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crop-chem-docs/corpus/epa_ppls/7969-387.md
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# CHARTER PB FUNGICIDE SEED TREATMENT
- EPA Reg No: **7969-387**
- Registrant: BASF AGRICULTURAL SOLUTIONS US, LLC
- Signal word: Warning
- Active ingredients: Thiram (12.5%); Triticonazole (1.25%)
- Label accepted: 2010-06-14
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/007969-00387-20100614.pdf
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:~
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
WASHINGTON, D.C. 20460
Edward Jordan
BASF Corporation
26 Davis Drive
Research Triangle Park, NC 27709
Subject Charter PB Fungicide Seed Treatment
EPA Reg. No. 7969-387
Amendment dated: March 5, 2010
EPA Decision No. 430167
Dear Mr. Jordan,
OFFICE OF
PREVENTION, PESTICIDES
AND TOXIC SUBSTANCES
JUN 1 4 20'0
The amended label referred to above, submitted in connection with registration under the
Federal, Insecticide, Fungicide, and Rodenticide Act as amended is acceptable provided the
following changes are made.
On page 3,
1. Within the Storage and Disposal box, change the heading Container Disposal to
Container Handling.
2. Add the following sentence to the end of the Container Handling - Nonrefillable
container text. "If burned, stay out of smoke."
On page 4,
3. Within the Storage and Disposal box, change the heading Container Disposal to
Container Handling.
4. Change the heading "General Information" to "Product Information"
On page 6,
5. Within the second paragraph under the heading "Method of Application", in the first
sentence change "should" to "must".
Charter PB Fungicide Seed Treatment
EPA Reg. No. 7969-387
Page 2 of2
One copy of the label stamped "Accepted with Comments" is enclosed for your records. This
label supersedes all labels previously accepted for this product. Please submit one copy of the
final printed label that incorporates the required changes before the product is released for
shipment. Should you have any further questions, please feel free to contact Shaunta Hill via
email at hill.shaunta@epa.gov or telephone at 703.347-8961.
Enclosure:
Label stamped Accepted with Comments
Sinc~ t.~ .
Erik Kraft ~
Acting Product Manager (20)
Fungicide Branch
Registration Division (7504P)
-
-BASF
The Chemical Company
ACQ."'PTJU)
with COMMEs.'ITS
in EPA Letter Dated
JUN 1 4 2010
UDI!er the FC!deraI ~
Ftmdleide, and B~~
WI tlJDeuderl, C(dO Ghe pcedek;e
!'egiQ¢ereU mad,~ at~ ~oNo.
_, ......... -.:-".:~_~ 19 -.3 g 7
FUNGICIDE SEED TREATMENT
A liquid flowable for control of various seedborne diseases in
barley, oats, rye, triticale, and wheat
Active Ingredients*:
triticonazole .' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.25%
thiram ................................. '. . . . . . . . . . . . . . . . . . . . . .. 12.50%
Other Ingredients: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 86.25%
Total: ........................................................ 100.00%
'Contains 0.12 Ib of the active ingredient triticonazole and 1.21bs of the active ingredient thiram
per U.S. galion.
EPA Reg. No. 7969-387 EPA Est. No.
KEEP OUT OF REACH OF CHILDREN
WARNING/AVISO
Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en
detalle. (If you do not understand this label, find someone to explain it to you in detail.)
See inside for complete First Aid, Precautionary Statements, Directions For Use,
and Conditions of Sale and Warranty.
In case of an emergency endangering life or property involving this product,
call day or night 1-800-832-HELP (4357).
Net Contents:
BASF Corporation
26 Davis Drive, Research Triangle Park, NC 27709
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FIRST AID
• Move person to fresh air.
If inhaled • If person is not breathing, call 911 or an ambulance; then give artificial respiration, preferably
mouth to mouth if possible.
• Call a poison control center or doctor for further treatment advice.
• Immediately call a poison control center or doctor for treatment advice.
• DO NOT induce vomiting unless told to do so by a poison control center or docto~.: : . If swallowed • Have a person sip a glass of water if able to swallow.
• DO NOT give anything by mouth to an unconscious person. .,
• Take off contaminated clothing.
If on skin or clothing • Rinse skin immediately with plenty of water for 15 to 20 minutes.
• Call a poison control center or doctor for treatment advice.
• Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes.
If in eyes • Remove contact lenses, if present, after the first 5 minutes; then continue rinsing.
• Call a poison control center or doctor for treatment advice.
HOTLINE NUMBER
NOTE TO PHYSICIAN: No specific antidote is available. Treat symptomatically. Consumption of alcoholic beverages
increases the toxic effects of thiram. Have the product container or label with you when calling a poison control center or
doctor or going for treatment. You may also contact BASF Corporation for emergency medical treatment information at
1-800-832-HELP (4357).
Precautionary Statements
Hazards to Humans and Domestic Animals
WARNING. May be fatal if inhaled. Harmful if swallowed.
Harmful if absorbed through skin. Causes moderate eye
irritation. DO NOT breathe vapor or spray mist. Avoid con­
tact with eyes, skin, or clothing. Wash thoroughly with soap
and water after handling and before eating, drinking, chew­
ing gum, using tobacco, or the toilet. Wear dusVmist
filtering respirator (MSHNNIOSH approval number prefix
TC-21C) or a NIOSH-approved respirator with any N, R, P,
or HE filter, long-sleeved shirt, long pants, shoes, socks
and chemical-resistant gloves (barrier laminate, butyl rub­
ber, nitrile rubber, polyvinyl chloride, viton, selection
Category C). Prolonged or frequently repeated skin con­
tact may cause allergic reaction in some individuals.
User Safety Requirements
Follow the manufacturer's instructions for cleaning/main­
taining PPE. If no such instructions for washables exist, use
detergent and hot water. Keep and wash PPE separately
from other laundry.
Personal Protective Equipment (PPE)
Some materials that are chemically resistant to this product
are barrier laminate, butyl rubber> 14 mils, nitrile rubber
> 14 mils, neoprene rubber> 14 mils, polyvinyl chloride
(PVC) > 14 mils, viton > 14 mils. If you want more options,
follow the instructions for Category C on an EPA
chemical-resistance category selection chart.
2
All mixers, loaders, applicators, and other handlers
must wear:
• DusVmist filtering respirator (MSHNNIOSH approval
number prefix TC-21 C) or a NIOSH-approved respirator
with any N, R, P, or HE filter
• Long-sleeved shirt and long pants
• Shoes plus socks
• Chemical-resistant gloves
• Chemical-resistant apron when mixing, loading, cleaning
up spills, or cleaning equipment, or otherwise exposed to
the concentrate
USER SAFETY RECOMMENDATIONS
Users should:
• Wash hands before eating, drinking, chewing gum,
using tobacco or using the toilet.
• Remove clothing/PPE immediately if pesticide gets
inside. Then wash thoroughly and put on clean clothing.
• Remove PPE immediately after handling this product.
Wash the outside of gloves before removing. As soon as
possible, wash thoroughly and change into clean
clothing.
Endangered Species
This bag contains seed treated with thiram. This product
may have effects on federally listed threatened or endan­
gered species or their critical habitat in some counties. It is
a violation of federal law to kill, harm, or harass listed ani­
mal species without authorization. To limit the potential for
such impacts when using this product, consult and follow
the instructions provided in the EPA Endangered Species
Bulletin for the county or parish in which you are applying
the seed. To determine whether your county or parish has
a bulletin, consult http://www.epa.gov/espp before each
season's use of this product.
)
Environmental Hazards
This chemical is toxic to fish, aquatic invertebrates, oysters,
and shrimp. DO NOT apply directly to water, or to areas
where surface water is present, or to intertidal areas below
the mean high water mark. Drift and runoff from treated
areas may be hazardous to aquatic organisms in neighbor­
ing areas. DO NOT contaminate water when cleaning
equipment or disposing of equipment washwater or
rinsate.
Treated seeds are hazardous to fish, birds and mammals.
DO NOT plant treated seeds by broadcasting to the soil
surface. Ensure that all seeds are thoroughly covered with
soil, especially in turn areas. If seeds are not thoroughly
incorporated by the planter during planting, additional
incorporation may be required to thoroughly cover exposed
seeds.
Treated seed exposed on soil surface may be hazardous to
wildlife. Cover or collect treated seeds spilled during load­
ing and planting. Dispose of all excess treated seed by
burying seed away from bodies of water.
Directions For Use
It is a violation of federal law to use this product in a man­
ner inconsistent with its labeling.
Read entire label before using this product.
DO NOT apply this product in a way that will contact work­
ers or other persons, either directly or through drift. Only
protected handlers may be in the area during application.
For any requirements specific to your state or tribe, consult
the agency responsible for pesticide regulation.
3
AGRICULTURAL USE REQUIREMENTS
Use this product only in accordance with its labeling and
with the Worker Protection Standard, 40 CFR part 170.
This standard contains requirements for the protection of
agricultural workers on farms, forests, nurseries, and
greenhouses, and handlers of agricultural pesticides. It
contains requirements for training, decontamination, noti­
fication, and emergency assistance. It also contains
specific instructions and exceptions pertaining to the
statements on this label about personal protective equip­
ment (PPE) and restricted-entry intervals. The
requirements in this box only apply to uses of this product
that are covered by the Worker Protection Standard.
After the seeds have been planted, DO NOT enter or
allow worker entry into treated areas during the
restricted-entry interval (REI) of 24 hours.
EXCEPTION: Once the seeds are planted in soil or other
planting media, the Worker Protection Standard allows
workers to enter the treated area without restriction if
there will be no worker contact with the seeds.
PPE required for early entry to treated areas permitted
under the Worker Protection Standard and that involves
contact with anything that has been treated, such as
plants, soil, or water, is:
• Coveralls
• Shoes plus socks
• Chemical-resistant gloves made of waterproof material
• Protective eyewear
STORAGE AND DISPOSAL
DO NOT contaminate water, food, or feed by storage or
disposal.
Pesticide Storage
Store in original container. Keep container closed and in a
secure place. Store in an area that is out of reach of chil­
dren and animals, away from food, feedstuffs, fertilizers
and seed. Protect from frost and freezing.
Pesticide Disposal
Wastes resulting from the use of this product may be dis­
posed of on-site or at an approved waste disposal facility.
Container Disposal
Nonrefillable Container. DO NOT reuse or refill this
container. Triple rinse or pressure rinse container (or
equivalent) promptly after emptying; then offer for recy­
cling, if available, or reconditioning, if appropriate, or
puncture and dispose of in a sanitary landfill, or by incin­
eration, or by other procedures approved by state and
local authorities.
(continued)
5
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)
STORAGE AND DISPOSAL (continued)
Container Disposal (continued)
Triple rinse containers small enough to shake
(capacity ~ 5 gallons) as follows: Empty the remaining
contents into application equipment or a mix tank and
drain for 10 seconds after the flow begins to drip. Fill the
container 1/4 full with water and recap. Shake for 10 sec­
onds. Pour rinsate into application equipment or a mix
tank, or store rinsate for later use or disposal. Drain for
10 seconds after the flow begins to drip. Repeat this pro­
cedure two more times.
Triple rinse containers too large to shake
(capacity> 5 gallons) as follows: Empty'the remaining
contents into application equipment or a mix tank. Fill the
container 1/4 full with water. Replace and tighten clo­
sures. Tip container on its side and roll it back and forth,
ensuring at least one complete revolution, for 30 sec­
onds. Stand the container on its end and tip it back and
forth several times. Turn the container over onto its other
end and tip it back and forth several times. Empty the rin­
sate into application equipment or a mix tank, or store
rinsate for later use or disposal. Repeat this procedure
two more times.
Pressure rinse as follows: Empty the remaining
contents into application equipment or mix tank and con­
tinue to drain for 10 seconds after the flow begins to drip.
Hold container upside down over application equipment
or mix tank, or collect rinsate for later use or disposal.
Insert pressure rinsing nozzle in the side of the container
and rinse at about 40 PSI for at least 30 seconds. Drain
for 10 seconds after the flow begins to drip.
Refillable Container. Refill this container with
Charter'" PB fungicide seed treatment only. DO NOT
reuse this container for any other purpose. Triple rinsing
the container before final disposal is the responsibility of
the person disposing of the container. Cleaning before
refilling is the responsibility of the retiller.
Triple rinse as follows: To clean the container before
final disposal, empty the remaining contents from this
container into application equipment or mix tank. Fill the
container about 10% full with water. Agitate vigorously or
recirculate water with the pump for 2 minutes. Pour or
pump rinsate into application equipment or rinsate collec­
tion system. Repeat this rinsing procedure two more
times.
Returnable Containers. After use, return cleaned con­
tainer to point of purchase or designated locations.
DO NOT reuse container for any other purpose. Refill
only with Charter'" PB fungicide seed treatment. For
information on the disposal of unused or unwanted
product, contact your State Pesticide or Environmental
Control Agency, or the Hazardous Waste representative
at the nearest EPA regional office for guidance.
4
In Case of Spill
In case of large-scale spillage regarding this product, call:
• CHEMTREC 1-800-424-9300
• BASF Corporation . 1-800-832-HELP (4357)
General Information
Charter PB is a liquid seed treatment used for control or
suppression of certain seed borne and soilborne diseases
of barley, oats, rye, triticale, and wheat. Charter PB will
increase emergence and plant stands by controlling or
suppressing these diseases.
When handling Charter PB and when treating seed or
while augering or handling treated seed, work in a
well-ventilated area . .
See the following table for diseases controlled or
suppressed by Charter PB.
Charte~ PB fungicide seed treatment Crop-specific Instructions
Crop Dise~se Con'ro\led Di~ease Suppres=;;ed1 Product Use Rate
.(t1 ozs/100 Ibs seed)
Barley Covered smut Common root rot 5.5
Ustilago hordei Coch/iobo/us spp.
False loose smut Dry seed decay
Usti/ago nigra Penicil/ium spp.
Fusarium seedling blight Fusarium crown rot
Fusarium spp. Fusarium spp.
Fusarium seed rot Fusarium root rot
Fusarium spp. Fusarium spp.
True loose smut pythium damping-off
Usti/ago nuda Pythium spp.
Rhizoctonia root rot
Rhizoctonia so/ani
Oats Covered smut Common root rot 5.5
Ustilago kol/eri Coch/iobo/us spp.
Fusarium seedling blight Fusarium crown rot and root rot
Fusarium spp. Fusarium spp.
Fusarium seed rot pythium damping-off
Fusarium spp. Pythium spp.
Loose smut
Usti/ago avenae
Rye Common bunt Common root rot 5.5
Til/etia caries Cochliobo/us spp.
Fusarium seedling blight Fusarium crown rot and root rot
Fusarium spp. Fusarium spp.
Fusarium seed rot Pythium damping-off
Fusarium spp. Pythium spp.
Triticale Common bunt Common root rot 5.5
and Til/etia caries Coch/iobo/us spp.
Wheat Flag smut Dry seed decay
Urocystis agropyri Penicillium spp.
Fusarium seed rot Fusarium crown rot
Fusarium spp. Fusarium spp.
Fusarium seedling blight Fusarium root rot
Fusarium spp. Fusarium spp.
Loose smut Pythium damping-off
Ustilago nuda var. tritici Pythium spp.
Rhizoctonia root rot
Rhizoctonia solani
1 Suppression is defined as suboptimal control which is still of commercial benefit.
5
Method of Application
Seed should be well conditioned and free of chaff before
treating with CharterG' PB fungicide seed treatment.
Treated seed should not require drying after treatment and
can be stored or bagged immediately (provided excessive
slurry volumes are not applied to the seed). Charter PB
may be applied using standard commercial seed treatment
equipment (such as, but not limited to, slurry or mist-type
equipment) or on-farm seed treatment equipment.
Charter PB may also be used in on-the-go type air seeder
treatment systems.
Charter PB should be applied to barley, oats, rye, triticale,
and wheat at the rate of 5.5 f1 ozs of product per
100 pounds of seed. Thorough seed coverage and proper
application equipment calibration is essential for good dis­
ease control. To achieve thorough coverage, Charter PB
may be diluted with water, if needed, into a slurry. Direct
application into a planter box is prohibited.
Use Restrictions
• DO NOT use treated seed for food, feed, or oil
processing.
• Store treated seed away from food and feedstuff.
• DO NOT contaminate feed or foodstuff.
• DO NOT contaminate bodies of water when disposing of
planting equipment washwater.
• DO NOT plant any crop not listed on this label within
30 days after planting Charter PB-treated seed.
• Plant barley, oats, rye, triticale, and wheat seed a mini­
mum of 1-inch deep.
• DO NOT use the same auger for treating seed that will
handle commercial or feed grains.
• DO NOT store leftover seed where there is a chance of it
becoming mixed with untreated seed. Store treated seed
in cool, dry conditions.
SEEDS THAT ARE TREATED WITH THIS PRODUCT
AND ARE THEN PACKAGED OR BAGGED FOR
FUTURE USE MUST CONTAIN THE FOLLOWING
LABELING ON THE OUTSIDE OF THE SEED BAG.
"This seed has been treated with Charte .... PB fungicide
seed treatment containing triticonazole and thiram.
Persons opening this bag or loading/pouring the treated
seed must wear long-sleeved shirt, long pants, shoes,
socks, and chemical-resistant gloves.
• DO NOT use for food, feed or oil processing.
• DO NOT allow children, pets or livestock to have access
to treated seeds.
• Treated seeds exposed on soil surface may be hazardous
to wildlife. Cover or collect treated seeds spilled during
loading and planting.
• Dispose of all excess treated seed by burying seed away
from bodies of water.
• Dispose of seed packaging or containers in accordance
with local requirements.
6
• DO NOT plant any crop other than barley, oats, rye,
triticale, or wheat within 30 days of planting Charter PB­
treated seed.
After the seeds have been planted, DO NOT enter or allow
worker entry into treated area during the restricted-entry
interval (REI) of 24 hours.
EXCEPTION: Once the seeds are planted in soil or other
planting media, the Worker Protection Standard allows
workers to enter the treated area without restriction if there
will be no worker contact with the seeds.
Treated seeds are hazardous to fish, birds, and mammals.
DO NOT plant treated seed by broadcasting to the soil
surface. Ensure that all planted seeds are thoroughly
incorporated by the planter during planting, additional
incorporation may be required to thoroughly cover exposed
seeds. DO NOT apply to water, to areas where surface
water is present, or to intertidal areas below the mean high
water mark. DO NOT contaminate water when disposing
of equipment washwater or rinsate or by disposal of
wastes.
This bag contains seed treated with triticonazole and
thiram. This product may have effects on federally listed
threatened or endangered species or their critical habitat in
some counties. It is a violation of federal law to kill, harm or
harass listed animal species without authorization. To limit
the potential for such impacts when using this product,
consult and follow the instructions provided in the EPA
Endangered Species Bulletin for the county or parish in
which you are applying the seed. To determine whether
your county or parish has a bulletin, consult
http://www.epa.gov/espp before each season's use of this
product."
Conditions of Sale and Warranty
The Directions For Use of this product reflect the
opinion of experts based on field use and tests. The
directions are believed to be reliable and must be
followed carefully. However, it is impossible to eliminate all
risks inherently associated with the use of this product.
Crop injury, ineffectiveness or other unintended
consequences may result because of such factors as the
presence of other or untested or unapproved materials,
seed of low quality or low vigor or low germination, use of
the product in a manner inconsistent with its labeling,
misapplication of the product, or weather conditions at
planting or environmental conditions during seed storage,
all of which are beyond the control of BASF
CORPORATION ("BASF") or the Seller. To the extent
consistent with applicable law, all such risks shall be
assumed by the Buyer.
BASF warrants that this product conforms to the
chemical description on the label and is reasonably fit for
the purposes referred to in the Directions For Use,
subject to the inherent risks, referred to above.
TO THE EXTENT CONSISTENT WITH APPLICABLE
LAW, BASF MAKES NO OTHER EXPRESS OR
IMPLIED WARRANTY OF FITNESS OR
MERCHANTABILITY OR ANY OTHER EXPRESS OR
IMPLIED WARRANTY.
TO THE EXTENT CONSISTENT WITH APPLICABLE
LAW, BUYER'S EXCLUSIVE REMEDY AND BASF'S
EXCLUSIVE LIABILITY, WHETHER IN CONTRACT,
TORT, NEGLIGENCE, STRICT LIABILITY, OR
OTHERWISE, SHALL BE LIMITED TO REPAYMENT
OF THE PURCHASE PRICE OF THE PRODUCT.
TO THE EXTENT CONSISTENT WITH APPLICABLE
LAW, BASF AND THE SELLER DISCLAIM ANY
LIABILITY FOR CONSEQUENTIAL, EXEMPLARY,
SPECIAL OR INDIRECT DAMAGES RESULTING
FROM THE USE OR HANDLING OF THIS PRODUCT.
BASF and the Seller offer this product, and the Buyer and
User accept it, subject to the foregoing Conditions of
Sale and Warranty which may be varied only by
agreement in writing signed by a duly authorized
representative of BASF. ST1108
7
Charter is a registered trademark of BASF.
© 2010 BASF Corporation
All rights reserved.
007969-00387.201 00304.NVA 2010-04-277-0008
Supersedes: NVA 2009-04-277 -0161
BASF Corporation
26 Davis Drive
Research Triangle Park, NC 27709
mBASF
The Chemical Company
q
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