a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
235 lines
14 KiB
Markdown
235 lines
14 KiB
Markdown
# SECURE II LIQUID STORED GRAIN INSECTICIDE
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- EPA Reg No: **264-994**
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- Registrant: BAYER CROPSCIENCE, LLC
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- Signal word: Caution
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- Active ingredients: Spinosad (23.21%)
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- Label accepted: 2009-11-10
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000264-00994-20091110.pdf
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---
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---- ------ --------
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, 1/ , 0 I ~ 00 G)
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
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WASHINGTON, D.C. 20460
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Mr. Larry R. Hodges
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Bayer CropScience LP
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2 T. W. Alexander Dr,
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NOV 1 a 2009
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Research Triangle Park, NC 27709
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OFFICE OF
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PREVENTION, PESTICIDES
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AND TOXIC SUBSTANCES
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Subject: Secure II Liquid Stored Grain Insecticide, EPA Reg. No. 264-994
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Date of Registrant Submission: July 17, 2009
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Decision: 419960
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Dear Mr. Hodges:
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The labeling referred to above, submitted in connection with registration under the
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Federal insecticide; Fungicide, and Rodenticide Act, as amended, is acceptable
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Two (2) copies of the finished labeling must be submitted prior to releasing the
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product for shipment. A stamped copy of the label is enclosed for your records. If you
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have any questions regarding this letter, please contact Samantha Hulkower at (703) 603-
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0683.
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Enclosure: Copy of Label Stamped "Accepted"
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1
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( (' 'AC(OEPTED ;;2.}\()
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S
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™ NOV 1 0 2009
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ECURE II Liquid ~~
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Stored Grain Insecticid~~fle:
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ACTIVE INGREDIENTS:
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Spinosad (CAS Number 131929-60-7) ............................................................................ 23.21%
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INERT INGREDIENTS .................................................................................................. 76.790/0
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TOTAL ..................................................................................................................... 100.000/0
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EPA Reg. No. 264-994 EPA Est.
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KEEP OUT OF REACH OF CHILDREN
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CAUTION
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FIRST AID
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IF IN EYES • Hold eye open and rinse slowly and gently with water for 15-20 minutes.
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• Remove contact lenses, if present, after the first 5 minutes, then continue rinsing.
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• Call a poison control center or doctor for treatment advice.
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Have the product container or label with you when calling a poison control center or doctor, or going for
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treatment. In case of emergency call toll free the Bayer CropScience Emergency Response Telephone No.
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1-800-334-7577. Have a product container or label with you when calling a poison control center or doctor,
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or going for treatment.
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PRECAUTIONARY STATEMENTS
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HAZARDS TO HUMANS AND DOMESTIC ANIMALS
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CAUTION
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Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling
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and before eating, drinking, chewing gum, or using tobacco.
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PERSONAL PROTECTIVE EQUIPMENT (PPE):
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Applicators and other handlers must wear: long-sleeved shirt and long pants, chemical-resistant gloves made of any
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waterproof material, and shoes plus socks and protective .eyewear. Follow manufacturer's instructions for cleaning I
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maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from
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other laundry.
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USER SAFETY RECOMMENDATIONS
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Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using
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tobacco.
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, Page 1 of 5
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( (
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ENVIRONMENTAL HAZARDS
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This product is highly toxic to mollusks. Do not contaminate water when disposing of equipment washwaters or rinsate.
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DIRECTIONS FOR USE
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It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
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STORAGE AND DISPOSAL
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Do not contaminate water, food or feed by storage or disposal.
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PESTICIDE STORAGE: Store in original container only. In case of leak or spill, contain material with absorbent materials
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and dispose of as waste.
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PESTICIDE DISPOSAL: Wastes resulting from the use of this product may be disposed of on site according to label use
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directions or at an approved waste disposal facility.
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CONTAINER HANDLING: Rigid, Non refillable containers small enough to shake (i.e. with'capacities less than 5 gallons).
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Non-refillable container. Do not reuse
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or refill this container. Clean container promptly after emptying. Triple rinse container (or equivalent) promptly after
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emptying. Triple
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rinse as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the
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flow begins
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to drip. Fill the container 1/4 full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a
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mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure
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two more times. Once container is rinsed, offer for recycling if available or puncture and dispose of in a sanitary landfill or
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by incineration.
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Rigid Non-refillable containers that are too large to shake (i.e., with capacities greater than 5 gallons or 50 Ibs).
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Non-refillable container. Do not reuse or refill this container. Refer to Bottom Discharge IBC or Top Discharge lBe,
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Drums, Kegs information as follows.
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Bottom Discharge IBC (e.g. - Schuetz Caged IBC or Snyder Square Stackable)
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Pressure rinsing the container before final disposal is the responsibility of the person disposing of the container. To
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pressure rinse the container before final disposal, empty the remaining contents from the IBC into application equipment
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or mix tank. Raise the bottom of
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the IBC by 1.5 inches on the side which is opposite of the bottom discharge valve to promote more complete product
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removal. Completely remove the top lid of the IBC. Use water pressurized to at least 40 PSI to rinse all interior portions.
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Continuously pump or drain rinsate into application equipment or rinsate collection system while pressure rinsing.
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Continue pressure rinsing for 2 minutes or until rinsate becomes clear. Replace the lid and close bottom valve.
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Top Discharge IBC, Drums, Kegs (e.g.- Snyder 120 Next Gen, Bonar B120, Drums, Kegs).
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Triple rinsing the container before final disposal is the responsibility of the person disposing of the container. To triple
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rinse the container before final disposal, empty the remaining contents from this container into application equipment or
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mix tank. Fill the container at least 10 percent full with water. Agitate vigorously or recirculate water with the pump for 2
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minutes. Rinse all interior surfaces. Pour or pump rinsate into application equipment or rinsate collection system. Repeat
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this procedure two more times.
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Once container is rinsed, offer for recycling if available or puncture and dispose of in a sani~ary landfill or by incineration.
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SECURE II is a 2 Ib/gallon SC formulation that can be used to protect stored grains and other commodities from insect
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damage at an active ingredient concentration of 1 ppm by weight.
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Page 2 of5
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( (
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PRODUCT INFORMATION
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STORED GRAIN: For protection of the listed stored food, feed and oil grain commodities against injury from insect pests
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including, but not limited to, lesser grain borer, indian meal moth, angoumois grain moth, Texas rice moth, almond moth,
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confused flour beetle, and flat grain beetle. Additional pests such as rice weevil, granary weevil, maize weevil, red-flour
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beetle, sawtoothed grain beetle, and rusty grain beetle are suppressed to low levels. Protection is achieved by breaking
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the pest life cycle through control of adults and/or immature life stages. .
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For optimum results, thoroughly clean and treat grain storage areas prior to storage of grain. If grain is insect infested,
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fumigate with a registered insecticide to control existing populations and apply SECURETM II Liquid Stored Grain
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Insecticide for residual protection.
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STORED SEED: For the protection of stored seed against injury from the stored grain insects listed above. For optimum
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results, thoroughly clean and treat seed storage areas prior to storage of seed. If seed is insect infested, fumigate to
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control existing populations and apply SECURETM II Liquid Stored Grain Insecticide for residual protection.
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SECURETM II Liquid Stored Grain Insecticide may also be used in conjunction with registered fungicides or other.
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insecticide seed protectants. Seed treated with SECURE II Liquid Stored Grain Insecticide alone, is considered food
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quality grain. Seed treated with other seed protectant products may be required to be colored and tagged. Requirements
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for coloring and tagging can be found on the product labels.
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Application Rates:
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For Crops Typically Treated per 1,000 Bushels, See the Following Table:
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SECURETM II Liquid
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per 1,000 bushels·
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(to deliver 1 ppm)
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Target Crop floz ml
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Barley 3 89
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Bird seed See rate/ton** See rate/ton**
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Corn(field, sweet, pop, grown for seed) 3.6
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Millet, foxtail 3.2
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Millet, pearl 2.2
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Millet, proso 3.6
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J
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Oats 2.2
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Rice 2.9
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Sorghum/Milo 3.6
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Triticale 3.8
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Wheat 3.8
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*Apphcatlon rates are based on nominal commodity test weight.
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**Ton = U.S. ton (2,000 Ibs.)
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106
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95
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65
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106
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65
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86
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106
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112
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11
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Specific Use Directions: Dilute SECURpM II Liquid Stored Grain Insecticide with water and mix thoroughly and
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occasionally agitate. Apply as a course spray to the moving grain to give a deposit of the desired concentration treating
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the entire grain mass. Apply 5 gallons of spray mixture per 1,000 bushels of grain, for all grain listed above except rice.
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For rice apply 10 gallons of spray mixture per 1,000 bushels due to the absorbant grain coat.
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Application per Ton of Grain or Seed: For crops typically treated per metric tonne (2,200 Ib), such as grain for export,
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apply 0.14 fl oz or 4.1 milliliters per metric tonne to deliver 1 ppm of active ingredient.
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For crops typically treated per ton (2,000 Ib), i.e., bird seed or any crop listed in the table above, apply 0.13 fI oz or 3.8
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milliliters per ton to deliver 1 ppm of active ingredient.
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Top Dressing Treatments: These treatments are not as effective as treating the full grain column, but they can provide·
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significant protection from some insects such as indian meal moth. For each 1,000 sq ft of surface, mix 1.0 fl oz of
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SECURE II Liquid grain Insecticide in 2.0 gallons of water. Apply one-half of the total application amount evenly across
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the surface and then rake to a depth of at least 4 inches. Complete the treatment by applying the remaining half to the
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surface and leave undisturbed.
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Page 3 of5
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( (
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RECOMMENDATIONS and RESTRICTIONS:
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• International tolerances and residue limits for crops and commodities treated with this product may not yet be
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established in one or more countries outside the United States. For this reason, this product should be used only on
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crops and commodities intended for consumption in the United States or on crops and commodities that will be
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imported to a country(ies) where you have confirmed the specific import residue policies and applicable residue limits
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permit such import.
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• Avoid application at extremely dusty sites.
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• When drying grain, apply SECURETM II Liquid Stored Grain Insecticide after the grain has cooled.
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• Do not treat grain more than once.
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• Maintain accurate records, especially if commodity is destined for export.
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• Calibrate application equipment and grain flow rates daily and when significant changes occur to ensure proper
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application rates. ..
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• Always start with clean storage bins that have been treated with a protectant with a different mode of action.
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• For resistance management, rotate chemical modes of action each year.
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• No withholding period is required for grain used for food, feed or oil purposes.
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• Always shake the container well before mixing to suspend product that may have settled during storage.
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Note: Refer to the Environmental Hazards section of the product label attached to the product container for required
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protective measures.
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Page 4 of 5
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(.i
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IMPORTANT: READ BEFORE USE
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Read the entire Directions for Use, Conditions, Disclaimer of Warranties and Limitations of Liability before using this
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product. If terms are not acceptable, return the unopened product container at once.
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By using this product, user or buyer accepts the following Conditions, disclaimer of Warranties and Limitations of Liability.
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Treatment of highly mechanically damaged seed, or seed of known low vigor and poor quality, may result in reduced
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germination andlor reduction of seed and seedling vigor. Treat and conduct germination tests on a small portion of seed
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before committing the total seed lot to a selected chemical treatment. Due to seed quality conditions beyond the control of
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Bayer CropScience, no claims are made to guarantee germination of carry-over seed.
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CONDITIONS: The directions for use of this product are believed to be adequate and must be followed carefully. However,
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it is impossible to eliminate all risks associated with the use of this product. Crop injury, ineffectiveness or other unintended
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consequen~s may result because of such factors as weather conditions, presence of other materials, or the fTlanner of
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use or application, all of which are beyond the control of Bayer CropScience. All such risks shall be assumed by the user
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or buyer.
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DISCLAIMER OF WARRANTIES: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BAYER CROPSCIENCE
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MAKES NO WARRANTIES, EXPRESS OR IMPLIED, OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR
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PURPOSE OR OTHERWISE, THAT EXTEND BEYOND THE STATEMENTS MADE ON THIS LABEL. No agent of Bayer
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CropScience is authorized to make any warranties beyond those contained herein or to modify the warranties contained
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herein. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BAYER CROPSCIENCE DISCLAIMS ANY LIABILITY
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WHATSOEVER FOR SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES RESULTING FROM THE USE OR
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HANDLING OF THIS PRODUCT.
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LIMITATIONS OF LIABILITY: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, THE EXCLUSIVE REMEDY
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OF THE USER OR BUYER FOR ANY AND ALL LOSSES, INJURIES OR DAMAGES RESULTING FROM THE USE OR
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HANDLING OF THIS PRODUCT, WHETHER IN CONTRACT, WARRANTY, TORT, NEGLIGENCE, STRICT LIABILITY
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OR OTHERWISE, SHALL NOT EXCEED THE PURCHASE PRICE PAID, OR AT BAYER CROPSCIENCE'S ELECTION,
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THE REPLACEMNT OF PRODUCT.
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NOTICE TO BUYER
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Purchase of this material does not confer any rights under patents governing this product or the use thereof in countries
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outside of the United States.
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NET CONTENTS:
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SECURE is a trademark of Bayer CropScience
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Produced for
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EI'. BayerCropScience
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Bayer CropScience LP
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P.O. Box 12014, 2 T.W. Alexander Drive
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Research Triangle Park, North Carolina 27709
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1-866-99BAYER (1-866-992-2937)
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Secure" Liquid Stored Grain Insecticide (PENDING) 06/30109, resubmitted 11/10/09
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Page 5 of 5
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