a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
293 lines
13 KiB
Markdown
293 lines
13 KiB
Markdown
# DREXEL D-264 PLUS CAPTAN SEED PROTECTANT
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- EPA Reg No: **19713-145**
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- Registrant: DREXEL CHEMICAL COMPANY
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- Signal word: Danger
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- Active ingredients: Diazinon (25%); Captan (24.44%)
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- Label accepted: 2002-04-30
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/019713-00145-20020430.pdf
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---
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'if/.38/~
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
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WASHINGTON, D.C. 20460
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Ms. Luz Piwonka
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Drexel Chemical Company
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P.O. Box 13327
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Memphis, TN 38113-0327
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Dear Ms. Piwonka:
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Subject: Amendment - Comply with 2000 Diazinon MOA;
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Delete Soybeans
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OFFICE OF
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PREVENTION, PESTICIDES
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AND TOXIC SUBSTANCES
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APR 3 02002
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Update First Aid per PR Notice 2001-1; and
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Update CSF/replacement diazinon source
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Drexel D-264-Captan Seed Protectant
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EPA Registration Number 19713-145
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Your submissions dated May 8, 2001, May 17, 2001,
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November 19, 2001, and associated submission
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dated April 16, 2002
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The anlendment referred to above, submitted in connection with
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registraL.on under FIFRA section 3 (c) (7) (a), is acceptable
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provided that you:
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1. Submit and/or cite all data or other material required for
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registration/reregistration of your product under FIFRA
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sectior 3(c) (5) or FIFRA section 4 when the Agency requires
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all registrants of similar products to submit such data.
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2. Make the labeling changes listed bel.ow before you release
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the prccJuct for shipment bearing the amended labeling:
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a. In the FIRST AID section, after the "If on skin or clothing"
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advice add an "If Inhaled" section with appropriate text per
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PR Notice 2001-1.
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b. In the first sentence of the Environmental Hazards, add
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"highly" before "toxic".
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c. Under the heading DIRECTIONS FOR USE, relocate "Reformulation
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or repackaging of this product is prohibited." to appear
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directly after "It is a violation of Federal ).aw to use this
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product in a manner inconsistent with its labeling.".
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3. Submit three (3) copies of your final printed labeling before
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you release the product for shipment.
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2
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If these conditions are not complied with, the registration
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will be subject to cancellation in accordance with FIFRA section
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6(e). Your release for shipment of the product constitutes
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acceptance of these conditions.
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A stamped copy of the label is enclosed for your records.
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The Basic Confidential statement of Formula (CSF) dated
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November 19, 2001 which identifies a replacement diazinon source
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Manufacturing Use Product is acceptable and has been added to
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this product's registration file.
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Sincerely,
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George T. LaRocca
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Product Manager 13
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Insecticide Branch
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Registratiop Division (7505C)
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RESTRICTED USE PESTICIDE
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Due to Avian and Aquatic Toxicity
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For retail to and use only by Certified Applicators or persons under their direct su!)ervision and only for those uses covered by the Cenified
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Apphcator's Certification.
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ACTIVE INGREDIENTS:
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Diazinon: O,O-Diethyl O-(2-isopropyl-6-
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methyl-4-pyrimidinyl) phosphorothioate
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Captan· ............................. .
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Related Derivatives .................... .
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OTHER INGREDIENTS: ................... .
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TOTAL: ......................... .
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~ N-Trich loro m eth yl1 h iO-4-cyclo hexene-' .2-dica rbox im id e
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25.00%
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24.44%
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0.56%
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50.00%
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100.00%
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KEEP OUT OF REACH OF CHILDREN
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DANGER I PELIGRO
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Si usted no entiende Ia etiqueta. busque a alguien para que se la explique
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a usted en detalle. (If you do not understand the label. find someone
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;0 explain it to you in detail.)
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EPA REG. NO. 19713-145
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;:PA EST. NO. 19713-MS·1
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FIRST AID
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Net Contents:
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WED; Drink !)romptly a large quantity of
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gelatin solu s or if these are not available. d
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of water, Avoid hoI.
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IF INHALED: Remov 'ctim to f
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artifiCial respiration. prefera~t:"~~
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IF IN EVES: Flush wit
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Diazinon is an or
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on this pesticide product (including th concerns,
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mergencies or pesticide incidents), call the Natl
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elecommunications Network aI1-800-858-7378.
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PRECAUTIONARY STATEMENTS
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Hazards to Humans and Domestic Animals
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DANGER: C~r.ros~ve. Caus~s irreversible eye damage. May cause
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contact senSitization following repeated contact with skin in suS
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ceptible individuals. If sensitization reactions result, consult 8 physician.
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Harmful if swallowed or inhaled.
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PERSONAL PROTECTIVE EQUIPMENT (PPE)
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Applicators and other handl.rs (other than mixers and load
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ers) must wear: long-sleeved shirt and long pants, water!)roof gloves.
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shoes piuS socks and protective eyewear.
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Mixers and loaders must wear: long-sleeved shirt and long pants,
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waterproof gloves, shoes plus socks, protective eyewear. chemi
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cal-resistant apron when mixing or loading and dust/mist filtering
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respIrator (MSHA/NIOSH a!)proval number prefix TC-21 C) or a NIOSH
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approved res!)irator with any R. P or HE filter.
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Discard clothing and other absorbent materials that have been drenched
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or heavily contaminated with this product'S concentrate. Do not reuse
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them. Follow manufacturer's instructions for Cleaning/maintaining
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PPE. if no such instructions for washables, use detergent and hot
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water. Kee!) and wash PPE se!)arately from other laundry
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USER SAFETY RECOMMENDATIONS
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User should: 1) Wash hands before eating. drinking, Chewing gum,
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using tob",cco or using the loilet. 2) Remove clothing Immediately
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if pesticid~ gets inside. 3) Then wash thoroughly and put on clean
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clothing. i1emove PPE immediately after handling this product.
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Wash thc' outside of gloves before removing. As soon as pos
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sible, wash thoroughly and change into clean Clothing.
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ENVIRONME:NTAL HAZARDS
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This pesticide product is to toxic to birds,
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fish and other wildlife including waterfowl.
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Exposed treated seed may be hazardous to birds
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and other wildlife. Collect or incorporate treated
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seeds that are spilled during loading or are
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visible on soil surface in turn areas. Dispose of
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all excess treated seed and seed packaging by
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burial away from bodies of water. Keep out of
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lakes, streams, ponds, tidal marshes and
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estuaries. Do not contaminate water by cleaning
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of equipment or disposal of equipment
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washwaters.
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DIRECTIONS FOR USE
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It is a violatlolJ of Federal law to use this product in a manner incon·
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sislent with its labeling. 00 NOT APPLY THIS PROOUCT THROUGH
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ANY TYPE OF IRRIGATION SVSTEM. For any reQuirements specific
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to your Statf!' or Tribe, consult the agency responsible for pesticide
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regulation. Reformulation or repackaging of ttll, produc:t is prohil<)rt .....
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AGRICULTURAL USE REClUIREMEM"
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Use this !)roduct only in accordanc} v it., It'l labeling arj with the
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Worker Protection Standard, 40 CFr{ Part '170. This ~tandard con
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tains requirements for the protection of agricultural we rk("'$ Ot farms,
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forests, nurseries, greenhouses and t,a'llth::r~ vf agricUilural !>tlsticides.
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II contains requirements for training, deco~t;minalion. no"f:~t::ln and
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emergency 3ssistance.1I also conlains specific instructions '!I,d exceptions
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pertaining to the stalements on this larel at-out personal protective
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equipment (PPE) and restricted entry i"t<:ll lal (REI). The re4uirements
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10 this box ooly apply to usas of this product that ar, ""ered by I
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the Worker Protection Standard.
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(Conf/nued)
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Manufactured By:
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Drexel Chemical Company
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P.O. BOX 13327. MEMPHIS, TN38"3-Q327
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,1U14+,i"
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'1EGP'"
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O':,64-CAPTAN Page 1 013
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AGRICULTURAL USE REQUIREMENTS (ConOnuedl
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Do nol apply this product in a way that will conlact workers or other
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persons, either directly or through drift. Only protected handlers
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may be in the area during application.
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Do nol enter or allow worker entry into treated areas during the
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restricted entry interval of 46 hours.
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PPE required for early entry to treated areas that is permitted under
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the Worker Protection Standard and that involves contact with anything
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that has been treated. such as plants, soil or water is: Coveralls.
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waterproof gloves, shoes plus 50cks and protective eyewear.
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NON-AGRICULTURAL USE REQUIREMENTS:
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Do nOI use on humans or permit children 10 go into treated areas
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until spray has completely dried. Keep out of reach of domestic
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animals. Do not permit pets to go into treated areas until spray
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has completely dried,
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WORK SAFETY RULES
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REPEATED EXPOSURES TO CHOLINESTERASE INHIBITORS SUCH
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AS ARE CONTAINED IN THIS PRODUCT MAY. WITHOUT WARNING,
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CAUSE PROLONGED SUSCEPTIBILITY TO VERY SMALL DOSES OF
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ANY CHOLINESTERASE INHIBITOR.
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Do not rub eyes or mouth with hands. If you feel sick in any way
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STOP work and get help right away. See -FIRST AID- section of this
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label.
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This product gives temporary protection of germinating seed and seedlings
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of Corn 810UI 6e;eu e from injury by Seed corn maggots and Seed
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corn beeUes and gives temporary protection to seed from seed-borne
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and soilborne fungi which cause seed decay and seedling blights.
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This product contains graphite to assist in accurate planting.
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Under some circumstances this prOduct may affect the rate of seed
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ing. It is necessary for the user to check planling rate frequenlly to
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assure himself that the desired planting rate is being obtained.
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MEASURING CUP ENCLOSED.
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SPECIFIC DIRECTIONS
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CORN: Use 5 ounces (3 level measuring cups) per bushel of Corn
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seed. APply 10 seed as planter box is being filled. Stir with paddle or
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lathe so that each seed is coated With seed protectant. If temperature
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is high and soil mOisture is low reduce dosage to one-half. especially
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for mId-season planting. DO NOT use BARE HANDS. Excess product
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flows with the seed into the furrow giving additional protection against
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soilborne diseases_
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ounces
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eed in the planter box a
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~ eve measurin e 0
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to lanting. Folio
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STORAGE AND DISPOSAL
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00 not contaminate water, food or feed by storage. disposal or
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cieaning of equipment.
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PESTICIDE STORAGE: Storage shOuld be under lock and key and
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secure from access by unauthorized persons and children. Storage
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should be in a cool, dry area away from any heat or ignition source.
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Do not allow storage in a damp or humid area. Do not stack bags
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over 2 pallets high. Move bags carefUlly so as not to tear or punc
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ture. 00 not move from one area to another unless they are se
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curely sealed to prevent dust from escaping. Keep container tightly
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sealed when nol in use. Keep away from any puncture source. Avoid
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storage near water supplies, food, feed and fertilizer to avoid con
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tamination. Avoid contamination wtth acids and alkalies. Store in
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original containers only. If the contents are leaking or material is
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spilled follow these steps:
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1. Collect and place in suitable containers for disposal.
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2. Wash area wHh soap and water to remove remaining pesticide.
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3. Follow washing with clear water rinse.
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4. 00 not allow /1,Inoff to enter sewer or conlaminate water sup-
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plies.
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5. Dispose of waste as Indicated below:
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PESTICIDE DISPOSAL: f"esticide wlStes are toxic. Improper djs~
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ponl of excelS pesticide, spray mixture or rinsale is a violation
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of Federal Law. If these wastes cannot be disposed of by use ac
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cording to label instructions, contact your State Pesticide or Envi
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ronmental Control Agency or the Hazardous Waste representative
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at the nearest EPA Regional Office for guidance.
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CONTAINER DISPOSAL: Completely empty bag into application
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equipment. Then dispose of empty bag in a sanitary landfill or by
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ino;:ineration, or, if allowed by State and Local authorities, by burn
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ing. If burned, stay oul of smoke.
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WARRANTY-CONDITION OF SALE
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OUR RECOMMENDATIONS FOR USE of this product ate based upon
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tests believed reliable, Follow directions carefully. Timing and method
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of application, weather and crop conditIOns, mixtures with other chemicals
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not ~pecificaUy recommended and other influencing factors in the use
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of this product are beyond the control of the Seller. Buyer assumes
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all dsks of use, storage and handling of this malerlal nol in strict
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accordance with directions given herewith.
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In no case shall the Manufacturer or the Seller be liable for consequen
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tial, special or indirect damages resulting from Ihe lise or handling of
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this product when such use and/or handling is not In strict accoraance
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with :jirections given herewith. The foregoing is a condition of sale by
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the Seller and is accepted as such by the buyer.
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0-264·CAPTAN Page 2013
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FIRST AID
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0-
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This product contains diazinon, an organophosphate insecticide that
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inhibits cholinesterase.
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If swallowed • Call a polson control center or doctor immediately
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for treatment advice.
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• Have a person sip a glass of water if able to swallow.
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• Do not Induce vomiUng unless told to do so by a poI-
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son control center or doctor.
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• Do not give anything by mouth to an unconscious or
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convulsing person.
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If In eyes • Hold eye open and rinse slowly and gently
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with water for 15-20 minutes. Remove contact
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lenses, If present, after the first 5 minutes, then
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continue rinsing eye.
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If on skin
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or clothing • Take off contaminated clothing.
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• Rinse skin immediately with plenty of water for 15-20
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minutes .
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. . ..
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Cal a. poison control cenler or doctor for trealment advice.liaw the produd
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. UI Iduel wnn you When C8RU19 a pOison COmrol center or doctor, or
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gOln9 for treaIDlent. FQr infQrm~tiQn Qn Ihili Q~IiU!Oi!!1l Q[l!!!Y!OI !illlO!!!Qi!!ll !lU!!!!
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~oncems, mlldlcal Ilm!:[lIencles or I1!!sUcidll iD!Oi!!l:ll!!il, COli l!!!! ~!!Ii!!nal
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P!:~ti~idll T~!!:s;Qmmyni!<!!tiQ~ Networ1c iI! 3~OO::!!§S-Z37§.
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NOTE TO PHYSICIAN
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•
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This product contains diazinon, an organophosphate that inhibits
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cholinesterase. If symptoms of cholinesterase inhibition are present, , ,
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atropine sulfate by Injection Is antidotal. 2-PAM is also antidotal, but ,
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should be administered only in conjunction with atropine. • f .: , ( ( ,
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I • , ,
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• . .. . ,' .,
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