a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
311 lines
20 KiB
Markdown
311 lines
20 KiB
Markdown
# PROPANIL 80 EDF
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- EPA Reg No: **9779-338**
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- Registrant: WINFIELD SOLUTIONS, LLC
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- Signal word: Caution
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- Active ingredients: Propanil (80%)
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- Label accepted: 1996-05-14
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/009779-00338-19960514.pdf
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---
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. \
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.. J
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PROPANIL ~OEDF
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For post-emergence control of weeds in rice and small grains
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ACTIVE INGREDIENT
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Propanil (3 ',4 '-Oichloropropionanilide) . . . . . . .•...••...
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INERT INGREDIENTS ..................•......•..•.•.........
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Total
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KEEP OUT 'OF REACH OF CHILDREN
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CAUTION
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STATEMENT OF PRACTiCAl. TREATMENT
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IF Ifrl EYES: Rush eyes with plenty of water, Can a physician if irritation persists.
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IF ON SKlN: Wash with pfenty of soap and water. Get medical attention if irritaUon persists.
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80.0%
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~
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100.0%
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IF INHALED: Remove ~ictim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Gel medical attention.
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PRECAUTIONARY STATEMENTS
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CAUTION
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HAZARDS TO HUMANS AND DOMESTIC ANIMALS
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Causes eye irritation. Do not get in eyes, on skin, or on clothing, Wash thoroughly with soap and w:':Iter after handling. AVoid
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breathing spray mist.
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PERSONAL PROTECTIVE EQUIPMENT
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Applicators and other handlel'S must wear !ong~leeved shirt and long pants, waterproof gloves, s.hoes plus socks, and protective
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eycwE'ar.
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Discard dothing and other ab$orbent matenals that have been drenched or heavIly contaminated with this product's concentrate. Do
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not reLJse them. Follow manufacturets instructions for cleanIng maintainfng PPE. It no such instructions for washables, use detergent
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and hot water. Keep and wash PPE separately from other laun(hy,
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When handlers use closed s.ystems, enclosed cabs, or aircran: tn a manner that meets the requirements listed in the Worker Protection
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Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d) (4.-6», the handler PPE requirements may be r(7duced or modified
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as specified in the WPS .
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USER SAFETY RECOMMENDATIONS
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Us.er should wash hands. before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately
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if pef.tjcide gets inside. Then wash thoroughly and put on clean clothing. Remove PPE immediately after handling thi$ product.
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Wash the outside of gloves before removing, As soon as possible, wash thoroughly and change Into clean clothing . . _--'
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Read Additional PRECAUnONAR1JilA.TEMENTS.
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ACCEI'TEU
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EPA Reg. No, 9779-
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Manufactured For
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RIVERSIDE/TERRA CORPORATION
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P.O. Box 6000, Sioux City, Iowa 51'102-6000
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R;Vf!}f'SJd" Serves AgriculturfJ, Agricultu,r;, Serves Everyon&.
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, ILl . 881fi'~
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In EPA LeUer Dated
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MAY ! 4 1996 Ei')'('p'st:No. 9779-A~-13
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,; ..
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" , ,
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• , ,: , , NET CONTE:;NTS
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L 95.
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)
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)
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ENVIRONMENTAL HAZARDS
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This pesticide Is tox)c to fish. Drift and runoff from treated areas may be hazardous to aquatic organisms in neighbolinQ areas. 00
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not apply directly to water, or to areas where surface water is present or to. intertidal areas below the mean high water mari<. Do not
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c.ontaminate water ;,.,fum disposing or equipment washwaters.
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DiRECTIONS FOR USE
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It is a viof3;tion of Federal law to use this product in a manner inconsistent with itS labelln.g.
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Do not apply this product in a way that wi" contact workers. or other persons, either dlrectty or through drift, Only protected handlers
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may be in the area during applicatton. For any requirements. speclrlc to your State or TMbe. consult the agency responsible for
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pesticide regulations.
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Do not apply this product through any type of irrigation system.
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Water drained from treated rice fields must not be used,to irrigate other crops or relea.sed within 112 mile upstream ofa potable water
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intake in flowing water (i.e .• river, stream. etc.) or within 112 mile of a potable water intake in a standing body of water such as a Jake,
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pond or reservoir. .
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00 not drain water from treated fields Into areas where catfish farming is practiced.
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Do not apply to fields. where commercial crayfish farming is practiced and do not drain water from treated fields into areas where
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crayfish farming is practiced.
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AGRICULTURAL USE REQUIREMENTS
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Use this product enly in accordance Wfth its labeling and with the Worker Protection Standard. 40 CFR part 170. This Standard
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contains requirements for the- protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of
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agricultural pesticides, It contains requirements for training. decontamination, notification, and emergency assistance. It also
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J:ontains specific ins.truct!ons and exceptions pertaining to the statements on this label about personal protective equipment
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(PPE), and restncted-entry intervat. The requirements in !hi.s box only apply to uses of this product that are covered by the
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Worker Protectio~ Standard.
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Do not enter or allow worker entry into treated areas during the res.tricted enby interval (REI) of 24 hou($..
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PPE required for earty entry to treated areas that i$ permitted under the Worker Protection Standc.ard and that Involves contact
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with anything that has been treated, such as pfants. soil, or water, is: covera[ls, waterproof gloves. shoes plus. socks and
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protective eyeweac
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.•..... ---.•.•.. ..:. -----
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STORAGE AND DISPOSAL
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DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL
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STORAGE
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Store in a dry location away from children, animals, foods, feeds, seeds, or other agricultural chemicals. Handle in accordance with
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information given under PRECAUTIONARY STATEMENTS. In the event of spillage or leakage, scrape up material and dispose of
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in accordance with information given under DISPOSAL. Repackage and relabel useable product in a sound container. In case of
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fire or other emergency, report at once by toll-free telephone to 800-424-9300,
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DISPOSAL
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PESTICIDE' DISPOSAL: Wastes resulting from the use of this product may be disposed of on $ite or at an approved waste d~posal
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facility .
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CONTAINER DISPOSAL: Completely empty bag into application eqUipment. Then dispose of empty bag in a sanitary landfill or by
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incineration, or, if allowed by state and toeal authorities, by burning. If bumed, stay out of smoke.
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GENERAL INFORMATION
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PROPANll eOEDF ii: a post-emergence herbicide fur the control of many grasses and broadleafweeds in rice fields, and \'lher,hnk
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mixed with MCPA, on s.mall grains (s.ee the "Sma" Grain" section for specific crops), n may be applied by either ground or aefi'il.:~.p,ray
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eqUipment atter dilution and thorough agitation with water. PROPANllaOEOF is not a hormone-type herbiqkjf}.,.b,ul kilts suscerttible
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plants by direct contact. Thorough spray coverage of weeds is necessary for best resutts. ) •
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PROPANIt. 80EDF should be applied when weeds and grasses are small (See directions for use for spe~lfi,:cr~.)s) Us~ oniy' on
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rice fields which have been drained of flood water. Balds to be treated shOUld be inspected frequently befofe~the applicaH?n of
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PROPANIt. 80EDF to in$ur(~ that grass is at the proper stage of growth (1 to 3 leaf stage with an occasional;4 (ejJf plant).-' J J
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.' J'" ,
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ATTENTION: Neyer apply PROPANll SCE-OF except as recommended on this Jiilbel because use in any other way rna .. ; re,$-Olt in
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damage or injury to persons, animals, or crops, or other unintended consequences.
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Do not apply to any crops other than rice, spring barley, durum or hard red spring wheat.
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Before applying PROPANIL 8OEDF. make sure the spray equipment is properly calibrated to avoid over~ or under-trcatmcnt
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"
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Do not apply PROPANIL 80EDF under windy conditions which will aUow drift to adjacent susceptible crops such as beans, soybeans.
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cotton, satnower. cucurbits, vegetab~s. orchards, and other sensitive crops, WInd velocity greater than 5 miles per hour wiH often
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cause applications to be streaked and give less than maximum herbicidal control.
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USE RESTRICTIONS ON RICE
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To avoid excessiVe residu(ts at har .... est. do not apply after the end of iillering for the: rico variety being trea!e-d. Co not ::cppty more
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than a maximum of six pounds active ingredient per acre in a single appHcatlon or exceed eight pounds of actiVe ingredient per acre
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total dosage per ,season. Do Not Apl2.ti.£B.Q~l aOEQF wtthin fourteen (14) day. before of after insecticide applications becau$e
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serious da mage to rice may occur. Do Not Apptv ...f.B.Q£A..BIL 80EDF to rice fields that were planted wtth rice seed treated wjth bird
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repellents containing methiocarb.
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RICE
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WEEDS CONTROLLED
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"8amyardgrass (Watergrass)
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Echi/1ochlOll crus-gaiN or Echinochloa colonum
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8rachiaris
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BrachilJria spp.
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Crabgrass, large
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Digitsrig sanguinllJis
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Croton, wooly
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Croton capitatus
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Cuny Indigo
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Aeschynomene v/rgfnica
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Foxtail
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Setaria spp,
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Goosegrass
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Eleusinct indica
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Gulf cockspur
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Echinochloa crus·pavonis
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Hoorahgrass
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Fimbristylis mifiaceae
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Mexican weed
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. Cllperonia t;lIstanaofofia
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Paragrass
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Panicum pupuTascens
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Pigweed, redroot
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Amaranthus retroflexus
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Redweed
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MeJochl. corchorifolia
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Cuny Dock
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Rumex crlspus
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Spearhead
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Rhynchospora corniculate
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Tall Indigo or Coffee Bean (Hemp eesbania)
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Sesbania e:ialtata
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Texas Minet (Texas panicom)
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Panicum t&xanum
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Wtregrass (Spikerush)
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Eleocharis spp.
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"In Isolated instances, b1ot'lpe& of bamyardgra$S may develop that cannot be effectively controlled by propanil
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alone. Where these biotypes are known or sU$pected to be pres.ent, and are found in a mixed weed population
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in which Propanil is effectNe, a tank mixture of Propanil80EDF herbicide with either Pro~ or Bokl-ro*SEC
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is recommended to control bamyardgr3ss (up to the 3 leaf stage). These tank mixtures may r.edl,.(ce crop
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tolerance and are applied at the users r!sk. Read and observe ai1label directions betcrc IJsing. V'.Jhen tank
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mixing, aJv.lays read aU indl .... idual manufacturer's labels. In interpreting all labels for tank mlxtIJres, the most
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restrictivc situations must ~pply
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The addition of spray additives such as crop oil concentrates and nanionic surfactants to Propanil 80EDF and
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Propanil80EOF tank mixes can Improve co~rol of problem weeds. Riverside Activate Plus TU at 1 ~ 2 pints per
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100 gallons of water or Rh'erside Prime oiF at 0.5 to 1.0 pint per acre are recommended. Addition of $pray
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addltivcscan reduce crop tolerance to Propanll80EDF under certain conditions and sho-ukj always be considered,
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Nways follow label directions. concerning use of surfactants and crop oils. for an products used in a tank~mix with
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Propanil80EDF.
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Arrowhead
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Sagittaria spp.
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6ermudagrass
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Cynodon dactylon
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Cattail
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Typha latifolia
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Oucksalad
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Heteranth"rlJ ~pp_,
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WEEDS NOT CONTROl~ED
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Johnsongrasa
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Sorghum halepense
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Nutgrass
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Cyperus spp.
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Red Rice
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Oryza $lItiVa
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Sprangletop
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Leptoch/oa spp
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' .. , , . ~
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Rice fields should be we-t! prepared and free of large clods to obtain unlfonn germination of grasses and weedS. and insu!'s~ urifo.'n1
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Rood levels. If necessary, nelda may be flushed prior to treatment to produce uniform grass genninatiOn. 'Ir:rielo'$~are l'lusti'e(f prior
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to treatment, Rush in sufficient time so that grass and rice are growing vigorously at time of treatment. Wate'r .i'ludld be drainea'from
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ooids before spraying so that grasses and weeds are futty exposed to the spray.
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PROPANIL eOEDf acts only on grasses and weeds which have already germinated. (Maximum activity u!.uaUy is not apparent until
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5 to 7 days af.er application.) To prevent more weeds from germinating after treatment, fields should be ftooded within 24 hours after
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spraying, or as soon as possible al'ter 24 hQurs. Flooding after spraying win improve the grass control after PROPANIL SOEDF
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treatment. In eases where nooding of the field would not be complete wrthin seven days or tess after application of PROPANIL SOEDF,
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it is best to treat a. portion of the field, floed that treated portion, and thon treat the remaind~r. This wilf heIRPJ~v~=!t~!!,~statJon of
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weeds and grasses. Hloher rates 5 - 7.5 Ibs. may be necessary on the remaInder since the grass wilt be more mature.
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If the rice is too small to maintain a neod on the fleW, treatment should 00 delayed unbl rice Is large enough. The grass may then
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be farge enough to require 5 - 7.5 Ib$. of PROPANll80EDF. Avoid treatment if rain threatens within 8 houR or If high winds may
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cause uneven application c)r drift.
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In case of unseasonably coofweather, higher rates (5 - 7.5IbaJacre) of PROPANIL 8O€DF may be necessary. The number of leaves
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of barnyard or watergrass determine the til'llt' and amount of PROPANfL 80EDF to spray, regardless of the size of the rice.
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The temperature a few days before and after applying PROPANll 80EDF herbicide has an important bearing on the weed kimng
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activity. The actiVity increase .. 3S dally maximum temperature'S increase above 75°F and decreases as the daily maximum
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temperatures decline below 7SoF. 00 not apply PROPANIL 8OEOF herbicide when ma)('nnum temperatures have been or are
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expee1:ed to stay below 6S
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F or to go -above 100~. low temperaruce at Ume of application is not 90 important as long aa it warms
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up later during the day.
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The grower should inspect fields frequently to determine p.roper time of application. The ideal application time is when most
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bamyardgras8 has one to three leaves, with only an occasional plant having four leaves. During drought conditions grasses may reach
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the three leaf stage while still quite short or stunted, so special attention to stage of growth is necessary In those situations to avoid
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grasses becoming foo mature for be$t resWts.
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Apply 3.75 ~ 5.0 Ibs. of PROPANll 80EDF per acre when most grass has reached the one to three feaf stage, Use 5.0 - 7.5Ibs. of
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PROPANIL 80EDF per acre ifgrasscs are targer, with most in the four to six leaf stage. Mix PROPANll80EDFthoroughly with water
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for spraying, w:.ing vigorous. mechanical agitation. For AERIAL APPLICATION dilute the proper amount of PROPANIL SOEDF with
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10 to 12 gallons of water per acre If humidities are low, incre~se to 12 to 15 gallons of water per acre. For GROUND EQUIPMENT
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dilute the prl)per afnollnt of ?ROPM~IL 80EOF with 15 to 25 gallons of water per acre. Lesser amounts of water onli3n give inadeqtlate
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coverage and may cause poor resutts.
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If fields eannot be completely drained $0 that all of the grass is exposed, a higher dosage of PROPANIL 80EDF (5 ~ 7.5IbsJacre)
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must be used,
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NOTE: VVhcn PROPANfL 80EDF is. applied, especially after the fourth Icarstage of growth aftho rice, under some conditions, visible
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leaf injury on rice may result However, the rice pl-dnts quick~:I outgrow such injur/ when caused by the later applications.
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USE IN CALIFORNIA ONLY _1fJhere rice fields are not completely drained.
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To control watcrgrass, app~y PROPANll 80EDF 30 to 45 days after planting, before rice is ful~J tiller-cd, ..... 'hen watergrass extends 6
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to a inches above water surface. If rice has a deep ncod, water leve! may be lowered to 3-4 inches over highest part of field to expose
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6-8 inches of water grass. ('M"1en lowering water level, do so slowly to avoid pulling down rice plants.) Use 5 Ibs. pe( acre .f mostgrnss
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has developed 3-5 leaves, u~e 6.25 Ibs. if most gra&s has 5-6 leaves, and u'Se 7.5Ibs. per acre if most gran has 7 or more leaves.
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Apply in no less than 10-12 gallons of water. using a medium-fine spray. If higher water level is desired after treating, refiooding may
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be &tarted 12 hours afte( treatment
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USE RESTRICTIONS ON SMALL GRAINS
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If another herbicide is required, a 3-day interval should be allowed,between the application of a PropaniVMCPA combination and the
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other herbiCide.
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Grain crops that hive been or will be treated with PropaniVMCPA combination should not be treated with carbamate insecticid"!'\ '1' Ich
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as carbaryl (Sevirf), mettlOmyl (Lannate-,,), or organophosphates (methyl paratl'lion, Guthiorf) or severe Injury or kill may 'r~"'I·tt" If
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iii foliar insecticide is nec-es.sary, malathion can be safely applied 14 days before or after treatment.
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Do not spray a PropanillMCPA tank miX on spring ba~v. dUruJ'Th or hard..J:ed spring wheat [fthe field was t~e.a_!e.d.~e preylous year
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with soU-applied systemic organophosph~es (Counte?, Dfsystorf';'Thimer") or that has been treated at ptan~ng t:nK.:with $o.iI~,appl~d
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s.ystemic insecticides (Oisyston, Furadart~, Thimet). , • , , , , " . , '
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Do not mix or apply a PropaniVMCPA combination with any other pesticide, spray adjuvant or with furtilizer except as s'1ecifipa!Jy
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recommended on this label. . , " ,
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Do not graze treated crop or cut rof green chop feed.
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'. '
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,)
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SMALL GRAINS
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(Hard Red Spring VVheat, Durum Wheat. and Spring Barley in North Dakota. South Dakota, Minnesota, and Montana)
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WEEDS CONTROLLED
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-."~'-'-
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'".,.
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-'
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Weed Controlled Seedling Stage·
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Pigeongrass 1 to 3 leaf
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Foxtail, green (Setaria viridis) 1 to 3 Ie.f
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Foxtail, yellow (Setaria Iete&Cens) 1 to 4 leaf
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Buckwheat, wild (Potygonum conYoivulus) 1 to 4 lea'f
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Kochia ..... (Kochfa scoparia) 1 to 4 leaf
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Lambsquarters, common (Chenopodium album) 1 to 4 leaf
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Mustard, wild (Brasslc:a kaber) 1 to 4 leaf
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Pigweed, prostrate (Amaranthus bntoides) 1 to 4 leaf
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Pigweed, redroot (Amaranthus retrollexus) 1 to 4 leaf
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"'Refers to weed seedling stages for control. Pigeongrass greater than the 3 leaf stage or listed broadleat weeds beyond the 4 $eaf
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stage will not be controlled.
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""SuppreMion ~ may cause spotting, stunting or death of kochia not exceeding the 4 leaf stage.
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A Propana 80EDFIMCPA tani< mix is recommended for control of susceptible weed seedlings when applied as a single post
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emergence application at the rate of 1.2-1.42 Ibs. Propantl80EDF plus g..11 oz. of either MCPA LV Eeter or SEE® MCPA LV Ester
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per acre {3.7Ibs. af. per gallon). The lower rate shoukl be applied when weed eeedlings are growing under favorable s.oil moisture
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condftions. The higher rates are recommended when heavy weed pressure is present or less than favorable soil moisture conditions
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exist. Do not apply when soil moisture levels are deeper than 1.5 inches from the soil surface and actNe plant growth stops.
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The addition of a crop oil concentrate such as Riverside Prime Oil at a rate of 1 pint per acre to Propanil 80EDF is required to
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achieve consistent weed control.
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A PropaniliMCPA tank mix is most eRective in controJnng foxtail if spray applications are made when the majortty orthe emerged foxtail
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are in the 2 to 3 reaf stage. Effectiveness declines rapidly as the 4th leaf of the foxtail begins to emerge. Fields should be checked
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frequently for emerging foxtait starting 2 to 2 112 weeks after planting.
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This tank mi:< may causa temporary yetlowing or tip browning to the leaves of the grain crop 2 to 5 days. after application. The effects
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are temporary and usually win disappear 10 to 14 days after application. New leaves win have normal green color, Application under
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adverse growing condition$ may result in greater crop injury and slower recovery. Do not apply ir frO$t Is expected within 24 hours
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or when temperatures are above 85
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1l
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F, especfalty with drying Winds.
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AppHcations should be made only to actively growing (healthy) grain crops in the seedling stages recommended below:
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Crop Seedling Stage
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Hard Red Spring Wheat 2 to 5 leaf
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Durum Wheat 2 to 4 leaf
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Spring Baney 2 to 4 leaf
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For ground application use a minimum of 10 gallons of water per acre and for aerial appUcation usc 5 gallons. of water per acre.
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Pro......fl' • Counter and Thimct are trademarks of American Cyanamid Company
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Bolero~ is a trademark of Kumiai Chemical Industry Co., Ltd.
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Activate Plus TV and Prime Oi(lP are trademarks of Terra International. Inc.
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Sevin'; Is a trademark of Rhone Poulenc, Inc.
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lannafe® fs a tradema~ of E.!. duPont de Nemous & Co.
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Guthion: and Disyston are trademark$ of Bayer Corp,
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Furadan !s a trademar1< of FMC Corp.
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NOTICE; SeJlerwarrants that the productconkmns to its chemical descnptionand is reasonably fit rorthe purp;,~,~:stated Oli ~~ ~t.·el
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when used in accordance with directions under normal conditions of use, but neither this warranty nor "ny other warranty of
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merchantability or fitnes.s for a parUcular purpose, express or implied, extends to the use of this product contrarY i& labei instructions,
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or under abnormal condrtions, or under conditions not reasonably foreseeable to Seller, and Buyer assumes the risk of any ~u('.h',~~e.
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