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crop-chem-docs/corpus/epa_ppls/9779-288.md
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Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
docker: production image + Gitea Actions for monthly refresh
Dockerfile: self-contained image with corpus + Chroma + BM25 baked
in. Drawbar's compose pulls + runs without volume mounts. Built from
sources.json (labels schema), PRODUCT_NAME=crop_chem by default,
HYBRID_SEARCH=true (always-on for production quality). RERANK_URL +
OLLAMA_URL get set at compose time.

.gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does
full scrape → reindex → image push. Scrapes Bayer (~30 min) +
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diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>.

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image, pushes. ~10 min vs ~9h full refresh.

.gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md +
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chroma/ + bm25/ still gitignored (regenerable binary indexes).

.dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md,
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explicitly NOT in dockerignore (those go INTO the image).

Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
2026-05-24 12:32:41 -04:00

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# VALCO BRAND METHYL PARATHION EMULSIFIABLE NO. 4
- EPA Reg No: **9779-288**
- Registrant: WINFIELD SOLUTIONS, LLC
- Signal word: Danger
- Active ingredients: Chevron 100 (48.26%); Methyl parathion (45.49%)
- Label accepted: 1985-01-14
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/001063-00104-19850114.pdf
---
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~ )'our' State De:
.. d;a are exp<!cted
trNted 1,Iqth this
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19 In [ormatIOn
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109 lOr -\6 houa
this product label
.)n ((lod or forage
l" ~DirlX{inns (or
.yl parathion ttH.)'
ct. mhalation or
Of under ..... ('athl'r
reas 1"101 Jnlended
protC'-Cte-d humans
;lnd other ...... Jdhle
",liN. Keep nut of
. Shrimp .md crab
Ibis lahel, Do flot
apply '~'here fun­
er condltlor,$ favor
;.er by deamrlg of
t only as specified
.::IirKt treatment or
obtaine4 (rom )'OUf
ARO
heat or name.
\
RESTRICTED USE PESTICIDE
For retail sa.le to and use only by Certified Applicators or persons und(>T their direct supeTvision, and only tor those
uses covered by the Certiried Applicator's certiflcation.
®
\
NET CONTENTS ______ GALLONS
ALeo
B R A N
METHYL PARATHION
EMULSIFIABLE NO. 4
D
(CONTAINS 4 LBS. METHYL PARATHION PER GALLON)
ACTIVE INGREDIENTS: BY WEIGHT
O,O-dimethy! O-p-nitrophenyl
Related Compounds
Thiophosphate' 13.22·-~
Aromatic Petroleum Solvent
I:-<ERT INGREDIENTS:
TOTAL.
'Methyl Parathion
2.27%
-18.26%
6.25:0
100.00%
DANGER: BEFORE USING, READ THIS LABEL
CAREFULLY
~ POISON
DANGER
KEEP OUT OF REACH OF CHILDRSN
SEE OTHER WARNINGS ON LEFT PANEL
Manufactured By
VALLEY CHEMICAL COMPAft'V
GREENVILLE P. O. BOX 1317 MISSISSIPJ-.
/
I
/
/
/
(
DANGER - POISON - PRECAunONS
NOT FOR HOME USE
r·~I~(t~
_~Jl'P.i"'~'U'_
.. ~ -.,. "'" ... ..,. ~ ---..... -~-... --. "' ..
-- ........... 1 • ...-
..Wt..MJ._et~'!I_~!...,,'1.
.... .-...." .... ,.,. ....... -............. _ .. ,." ••• -0,..
---_ .... ,-..... ........
--,-
... :ft~~~ • ... .. -....... -
~ PQlSOK SIGHS (SymptomJ)
~!ethyl ~arathion i5 a very danierous poison. It rapid!>" colen the
budy Oil contact with aU ,kin sw-faces and ey~. Clothing wet v. lib
this materia! mW;t be remO\'ed immediately. Exposed persons must re­
ceive prompt medical treatment or they may die.
Some 01 the signs and .yrnptoms of po[~oning art headaches, nausea,
\·omlt~ng. cramp$. \l.uknes:s, blurred vision, pin_point pupils, tightness
In chest. labore..i bredthing, nef'''ousness. sweating, watering (If eyes,
droohng or froll-ung of mouth and m:·se. muscle spasms and CQma.
POISON
ATROi>lNE IS AN ANTIDOTE.
CONSULT PHYSICIAN FOR
EMERGENCY SUPPLY.
CALL A PHYSIClAS AT ONCE IN ALL CASES OF SUSPECTED
~tETH\'L PAR.A.THlO:-i POISONING
If symJltoms or signs of poisoning include blurted vision. abdominal
cramps. and ngntn<:ss in the chest, do not \I.·<lit for a doctor but gi\'~
t ..... o atropine t~blets :;each 11100 gnin of 0.65 milligrams) at once
,r)n" tablet :0 ch!icren under {iv(o years of aie.)
+ FIRST AID TREATMENT +
STATEMENT OF PRACTICAL TREATMENT
(",d a doctor (ph)".'idaQ), dmic or hospital immediately. ExplaiQ
';,,..t the victim has toeen exposed to me:hyl parathion and de~rilx­
:r .. ~ ;::nndition. If doc\N cannot corne. takc \'Ictlm to clinic or hospital.
~!.,~ e patient irnn·,crl.ately (rom the area where methyl parathIOn is
'W-H'nt.
!F '-~:;HALED. rem·}~·c \1ctim to fresh air. U not breathing immel-Ii·
~t,,:)· gh'e ar~ifJ(~:'! respiration. prde:3bly mouth· to· mouth. and
InZl:ttain UntIl d·Xl')r sees nctim. If breathmg IS dlfflcl.!ll. gwe
o~:;g(;n.
IF l~ EYES Ok OX SKJ:ol, immediately flush with plenty of water
for ilt least U minutts while remol'i:!! contaminated personal
dCllting and sh(,e~ to avoid continued p?sslble e)tposure W \'ictim
or- persor.s in attendance.
• F SWALLOWED .• r,duct vomiting immediiltel)' by giving two glasses
of ,.,tater and by touching back of throat ... .ith finger. DO MOT IN­
D1jCE VOMITIXG OR GIVE ANYTHING lJY MOUTH TO AN
i:!'{CONSCIOUS PERSON. Han \'ic(jm lie down and k~~p quiet.
HOTE TO PHYSICIAN
Ail.!;j'ole - adrnin1!ler atropine sulfate in lafjte doses. TWO to FOUR
m.: ir..t~&\·enously or intramuscularly as 500n as ~yanosis i! over·
-:<;1' t'". H--peat at 5 to 10 minute intervals unl:1 signs of atropinization
.lp~""1or 2·PAM chlOride Is a pharmacolog.c antidote and may be ad·
m.I·''itued as an ad)J..:nd to, but not a subs·lltute fOr. atropine which
is .1 symptomatic ami often Hle·sa\,ing ao"ltidote. DO SOT GIVE
MORPHINE OR TRANQUILIZERS 8ECACSE THESE AXTIDOTES
~tA Y PRODUCE ADVERSE EFFECTS ACCENTUATING THE
PH.\RMACOLOcaC EFFECT OF THIS PRODUCT. ThiS product is
, ~~r~"g cholinesterase inhibitor affecting the central and I*ripheraJ
r .. _:,o'-lS ~ystems and producing cardiac: and respiratory depression.
.'t {'r:;.: !ign of pulmo)nary edema. the patient should be gl\'en s\,!p­
P:"'r~'\tal o,;ygen a~·1 treated sympl,(,matically_ Conhnued absorb.
~iOn "If tre poi..$on,!:1ay OCfur and fa~"l ~":~~es hiV"beil\ leportt<:
aft<-l \fl,tial imprr, emef\l:~ .• "ERY CL,')SE :tCPERVI~ION.OF THE
P;'T!';~T IS IND1(l,,-1TJ) rOR AT t.EA'iT .8 HOllRS .•
$.vQHK S~FrtY RiILFS' •• ••
REP£..'\ n:LI :EXPOS:'RF.8 TO Ct-IoLINisT[RAS~ lNtlIBITORS
S1jCH .... 5 ARE CO=--':'AIN:f.D IN THIS PRODUCT MAY. WITHOUT
WAlenSG, CAt:SE PROLONGED SUSCEPTIBILITY TO VERY
SMALL D.)SES 0: A).Y·:;HOL:NEST!fMSE nann:\'OR
• ( • '. f I
Penura workin, wi~h ti1..9. prot .... :t Lhot..f.":'~avl" t;cqu~'" blood. t~t.!J
.~f ~hfir cboUnt:ste!"~e t:e\"lis.j If '.he ch.Jlif.~tl.ulce le~t1- falb below
:: clllie-a; po!nl, no lurfile! d~}<U"~ st,".Jll,t & 4;1ol".t1 until it hilS
'~n d~term:ned h)' mead.! uf b.u\)d t«t.s lhat th~ .:hOIlc.~terase le ... el
h ... • returl'<:'d to non11l1. Ref¢re using this product consult tbe Stat~
Ap-iculturf' Exteruion Service or ~puiInental StOltion for s~ific
ue:ommendations fegudin, liueh blood tesu.
It handled indooCl, provide mechanical e)thaust \-entilation.
Keep all unprotected persoru and animals a""'<I), trom tr(!ated area or
.... ·here there is da.nger o( drilt.
Do not rub ~yes or mouth with hands It you feel ~ick in any way
STOP work <lnd ret help rirM a ..... a)·. See Fint Aid (Practkal Ireat·
ment) section.
USE ONLY WliEN WEARING T'HE FOLtOWlSG
PROTECTIVE EQUIPMENT AND CLOTHING
(I) Wear water·proof pOlnts. coil, hat. rubber bo<lu or rubber over­
shoes. (2) Wear ~afety goggl(!s (3) Wear a pesticid;} respirator jointly
appro\'ed by the Mining [nfr)r(":ement and Safety Administration
.formerI)· the U.S. Buruu of Mines) and the !{ational Institute for
(kcupational Safety and Health under the provisions of 30 CFR part
11 (4) Wear heavy duty nOltural rubber gloves.
I~LPORTA!ow." Befofe temO\·lOg gloves. \u~h them With soap and
water. AI ....... j"s wash hands, lace and arms ..... Ith soap and water be·
lore smoking. ealing or drinking
AFTER WORK take aU all work clothes and shoes. Shower using
soap and water. Wear only dean cloth('S ..... }:(!n lea\'lng the job. Do
not wear contaminated clothing. ""ash protectIVe clothing and pro~
teclwe equipment with soap and waler a(ter ea(:h use. Respirator
should be cle3.nfd and hlter replaced aCCOtdmg to Instructions Includ~
ed wllh re:plrator.
RtENTRY STATEMENT
Do not apply this product In such a mannt'r as to directly or through
dnft e)tpose .... ·orkers or other persons. The area being treated must
be \·acated by unprotected persOns.
D:I n()t enter treatcd areas (or 46 hours unless appropriate prot('('ti\·e
clothing is wotn.
8(,(,aUse certain states may rt""..(uire more restricth'{' reentry interl'als
for \'arious crops treated with this product. consult )'our Slate De~
partrnent of Agriculture for further information.
Written or oral warnings must be gh'en to workers who an~ expected
to be in a treated area or in an area about to bt' treated ",:Uh Ihis
product_
ORAL WARXIXGS shall inform workers of areas or fields that may
not be entered. wiihout protective equiptnent and clothing specified
On thIS label. during treatment or for 48 hours following treatm(!nt.
Follow First AId Treatment instructions shown on this lab(!1 in case
of acc~dcntal (!xosure
Whell oral ..... arnmgs are gi\·en. warnmgs shall be gwen In a language
cu,;tomarlly unaerstood by ..... orkers Oral warnmgs must te gwen If
there I! reJson to behe"e ~hat .... ·ritten ..... arnings cannot be understood
by ~HHk~rs.
WRITTE:-4 WAR!'OIXGS must include the foJ!lowmg information
DAXGER-Art'a tr{'ated ... ·ith ~tethyl parathion on __ (dale) __
00 nOl enter ..... lthout appropriate protecti\·e dothing for 48 hours
Follow First Ai<l Trealrr.ent Instructions shown on this prOduct label
In case of accidental exposure .
ATTENTIOH
To avoid e)tces--h'e residuei of methyl parathion on food or forage
crops always obsen·e the statements f{lund under ~Diree:tions for
t:~e." limiting the time before han'est when methyl parathion may
be applied
Because this material is poisonous by $kin contact. inhalation Qr
swaIJ'l ..... ing il should not be used in such a manner or under weather
conoiillons as will permit dnft of thE' £pray onto areas not intended
t ... be sprayed.
Do not apply (.;r aUow drift to areas occupied by Unprotected humans
or beneficl,ll animals.
ENVIRONMENTAL HAZARD
This product IS toxic to fiSh, shrimp. crab. birds, ;lnd other ..... ildlife.
Birds and other wlldllfe in treat.ed area$ may be killed. Keep out of
lakes. streams. ponds. tidal marshes and e-stuaries. Shrimp and crab
may be killed at application rates rC'Cornmendt'd On this label. Do not
apply where these are important resources. Do nl' -·· ... Iy ..... here run.
oU is likely to occur. Do not apply when weal . ~""Iditions favor
drift from areas treated. Do not contaminate wilter by cleaning of
equipment Or disposal or wastes. Apply this prodUct onl)' as specified.
on this label.
This product is highly toxic to bees expo!ed to dire<:t treatment or
residUe! on crops. Prote-ctive informatiOQ may be obtained from your
Coot>erative Agricl.lUural Extension Se ... ·ic~.
PHYSICAL on CHEMICAL HAZARD
Combustible: Do not we, POt "pill or store nUr heat or Game.
In case of
FIRE. USt wat~r spray. ~ . dry chemical or CO ...
<
~
/
I
I
SPILL or LE.AK keep ;1) unprotected penonS a ..... a)·. Cover with
.bwr~nt such as soda ash. lime, da)" or Slt....- dust. Sweep up and
bw),. Wash area thorouehly .... ·itt. s\t'1.>ni lye solution..
STORACE AND DISPOSAL
Do not contllmjn:;;t~ ..... a.t~r. food. or feed by ,Iorage or disposal
STORAGE AND HAh"ULlNG:
I. HUldIe container cU~fun)· so a$ to altoid damtge Vld prevent
luka,t.
2. Do not me or store In or around Ole horne.
3. Store «mlainer iii a well ventilated place.
4. Empty ('(Illtainer retams \, .. por and tm:)(Juct residue Observe .u
'.bel s.afeguards until container is <:leaned, .rf'C'Onditioned or destroyed.
S. Keep Ollt t)f rea~h of children and dOm~tk animals.
DtSPOSAL:
Wules of this pesticide are ilcutely hazardoU$. Improper disposal oj
UC'4$ peSticide. ~pray mixtures, or rinsate IS iii "'IQialion of federal
I.,,, ... If these ~'a~I['$ cannot be dBposed of aC«lrdmg to label U$e in~
strUttlOns, contact your state pestlcldt' or £n'I:ironmen\a\ Cl)n\ro\
Alency, or the Hazardous Waste Repre~entatwe at the ne~re.st EPA
Rellonal Office for guidance.
!~3:Ie...!~~;~ ';he~tYofi~~tf~~e:ec~:\~" ~:r c:~~~I~~~n s~t~~\on un~!~~~
to prevent other u~e 3nd dispOse of in an appro,,·t<:I 1andflfl. or by
other proc:~ure~ appfo ... ed b~' state and 1000ai 3uthorilie$.
DIRECTiONS FOR ust
It i$ • \'lo)a1l0n oJ Ff'deral Law \0 use thl~ pTodu1::1 in any manner
incooslstel:;{ with It, Itbehng.
Be !lure 1O read the precautionilry statements befor(' using~
Thb product i50 de5igoed for apphcatllm after dilution wllh water
and lor use by tramed operators uSing .llrplanc or power ground
equlpmen\, The h~lard< and prec'lulions tor handling Ih'" product in
thIS ~n13mer aTe equally apphcable to It after dilulion with ..... ater
for spray applicatlc.n Add the concentrate 10 the spray tank while
fjlline with ..... ater and mix thoroughly either b~' means of a tank
agitator or pump by~pass_ For best resuhs_ thoroughly ct)'l:U aU sur~
facts to be treated ..... ith spray. Rat("l: of applicatIOn gwen belov.·
should not be exceeded Ne"'er apply later than ihdicated 10 assure
r~sidul' )I;'\'eh at har .. e~\ ar~ bl!to ..... tolerances establ:shed b)' the Food
lind Drug Administration.
FOR CoNTROL OF:-Boll Wee'l:il. Thrips. Cotton Aphid, F1ea Hop­
pers. Lygu'5 Bug~, TarnISh Plant Bugs ahd Stlhk Bugs on rlee
MIXING: - Add the amount o! "aleu Bran~ MNh,,1 Paral~l.IQr. Em.
Ulsl'la.ble 1'0_ 4 rec::llnmended for thf' control o! each insect te> the
water n(ct'ssary to treat one aCH'_ MIlo; thoroughl~ belore d-pplYlng
If soluuon IS allo ..... ed t~ statld se\'eral hours. agitate well before uSing.
USt: ON COTTON: _ Use Valea Brand MetJwl Pa~athion Ernuls.h.
able ~o 4 at the rates reC'(lJr.mended belo ..... f'Or putiCUlar insect to'
be controlled. This product should be ll$ed on 3 to $ day inten·als.
or as nrtessary to keep insect under eontrol. The rate and inter"'al
of application will depend Ilpon the size of co\\on. degre-e of \Mecl
infe$l.ation ...... eather. and method of application Proper tuning ttnd
uniform application ttre essential for best resull.5_ Methyl parathion
hJ..$. to rapid action 01'\ ins~. but a short residual to:<:I(,l1y Frequent
ap);)lications are often necessary Make no application within IS days
of haf\,'eH or pasturing.
TliRlPS: - Appl)' at Tilte of one {1} g~"or, p,er 20 ~c~.
BOLL WEEVIL ANb COTTON VHID; - Apply at rate o( one (II
(aUon poE'r 8 to 16 ,u;:rE'"S_ ,
f"L.EAHOPPER. LYGUC BOGS AND TARNISHED PUNT BUGS:
Apply at rate of one (I) galon per 16 to 26 acres.
SOYBEANS: - For conlfol of BoUWorffiS apply a\ ute 01 one {U
,_Uon per 4 acre-s ?ot;:.ke no applicatIOns withm 20 d'n,·s of harvest
Do. not appl}' more lhan twice ~r growing season.
RICE: _ For control o( slink bugs ap);)ly at rate of one (I) gallon per
liS acr~s Make no application Within J5 days of han:est.
WHEN MAKiNG APPLICATION'S WITH AIRPLANES: - Follow
the- $Ame Apphcation Program given for ground spraye~. applying
one (1) eallon per 16 acres, in I to 3 gallons spray mix per acre.
MOTICl: TO USERS:
Selkr Vo'arrants that the product conforms to its chemical description
and is reasonably fit for the purpose staled on the label ... ·hen u.:.td,
In accordance .... ·ith directions W1der normal conditions of use but
~ith~r this warranty nor any (lther warranty of merchantability or
fitness for I particular purpose, txrress or implitd, extends to th~
UIIe 01 thili product conbaT)' \0 labe instructions, or under abnormal
eonditioru, or under condilions not reasonably forst-elilble to leUn.
IJ\d bUyer ~umes !.he rltk of .,. ... luch use.
S'Re-c. Trldemark (It V ALLE.~ ThtlCAL COMPANY
I-P.A. Re,. No. 1063·10. ~ EPA Ed. lDe.3~MS.1
StJPPL£M£NTAL LABI:L1NG
METHYL PARATHION f;MULSlFiABL£ NO .•
For States 01 Mississippi and Arkansas
sL:-i No. MS·8!O028 SLN No. AR·815533
For use on small grain; Bade}", Whc-at and Oats. apply 1I'l to 2 1/2 pts ;:X-J" s,:-re
for control of aphids ond army\\"orms. Us€' higher rates {or armyworm controi. DO
NOT apply within 15 days of harvest. B~t rf'Sults u·m be vbt..ained when daytime
tempcralur~~ are in Ute 70·s. Rt'fer to label on conta.iner (or mixing ir.:..t! oJ.:.-tivns
and safely informdtion. This labeling must be in the possession of the user at t}-,(> -;.;me of appHcation.
It is a violation of Federal lav: to use this product iI) a m.JflJlcr inconSlstant with
its laVcling.
METHYL PARATHION MIXTURE,
LIQUID, POISON 8, NA .. 2783, RQ
ACe E P 'l'-E D~
, , ..
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