a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
530 lines
23 KiB
Markdown
530 lines
23 KiB
Markdown
# CHARTER PB FUNGICIDE SEED TREATMENT
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- EPA Reg No: **7969-387**
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- Registrant: BASF AGRICULTURAL SOLUTIONS US, LLC
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- Signal word: Warning
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- Active ingredients: Thiram (12.5%); Triticonazole (1.25%)
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- Label accepted: 2010-06-14
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/007969-00387-20100614.pdf
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---
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:~
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
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WASHINGTON, D.C. 20460
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Edward Jordan
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BASF Corporation
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26 Davis Drive
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Research Triangle Park, NC 27709
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Subject Charter PB Fungicide Seed Treatment
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EPA Reg. No. 7969-387
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Amendment dated: March 5, 2010
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EPA Decision No. 430167
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Dear Mr. Jordan,
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OFFICE OF
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PREVENTION, PESTICIDES
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AND TOXIC SUBSTANCES
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JUN 1 4 20'0
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The amended label referred to above, submitted in connection with registration under the
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Federal, Insecticide, Fungicide, and Rodenticide Act as amended is acceptable provided the
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following changes are made.
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On page 3,
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1. Within the Storage and Disposal box, change the heading Container Disposal to
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Container Handling.
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2. Add the following sentence to the end of the Container Handling - Nonrefillable
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container text. "If burned, stay out of smoke."
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On page 4,
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3. Within the Storage and Disposal box, change the heading Container Disposal to
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Container Handling.
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4. Change the heading "General Information" to "Product Information"
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On page 6,
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5. Within the second paragraph under the heading "Method of Application", in the first
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sentence change "should" to "must".
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Charter PB Fungicide Seed Treatment
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EPA Reg. No. 7969-387
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Page 2 of2
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One copy of the label stamped "Accepted with Comments" is enclosed for your records. This
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label supersedes all labels previously accepted for this product. Please submit one copy of the
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final printed label that incorporates the required changes before the product is released for
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shipment. Should you have any further questions, please feel free to contact Shaunta Hill via
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email at hill.shaunta@epa.gov or telephone at 703.347-8961.
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Enclosure:
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Label stamped Accepted with Comments
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Sinc~ t.~ .
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Erik Kraft ~
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Acting Product Manager (20)
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Fungicide Branch
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Registration Division (7504P)
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-
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-BASF
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The Chemical Company
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ACQ."'PTJU)
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with COMMEs.'ITS
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in EPA Letter Dated
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JUN 1 4 2010
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UDI!er the FC!deraI ~
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Ftmdleide, and B~~
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WI tlJDeuderl, C(dO Ghe pcedek;e
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!'egiQ¢ereU mad,~ at~ ~oNo.
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_, ......... -.:-".:~_~ 19 -.3 g 7
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FUNGICIDE SEED TREATMENT
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A liquid flowable for control of various seedborne diseases in
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barley, oats, rye, triticale, and wheat
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Active Ingredients*:
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triticonazole .' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.25%
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thiram ................................. '. . . . . . . . . . . . . . . . . . . . . .. 12.50%
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Other Ingredients: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 86.25%
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Total: ........................................................ 100.00%
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'Contains 0.12 Ib of the active ingredient triticonazole and 1.21bs of the active ingredient thiram
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per U.S. galion.
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EPA Reg. No. 7969-387 EPA Est. No.
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KEEP OUT OF REACH OF CHILDREN
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WARNING/AVISO
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Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en
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detalle. (If you do not understand this label, find someone to explain it to you in detail.)
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See inside for complete First Aid, Precautionary Statements, Directions For Use,
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and Conditions of Sale and Warranty.
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In case of an emergency endangering life or property involving this product,
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call day or night 1-800-832-HELP (4357).
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Net Contents:
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BASF Corporation
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26 Davis Drive, Research Triangle Park, NC 27709
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~ 0
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() " I CJ 0
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Q ,
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)")')0")' 000.)
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)
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J ~ 0 1
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o 0
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'J ) 0
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')
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00.10 /)
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o
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) ~ ') .
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'I·'»)·')
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.3
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-'\
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)
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FIRST AID
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• Move person to fresh air.
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If inhaled • If person is not breathing, call 911 or an ambulance; then give artificial respiration, preferably
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mouth to mouth if possible.
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• Call a poison control center or doctor for further treatment advice.
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• Immediately call a poison control center or doctor for treatment advice.
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• DO NOT induce vomiting unless told to do so by a poison control center or docto~.: : . If swallowed • Have a person sip a glass of water if able to swallow.
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• DO NOT give anything by mouth to an unconscious person. .,
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• Take off contaminated clothing.
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If on skin or clothing • Rinse skin immediately with plenty of water for 15 to 20 minutes.
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• Call a poison control center or doctor for treatment advice.
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• Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes.
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If in eyes • Remove contact lenses, if present, after the first 5 minutes; then continue rinsing.
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• Call a poison control center or doctor for treatment advice.
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HOTLINE NUMBER
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NOTE TO PHYSICIAN: No specific antidote is available. Treat symptomatically. Consumption of alcoholic beverages
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increases the toxic effects of thiram. Have the product container or label with you when calling a poison control center or
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doctor or going for treatment. You may also contact BASF Corporation for emergency medical treatment information at
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1-800-832-HELP (4357).
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Precautionary Statements
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Hazards to Humans and Domestic Animals
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WARNING. May be fatal if inhaled. Harmful if swallowed.
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Harmful if absorbed through skin. Causes moderate eye
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irritation. DO NOT breathe vapor or spray mist. Avoid con
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tact with eyes, skin, or clothing. Wash thoroughly with soap
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and water after handling and before eating, drinking, chew
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ing gum, using tobacco, or the toilet. Wear dusVmist
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filtering respirator (MSHNNIOSH approval number prefix
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TC-21C) or a NIOSH-approved respirator with any N, R, P,
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or HE filter, long-sleeved shirt, long pants, shoes, socks
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and chemical-resistant gloves (barrier laminate, butyl rub
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ber, nitrile rubber, polyvinyl chloride, viton, selection
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Category C). Prolonged or frequently repeated skin con
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tact may cause allergic reaction in some individuals.
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User Safety Requirements
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Follow the manufacturer's instructions for cleaning/main
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taining PPE. If no such instructions for washables exist, use
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detergent and hot water. Keep and wash PPE separately
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from other laundry.
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Personal Protective Equipment (PPE)
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Some materials that are chemically resistant to this product
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are barrier laminate, butyl rubber> 14 mils, nitrile rubber
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> 14 mils, neoprene rubber> 14 mils, polyvinyl chloride
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(PVC) > 14 mils, viton > 14 mils. If you want more options,
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follow the instructions for Category C on an EPA
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chemical-resistance category selection chart.
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2
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All mixers, loaders, applicators, and other handlers
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must wear:
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• DusVmist filtering respirator (MSHNNIOSH approval
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number prefix TC-21 C) or a NIOSH-approved respirator
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with any N, R, P, or HE filter
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• Long-sleeved shirt and long pants
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• Shoes plus socks
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• Chemical-resistant gloves
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• Chemical-resistant apron when mixing, loading, cleaning
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up spills, or cleaning equipment, or otherwise exposed to
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the concentrate
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USER SAFETY RECOMMENDATIONS
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Users should:
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• Wash hands before eating, drinking, chewing gum,
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using tobacco or using the toilet.
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• Remove clothing/PPE immediately if pesticide gets
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inside. Then wash thoroughly and put on clean clothing.
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• Remove PPE immediately after handling this product.
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Wash the outside of gloves before removing. As soon as
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possible, wash thoroughly and change into clean
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clothing.
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Endangered Species
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This bag contains seed treated with thiram. This product
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may have effects on federally listed threatened or endan
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gered species or their critical habitat in some counties. It is
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a violation of federal law to kill, harm, or harass listed ani
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mal species without authorization. To limit the potential for
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such impacts when using this product, consult and follow
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the instructions provided in the EPA Endangered Species
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Bulletin for the county or parish in which you are applying
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the seed. To determine whether your county or parish has
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a bulletin, consult http://www.epa.gov/espp before each
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season's use of this product.
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)
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Environmental Hazards
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This chemical is toxic to fish, aquatic invertebrates, oysters,
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and shrimp. DO NOT apply directly to water, or to areas
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where surface water is present, or to intertidal areas below
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the mean high water mark. Drift and runoff from treated
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areas may be hazardous to aquatic organisms in neighbor
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ing areas. DO NOT contaminate water when cleaning
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equipment or disposing of equipment washwater or
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rinsate.
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Treated seeds are hazardous to fish, birds and mammals.
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DO NOT plant treated seeds by broadcasting to the soil
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surface. Ensure that all seeds are thoroughly covered with
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soil, especially in turn areas. If seeds are not thoroughly
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incorporated by the planter during planting, additional
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incorporation may be required to thoroughly cover exposed
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seeds.
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Treated seed exposed on soil surface may be hazardous to
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wildlife. Cover or collect treated seeds spilled during load
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ing and planting. Dispose of all excess treated seed by
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burying seed away from bodies of water.
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Directions For Use
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It is a violation of federal law to use this product in a man
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ner inconsistent with its labeling.
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Read entire label before using this product.
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DO NOT apply this product in a way that will contact work
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ers or other persons, either directly or through drift. Only
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protected handlers may be in the area during application.
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For any requirements specific to your state or tribe, consult
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the agency responsible for pesticide regulation.
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3
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AGRICULTURAL USE REQUIREMENTS
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Use this product only in accordance with its labeling and
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with the Worker Protection Standard, 40 CFR part 170.
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This standard contains requirements for the protection of
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agricultural workers on farms, forests, nurseries, and
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greenhouses, and handlers of agricultural pesticides. It
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contains requirements for training, decontamination, noti
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fication, and emergency assistance. It also contains
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specific instructions and exceptions pertaining to the
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statements on this label about personal protective equip
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ment (PPE) and restricted-entry intervals. The
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requirements in this box only apply to uses of this product
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that are covered by the Worker Protection Standard.
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After the seeds have been planted, DO NOT enter or
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allow worker entry into treated areas during the
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restricted-entry interval (REI) of 24 hours.
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EXCEPTION: Once the seeds are planted in soil or other
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planting media, the Worker Protection Standard allows
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workers to enter the treated area without restriction if
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there will be no worker contact with the seeds.
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PPE required for early entry to treated areas permitted
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under the Worker Protection Standard and that involves
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contact with anything that has been treated, such as
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plants, soil, or water, is:
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• Coveralls
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• Shoes plus socks
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• Chemical-resistant gloves made of waterproof material
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• Protective eyewear
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STORAGE AND DISPOSAL
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DO NOT contaminate water, food, or feed by storage or
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disposal.
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Pesticide Storage
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Store in original container. Keep container closed and in a
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secure place. Store in an area that is out of reach of chil
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dren and animals, away from food, feedstuffs, fertilizers
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and seed. Protect from frost and freezing.
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Pesticide Disposal
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Wastes resulting from the use of this product may be dis
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posed of on-site or at an approved waste disposal facility.
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Container Disposal
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Nonrefillable Container. DO NOT reuse or refill this
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container. Triple rinse or pressure rinse container (or
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equivalent) promptly after emptying; then offer for recy
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cling, if available, or reconditioning, if appropriate, or
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puncture and dispose of in a sanitary landfill, or by incin
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eration, or by other procedures approved by state and
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local authorities.
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(continued)
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5
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q
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)
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STORAGE AND DISPOSAL (continued)
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Container Disposal (continued)
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Triple rinse containers small enough to shake
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(capacity ~ 5 gallons) as follows: Empty the remaining
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contents into application equipment or a mix tank and
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drain for 10 seconds after the flow begins to drip. Fill the
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container 1/4 full with water and recap. Shake for 10 sec
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onds. Pour rinsate into application equipment or a mix
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tank, or store rinsate for later use or disposal. Drain for
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10 seconds after the flow begins to drip. Repeat this pro
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cedure two more times.
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Triple rinse containers too large to shake
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(capacity> 5 gallons) as follows: Empty'the remaining
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contents into application equipment or a mix tank. Fill the
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container 1/4 full with water. Replace and tighten clo
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sures. Tip container on its side and roll it back and forth,
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ensuring at least one complete revolution, for 30 sec
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onds. Stand the container on its end and tip it back and
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forth several times. Turn the container over onto its other
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end and tip it back and forth several times. Empty the rin
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sate into application equipment or a mix tank, or store
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rinsate for later use or disposal. Repeat this procedure
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two more times.
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Pressure rinse as follows: Empty the remaining
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contents into application equipment or mix tank and con
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tinue to drain for 10 seconds after the flow begins to drip.
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Hold container upside down over application equipment
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or mix tank, or collect rinsate for later use or disposal.
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Insert pressure rinsing nozzle in the side of the container
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and rinse at about 40 PSI for at least 30 seconds. Drain
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for 10 seconds after the flow begins to drip.
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Refillable Container. Refill this container with
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Charter'" PB fungicide seed treatment only. DO NOT
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reuse this container for any other purpose. Triple rinsing
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the container before final disposal is the responsibility of
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the person disposing of the container. Cleaning before
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refilling is the responsibility of the retiller.
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Triple rinse as follows: To clean the container before
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final disposal, empty the remaining contents from this
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container into application equipment or mix tank. Fill the
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container about 10% full with water. Agitate vigorously or
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recirculate water with the pump for 2 minutes. Pour or
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pump rinsate into application equipment or rinsate collec
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tion system. Repeat this rinsing procedure two more
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times.
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Returnable Containers. After use, return cleaned con
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tainer to point of purchase or designated locations.
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DO NOT reuse container for any other purpose. Refill
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only with Charter'" PB fungicide seed treatment. For
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information on the disposal of unused or unwanted
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product, contact your State Pesticide or Environmental
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Control Agency, or the Hazardous Waste representative
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at the nearest EPA regional office for guidance.
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4
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In Case of Spill
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In case of large-scale spillage regarding this product, call:
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• CHEMTREC 1-800-424-9300
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• BASF Corporation . 1-800-832-HELP (4357)
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General Information
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Charter PB is a liquid seed treatment used for control or
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suppression of certain seed borne and soilborne diseases
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of barley, oats, rye, triticale, and wheat. Charter PB will
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increase emergence and plant stands by controlling or
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suppressing these diseases.
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When handling Charter PB and when treating seed or
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while augering or handling treated seed, work in a
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well-ventilated area . .
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See the following table for diseases controlled or
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suppressed by Charter PB.
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Charte~ PB fungicide seed treatment Crop-specific Instructions
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Crop Dise~se Con'ro\led Di~ease Suppres=;;ed1 Product Use Rate
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.(t1 ozs/100 Ibs seed)
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Barley Covered smut Common root rot 5.5
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Ustilago hordei Coch/iobo/us spp.
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False loose smut Dry seed decay
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Usti/ago nigra Penicil/ium spp.
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Fusarium seedling blight Fusarium crown rot
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Fusarium spp. Fusarium spp.
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Fusarium seed rot Fusarium root rot
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Fusarium spp. Fusarium spp.
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True loose smut pythium damping-off
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Usti/ago nuda Pythium spp.
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Rhizoctonia root rot
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Rhizoctonia so/ani
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Oats Covered smut Common root rot 5.5
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Ustilago kol/eri Coch/iobo/us spp.
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Fusarium seedling blight Fusarium crown rot and root rot
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Fusarium spp. Fusarium spp.
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Fusarium seed rot pythium damping-off
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Fusarium spp. Pythium spp.
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Loose smut
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Usti/ago avenae
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Rye Common bunt Common root rot 5.5
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Til/etia caries Cochliobo/us spp.
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Fusarium seedling blight Fusarium crown rot and root rot
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Fusarium spp. Fusarium spp.
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Fusarium seed rot Pythium damping-off
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Fusarium spp. Pythium spp.
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Triticale Common bunt Common root rot 5.5
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and Til/etia caries Coch/iobo/us spp.
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Wheat Flag smut Dry seed decay
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Urocystis agropyri Penicillium spp.
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Fusarium seed rot Fusarium crown rot
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Fusarium spp. Fusarium spp.
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Fusarium seedling blight Fusarium root rot
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Fusarium spp. Fusarium spp.
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Loose smut Pythium damping-off
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Ustilago nuda var. tritici Pythium spp.
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Rhizoctonia root rot
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Rhizoctonia solani
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1 Suppression is defined as suboptimal control which is still of commercial benefit.
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5
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Method of Application
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Seed should be well conditioned and free of chaff before
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treating with CharterG' PB fungicide seed treatment.
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Treated seed should not require drying after treatment and
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can be stored or bagged immediately (provided excessive
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slurry volumes are not applied to the seed). Charter PB
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may be applied using standard commercial seed treatment
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equipment (such as, but not limited to, slurry or mist-type
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equipment) or on-farm seed treatment equipment.
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Charter PB may also be used in on-the-go type air seeder
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treatment systems.
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Charter PB should be applied to barley, oats, rye, triticale,
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and wheat at the rate of 5.5 f1 ozs of product per
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100 pounds of seed. Thorough seed coverage and proper
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application equipment calibration is essential for good dis
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ease control. To achieve thorough coverage, Charter PB
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may be diluted with water, if needed, into a slurry. Direct
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application into a planter box is prohibited.
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Use Restrictions
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• DO NOT use treated seed for food, feed, or oil
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processing.
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• Store treated seed away from food and feedstuff.
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• DO NOT contaminate feed or foodstuff.
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• DO NOT contaminate bodies of water when disposing of
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planting equipment washwater.
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• DO NOT plant any crop not listed on this label within
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30 days after planting Charter PB-treated seed.
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• Plant barley, oats, rye, triticale, and wheat seed a mini
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mum of 1-inch deep.
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• DO NOT use the same auger for treating seed that will
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handle commercial or feed grains.
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• DO NOT store leftover seed where there is a chance of it
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becoming mixed with untreated seed. Store treated seed
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in cool, dry conditions.
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SEEDS THAT ARE TREATED WITH THIS PRODUCT
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AND ARE THEN PACKAGED OR BAGGED FOR
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||
FUTURE USE MUST CONTAIN THE FOLLOWING
|
||
LABELING ON THE OUTSIDE OF THE SEED BAG.
|
||
"This seed has been treated with Charte .... PB fungicide
|
||
seed treatment containing triticonazole and thiram.
|
||
Persons opening this bag or loading/pouring the treated
|
||
seed must wear long-sleeved shirt, long pants, shoes,
|
||
socks, and chemical-resistant gloves.
|
||
• DO NOT use for food, feed or oil processing.
|
||
• DO NOT allow children, pets or livestock to have access
|
||
to treated seeds.
|
||
• Treated seeds exposed on soil surface may be hazardous
|
||
to wildlife. Cover or collect treated seeds spilled during
|
||
loading and planting.
|
||
• Dispose of all excess treated seed by burying seed away
|
||
from bodies of water.
|
||
• Dispose of seed packaging or containers in accordance
|
||
with local requirements.
|
||
6
|
||
• DO NOT plant any crop other than barley, oats, rye,
|
||
triticale, or wheat within 30 days of planting Charter PB
|
||
treated seed.
|
||
After the seeds have been planted, DO NOT enter or allow
|
||
worker entry into treated area during the restricted-entry
|
||
interval (REI) of 24 hours.
|
||
EXCEPTION: Once the seeds are planted in soil or other
|
||
planting media, the Worker Protection Standard allows
|
||
workers to enter the treated area without restriction if there
|
||
will be no worker contact with the seeds.
|
||
Treated seeds are hazardous to fish, birds, and mammals.
|
||
DO NOT plant treated seed by broadcasting to the soil
|
||
surface. Ensure that all planted seeds are thoroughly
|
||
incorporated by the planter during planting, additional
|
||
incorporation may be required to thoroughly cover exposed
|
||
seeds. DO NOT apply to water, to areas where surface
|
||
water is present, or to intertidal areas below the mean high
|
||
water mark. DO NOT contaminate water when disposing
|
||
of equipment washwater or rinsate or by disposal of
|
||
wastes.
|
||
This bag contains seed treated with triticonazole and
|
||
thiram. This product may have effects on federally listed
|
||
threatened or endangered species or their critical habitat in
|
||
some counties. It is a violation of federal law to kill, harm or
|
||
harass listed animal species without authorization. To limit
|
||
the potential for such impacts when using this product,
|
||
consult and follow the instructions provided in the EPA
|
||
Endangered Species Bulletin for the county or parish in
|
||
which you are applying the seed. To determine whether
|
||
your county or parish has a bulletin, consult
|
||
http://www.epa.gov/espp before each season's use of this
|
||
product."
|
||
|
||
Conditions of Sale and Warranty
|
||
The Directions For Use of this product reflect the
|
||
opinion of experts based on field use and tests. The
|
||
directions are believed to be reliable and must be
|
||
followed carefully. However, it is impossible to eliminate all
|
||
risks inherently associated with the use of this product.
|
||
Crop injury, ineffectiveness or other unintended
|
||
consequences may result because of such factors as the
|
||
presence of other or untested or unapproved materials,
|
||
seed of low quality or low vigor or low germination, use of
|
||
the product in a manner inconsistent with its labeling,
|
||
misapplication of the product, or weather conditions at
|
||
planting or environmental conditions during seed storage,
|
||
all of which are beyond the control of BASF
|
||
CORPORATION ("BASF") or the Seller. To the extent
|
||
consistent with applicable law, all such risks shall be
|
||
assumed by the Buyer.
|
||
BASF warrants that this product conforms to the
|
||
chemical description on the label and is reasonably fit for
|
||
the purposes referred to in the Directions For Use,
|
||
subject to the inherent risks, referred to above.
|
||
TO THE EXTENT CONSISTENT WITH APPLICABLE
|
||
LAW, BASF MAKES NO OTHER EXPRESS OR
|
||
IMPLIED WARRANTY OF FITNESS OR
|
||
MERCHANTABILITY OR ANY OTHER EXPRESS OR
|
||
IMPLIED WARRANTY.
|
||
TO THE EXTENT CONSISTENT WITH APPLICABLE
|
||
LAW, BUYER'S EXCLUSIVE REMEDY AND BASF'S
|
||
EXCLUSIVE LIABILITY, WHETHER IN CONTRACT,
|
||
TORT, NEGLIGENCE, STRICT LIABILITY, OR
|
||
OTHERWISE, SHALL BE LIMITED TO REPAYMENT
|
||
OF THE PURCHASE PRICE OF THE PRODUCT.
|
||
TO THE EXTENT CONSISTENT WITH APPLICABLE
|
||
LAW, BASF AND THE SELLER DISCLAIM ANY
|
||
LIABILITY FOR CONSEQUENTIAL, EXEMPLARY,
|
||
SPECIAL OR INDIRECT DAMAGES RESULTING
|
||
FROM THE USE OR HANDLING OF THIS PRODUCT.
|
||
BASF and the Seller offer this product, and the Buyer and
|
||
User accept it, subject to the foregoing Conditions of
|
||
Sale and Warranty which may be varied only by
|
||
agreement in writing signed by a duly authorized
|
||
representative of BASF. ST1108
|
||
7
|
||
Charter is a registered trademark of BASF.
|
||
© 2010 BASF Corporation
|
||
All rights reserved.
|
||
007969-00387.201 00304.NVA 2010-04-277-0008
|
||
Supersedes: NVA 2009-04-277 -0161
|
||
BASF Corporation
|
||
26 Davis Drive
|
||
Research Triangle Park, NC 27709
|
||
mBASF
|
||
The Chemical Company
|
||
q
|
||
---~
|