a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
429 lines
21 KiB
Markdown
429 lines
21 KiB
Markdown
# PROZINE 32/48
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- EPA Reg No: **241-300**
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- Registrant: BASF AGRICULTURAL SOLUTIONS US LLC
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- Signal word: Caution
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- Active ingredients: Atrazine (48%); Pendimethalin (32%)
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- Label accepted: 1986-11-20
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/009779-00278-19861120.pdf
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---
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',1'<fI:r< C PDT E D .:.C .. .J,..,I.L •
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Riverside Trademark 0 I NOV201986
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lJ::,·"'.· . "...:~·:.:llrH_cclici!'1 .
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. _ -: -: .. cm.1 Rcdo:::-uci·ju j,ct,
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" - . :,,,:!. I;:;: tho pu:Hicid .. PROZINE 32/48 . ...... . u'(";j""~ ~ J. i i:l'J~<~:('~-" l\~. - 7' I
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ACTIVE INGREDIENf
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Pendirnethalin (N-(I-ethylpropyl}-3,4-dirnethyl-2,6-
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dinitrobenzenamine} ..•...•..••••.•••.••..•••.•.••.•• 32.0%
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Atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-
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triazine} ••......•••..•••.••••••••••••.••.•..••..... 48.0%
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INERT INGREDIENTS................................... 20.0%
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Total 100.0%
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EPA REG. NO. 9779- EPA EST. NO. 9779-AR-13
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STOP-READ LABEL BEFORE USING.
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KEEP OUT OF REACH OF CHILDREN
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CAUTION
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STATEMENT OF PRACTICAL TREATMENT
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IF ON SKIN: Remove contaminated clothing and wash with soap and
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water.
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IF IN EYES: Flush eyes with plenty of water. Get medical attention
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if irritation persists.
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IF INHALED: Remove victim to fresh air and apply respiration if
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indicated.
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IF SWALLOWED: Contact your local poison control center, hospital,
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or physician. If the patient is unconscious, maintain breathing
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and heartbeat (cardiopulmonary resuscitation.) If the patient is
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conscious and alert, drink 1 or 2 glasses of water and induce
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vomitlng by touching back of throat with finger. NEVER GIVE ANYTHING
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BY MOUTH TO AN UNCONSCIOUS PERSON!
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..
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See additional PRECAUTIONARY STATEMENTS on .ide (or back) panel:':'
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Manufactured For
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RIVERSIDE/TERRA CORPORATION
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Terra Centre, 600 Fourth Street, Sioux City, Iowa SIIOI
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Riverside serves agriculture. Agriculture serves everyone.
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NET CONTENTS POUNDS
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.......
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!~i"' ')
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, .
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. J ' I
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'~'-;'~ '.- ~,-:;~)":'
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':--.:."
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de
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PRECAUTIONARY STATEMENTS
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CAUTION
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HAZARDS TO HUMANS AND DOMESTIC ANIMALS
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Harmful if swallowed, inhaled,
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breathe vapors or spray mist.
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clothing. Remove contaminated
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thoroughly with soap and water
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or absorbed throueh skin. Do not
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Avoid contact with eyes, skin or
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clothing and wash before reuse. Wash
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after handling.
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ENVIRONMENTAL HAZARDS
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This product is toxic to fish. Do not apply directly to lakes, streams,
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or ponds. DO NOT apply when weather conditions favor drift from target
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area. DO NOT contaminate water by cleaning of equipment or disposal
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of wastes.
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DIRECTIONS FOR USE
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It is a violation of Federal law to use this product in a manner inconsistent
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with its labeling.
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Do not app1y this product in such a manner as to directly or through drift
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expose workers or other persons. The area being treated must be vacated by
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unprotected persons.
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RE-ENTRY STATEMENT (FOR USE IN SWEET CORN IF HAND LABOR IS INVOLVED)
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Do not enter treated areas without protective clothing until sprays have dried.
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Protective clothing means, at least, a hat or other suitable head covering, a
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long-sleeved shirt and long-legged trou£ers or a coverall-type garment (all of
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closely woven fabric covering the body. including the arms and legs). imper
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meable gloves and boots. Because certain states may require more restrictive
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re-entry intervals for various crops treated with this product, consult your
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State Department of Agriculture for further information.
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• ...
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Written or oral warning~ must be given to workers who are expected to be tn a •••••• ••• • •• treated area or in an area about to be treated with this p~oduct. Wher? .q~~i • •
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warnings are given, warnings shall be given in a language customarily understood·:··:
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by workers. Oral warnings must be given if there is reason to believe.tha~ •• . . b b . . • ••••• • •••• written warnings cannot e understood y workers. Written warnings mu~t include. • .. . . .... the followlng lnformatlon: "CAUTION. Area treated with PROZINE on (d'tt~'(;i •
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application). Do not enter without appropriate protective clothing. 11 •••• • •••••
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• • •
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•• • • •• .. .
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•••• • • • .. .
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..
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• ••••• • • ••••
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,,:'_,,"-<";Z'
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. ~ ,;
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STORAGE AND DISPOSAL
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DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL.
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STORAGE
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Store in a dry location away from children, animals, foods, feeds,
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seeds, or other agricultural chemicals. Handle in accordance with
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information given under IIPrecautionary Statements. 1I In the event
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of spillage, scrape up spillage. If spillage is not suitable for
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use, dispose of in accordance with information given under
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"DISPOSAL." Repackage and relabel useable product in a sound
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container. In case of fire or other emergency, report at once by
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toll-free telephone to 800-424-9300.
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DISPOSAL
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Pesticide Disposal: Wastes resulting from the use of this product
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may be disposed of on site or at an approved waste disposal facility.
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Container Disposal: Triple rinse (or equivalent). Then offer for
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recycling or reconditioning, or puncture and dispose of in a sanitary
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landfill, or incineration, or, if allowed by state and local
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authorities, by burning. If burned, stay out of smoke.
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GENERAL INFORHATlON
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PROZINE controls many annual broad leaf and grass weeds in corn and sorghum.
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"""
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It may be applied before or after weeds emerge. The effectiveness of this pro
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duct depends on moisture to move it into the root zone. If weeds develop, a
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shallow cultivation or rotary hoeing will generally result in better weed
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control. Unusually cold, excessively wet, or hot and dry conditions that delay
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germination or extend ,germination over a long period of time can r€duce weed
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control.
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Seedling diseases, cold weather, excessive moisture, deep planting, low or high
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soil pH, high soil salt concentration, or drought can weaken seedlings au~.
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plants and increase the possibility of crop damage from this herbicide. Onder
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these conditions, crop yields can be reduced. : ••••
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••••
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I ,)
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•••••• • •• • • • ••••• • •• Application in Water or Liquid Fertilizer: Nitrogen solution or compl~te 1iquid ••
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fertilizer may replace all or part of the water as a carrier for preem4lUIl1:e o~·:··.
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corn. Check the compatibility of this product with liquid fertilizer and'~r ••••• , . .... nitrogen solution as shown below before use. Do not apply in nitrogen ~etbtiQn ••••••
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or complete liquid fertilizer after corn emerges. • ••••
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•• • • •• •• •
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•••• • •• •• •
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• ••••• • • •• ••
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... ,... .,-;:.1
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"
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-" To determine the compatibility of PROZINE with liquid fertilizer, pourthe pro
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duct into a small container of liquid fertilizer in the proportions shown below.
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For different spray volume or herbicide rate, make appropriate changes in the
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ingredients.
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For each pound of PROZINE to be applied per acre, add 1 level teaspoon of the
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product to one pint of liquid fertilizer (assuming a volume of 25 gallons per
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acre).
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After thorough mlx1ng, let stand ~ minutes. If the herbicide/fertilizer com
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bination remains mixed, or can be remixed readilYJ make a slurry with the her
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bicide before adding fertilizer and use the roixturl: only if this test shows it
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is compatible.
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ROTATIONAL CROPS: (1) Do not rotate to any crop except corn or sorghum until
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the following year, as injury may occur. (2) In the High Plains and :ntprmoun
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tain areas of the West where rainfall is sparse and erratic or where irrigation
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is required, use only when corn or sorghum is to follow corn or sorghum or when
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a crop of untreated corn or sorghum is to precede other rotational crops. (3)
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Injury may occur to soybeans planted in north-central and northwest Iowa, south
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central and southwest Minnesota, northeast Nebraska, southeast South Dakota, and
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other areas the year following application on soils having a calcareous surface
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layer. (4) In eastern parts of the Dakotas, Kansas, western ~innesota) and
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Nebraska, do not rotate to soybeans if the rate applied to corn sorghum was reore
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than 4 pounds per Acre (or equivalent band application rate) 0r soybean injury
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may occur. (5) Do not plant sugarb~~ts, tobacco, vegetables (including dry
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beans), spring-seeded small grains, or small-seeded legumes ar.d grasses the year
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following application as injury may occur.
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APPLICATION PROCEDURES
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GROUND APPLICATION: Use convel!t~onal ground sprayers equipped with .. "zzles that
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provide accurate and uniform application. Be certain that nozzles are uniformly
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spaced and are tha same size. Calibrate sprayer before use and recalibrate at
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the start of each season and when changing carriers. Unless otherwise spec
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ified, use a minimum of 10 gallons of spray mixture per acre for preemeq~ence
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and postemergence a9plications with ground equipment.
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Use a pump with capacity to (l) maintain 35-40 psi at nozzles, (2) provi,de
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sufficient agitation in tank to keep mixture in suspension, and (3) to p'r:5vide "
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minimum of 20% bypass at all times. Use centrifugal pumps which provit.le "pro- ...... : .. :
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peller shear action for dispersing and mixing this product. The pump ~\Mrid ••••••
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provide a minimum of 10 gallons per minute per 100 gallons tank size circ'ulated ••••
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through a correctly positioned sparger tube or jets. : ..... :.. ..": ...
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• Uae screens to protect the pump and to prevent nozzles from clcgging .•• ~<;,,~ens
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placed on the suction side of the pump should be l6-mesh or coarser. Do .not
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place a screen in the recirculation line. Use 50-mesh or coarser scre", .... be-
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.. .. .. . .
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........... .
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tween the pump and bOOlA, and where required, at" the nozzles. Check no"z.~l"e ... manu"-·: .... : .. " .. . factiJrer IS recommendatlons. .." ...
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AERIAL APPI.ICATION: Apply in a minim"l11 of 5 gall"ns
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application to humans) animals, or non-target areas.
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avc ... d inhalation of ~vr3y mist nnd prolongef~ contact
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thoroughly before eati~B and at the end of each day's
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of wC!ter per ncrt? Avoid
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Flagmen and loaders should
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with skin and should wash
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operation.
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-- "
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MIXING PROCEDURES -i;~,L USES: Be sure sprayer is cJ i1 and not contaminated '". ,) (
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with a~y other mate~ls, or :rop injury or sprayer'-'ogging may result. Fill
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tank! full with clean water J nitrogen solution, or complete liquid fertilizer.
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Start agitation. Be certain that the agitation system is working properly and
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creates ~ rippling or rolling action on the liquid surface. Pour product
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directly from container into tank. Let it wet and settle into solution.
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Continue filling tank until 90% full. lncrease agitation if necessary to main
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tain surface action. Finish filling tank. Maintain agitatton to avoid separa
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tion of materiale. Clean sprayer thoroughly immediately after use by flushing
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system with water containing a detergent.
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WEED SPECIES CONTROLLED
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CRASSES CONTROLLED
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Barnyardgrass (Echinochloa crus-galli)
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Crabgrass (Digitaria spp.)
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Crowfootgrass (Dactyloctenium aegyptium)
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Fall panicum (Panicum dichotomiflorum)
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Fiel1 sandbur (Cenchrus incertus)
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Foxtail (giant) (Setaria faberi)
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Foxtail «green) (Setaria viridis)
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Foxtail (yellow) (Setaria glauca)
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Goosegrass (Eleusine indica)
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Johnsongrass (from seed) (Sorghum halepense)
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Signalgrass (Brachiaria platyphylla)
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Texas panicum (Panicum texanum)
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Witchgrass (Panicum capillare)
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BROADLEAF WEEDS CONTROLLED
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Black nightshade (Solanum nigrum)
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Carpetweed (Mollugo verticil lata)
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Common ragweed (Ambrosia artemisiifolia)
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Florida pus ley (Richardia scabra)
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Kochia (Kochia scoparia)
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Lambsquarters (Ghenopo~ium album)
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Mustard (Brassica spp.)
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Pennsylvania smartweed (Polygonllm pensylvanicum)
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Pig"eed (Amaranthus spp.)
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Purslane (Portulaca oleracea)
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Spurge, annual (Euphorbia spp.)
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Velvetleaf (Buttonweed) (Abutilon theophrasti)
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Venice mallow (Hibiscus trionum)
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PROZINE will aid in the control and reduce competition from:
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Annual morningglory (Ipomoea spp.)
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Cocklebur (Xanthium strumarium)
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Groundcherry (Physalis spp.)
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Jimsonweed (Datura stramonium)
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Shattercane (Sorghulll bicolor)
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Wild oats (Avena fatua)
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Wild proso millet (Panicum miliaceum)
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.......
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\al
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CORN - FI ELD AND SliEET
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GENERAL INSTRUCTIONS
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Use only where adequate tillage is practiced to provide good soil coverage of
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the corn seed. Plant corn AT LEAST l~ inches deep to ensure good seed coverage.
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PROZINE is most effective in controlling weeds when adequate rainfall or over
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head irrigation is received within 7 days after application. If cultivation is
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necessary because of soil crusting, soil compaction or weed gerlnination before
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rain or irrigation, use shallow tillage (such as rotary hoe), and make certain
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corn seeds are below the tilled area. For maximum effectiveness, wait at least
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7 to 10 days before cultivating early postemergence treatments.
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Field Corn Grown In Minimum Tillage Systems
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PROZINE may be used in field corn in minimum tillage systems where adequate
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tillage is practiced to provide a seedbed without living vegetation and which
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allows for good seed coverage. Plant corn AT LEAST It inches deep to ensure
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good seed coverage. The use of no-till planters in minimum tillage corn under
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conditions which do not allow good soil coverage of the corn seed can result in
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reduced crop stand or injury if PROZINE contacts the germinating corn seed.
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Check equipment to ensure good seed coverage. Apply in 20 or more gallons of
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spray solution per acre.
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PREEMERGENCE (Surface Treatment After Planting)
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Apply PROZINE ~reemergence after planting, but before weeds or crop emerge.
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Apply in water or liquid fertilizer with ground equipment or in water with
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aircraft. Refer to section on application in water or liquid fertilizer for
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liquid fertilizer compatibility determinations. DO NOT INCORPORATE or serious
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corn injury will result.
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EARLY POSTEHERGENCE
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Apply PROZINE after corn emergence but no later than when corn is in the 4-leaf
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stage of gi~owth and when weeds are no more tl. ' I inch high J except for ~~>::as
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panicum w~nch must be no larger than the I to L leaf stage. Apply with g,'ound
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equipment or aircraft in water ONLY. For ground applications, flat fa~ Qot?les
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are preferred. DO NOT apply following PROWL preemergence treatment.
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R~STRICTIONS FOR EARLY POSTEMERGENCE APPLICATIONS . ,
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t , ,. t.~ t
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To avoid serious crop injury with early postemergence applications J obs'e-cv,,' the
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following restrictions:
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., .
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DO NOT INCORPORATE.
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DO N0T apply i" lilUid fertilizer.
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(0
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£ ~a
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\,C; BROADCAST RATE PER ACRE OF p( .INE Ii, F 1('
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Preemergence and Early Postemergence in Corn
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Less than 1. 5% 1.5 to 3.0% More than 3%
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Soil Texture Organic Hatter l Organic Hatter Organic Matter
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COARSE 2.5 to 3.0 Ibs. 3.0 Ibs. 4.25 Ibs.
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HEDIUH 3.0 Ibs. 4.2S lbs. 4.25 Ibs.
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FINE 3.0 Ibs. 4.25 lbs. 4.25 Ibs.
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IPROZINE may be applied in sweet corn in Illinois, l-iinnesota, Wisconsin, and
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New York only.
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NOTE: If corn crop loss occut·s due to weather conditions and corn is replanted,
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seeding depth must be below retilled area.
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NOTE FOR ALL APPLICATIONS TO CORN: DO NOT graze or feed forage from treated
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areas for 21 days following application.
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FIELD CORN AND GRAIN SORGHUH
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POSTEHERGENCE INCORPORATED APPLICATIONS
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GENERAL INFORHATION: Winter wheat and winter barley may be planted in the fall
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90 days after an application with PROZINE postemergence incorporated in irri
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gated field corn or grain sorghum or 120 days after an application in dry land
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field corn or grain sorghum. The treated crop must be grown to maturity and
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harvested be {ore planting wheat or barley. See GENERAL INFORHATION for comple.te
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rotational instructions.
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PROZINE applied as a postemergence incorporated treatment will control most late
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season annual grasses and certain broadleai weeds in field corn or grain
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sorghum. Treatments can be applied from the 4-inch growth stage to as late as
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the last cultivation (layby) of field co,n or grain sorghum. Treatments will
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not control established weeds. EHERGED WELDS HUST BE DESTROYED BY GULTI~ATION • PRIOR TO APPLICATION. • •• •• • ••••
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• ••••• • •• • •
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APPLICATION TECHNIQUES: The field must De cultivated and all emerged we~ds mu~~:":
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be destroyed prior to application. Cultivation should be accomplishe~.~itP a ••• ::
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sweep-type or rolling cultivator operated at sufficient speed to thro~ at least.: •• '
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ona inch of 80il over the base8 of the field corn or grain sorghum p14nt~~. This.
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will kiD. small weed seedlings growing in the field corn or grain sorg~um· row •••••• • •• and will prevent direct contact of the zone of brace root formati"n dU\ln~ ••
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application. •••••• ..: •• :
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•••• ••• • Apply with ground sprayer. Uniform soil coverage must be obtained. ~ •• p:
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nozzles should be used if field corn or grain sorghum foliage will prevent uni
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form coverage of the soil surface within the rows.
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(
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• must be thoroughly and uniformly incorporated into the soil (l) with
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8 sweep-type or rolling cultivator set to provide thorough incorporation in the
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top 1 inch of sailor (2) with adequate irrigation water or rainfall. For beat
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results, treatments should be incorporated as soon as possible after application
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but incorporation must be completed within 7 days after application. If ade
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quate moisture is not received within 7 days after application, PROZINE must be
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incorporat~d with a sweep-type or rolling cultivator.
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Under situations of-low rainfall or soil moisture) when deep germinating weeds
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such as shattercane or field sandbur are anticipated) mechanical incorporation
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will provide best results.
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If cultivation is needed after application and incorporation, the depth of cut
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should be no deeper than the depth of cut used to incorporate.
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DO NOT APPLY PROZINE in field corn or grain sorghum more than once per crop
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season.
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WEEDS CONTROLLED: When applied as directed, PROZIN~ will control shattercane
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(Sorghum bicolor) and wild proso millet (Panicum miliaceum) in addition to the
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WEED SPECIES CONTROLLED previously listed.
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ADDITIONAL HERBICIDE APPLICATIONS: Postemergence incorporated applications of
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PROZINE can be applied in field corn or grain sorghum previously treated with
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herbicides registered for use in field corn or grain sorghum. Consult the
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labels of those herbicides for suggested treatments, rates to be used, and pre
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cautions 0E restrictions for use in field corn or grain sorghum and for restric
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tions on following crops.
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FIELD CORN
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DO NOT APPLY PROZINE preplant incorporated in field corn as serious crop injury
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can result.
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o
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.. 0
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o
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• •• •• 0
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••••
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•
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o 0
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....... •
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· .. 000
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||
••••
|
||
• ...
|
||
• o. .. 0
|
||
•••• o ••
|
||
.. 0
|
||
•••••• • •• • •
|
||
• ••••• o •
|
||
'0
|
||
• •••• • • •••••
|
||
•
|
||
• ••••• • • ..
|
||
• •••••
|
||
• 0 ••••
|
||
|
||
!'ar
|
||
BROADCAST RATe PER ACRE
|
||
Soil Texture Southern States l Northern States l
|
||
COARSE 2.25 Ibs. 2.25 to 3.0 Ibs.
|
||
HEDIUH 2.5 to 3.0 Ibs. 3.25 to 4.25 Ibs.
|
||
FINE 2.5 to 4.25 1 bs. 3.25 to 4.25 Ibs.
|
||
ISee map below.
|
||
GRAIN SORGHUH
|
||
DO NOT APPLY in grain sorghum preplant incorporated or preemergence as sErious
|
||
crop injury can result.
|
||
DO NOT APPLY in grain sorghum which is planted in double row beds since this
|
||
cultural practice does not permit adequate soil coverage of the bases of the
|
||
grain sorghum plants with cultivation.
|
||
BROADCAST RATE PER ACRE
|
||
Soi 1 Texture Southern States l Northern States 1
|
||
COARSE DO NOT USE DO NOT USE
|
||
HEDlUH 2.5 to 3.0 lbs. 3.25 to 4.25 Ibs.
|
||
FINE 2.5 to 4.25 lb •• 3.25 to 4.25 lbs.
|
||
ISee map below.
|
||
NOTE: Observe all precautions) limitations, and cropping restrictions referred
|
||
to in GENERAL INFORMATION section. Livestock can graze or be fed forage from
|
||
treated grain sorghum fields 21 days following application.
|
||
• ••• •
|
||
REGIONAL MAP FOR RATE DETERMINATION • •• • • • ••••
|
||
•
|
||
• • •••••• •
|
||
• .. • • • ••••
|
||
• .. • • • • .. •
|
||
•••• • • • •• •
|
||
•••••• • • • • • • ••••• • • .. ... • • • •••••
|
||
• • ••••• • • ••
|
||
•••••• • • .. ••
|
||
|
||
,
|
||
j
|
||
,
|
||
•
|
||
Seller ~arrant8 that the product conforms to its chemical description
|
||
and is reasonably fit for the purposes stated on the label when used in accor
|
||
dane'! \lith directions under normal conditions of use, but neither this warranty
|
||
nor any other warranty of me~chantability or fitness for a particular purpose,
|
||
express or implied, extends to the use of this product contrary to label
|
||
instructions" or under abnormal conditions I or under conditions not reasonably
|
||
foreseeable to Seller, and Buyer assumes the risk of any such use.
|
||
• ... •
|
||
• .. • • • ••••
|
||
•
|
||
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|
||
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|
||
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|
||
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|
||
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|
||
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|
||
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|
||
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|
||
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|