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crop-chem-docs/corpus/epa_ppls/241-110.md
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Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
2026-05-24 12:32:41 -04:00

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This file contains invisible Unicode characters
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# MALATHION ULV CONCENTRATE INSECTICIDE
- EPA Reg No: **241-110**
- Registrant: BASF AGRICULTURAL SOLUTIONS US LLC
- Signal word: Caution
- Active ingredients: Malathion (NO INERT USE) (95%)
- Label accepted: 1976-06-11
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000241-00110-19760611.pdf
---
~<I/- II () 0-11-197("
ACCEPTED
« JUN 11 1976
Unu.·;r ~ Federal t~klo.
Fungu.i,de. ono Eodentleld. Ad,
~ ~d~~, L'. :~9 reqiateIed under -/I OK
EPA No. -
l~\-\\D
.J
1
CYANAMID
IMPORTA-,"T
Before Using
5 TOP
Read Directions
in This Leaflet
Undiluted spray drople;; of CY·
THION" Insecticide, 'The ?remium
Grade Malathion" or M,A1.';THIO"
ULY* Concentrate Insecticide wi II
permallently. da ~P<le. =i1>m"bi:e '"'. . . .. ... . ~ . .. ........ ,.
Paint lHv.es~ th~se·spet"',- ::·ln~tL.,;c·
I .. • ..... ,j
.. ... . . ..
\
tions for ground and aerio l appli·
cation are f~lIoYfed.' ~ .. 8 ... ... . ..
L .. ....... .. .
~--------:-:-: -:-:----:-:-!------.-~-
• • • • .. .. " .. I •
.",.:
Contents Of This Leaflet Apply To Both:
CYTHIOj
"TMI! !'flEMIUM GRADE MAUTHION 4I
EPA Reg. No. 241·208·AA
MAlATHION ULV*
CONCENTRATE
Insecticide
EPA Reg. No. 241-11 O-AA
""Trademark
Active Ingredient:
Malathion** 95.0%
Inert Ingredients ...... 5.0%
**0, O-dimethyl phosphorodithioate of diethyl
mercaplosuccinate
(One gallon contains 9.7 pounds of malathion)
Al USUARIO; 5i usled no lee ingl~5. no use esle produdo
hasta que 10 etiqueta Ie haya sido explicada
ampliamente.
(TO THE USER: If you cannot read English, do Mt use
this product until the label has been fully ex­
plained to you)
Before using, read the directions contained in this leaflet
for the proper methods and procedures which must be .
followed to achieve effective insect control and avoid·
permanent damage to automobile and other paint
finishes.
CAUTION!
KEEP OUT OF REACH OF CHILDREN
HARMfUL BY SWALLOWING, , ( , , (' .
INHHA T1c.lN OR SK,IN CaNT ACT
" '. ". ( 'Avoid; Br:dthing ,,~yC Mist
Avoid Contact With Skin
• ( t W<lsh Thor?Ughl:, Afhlr ijandling
1
• c.:l',Jng~ ,C~n~an':hat~. tlothing
l' <'" " ••
Do Not Ct.ntum;nafe voed t)r ~eed Products , (, " , ( ( ..
2
r
j
This product i. taxic to fi.h. Keep out of lakes, streams,
pond. tidal marshes and estuarle.. Do not apply were
runoff ia likely to occur. Do not apply when weather
conditiona favor drift from areas treated. Do not contami­
nate water by cleaning of equipment, or disposal of wastes.
Shrimp and crab may be killed at application rates re­
commended on this label. Do not apply where these are
important reaourc«. Apply this product only as specified
on this label •
In cose of on emergency endangering
life or property involving this product,
call collect, day or night,
Area Code 201-835-3100
American Cyanamid Company
Agricultural Oivision
P. O. Box 400
Princeton, New Jeney 08540
DISCLAIMER
The label instructions for the use of this product
refled the opinion of experts based on field use and
tests. The directions are believed to be reliable and
should 'be followed carefully. However, it is impossible
to eliminate all risks inherently associated with use of
this product. Crop injuury, automobile point damage,
ineffectiveness or other unintended consequences may
result because of such factors as weather conditions,
presence of other materials, Or the manner of use or
application all of which are beyond the control of
American Cyanamid Company. All such risks shall be
assumed by the user.
American Cyanamid Company warrants only that the
material contained herein conforms to the chemical
description on .he lo.el ard- tis .. lfCtSonabt, fit for the
use therein d.c~bed v,hen uled irt accorcJci.v:e with the
directions for U!t!', su~iecfl'to th; ri~i r@fer~~ to above.
Any damage. ~~is~. from ; bre .. ch of .t6.IS warranty
shall be limited to direct damages and shall not include
consequential commercial damages such as loss of pro­
fits or values or q{'Iy.other. speciPl,pr in~ir.rl.damages.
Am?rica,n Cyananti~:C~nlJtan..)' D"nes "t» other express
or Implied warrant)', w'ic"'din~ CW'ly. other ... press or
;mpl;ed wa"anty'<of:FIT~CSS 0' p' ~~ItCtV\~TA8Il1TY.
3
'. ,. .. " ~ ...
Directions For Use
CYTHION or MALATHION ULV may be used for the
preparation of malathion insecticides. Before using
for this purpose, manufacturers should consult
American Cyanamid Company for manufacturing
and safe handling instructions.
~
The sale of this product does not include a license
under any patent owned by the American Cyanamid
Company.
Mosquito Control
with Thermal Aerosols or Fogs
Applied by Ground Equipment
IMPORT ANT NOTICE
TO BE APPLIED ONLY BY TRAINED ~ERSONNEL OF
PUBLIC HEALTH ORGANIZATIONS, MOSQUITO ABATE.
MENT DISTRICTS OR PEST CONTROL OPERATORS.
DIRECTIONS FOR USE
For control of adult mosquitoes with thermal aerosols or
fogs, apply CYTHION or MALATHION ULV at the rate
of 6·8 oz. actual/gallon {3.9-S.2 gallons CYTHION or
MALATHION UlV in 100 gallons finished solution*l by
ground equipment delivering 40 gallons per hour at a
vehicle speed of ~miles per hour to treat a swath width
of 300·400 feet. . (, '( ( •
• • l' .. •
0There Is ~ ~reat v,.~atIOf'l; in the ch .. m~:1 composition of
fuel oils whtch may b~ used' as theM~ follotvents. These
differences may cause sludge and/or affect the solubility of
the CYTHION or MALATHtON ULV. For more complete
details or( fe'ts'or Sl~g~ form~tion ifnd:solubllity In thermal
fog solutit.lns, ....r.Jte AnJer.\c:an Q)tsnardrl Company, P. O. Box
400, Printeton, ~er.- .terYy OS$O.: : : . .. " . . . .
','
.'
AGRICULTURAL USES
Directions For Use
For Ultra Low Volume Applications
Do not use this product
for any usas other than those
specified in this leaflet
CYTHION or MAlATHIQt.,I UlV is used undiluted in specl·
ally designed aircraft or ground equipment capable of
applying ultra· low volumes for control of the Insects
indicated. Aerial applications are most effective when
made at a boom hei~t of 6.fee" • .-d a swath width of
•• • • • •• 50 feet. Do-n~ mo.Jcie ~pplt:otiotJ w~e"'¥1nds exceed
5 mph. • •• :.. :-:. • ••
Mist blowers and boom sprayers utilizing a controlled
air flow to facili'te! part~le sile ~nd :pr~; deposition
•• ••• ••• •• • may be used at a; v~i~e :peect:of:4 to ~ 0 Mp'h.
•••• • •••••
5
,-. - ,-
.-:~.;-:: ---.~:. - - - : .. -'.
-
Mist blowers with a pump capable of producing up to
40 psi and blower speeds of 2600 rpm are satisfactory,
Use flat fan nozzles. 8001 to 8002, placed 30· into air
blast or rotary atomizers into the air blast that produce
an efficient spray particle with a mass median diameter
of 40 to 100 microns. Swath widths should not exceed
30 feet, and application should not be made when winds
exceed 5 mph.
Boom sprayers with a filtered rotory air compressor,
either PTO or gas engine driven or an air pump capable
of producing at least 12 psi are satisfactory. Use air
pressure on chemical tanks and an accurate metering
valve to assure a calibrated flow of the pesticide. Air
should be regulated with relief valve and gauge for
proper air and I1q'uid mixture. Pneumatic.type spray
nozzles, as suggested by equipment manufacturer,
should be used for spray particles with mass median dia­
meter of 30 to 100 microns. Applications should not be
made when winds exceed 5 mph.
Repeat applications should be made as necessary unless
otherwise specified.
'" t •• •• t
, ,
, ,
... • • • •• .. • • .' •
..
••• • • • •
, . ,
6
" f' f,
" .
• • • . • • • •• • • • • ..
---------~,
• • • • • •• • ••
• ... ••• • • • • • • • • • • • • • • •• •• • •• • • • •
• • • • • • • • • • • • • • • • • • •• •• • • • • • • • • • • • • • • • • • • •• •
" ..
IMPORTANT - Undiluted spray droplets of CYTHION or
MAlATHI0t-t UlV will permanently damage automobile
paint. If accidental expOsure does occur, the vehicle
should be washed immediately.
Consult your stote experiment station or state extension
service for proper timing of sprays.
Crop Pests Controlled
----------~------r_--~~~~~~------~.
Alfalfa
Beans (lima, green,
snop, Nav'f, red. •• ,
kidney, ¥.('JX: dry, :
blackeye): ' • :
· · .. ... · · • • . .
'"
..
8
Alfalfa caterpillar
Western yellow striped
armyworm
Alfalfa weevil larvae
Beet armyworm
Grasshoppers
Mexican bean beetle
leo{I,opperl\
Gretn clO:V'e~ worm
Jupall.ese ,beetle
lyg,,'s. ~ugs. •
. .. .. • . • . ..
This product is highly toxic to bees exposed to direct
treatment or residues on crops. Protective information
may be obtained from your Cooperative Agricultural
Extension Service.
Fluid Ounces
Jler Acre
8
12
16
8
16
8
Days to Harvest or
Grazing & Comments
o day. Apply when larvoe are small
5 days. Apply when larvae are large
or when foliage is dense.
5 days. Apply when day temperatures
or. expected to exceed 6S'F. and
when 50-75% of leaves show feeding
damage.
o day. Apply when larvae are small.
5 days. Apply when larvae are lorge
or when foliage is dense.
o day.
Do not apply to alfalfa in bloom
Do not apply to seed alfalfa
• • • •• ••• • 8 • • : day.: • • • • • • • • •• • • • • • •• • •• •• • •• •• • · ••
(Continued)
• • • • • • ••• • • • • • • • •• .. • ••• .. • • 0 • • • • • 0 o •
0 0 0 0 0
• 0 0
0 .. ...
9
;" ..
.",.:
(Continued)
Crop
Blueberri~s
~
Cherries
Cereal crops (barley,
corn, oats, wheat)
and grasses
Clover, Pasture and
Range Grass, Grass,
Grass Hay, Non-
agricultural Lands
(wastelands, roadsides)
Corn
Cotton
• <
• .. •
... .. .. ,
. -... .
••
.. ... • •
Pests Controlled
Blueberry maggot
Cherry fruit fly
Cereal leaf beetle
Grasshoppers
Adult corn rootworm
Early Season Insects:
Thrips
Fleahoppers
leafhoppers
Boll weevil
Grasshoppers
• • • • • •• • l'llJus ~l'~s
• r, f' C ~
• • . .. .. . • ..
10
,.
!
-
.
"
Fluid Ounces
Per Acre
10
12·16
4·8
8
4
4-8
8-12
16
8
8·12 ..
.. ..
16 ." .. ....
o day
1 day.
Days to Harvest or
Grazing & Comments
Apply by aircraft only. Us.
higher rate when foliage is heavy or
infestation is severe. Make first
application as soon as flies appear .
Barley, oats, wheat: 7 da)'s.
Corn: 5 days. Grasses: o day.
o day. Do not apply to clover ;n
bloom.
5 days.
Early to mid season
late season o Doy
.. "4" a'l'l _ 'I~
~~
" . " .. ~
"'ter., he;lY rfJi~rCtjn~t
"1lopulatl!Ons. .. .. ..
.. .. ... " .... "~: (Continued)
11
.. ,
(Continued)
Crop Pests Controlled
Grain Crops (barley, 1:orn
oats, rye, rice, grain Grasshoppers
sorghum and wheat)
Grain Sorghum ~ Sorghum midge
Peas (Northwest) Pea Weevil
Rice-Grain Form Rice stink bug
(louisiana, Texas)
Safflower Grasshoppers
"lygus bugs
Soybeans Mexican bean beetle
Grasshoppers
Japanese beetle
Green doverworm
Sugar Beets Grasshoppers
Sugar beet root
maggot adults
Nonagricultural Lands Beet leafhopper
(on wild host plants)
Beef Cattle-Feed lots and Adult flies and
Holding Pens Mosquitoes
OTHER AGRICULT1lIIAL USES,
Alfalfa, Cla,(&'rl Posture a1nJi' Range Grf1;s. Gross and
Grass ~ay, !ql'..1ir:. Cr:,"'ps, pea~s, ~ice, C"!dmatoes .and
Nonagrlcult ....... al landS! (wnrteland): .Mult mosquitoes
and flies-App~)' CYTH\ON 6r MAl!J(flilON' ULV at the
rate of 2 to .4 fluid ounces for control of adult mosquitoes
and at 6 to 8 fluid ounces per acre for control of adult
flies and "1d~ltuiioes. :R~oeat ~ppli~..lti!-,ns as necessary.
" '"
" .,
12
,
;
, '
..
I
Fluid Ounces
per Acre
8
8-12
8
8
8
8
8
8
6-8
Days to Harvest or
Grazing and Commenh
7 days. except corn. Corn: 5 days
7 days. Apply during the bloom stage.
14 days
7 days. Apply by aircraft only. Apply
during early milk and dough stage of
growing rice.
3 days of horvesting seeds.
7 days
o day
7 days. If tops ore to be used for
food or feed.
o day
o day
On alfalfa, clover, ~asture and tq,nge grpss, grass and
grass hay, 1"i~)Io be ~pliecf:'~ do," of hmveut or grazing.
Do not apFtY.Jo aJft:llf" ac$d cloler In ~aom. Do not
use on seed alAal6a. On gf'C!'in CfCfpS, ma~ no applica­
tion within ,,]-dals·tf har.J'est 01 forag~·use; on corn,
within 5 days of harvest or forage; on rice, within 7 days
of harvest; on beans and tomotoes, within 1 doy of
harvest. :::::: •• :
•• ••• ••• •• •
: : :: :::: • :(Contlnued)
~~ ~~ .....
13
(Continued)
FOREST INSECTS
Apply with aircraft equipped for ultra low volume ap-
plication. Make application when air is calm and
temperature is below 68"F. Do not allow spray to con-
tact ferns, hickory CWd maples as injury may result. Do ,
not spray on elms under extreme heat, drought and
disease conditions.
. .
Fluid Ounces
Tree Pest Controlled per Acre Commenh
Douglas Fir 13 Apply when highest percentage of True Fir Spruce budworm larvae are in the fifth inster. Spruce
Hemlock Hemlock looper 8 Apply when most larvae ore in third
and fourth inster.
Apply when larvae are in the first or
European pine sawfly second instor or before they reach 1/2
Pines 10 inch in length.
5arotoga spittlebug Apply when 95%
hos become adult.
of the population
8 Apply in spring as soon as larvae
Larch Larch casebearer break hibernation and begin feeding
on new foliage.
0
- .. 'j," (t"" ,. , '..1---' ~
• • • • • • • . . o.
" . ' • ,
• • • • • • , , . .. • , • , ,
t t, 0
· • • • .. ... • • • ,. • GO
• .. .. • • .. • lA~de :and • .. · • ... .. <0 ~~(. PIliRted in U.S,A.
, ... • · · • • • , · · • • • ...
• • • • • • • • • • • • • •
· .. ... · .. .. •• .. • • •• .. · .. · • · • • • • • • • • • • • • • .. • · • 0 • • • • • " • • • • • • • • ... .. • .. .. " .. .. " .. ... " ....
14 15
-------,,--_._--;.
Ultra Low Volume Aerial
Application where
automobiles, trailers,
trucks and pleasure
boats are present
IMPORTANT NOTICE
TO BE APPLIED ONLY BY TRAINED PERSONNel OF
PUBLIC HEALTH ORGANIZATIONS, MOSQUITO ABATE.
MENT DISTRICTS OR PEST CONTROL OPERATORS.
DIRECTIONS FOR USE
ADULT MOSQUITO CONTROL OVER. CITIES, TOWNS,
AND OTHER AREAS WHERE AUTOMOBilES, TRAilERS,
TRUCKS AND PLEASURE BOATS ARE PRESENT, Apply
2.6 to 3.0 fluid ounce~ of CYTHION or MALATHION UlV
per acre. Aerial spraying should not be attempted when
the wind is at or above 10 mph or temperatures are
above 82°F.
IMPORTANT - Undiluted spray droplets of CYTHION or
MALATHION Ul V wilt permanently damage vehicle paint
finishes unless the aircraft used for the ultro low volume
application meets all of the specifications listed below:
fiXED WING AIRCRAfT
1. Aircraft is operated at 1 SO mph or more.
2. There are no leaks in 'the ultra low volume spray
system.
3. Nozzles, ar~ f'1to.cid .~'\ the poam lit a 45° angle
down ond Into the wmd. e ••
•• • c • ••
4. ~iaphtcfg":, :h1~ vo,h:es dire IIsfd!Gn all nozzles to
Insure l'o.slf1ve wt 0 f.of the.S(lfay .• c
5. Dosage of CYTHION or MALATHION ULV does not
exceed 3 fluid ounces per acre.
"" '···t 6. The I.proy,slstem I"roduC'es doop '3ts of this product
in titt set t~ ~":m6sS: ~edld'l diameter (MMD)
micrf''i la~\I/!' 'lfi!" no n:~rt: t~.~ft 10% of the drop-
16
lets exceeding 100 microns, as determined by read­
ings made from microscope slides coated with
DRI-FILM* or TEFlON@.
HELICOPTER
Equipment Specifications
1. Rotary nozzle equivalent to Beecomist Spray Head
Assembly Model No. 350 equipped with:
a. a direct reading RPM tachometer or low RPM
signal light readily visable to operator;
b. a stainless steel porous metal sleeve, 20 micron
pore size, dynamically balanced to the nozzle;
c. a diaphragm check valve as near to the rotary
nozzle as possible to insure positive cut off of
the spray;
d. nozzle on-off switch separate from main switch
and pump switch.
2. Minimum no-load nozzle speed of 10,500 RPM.
3. A cOntinuous nonpulsating metered flow must be
maintained by a variable speed metering pump
equipped with:
a. a positive cut off valve between tank and pump;
b. a flow guage or tachometer visible to operator;
c. a pump on-off switch separate from main
switch and nozzle switch.
4. Maximum flow rate of 0.5 gallon per minute per
nozzle.
S. Rotary nozzle must be mounted behind and below
the boom with the sleeve directed toward the rear
of the aircraft and parallel to the ground during
flight. Nozzle must be positioned to minimize air
turbulence and the collection of CYTHION or MALA­
THION UlV droplets on mounting brackets, feed
lines, fillings, etc., or any part of the aircraft.
Operating Pro~E~~res :: "~; '. r .. ""
6. CYTHION··U"·:MAt.ATHIOh~ ULV~:mu]t be. "prefiltered
through q. 1,0 rrfiCfC?n filte~:prioUo tror:'.s.~er into heli­
copter tonk. A" 50 mesh stainless steel line strainer
must be installed in the pump feed line.
r,,, " Co ,. ~
~Trademark of Gem?r-:d: Eler.t~ic ... C;:T...p.~ny "~
n Registered TrademHr,<:of:f. ~ dUPq)1t oe ~e~our~ ~ Co .. Inc.
17
7. Entire system, including tonk, pump, nozzle and
feed lines, to be used only for application of
CYTHION or MALATHION ULV.
8. Entire system must be inspected daily to insure 1hat
there are no leaks.
9. Sleeve must be removed and cleaned immediately
after each use by washing with hot water and
blowing dry from outside in with clean air.
10. Rotating nozzle""" must be turned on and operating
before turning on pump. For shut off. pump must
be shut off and lines cleared prior to stopping noz·
Ie rotation.
11. Dosage of CYTHION or MALATHION ULV does not
exceed 3 fluid ounces per acre.
12. The spray system must produce droplets of CYTHION
or MALATHION ULV with a mass median diameter
(MMD) of less than 50 microns, with no more than
2.5% of the droplets exceeding 100 microns. as
determined by readings made from microscope
slides coo ted with DRI·FILM or TEFLON.
-• .. . ... • • • • • • • · • • • • • • • • • • .. •• .. • • .. ... ..
... • • • • • • • • • .. ... .. .. .. • • • • • • • • • • • • • • • • ... .. ... ..
18
Ultra Low Volume
Application
NONTHERMAL AEROSOLS
Applied by
GROUND EQUIPMENT
IMPORTANT NOTICE
TO BE APPLIED ONLY BY TRAINED PERSONNEl OF
PUBLIC HEALTH ORGANIZATIONS, MOSQUITO ABATE·
MENT DISTRICTS OR PEST CONTROL OPERATORS.
DIRECTIONS FOR USE
Adult Mosquito Control - For control of adult mosquitoes
over a 300·foot swath with nonthermal aerosols of
CYTHION or MALATHION ULV using the ultra low volume
method, use the folloWing rates at the indicated vehicle
speeds:
Vehicle Speed Flaw Rate of &YT.JUON or MALATHION ULV Maximum Fig.
Miles per Kour Fluid OllCes per Minllte Rate per HOir
5 1.0 to 2.1 fluid ounces 1 gallon
10 2.0 to 4.3 fluid ounces 2 gallons
Adult Stable Fly Control- For control of adult stable flies
over a 300·foot swath with nonthermol aerosols of
CYTHION or MALATHION ULV using the ultra low
volume method, use the following flaw rates at the
indicated vehicle speeds:
Vehicle Speed
Miles per Multi'
5
10
Flaw Rate of &YTKION Of MALATHION ULY
Fluid Oances per Minute
2.1 fluid ounces
4.3 fluid ounces
DROPLET SIZE
Muimllm Fill ..
Rate per KOlr
1 gallon
2 gallons
1. The mass median diameter (MMD) of the droplefs
should not exceed 17 microns. The MMD is the
drop diar;leter ... ·.hich -i::v~de,s .tSe sprcy volume into
two eq,?:al~~parts,;: i.e. 59% o~: the vi?hJJne is, in the
drop size •• be1c,w t~e I\\MD (md .50%" :'5 above the
MMD. ,. It'' ~ -' _. I:"~ I:"~ ,,'"
2. Spray droplets should not exceed 32 microns in size.
Three percent of the spray droplets (6 droplets out of
200) can e~ce~d 3~ micrpnf proy,idJr:'.9, the MMD
does not exree,d 17 O'Iicro..-..s CI./Od n~ drop~ets exceed
a maximum,dt:48, m;cr'6ni=~ ',"o.~g·e.r dro~lets, when
transported" ~y 'n,a.;'ural-:· ~r "c,uyre..n!!l1 impinge
19
more readily on objects in their pathway and will
permanently damage automobile-type paints.
3. More than one-half of the total spray mass must
consist of droplets in the 6 to 18 micron range to
achieve adequate dispersal of insecticide over 0
300-foot swath.
4. A minimum of two-thirds, preferably four-fifths of
the total spray mass must consis.t of droplets not
exceeding 24 microns in range.
~
OPERATING EQUIPMENT
Each Nonthermal Aerosol Generator used for dispersal
of CYTHION or MALATHION ULV to control adult mos­
quitoes must have minimum capability of producing the
droplet spectrum described under DROPLET SIZE. The
initial determination of droplet size is made after the
unit is installed in a vehicle and prior to its use in mos­
quito control operations. The unit should be rechecked
as frequently as necessary to insure that proper droplet
size is maintained for each operation. Determination of
droplet size every two months is usually suffiCient if the
unit has been mainta:ned in good opero'ting condition.
EqUipment manufacturer's instructions setting forth clean­
ing and maintenance of the unit must be followed. The
unit must be inspected before each operation to correct
any leaks or obstructions in the spray system; to detect
whether the nozzle, hoses, or other ports are worn and
need replacement; to insure that the flow meter is
properly calibrated; and to determine that the pressure
recommended by the manufacturer is being maintained.
Flow Rate - must be regulated by accurate flow meter.
not greater than 1 gallon per hour at 5 mph
or 2 gallons per hour at 10 mph.
Nozzle Direction - rear of the vehicle.
..,., upword at an angle of 45° or more.
Vehicle SP"'1l. - nAC ~rehj/l- tho~ 10 'l'~~s per hour.
• • - shlfl off ~ra~ ~uip",eM when vehicle
• • • is. :top~. '.: •
• • • • •• • • •
IMPORTANT -
...
• .. • ...
Spray droplets of undiluted CYTHION or
MALATHION ULV will permanently
:dam~~Et aut0l"0.bilf ~int unless all the
.«mdltIO«S ede(.4(.befl. and recommended
:in:.t~s {eafleC ate )n~.
• • • • • • •
20
Directions for Determining
the droplet size of
CYTHION or MALATHION ULV
nonthermal aerosols
Permanent records of each droplet size determination
must be kept and made available to American Cyanamid
upon req uest.
I. Preparation of Slides with DRleFILM
CYTHION OR MALATHION ULV droplet sizes are deter.
mined by depositing a sample of the aerosol on a coated
gloss slide and measuring the droplets under a high.
power microscope. Ordinary 3" xl" gloss slides may
be cooted with silicone (General Electric SC-87 DRI-FILM)
prior to sampling to prevent excessive spreading or coale­
scence of the droplets. The slides are dipped into a
10 percent so-:ulion of DRI·FILM in toluene, drained and
dried at about 200"F. for 30 minutes, ofter which they
are dipped in acetone, allowed to dry and stored in a
tight slide box. Cooting solution must be freshly pre­
pared. 00 not store coating solution because it wi1\
deteriorate. Slides are lightly polished with a soft tissue
before using to remove any foreign particles.
II. Deposition of CYTHION OR MALATHION ULV
Droplets on Slides
Droplets should be collected under ideal operating con­
ditions to insure representative sampling of droplets in
the aerosol. A sample of the CYTHION or MALATHION
ULV aerosol is deposited on a slide by waving the slide
as rapidly as possible perpendicular through the aerosol
cloud at a distance of 25 feet from the point of discharge.
The slide velOCity may be increased by attaching it to a
3 or 4 foot stick by means of a spring paper clip. At
least two slides. should. ~e ~~p'os:~ Ito ins~re on ade·
quote sample.. .~tore .shdes .. n a ,fight !hd:1 box for
transfer to a lotcat~n '1;'1er~ m~asure'<men}s co,~ be mode.
Avoid excessive ,.hellt during< '.~ron..;ii and ~':ore in c
cool place untirmeas\SUmenls tan be made.'
Although label specifications require the aerosol non Ie
to be angled upwo[d .. at 45.
0
or -:,",o,e dU{,inr, ,[,peration,
it is more convenioot'lto pCGition. th,r" nozde purallel to
the ground for dropfe'f sqrhpling:, 'I~ thi~}s nc;t.:possible
it .will be ne~esso}y, :IO'?~ posdi,ohed <~t .p't lufficient
height to oblom a representative sample of the aerosol.
21
-
III. Determination of CYTHION or MALATHION ULV
Droplet Sizes
A microscope with mechanical stage and an eyepiece
micrometer are used to determine the size of the indivi­
dual aerosol droplets. Prior to taking measurements, the
divisions of the eyepiece micrometer must be calibrated
into microns by means of a stage micrometer. In the
example represented in Table 1, droplets were measured
at 400x magnification. At that magnification each
division of the eyepiece was calibrated to equal 3.5
microns.
At least 200 droplets should be measured. Usually this
is easily accomplished on one slide. An accurate method
is to measure all droplets that pass through the micro­
meter scale as the slide is moved from one edge to the
other by using the mechanical stage. Measurements
should nat be taken along the margins of the slide. It
is more convenient to measure in terms of the divisions
of the eyepiece micrc.:neter and then convert these divi­
sions into microns.
The measurements converted into microns must then be
corrected for the amount of spread that occurred on the
slides. The CYTHION or MALATHION ULV spread factor
for silicone-coated slides is 0.5. Therefore, in, Table 1
each division of the eyepiece odually equals 1.75 mic­
rons (3.5 microns times the 0.5 spread factor).
lhe spread factor for TEflON-coated slides is 0.69. The
following procedure as given for silicone-coated slides,
would be the same for TEflON-coated slides once the
value for each eyepiece division has been determined.
The measurements are tabulated and processed as in
Tobie 1. The Maximum Diameter is calculated by con­
verting the diameter of the largest droplet measured into
microns. In Table 1, the lorgest droplet measured had a
diameter of 19 eyepiece divisions. Therefore, the Maxi·
mum Diameter is 33.3 microns (19 x 1.75 = 33.3),
• ••• ••• • • To determ~e: the I$ss If,edion:Diantetetr (MMO), the
accumulatiU peltCenktges irolT9tha.lastuo'umn in Tobie
1 are plott~d ~gaintCthe·~epiec~ ptvis'~f'\S (0) on arith·
methic probability paper as in Figure 1. Directly across
from the 50 percent point on the line is the median drop­
let size i",,~p,ece cijviiions ¥"hich.m~st be converted to
microns .• \n F~.ure.(, ".2 e:epieoe civisions times 'the
conversioZ,. foc"'·, .ot!, ~5· e<WoJs ~. Vtass Median Dia-
meter of '~\1 ~lldorfs. • : •• : ••
22
'"
If
15
iii
5 14
~
~lJ
~
~ 12
1111
Z
2 10
'" ~ , o
" . '" z Q 7
'" :;
Ci •
'" hl 5
ii:
'" . ~
2
figure 1.
Percentage of the total volume of aerosol samples be­
low each stated droplet size (from Table 1). The Mass
Median Diameter 'is determined from the 50 percent
point on the line. The Mass Median Diameter (MMD)
= 9.2 divisions times 1.75 = 16.1 microns.
I
ill
Ilffi!
I
~
~ II II F
-1= ,
~.
'",',." I ,.,
I
I
m
I
I.Ot = , : 1 ACCUMULATIVE PERCENT;·~E • • • •• •• • • • • • , • • • • , , , .. •
23
."
,
-. - .~--~-
• .:: . .... ~ ..
• • • • • • • • • • • · . · .
24
','
-',
-- _., ~.',,,. . '."
-'ill" ;'--~' liiiA&;, 5
Table 1. - Representative Count of CYTHION or
MALATHION ULV Concentrate Aerosol
Droplets Impinged on Microscope Slides
Coated with DRI-FILM.
EyeplKI "Imber of % If lltal Aceamolatin DiYisius Droplets DXN DXN
(0)' 00 • (1)XN) Permtages
5 5 0,31 0,31
2 10 20 1.22 1.53
3 9 27 1.65 3,18
4 12 48 2,93 6,11
5 15 75 4.58 10.69
6 12 72 4.40 15.09
7 25 175 10.70 25.79
8 14 112 6.85 32.64
9 28 252 15.40 48.04
10 19 190 11.61 59.65
11 14 154 9.41 65.06
12 10 120 7.33 76.39
13 6 78 4.77 81.16
14 4 56 3.42 84.58
15 11 165 10.09 94.67
16 2 32 1.96 96.63
18 2 36 c 2.20 98.83
19 (. (,19 , (!f.16!' 99.99
'T6li6 ' , ,
Total 199 6 , , • • , •• .. .. ••• 0 •
·Measurements were taken at 400x mag.ification. Each eyepiece lIiyision eqllals
1.1~ microns (3.5 mlcrons:timts the 1.5 sprefllJctor).: t"
C. • ••• •• , • (
. . . ~
~ . . .
• t ••
25
~ . . (
• • • t.
"
,
Also for use in accordance with the recommenda.
tions and instructions issued by the United Stotes
Department of Agriculture for quarantine programs.
To be used only by or under the direction of
Federal/Slale personnel for quarantine treatments.
" ,
. ~, .....
t ( ••
, . • • , .
.~
• • • •• • •• · .. _---
·11~;r~THlo. N ULV' I
• CO~~~eEc~~~~TE I
l! _-!- ____ . ______ -.-----J
.. • • • • . .
.j