justin
a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
343 lines
15 KiB
Markdown
343 lines
15 KiB
Markdown
# VALENT WEED KILLER "D"
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- EPA Reg No: **10182-377**
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- Registrant: SYNGENTA CROP PROTECTION
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- Signal word: Warning
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- Active ingredients: Diquat dibromide (4.35%)
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- Label accepted: 1982-05-17
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000239-02279-19820517.pdf
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---
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PRECAUTIONARY STATEMENTS
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HAZARDS TO HUMAN~ & DOMESTIC ANIMALS
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WARNING
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Md~ lot' 4"_,,, " ".4':" .. tl:': .'''."ell "I ~bsortltG 1t·'U .. ~·l sa. '" ,. '1
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(un'."! JiI" (au~ \t,tl, ",:j"'J": Soc oot atl I"'~:tr a "~ !>~.n .. .,t ..
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or (,o!!,:,r,,.: Conti! .. ,. ~~ ~ !'T,j~ ,"',pa'>e daniel ()t atls.orp~ ..
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S.,."T'p!orn .. 0' ,r" ... ,.., ""<1, l!~ (jt,~,td ilt.! fjd~ \'": p'1 ;uMd' 2',)01'\
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dnd !Jbber 4iprl. , 11\"' en ~dn;jll~.i: r",nctnln't u<J nd t;!tJlhe \,",a
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,.,-:,,!>' n :Ir~"-"' to h .J nH4' l"rOd! and It~p'ra'iH., 'U"' .'I,Iill ("n
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'II.~n Si,·,~,n~,· fIIt-ero wnf,nltn. ~;l'J)td __ f'f:I",', " ... tl .""1 !IOl',ty
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~f'* ~' r, 'I oil'" ... !~trpIOO! "Xl,,,,,,., ,.-,j ((.~ to,,'
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STATEMENT OF PRACTICAL TREATMENT
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If "lIiIi':m"f>t:l I"WEDIATlLY CAU A DOC10R I' [(jr'\l'I.I<.~ .. ,.t , J'ir
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.1-- ,j'1' ".'~f" "J 1:!I,nll, .~,i" ,." ;-';") ,r'", I~' .~ .. Jf ~ •. n,'"
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'1' ....... " .m ..... t'u."· .. 'y "" , .... "',,: ... remJ.t ,.·,;:rllnf. ,,: 1 .. .t .. " ~~ r,
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....... >! fit' ,.~~, • ., fur t~1'"> .H/I ,'"'OfOl,;i"', ... ''") ... "It l JilJ St'l
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"Qlt 10 PhY\.I(lans.' I 'I'~il'n 1 ;r.f~)' "'~ ,n (d, ,41~j /jj j/jl
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ENVIRONMENTAL HAZARDS
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Or, 1'101 tl;JOi, tI'f~"" 'e ".If" t l. ep. <I); !> ,1'(11.. j vM t~.!> I<ltt
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:..0 I.~'· ,,5It' 'Itd!ed "';lle: 'JI ,j!'WT",J 'O'1~.J"7".DI'c' !..,f'"'TI n~ <;'.1, r.;.
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0' '"'' JI.(\1' .... :,,'1'1 ;4 dd.S ,tlk! Irt~~rntn' [lr, ~.'.~ lose ',ulec "a!~' I'll
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d',1l1o Pill p~"l<J'lot'!o .J":" 14 d .. ,') ,I'cr 1It'.3I ..... , .. n: T't>,!T.tr.t ot etnst
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""1:'0 JfeJ" ',In f~\,Jll·n ~I.,":>:"'ll( .• 'lo 110'TI Ct";.()'T"'j)O'>·I,un (.1 Ot'JO "eed')
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T~I~ '0 .. \ (,,1'1 (.1\..,Y '1 .. 11 SJflr'-,'iI,,)!'O T ..... 'u'e :rl'JI onl, I) Iv '. ot
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°f't ~~. ~ ...... ~c ,1'''1\ al. t.:-- .. an.1 ... ·' 14 d., .. btllllr .. "n f'r~:men!~
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DO "LT APPI' ltJ -"UOO'f "All R A.o.O crtill,ng rTl.'"'~; .... ·~r ( . ~i
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dP~I,C-'llon 00 ni" a~~, ,"dtr cor.a,tlor1 (I t '1''1 .. ~.~ a'1rl .".e a'
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:,on Uo f101 oJpp', ... !1tre r In'') art co.tr"d •. '~ IT ~1 ·~fI<;Jo".a Cons .. 1
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~' .. :..' ::,td~t i ,VI .nl! G3me A.tmlts bt10re .ppt"r'g th'" proC,jel to
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t:'~'j Ie .':~i'f\
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DlRfCIIONS FOR Us{
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iI .. ~t'f'1 1",1" ~ .. t(l~e:.l"'1l
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!IUD ENIIRE LABEl. US{ SIP'ICIlY IN ACCOR~A'CI
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CAUTlONAkY STAHMENIS AND OIRlCIION>. AND \'IIIH
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STATE AND F[D(RAl Rf'ULATIONS
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STORAGE AND DISPOSAL
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PROHIBITIONS
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'" 01 ec,.·. • (,;,,'1 :
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,,' 0' '''''..!. tr~~· 6,.~ .1 " \,
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'f! .. '" >"t::~.!
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STORAGE
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"1'.;, ~~ ... J .. 1 (" ji! ".,1 t(n!'·~t·
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,n!') ". c [,! j- "~ "J "".\ {l(' ~
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'f':l~,r~ ... "',, LY, flu! <;!O't ::t' "J' ';'"
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It '1;,~ . .,'1. "\ .1~'C.t 1.
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P[STICIDE DISPOSAL
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. -~.: "-" .
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WITH PR£
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APPli~
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"
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> .'. J .
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,.
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,o'... ,.~!.# .. ~ " l~ill (~'ll'll' :c; "'.! ~, . 1
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• ~~ r L ,' :.' :~~o.,.~ _f 1 (..
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It .:0-' ,
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CONTAINER DISPOSAL
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Of D~OlL'~ ,"1 ,,:~, ., (,1 I" I ~I" ~ !',
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sU'" lnd '0(.,· ;"(.t'~ .• $
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"II ';1 T jrl,n,.::
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"' ~, ot"t( .~~D''l.f'd
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ONlhl' " .. ".~ ~ ,,' f' .. " 'lC' .' l~ ~ "'f :. ,Id. ~ht'Tl'LJ ft.e· "1'it:1~t'':
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'or .. \~ n J ~ .. n.·11 ... , J • ·t' d~::: n an aC~6' c .... t'd ~ " A-
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IOI'pl".;n ~::J ht,~., Jj. ~('I' - .. ~L' ~ ';. It '~~. ,I ..... " .... '. , '. J·t
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In. , .. " (",'" Il n .. ;> <1': \tl'., t'!<_,j,.. ... {"11 Ip,.r "i" , .... ",j'tt .'!t' o.I"~
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AVU':' 1'''1 ..... ·~,III I~ ,o;'~ ... • ," --l, ut CJ"'d~t"d d:..~.ri lDD'" J',o"
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Do no: ,,' II'~ \~,I! 'JM'~ o''',f'' !~.n (lllfl-l'J IiI ·,prt.Of" ,l'I()n ')rhr
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1\ I~.. • " ,I f ·O:;~dl .... 4W :-Of' "1~. f'd
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DIO[CTlONS
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NO .. CROP' OR ,,-0" PLJ,'HID ARt ~ R,&MS 01 WI" IM.ud.na. R.·lf~.d$
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H"IIM." Ro.ds, Dn,J;Jer, .,,4 Mrd.,", Plpt:llnn. Pl,lbh( Utility L I~S,
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IIK..Iwd1nl PU"'~f'Ii S!.hof'l$ T"n,t"".." St.tte." Ind Sllbt.uh~"\
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Arw,.d (.t'(:TI( Ul ... !'t'. to,,·Mew.J BUlld,nili. W."ul.ctLl1IMi P14 ,!..t.
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SI .... K. h,d, R.II h,d, hl'l,t liMn .nd .. ., ..... " Id.:" Ind No"
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fl~d ~"1.ol'l$ lit "of'ld$ l",n Inti Orl:hn ',10 A.aund O,n.,lItnh'
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''''''''$ 'IIu .... 'S. P.IIO' Itnultl Grt'tnhauM Btln(ht'\. AUilnj/ On"
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... " .00 I.flHlnd ,"till Co",rw, To ". U.,dnll.bl. Abo., "l)Und 'flU
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.I'I1II "u~, •• 1 ..... '4 ,,_u, - ." ;. ~\ .., 'v 1', 'f 1)11· .. ·
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I" . "''1" Pt" \.10. ¥d~ "'d' .. , ,',', G' ,,~'H" "' ... 1
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.... '_~ """,0(1"~ ;";1-11'1" r""~'" '0~
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~l III",,· l.,p, t., ""41- t",j ...... , . .:~ .I'''~ ,,"',' .... I
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"'_ *,,~, ,.,." \,,,-' .... H .. ' " ...... ", .... ' ...... ··'4· ..... n·
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DRTHO
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Weed
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Killer "D"
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(HERBICIDE)
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Act .... I,'grpd"e'" Ih 'Nt
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D'Q"'o: d,bror' .at' ',7 (1 h ''::- _J.~, .... J . ..) J 2 ~~ 2.1 .. '
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9565"
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o~'::J1Jib . -'
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~t .....
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HEr' OUT Of ~lACH OF CHILDRtN
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WARNING
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fOW AliRI(.UUURAl US,1 ONL l uR tOit SAl[ TO, U~ AltO STOR ... Ct
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By SIR"cr PIRSON; 0101' DO 1101 SIORI. IN AO[AS ACCcSSlllI
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10 CHILDRIN
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SEE SIDE PANEL FOR ADDITIONAL
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PRECAUTIONARY STATEMENTS
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.,' . 'r ' '.
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Chevron Chemical Companl'
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'~'. "'Ii:'
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~ ')4" '" ,,1'-
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, . ~'J~j' l':M~
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NET CONTENTS
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- ---
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1
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--
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, • . "d o;',~.~ \"rd ... r"~~ ... e:j ~;ri!~
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1'\011 Ot r,":[H~r, oJ ",.",''',' .','.'." , ) ~ (I l.'rl.rnentJI Vl, .. ,,~\
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rt>r't'. T 1iII111'I !Ol'~;'> "."
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_TIC U.S[to~~~f,t1~OHD~rlC\ :~h'\ Jr~ l!ljll'1.lr,t' ct,_~~, ... c,~ ~"I:~e til' apt'''~ , " I! ptit " 1'0 :; .. ~1,()"" ,., lI'I~h" Jill! ,,' 'L. ' Jlt! lo'.j:'y ullu!"1 It-t lUn,,<l:
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"I,'", ;:rOOll-' \ user tI,) n,)! \,'>.t '~t !,,, .. It'd '!IIJfer 'uf In,m,, 'r~, ",
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' . .-.r ~1Io.1'" ~I wrj~I/l': '1,,,~"U'l c dr,l""f\T.l ~v P05el I. 14 CJ,\
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':'f' ~rf;'T'f" Do nol .Hlp ~ :u ~'l"'.:;". \,tll:~ ,n I,.' .~~ ,
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WElD sr£CIES COAlS., SURFA({ ACRE
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SltlM{RS£D WHO$. 11,,1.:)\,;, .. :.:t,,' Pona!. lallt') O.Td1tS or pottlon~
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TIIt!fl,l)
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lladUtwOll (tJtrtculirla $PP )
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Coonull (Ctritophyilum demelS,um)
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Elodei (ftod .. spp)
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N~'" ("'iu ",p.)
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10 :0
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~O
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20
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10
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:0 Pondllfttd1; (PoUmOi,~lon s.pp ). . .
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e[Icept P. robbl"$II, .110 ~hch'fdson pond_eed ,I'. nchardsonl1} In
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tllnntsclit
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W,',," I:", (M,'<oP,,::um .pp ) ID :0
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IIfllCAtlON: In ear:! :s.tason 'Ill' f'fe SJ~rqefS~j .... ttd g'Olll'" hd~ flO!
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ruched the 5I.I,f.ce apply OklHO I\'ff'd KH:er IJ bv pOI.Ht"K a"I',: 'i
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heM the cont"ne. Inlo I~e \lillie! ",hilt fT10y,nt; So ,,)I""J O_'~I t~e ",~'tr
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$IIrtl:e ,ft • boit. Dls!rlbute t'ienly ovtr Intes'eel -ileas ,n slnps 40 leet
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JP'rt In mu.ed Wlttd populations.. LI~ the hli~ "It JI app.lwt1on ;'$
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WJ"CI~ed by ~s pIner'll
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'n 1~le SUSAn 01 _here Ulbrr.erstd ... tej gr" .. th ras readIed I~e '#rIdter
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.,rt~e II'HO ... ihOLt Ihe Zle. to be treatel1 :ipply ORTHO 'hteo I\"ier
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1)" by touttni n above Of mj«~lng belo" the WIater syria,! In striPS
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110 mUlf th,n 2'0 leet ap~lt U~ the tHgn ,ate of app~,cahon as ind cated
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tI, f!'le IIffds present Vehtre aliae lie preSt,!1 11('Oni, \IIIrlh the sub
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_,sed .e~s. prt trutmtl,t lIiIIilh Co;;pe! Suipha~e at recommended
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utes I~ adYI~"d ,(,1 bts. reSuUs ".Ih OHTHO "-etd K,lie, . [)
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FlOATlIK WUDS
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Pt!\flP"Clf1 (HydI(K.oty:~ umb~datl) 5· 7' :
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51"'1:"111 (SlIVi!'ll~ f'OhJnClfohl) . 57:/1
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Wal,rhYklnlh ([,tl-.ht~"i ... cri!l$,$ipes) 5·7 1,i
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W.ttfltt t -:ct (pJ~t,a $~ra!l:llel) , 5· 7',1
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II'rtJeAllON: 150 to 200 Ilal,or'\ 01 ",a!tt pluS. 1 pi QRIHI) X 71 Spleadt:l
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(non tOn.c) should t:.e apr:.ed lS.'In owe:.! 15:;1',,) for control 01 the .bo .. e
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....
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The hlih j4tes at QHTHO -'leed kilief . 0 Should bt us.td 101 latt
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:llUton lD:PhCd!)on
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Ouckw'!tt! (l\:mn, ~) 10
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APft.t(.AHON: }Ol ron'ro! dj;lpl, ,]~!HO .... ttd "Iller D' 15. '" :)~{>I
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'il ~yl4j !'"I ~ te, 1~ ;~is. of ".,ttr ::.e' ICre Care $ho').C1 Le !'''en
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to tt.O(Qllli:~' 1 lO~e( '11 P:ll'lts r,t) ""dt.:f nd on dlmp m'lgIIH~1 'fe~s
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Rflntntu,ot\ (If d .. ( .... ~.:1 0':(:';15 read,:, Hom untrelted 'f~aS Relleal
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,,",fl! '" l" O/i/!HO We-ed 1I,':!er "0' mJ, t.e ne 1?\5"j:) '0 OtJ~ 'In ~~d~ ,f'
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i;,.r:1 Cl)r;~,-:"
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WUD sr£CIES W,$.!100 W,$. WAIER
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MtlKUW, WUDS \lnle')lIr.i ~I-.e Edges and ~her Panlors of PondS.
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lu~~ ~nCl D,I~'1tSI
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C!n,h! (if:;t~a spp) 10
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U'UCAlIUN: .01 TOP kill '~;.J', QR1HO ..... t' .. d KI"t' [J ·n h(l
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.41;:' ".1'1 p'IlS J PI ORfHO. , , ')pre.:l,ter {nOi1 IOniC) f(or t..:1 co_er."e
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.nc trOI(;,:~r. "',ed ·,·"0 ~!'iH",,1 ~'tr:!-nt'd .', :" e'>' .. ,H) ~o ,or~'o' Ir
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ifU.;'1 tor be!.! (t~iJ' ~ J;.;J', t·I/O:':' f'O"tlifll!.
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AlW. !'WIHO 11 .... ,j Io,,~: tr lfII"j, ",' , Cf"d r t, ~""r:'!(1 ') ".t'
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5;>I't(,') !.;J~l aft(! P,I!'Io,t'.Ofl "PP' App!y G ~ IJ I ~ 'l ~ 'T' IiIrI 0;"1 ri"
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1J't' .... ; 1', ,f" ~) tor ui"f'O Apr (4',ln m.'~"C· ·~:,IT'!!,y1
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-F.,.II J\H' PMts 'If M"'t.v.. (PP .. , R.toihfPfndol~nS
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G!t·~ ', .. ')t P u IT! ·t c·mm!!~.~rd • Jrre,gr C" ",~lo:~ I .• ' .... r.l/.t Jr'c'~
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01 •• !t I l'
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fOt uam,,:e- _1] "p m recom'T'ef1d.J:,on~ '''''" JU!! pond , t~!"
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htra~fL t'.e.., •• ~ 11 l '! I ~ I 14 '.t.; i" II'. t'
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Dt ""I ~pfy unQer ~J"t..t"',l' 1"'IOhlln, PG",.blt dntt to food. fonlt e
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.. "llMf r1antlnas tu' ., .... be d.,uetd Of tM ""PI therHf ,,'.defed
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Wlflt ,\,., ~.,'. "If Of (Onsu..-pt""'.
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COMOtt'Mrts Of Wl 1 Che .... 'on C"r~.lal Wmp6n., Ibr .. !"nl "Jf/,,:1~S
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that th,s 1T'.,',e'Ial CO"!L),.T1~ 10 the chr"'IILdl dty I,p! .I!l on I"t u:,.,,1 4nt!
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i$ IU'OnltJ) lit lor LlV d'> Cl,r,!,;ltd t ",rf)" C, t, e, f"'~ ~~,., '''151 M'
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IV!I\O"<~~ ~.'~ .J';~~~ G( (.; f·'~r.' ~h ... t 10 n.ll~ .tn, v .... ' "H~ldl"llJ' 01
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FIT'l)\ o· of M(H(l-'t','tt"lIT) f:1J~'JII~et 0' ·t",fflv.nl.J!un el;:'l'~~~
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o· 'I'rIPI~ (""[I"n,o. thiS IT'j,PrI.t
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'1 C1. I:jl and .. n! )Irwt'ble t~, ~or\ ~~,:)"d ('I'r.'f)(' ~ ".,troi pr .. ,t- r !
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II fro ... l ,:1" ".t,!'!,; aB fl~~5 1ft rof'''f' '. "'I ,,~'I \' e I..~ r:f ("'p.,!; . .t"
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SIIC'" .,.~~ 1.C"Udt ·JiJ···, ~ n{' 11~1 ~.,j ') ~JI""~" l(j "-,,,'S .t1'l<1 nn;J~
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to .t'],.'1 :,e m.ttr,.1 I) iI .. ~ ,ed ":. 01 (U~p· .. tt 1.',I"'!lol olrd :].' .... he
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~'uW'd I)" dr,ft to :.l~I'1 .. p'a '. r.;-, ""\"~ ' ..... J' t,p'l 'l'1c ui"
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UW! pfOol:'~c! IS rfuon".,,~ I" t, ~"c ,~~ \','I';j ~""'J.' jn::l evtn ~ .. , .. &'1
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!,btl d ·t'.t'(ln" .'~ tCJ O"t'C i', ~f! "r.! ~Y" ,'· .. ·~'1fII t'~,·.~ "r.' ''>~.J'''~
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.:1 1'111.\ .!'lc! db, 'h (fl' O>;J' f" V , ... \_~'r'\~ ~ i C ..... ·:'· ".1fl I !~('~t'
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r' .... ':"'1i h .. "'1 ".nd ,r-a !o:t'I.~t' 1"d .,5' o~ .~ > r'"l1',. ,<1
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1
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•
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I
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I
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-•. __ .="'4.",_" ------
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DRIHO
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Weed
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Killer "D"
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(HERBICIDE)
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SUPPLEMENTAL LABELING
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A(flve I"gte-d,e,,!
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Dtquat d,brorrHd. 6.7 d,h.,d,od'Pf"do '2 u 1.1 (
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Py,ol,nfOd"um dlbrom,de
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Ine'rt I"g,..d, • .,~
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(on,o.1'\I 0 2 Ib DIQ ... at (.01,Of' Pil'" go: (H 0 JlJ !b
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,olt per go',on
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KEEP OUT Of REACH OF CHILDREN
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WARNING
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REFER TO CONTAINER LABH FOR
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PRECAUTIONARY AND STO~AGE ,>.ND
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DISPOSAL STATEMENTS
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h WI
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I
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~ ____________________________________ J
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AQUAllC ~.[ DIR~OTJONS
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for .iPPlh."'-I'~fl.tC· ~-;nd!l lalo.b r·:;.:'~., "jf..)~'f·) ~,~.,.; .. ., :::",;., ~r';
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ditcr.t-s· Ctf. ~~ ~'!'J":'::' and r,-'t;.) o\~'.' J', '.,",.'~ 'f. ;t.,f-\ttn!
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