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(",d a doctor (ph)".'idaQ), dmic or hospital immediately. ExplaiQ
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';,,..t the victim has toeen exposed to me:hyl parathion and de~rilx
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:r .. ~ ;::nndition. If doc\N cannot corne. takc \'Ictlm to clinic or hospital.
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~!.,~ e patient irnn·,crl.ately (rom the area where methyl parathIOn is
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'W-H'nt.
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!F '-~:;HALED. rem·}~·c \1ctim to fresh air. U not breathing immel-Ii·
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~t,,:)· gh'e ar~ifJ(~:'! respiration. prde:3bly mouth· to· mouth. and
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InZl:ttain UntIl d·Xl')r sees nctim. If breathmg IS dlfflcl.!ll. gwe
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o~:;g(;n.
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IF l~ EYES Ok OX SKJ:ol, immediately flush with plenty of water
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for ilt least U minutts while remol'i:!! contaminated personal
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dCllting and sh(,e~ to avoid continued p?sslble e)tposure W \'ictim
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or- persor.s in attendance.
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• F SWALLOWED .• r,duct vomiting immediiltel)' by giving two glasses
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of ,.,tater and by touching back of throat ... .ith finger. DO MOT IN
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D1jCE VOMITIXG OR GIVE ANYTHING lJY MOUTH TO AN
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i:!'{CONSCIOUS PERSON. Han \'ic(jm lie down and k~~p quiet.
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HOTE TO PHYSICIAN
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Ail.!;j'ole - adrnin1!ler atropine sulfate in lafjte doses. TWO to FOUR
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m.: ir..t~&\·enously or intramuscularly as 500n as ~yanosis i! over·
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-:<;1' t'". H--peat at 5 to 10 minute intervals unl:1 signs of atropinization
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.lp~""1or 2·PAM chlOride Is a pharmacolog.c antidote and may be ad·
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m.I·''itued as an ad)J..:nd to, but not a subs·lltute fOr. atropine which
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is .1 symptomatic ami often Hle·sa\,ing ao"ltidote. DO SOT GIVE
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MORPHINE OR TRANQUILIZERS 8ECACSE THESE AXTIDOTES
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~tA Y PRODUCE ADVERSE EFFECTS ACCENTUATING THE
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PH.\RMACOLOcaC EFFECT OF THIS PRODUCT. ThiS product is
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, ~~r~"g cholinesterase inhibitor affecting the central and I*ripheraJ
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r .. _:,o'-lS ~ystems and producing cardiac: and respiratory depression.
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.'t {'r:;.: !ign of pulmo)nary edema. the patient should be gl\'en s\,!p
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P:"'r~'\tal o,;ygen a~·1 treated sympl,(,matically_ Conhnued absorb.
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~iOn "If tre poi..$on,!:1ay OCfur and fa~"l ~":~~es hiV"beil\ leportt<:
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aft<-l \fl,tial imprr, emef\l:~ .• "ERY CL,')SE :tCPERVI~ION.OF THE
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P;'T!';~T IS IND1(l,,-1TJ) rOR AT t.EA'iT .8 HOllRS .•
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$.vQHK S~FrtY RiILFS' •• ••
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REP£..'\ n:LI :EXPOS:'RF.8 TO Ct-IoLINisT[RAS~ lNtlIBITORS
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S1jCH .... 5 ARE CO=--':'AIN:f.D IN THIS PRODUCT MAY. WITHOUT
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WAlenSG, CAt:SE PROLONGED SUSCEPTIBILITY TO VERY
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SMALL D.)SES 0: A).Y·:;HOL:NEST!fMSE nann:\'OR
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• ( • '. f I
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Penura workin, wi~h ti1..9. prot .... :t Lhot..f.":'~avl" t;cqu~'" blood. t~t.!J
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.~f ~hfir cboUnt:ste!"~e t:e\"lis.j If '.he ch.Jlif.~tl.ulce le~t1- falb below
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:: clllie-a; po!nl, no lurfile! d~}<U"~ st,".Jll,t & 4;1ol".t1 until it hilS
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'~n d~term:ned h)' mead.! uf b.u\)d t«t.s lhat th~ .:hOIlc.~terase le ... el
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h ... • returl'<:'d to non11l1. Ref¢re using this product consult tbe Stat~
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Ap-iculturf' Exteruion Service or ~puiInental StOltion for s~ific
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ue:ommendations fegudin, liueh blood tesu.
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It handled indooCl, provide mechanical e)thaust \-entilation.
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Keep all unprotected persoru and animals a""'<I), trom tr(!ated area or
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.... ·here there is da.nger o( drilt.
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Do not rub ~yes or mouth with hands It you feel ~ick in any way
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STOP work <lnd ret help rirM a ..... a)·. See Fint Aid (Practkal Ireat·
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ment) section.
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USE ONLY WliEN WEARING T'HE FOLtOWlSG
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PROTECTIVE EQUIPMENT AND CLOTHING
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(I) Wear water·proof pOlnts. coil, hat. rubber bo<lu or rubber over
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shoes. (2) Wear ~afety goggl(!s (3) Wear a pesticid;} respirator jointly
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appro\'ed by the Mining [nfr)r(":ement and Safety Administration
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.formerI)· the U.S. Buruu of Mines) and the !{ational Institute for
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(kcupational Safety and Health under the provisions of 30 CFR part
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11 (4) Wear heavy duty nOltural rubber gloves.
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I~LPORTA!ow." Befofe temO\·lOg gloves. \u~h them With soap and
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water. AI ....... j"s wash hands, lace and arms ..... Ith soap and water be·
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lore smoking. ealing or drinking
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AFTER WORK take aU all work clothes and shoes. Shower using
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soap and water. Wear only dean cloth('S ..... }:(!n lea\'lng the job. Do
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not wear contaminated clothing. ""ash protectIVe clothing and pro~
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teclwe equipment with soap and waler a(ter ea(:h use. Respirator
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should be cle3.nfd and hlter replaced aCCOtdmg to Instructions Includ~
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ed wllh re:plrator.
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RtENTRY STATEMENT
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Do not apply this product In such a mannt'r as to directly or through
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dnft e)tpose .... ·orkers or other persons. The area being treated must
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be \·acated by unprotected persOns.
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D:I n()t enter treatcd areas (or 46 hours unless appropriate prot('('ti\·e
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clothing is wotn.
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8(,(,aUse certain states may rt""..(uire more restricth'{' reentry interl'als
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for \'arious crops treated with this product. consult )'our Slate De~
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partrnent of Agriculture for further information.
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Written or oral warnings must be gh'en to workers who an~ expected
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to be in a treated area or in an area about to bt' treated ",:Uh Ihis
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product_
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ORAL WARXIXGS shall inform workers of areas or fields that may
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not be entered. wiihout protective equiptnent and clothing specified
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On thIS label. during treatment or for 48 hours following treatm(!nt.
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Follow First AId Treatment instructions shown on this lab(!1 in case
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of acc~dcntal (!xosure
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Whell oral ..... arnmgs are gi\·en. warnmgs shall be gwen In a language
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cu,;tomarlly unaerstood by ..... orkers Oral warnmgs must te gwen If
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there I! reJson to behe"e ~hat .... ·ritten ..... arnings cannot be understood
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by ~HHk~rs.
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WRITTE:-4 WAR!'OIXGS must include the foJ!lowmg information
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DAXGER-Art'a tr{'ated ... ·ith ~tethyl parathion on __ (dale) __
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00 nOl enter ..... lthout appropriate protecti\·e dothing for 48 hours
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Follow First Ai<l Trealrr.ent Instructions shown on this prOduct label
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In case of accidental exposure .
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ATTENTIOH
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To avoid e)tces--h'e residuei of methyl parathion on food or forage
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crops always obsen·e the statements f{lund under ~Diree:tions for
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t:~e." limiting the time before han'est when methyl parathion may
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be applied
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Because this material is poisonous by $kin contact. inhalation Qr
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swaIJ'l ..... ing il should not be used in such a manner or under weather
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conoiillons as will permit dnft of thE' £pray onto areas not intended
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t ... be sprayed.
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Do not apply (.;r aUow drift to areas occupied by Unprotected humans
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or beneficl,ll animals.
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ENVIRONMENTAL HAZARD
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This product IS toxic to fiSh, shrimp. crab. birds, ;lnd other ..... ildlife.
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Birds and other wlldllfe in treat.ed area$ may be killed. Keep out of
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lakes. streams. ponds. tidal marshes and e-stuaries. Shrimp and crab
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may be killed at application rates rC'Cornmendt'd On this label. Do not
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apply where these are important resources. Do nl' -·· ... Iy ..... here run.
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oU is likely to occur. Do not apply when weal . ~""Iditions favor
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drift from areas treated. Do not contaminate wilter by cleaning of
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equipment Or disposal or wastes. Apply this prodUct onl)' as specified.
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on this label.
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This product is highly toxic to bees expo!ed to dire<:t treatment or
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residUe! on crops. Prote-ctive informatiOQ may be obtained from your
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Coot>erative Agricl.lUural Extension Se ... ·ic~.
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PHYSICAL on CHEMICAL HAZARD
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Combustible: Do not we, POt "pill or store nUr heat or Game.
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In case of
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FIRE. USt wat~r spray. ~ . dry chemical or CO ...
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<
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~
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/
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I
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I
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SPILL or LE.AK keep ;1) unprotected penonS a ..... a)·. Cover with
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.bwr~nt such as soda ash. lime, da)" or Slt....- dust. Sweep up and
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bw),. Wash area thorouehly .... ·itt. s\t'1.>ni lye solution..
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STORACE AND DISPOSAL
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Do not contllmjn:;;t~ ..... a.t~r. food. or feed by ,Iorage or disposal
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STORAGE AND HAh"ULlNG:
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I. HUldIe container cU~fun)· so a$ to altoid damtge Vld prevent
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luka,t.
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2. Do not me or store In or around Ole horne.
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3. Store «mlainer iii a well ventilated place.
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4. Empty ('(Illtainer retams \, .. por and tm:)(Juct residue Observe .u
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'.bel s.afeguards until container is <:leaned, .rf'C'Onditioned or destroyed.
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S. Keep Ollt t)f rea~h of children and dOm~tk animals.
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DtSPOSAL:
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Wules of this pesticide are ilcutely hazardoU$. Improper disposal oj
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UC'4$ peSticide. ~pray mixtures, or rinsate IS iii "'IQialion of federal
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I.,,, ... If these ~'a~I['$ cannot be dBposed of aC«lrdmg to label U$e in~
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strUttlOns, contact your state pestlcldt' or £n'I:ironmen\a\ Cl)n\ro\
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Alency, or the Hazardous Waste Repre~entatwe at the ne~re.st EPA
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Rellonal Office for guidance.
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!~3:Ie...!~~;~ ';he~tYofi~~tf~~e:ec~:\~" ~:r c:~~~I~~~n s~t~~\on un~!~~~
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to prevent other u~e 3nd dispOse of in an appro,,·t<:I 1andflfl. or by
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other proc:~ure~ appfo ... ed b~' state and 1000ai 3uthorilie$.
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DIRECTiONS FOR ust
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It i$ • \'lo)a1l0n oJ Ff'deral Law \0 use thl~ pTodu1::1 in any manner
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incooslstel:;{ with It, Itbehng.
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Be !lure 1O read the precautionilry statements befor(' using~
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Thb product i50 de5igoed for apphcatllm after dilution wllh water
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and lor use by tramed operators uSing .llrplanc or power ground
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equlpmen\, The h~lard< and prec'lulions tor handling Ih'" product in
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thIS ~n13mer aTe equally apphcable to It after dilulion with ..... ater
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for spray applicatlc.n Add the concentrate 10 the spray tank while
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fjlline with ..... ater and mix thoroughly either b~' means of a tank
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agitator or pump by~pass_ For best resuhs_ thoroughly ct)'l:U aU sur~
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facts to be treated ..... ith spray. Rat("l: of applicatIOn gwen belov.·
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should not be exceeded Ne"'er apply later than ihdicated 10 assure
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r~sidul' )I;'\'eh at har .. e~\ ar~ bl!to ..... tolerances establ:shed b)' the Food
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lind Drug Administration.
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FOR CoNTROL OF:-Boll Wee'l:il. Thrips. Cotton Aphid, F1ea Hop
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pers. Lygu'5 Bug~, TarnISh Plant Bugs ahd Stlhk Bugs on rlee
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MIXING: - Add the amount o! "aleu Bran~ MNh,,1 Paral~l.IQr. Em.
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Ulsl'la.ble 1'0_ 4 rec::llnmended for thf' control o! each insect te> the
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water n(ct'ssary to treat one aCH'_ MIlo; thoroughl~ belore d-pplYlng
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If soluuon IS allo ..... ed t~ statld se\'eral hours. agitate well before uSing.
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USt: ON COTTON: _ Use Valea Brand MetJwl Pa~athion Ernuls.h.
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able ~o 4 at the rates reC'(lJr.mended belo ..... f'Or putiCUlar insect to'
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be controlled. This product should be ll$ed on 3 to $ day inten·als.
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or as nrtessary to keep insect under eontrol. The rate and inter"'al
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of application will depend Ilpon the size of co\\on. degre-e of \Mecl
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infe$l.ation ...... eather. and method of application Proper tuning ttnd
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uniform application ttre essential for best resull.5_ Methyl parathion
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hJ..$. to rapid action 01'\ ins~. but a short residual to:<:I(,l1y Frequent
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ap);)lications are often necessary Make no application within IS days
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of haf\,'eH or pasturing.
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TliRlPS: - Appl)' at Tilte of one {1} g~"or, p,er 20 ~c~.
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BOLL WEEVIL ANb COTTON VHID; - Apply at rate o( one (II
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(aUon poE'r 8 to 16 ,u;:rE'"S_ ,
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f"L.EAHOPPER. LYGUC BOGS AND TARNISHED PUNT BUGS:
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Apply at rate of one (I) galon per 16 to 26 acres.
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SOYBEANS: - For conlfol of BoUWorffiS apply a\ ute 01 one {U
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,_Uon per 4 acre-s ?ot;:.ke no applicatIOns withm 20 d'n,·s of harvest
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Do. not appl}' more lhan twice ~r growing season.
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RICE: _ For control o( slink bugs ap);)ly at rate of one (I) gallon per
|
||
liS acr~s Make no application Within J5 days of han:est.
|
||
WHEN MAKiNG APPLICATION'S WITH AIRPLANES: - Follow
|
||
the- $Ame Apphcation Program given for ground spraye~. applying
|
||
one (1) eallon per 16 acres, in I to 3 gallons spray mix per acre.
|
||
MOTICl: TO USERS:
|
||
Selkr Vo'arrants that the product conforms to its chemical description
|
||
and is reasonably fit for the purpose staled on the label ... ·hen u.:.td,
|
||
In accordance .... ·ith directions W1der normal conditions of use but
|
||
~ith~r this warranty nor any (lther warranty of merchantability or
|
||
fitness for I particular purpose, txrress or implitd, extends to th~
|
||
UIIe 01 thili product conbaT)' \0 labe instructions, or under abnormal
|
||
eonditioru, or under condilions not reasonably forst-elilble to leUn.
|
||
IJ\d bUyer ~umes !.he rltk of .,. ... luch use.
|
||
S'Re-c. Trldemark (It V ALLE.~ ThtlCAL COMPANY
|
||
I-P.A. Re,. No. 1063·10. ~ EPA Ed. lDe.3~MS.1
|
||
|
||
StJPPL£M£NTAL LABI:L1NG
|
||
METHYL PARATHION f;MULSlFiABL£ NO .•
|
||
For States 01 Mississippi and Arkansas
|
||
sL:-i No. MS·8!O028 SLN No. AR·815533
|
||
For use on small grain; Bade}", Whc-at and Oats. apply 1I'l to 2 1/2 pts ;:X-J" s,:-re
|
||
for control of aphids ond army\\"orms. Us€' higher rates {or armyworm controi. DO
|
||
NOT apply within 15 days of harvest. B~t rf'Sults u·m be vbt..ained when daytime
|
||
tempcralur~~ are in Ute 70·s. Rt'fer to label on conta.iner (or mixing ir.:..t! oJ.:.-tivns
|
||
and safely informdtion. This labeling must be in the possession of the user at t}-,(> -;.;me of appHcation.
|
||
It is a violation of Federal lav: to use this product iI) a m.JflJlcr inconSlstant with
|
||
its laVcling.
|
||
METHYL PARATHION MIXTURE,
|
||
LIQUID, POISON 8, NA .. 2783, RQ
|
||
ACe E P 'l'-E D~
|
||
, , ..
|
||
i
|
||
\
|
||
1 -.
|
||
I I
|