a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
286 lines
20 KiB
Markdown
286 lines
20 KiB
Markdown
# MCPA LV ESTER
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- EPA Reg No: **9779-265**
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- Registrant: WINFIELD SOLUTIONS, LLC
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- Signal word: Caution
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- Active ingredients: MCPA, 2-ethylhexyl ester (68.7%)
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- Label accepted: 2008-07-23
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/009779-00265-20080723.pdf
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---
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( 7-~3~~Dg-
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~----------------------~ -------------------~----~( U.S. ENVIRO~MENT AL PROTECTION
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AGENCY
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Office of Pesticide Programs
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Registration Division (7505P)
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Ariel Rios Building
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1200 Pennsylvania Ave., NW
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Washington, D.C. 20460
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NOTICE OF PESTICIDE:
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_ Registration
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. --X. Reregistration
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(under FIFRA, as amended)
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Name and Address of Registrant (include ZIP Code):
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Agriliance, LLC
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P.O. Box 64089
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St. Paul, MN 55164-0089
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. EPA Reg. Number: Date of Issuance:
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9779-265
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J UL 2. 3 21)08
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TenTI of Issuance:
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Name of Pesticide Product:
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Agrisolutions MCPA LV Ester
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~iJ~~~~~~~$~~i~~i~~~~i;i~;~~~l~~~~~~~i~!}f¥i~'"
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On the basis of infonnation furnished by the registrant, the above named pesticide is hereby
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registered/reregistered under the Federal Insecticide, Fungicide and Rodenticide Act. Registration is
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in no way to be construed as an endorsement or recommendation of this product by the Agency. In
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order to proteCt health and the environment, the Administrator, on his motion, may at any time
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suspend or cancel the registration of a pesticide in accordance with the Act. -The acceptance of any
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name in connection with the registration of a product under this Act is not to be construed as giving
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the registrant a right to exclusive use of the name or to its use ifit has been covered by others.
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This product is reregistered in accordance with FIFRA sec. 4(g)(2)(C) provided that you:
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1) Submit and/or cite all data required for registration/reregistration review of your product when
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the Agency requires all registrants of similar products to submit data.
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2) Revise the First Aid statements to: "IF ON SKIN OR CLOTHING: Take off contaminated
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clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control
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center or doctor for treatment advice. IF SWALLOWED: Immediately call a poison control center
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or doctor. Do not induce vomiting unless told by a poison control center or doctor. Do not give any
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liquid to the person. Do not give anything by mouth to an unconscious person.".
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Signature of Approving Official: ~
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~,~
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Joanne
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Product Manager 23
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Herbicide Branch
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Registration Division (7505P)
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Date:
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JUt 2.3 .2DOO
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(
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Page 2
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EP A Reg. 9779-265
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3) Change the Hazards to Humans and Domestic Animals statements to "May be fatal is
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absorbed through skin. Causes skin irritation. Harmful if swallowed. Do not get in eyes, on
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skin, or on clothing."
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4) The text in bold must be added to the label: "Follow manufacturer's instructions for
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cleaning/maintaining PPE. If no such instructions for washables exist, use detergent and hot
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water. Keep and wash PPE separately form other laundry.".
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5) Delete the text "this pesticide may be toxic to fish, aquatic invertebrates and aquatic plants"
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from the Environmental Hazards section.
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6) To the Non-Agricultural Use Requirements box change the last sentence to "Do not enter or
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allow others to enter the treated area until sprays have dried.".
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7) To the Spray Drift section change "apply only then ... " to "apply only when ... " in the wind
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speed text.
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8) The directions for use on flax which allow rates as high as ~ pint per acre if Canada thistle is
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present exceed the maximum allowed rate of V2 pint per acre and must be revised.
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9) To the Storage and Disposal section change "Storage" to "Pesticide Storage".
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10) To the Warranty section add "to the extent consistent with applicable law" in front of "seller
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makes no other".
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11) On page 4 change "6 pints" to "6.5" pints.
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If these conditions are not complied with, the registration will be subject to cancellation in
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accordance with FIFRA sec. 6(e). Your release for shipment of the product constitutes
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acceptance of these conditions. A stamped copy of the label is enclosed for your records.
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Submit 1 copy of the firial printed label for the record.
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If you have any questions please call Erik Kraft at 703-308-9358 or email atKraft.Erik@epa.gov.
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~gfi50LUTlON51
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MCPA LV Ester
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For Postemergent Control of Many Broadleaf Weeds
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ACTIVE INGREDIENT:
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2-methyl-4-chlorophenoxyacetic acid isooctyl (2,.ethylhexyl ) ester* ..... " ...................................... 68.7%
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INERT INGREDIENTS: .............................................................................................................................. 31.3%
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TotaL ......................................................................................... 100.0%
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• Equivalent to 44.1 % of 2-methyl-4-chlorophenoxyacetic acid or no less than 3.7 Ibs. of MCPA acid per gallon at
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68
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0
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F. Isomer specific by AOAC Method No. 6.A18-22 (13th ed.). Product contains petroleum distillates.
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KEEP OUT OF REACH OF CHILDREN
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WARNING AVISO
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Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle.
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(If you do not understand the label, find someone to read it to you in detail.)
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FIRST AID
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IF SWALLOWED: Call a poison cOQtrol center or doctor immediately for treatment advice. Have person sip a glass of
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water if able to swallow. Do not induce vomiting unless told to by a poison control center or doctor.
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IF IN EYES: Hold eyelids open and rinse slowly and gently with water for 15-20 . minutes. Remove contact lenses, if
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present, after the first 5 minutes, then continue rinSing. Call a poison control center or doctor for treatment advice.
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IF ON SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison
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control center or doctor for treatment advice. .
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IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration,
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preferably mouth-to-mouth if possible. Call a poison control center or doctor for treatment advice.
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Note to Physician: Contains petroleum distillate - vomiting may cause aspiration hazard.
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Have the product container or label with you when calling a poison control center or doctor or going for treatment.
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For additional information in case of medical emergency call toll free -1-877-424-7452.
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PRECAUTIONARY STATEMENTS
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HAZARDS TO HUMANS AND DOMESTIC ANIMALS
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WARNING
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Harmful if swallowed, inhaled or absorbed through skin. Causes skin irritation. Avoid contact with skin, eyes, or clothing.
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Avoid breathing spray mist.
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Personal Protective Equipment (PPE):
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Some materials that are chemical-resistant to this product are neoprene, nitrile rubber, barrier laminate, or viton. If you
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want more options, follow the instructions for category E on an EPA chemical resistance category selection chart.
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Mixers, loaders, applicators, flaggers, and other handlers must wear:
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- Long-sleeved shirt and long pants.
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- Chemical-resistant gloves when mixing, loading, or using any hand-held equipment.
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- Shoes plus socks. ""',
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:. ~
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- Protective eyewear. ACCEPTED
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w.ith COMMENTS
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in EPA Letter Dated
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Ir
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EPA REG. No. 9779-265 JUL 2. 3 .m EPI -:st. ."'0.
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Distributed by Agriliance, LLC
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P.O. Box 64089, St. Paul MN 55164-0089
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Under the Federal Insecticide NET CONTENTS 2.5 GALS. (9.46 L) Fungicide, and Rodenticide Act
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as . amended, . for :tttc pesticide
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registered under EPA Reg. No. 0/K01/6
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( (I-'age L or 4 '1/ h
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Additional PPE requirements for 't,,,,<ers and loaders supporting aerial applic'c. •. .;JJ¥to rangelands, pasture lands OJ
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noncropland. These mixerslloaders also must wear:
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- A chemical-resistant apron. .
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- A NIOSH-approved respirator with a dust/mist filter with MSHAINIOSH apol 0\(al number prefix TC-21 C or an);"I' -
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P, or HE filter. .
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See Engineering Controls for additional requirements .
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. Dlscara ciulilingor other II ,alenals that nave oecom!:: UI cllched or heavily contaminated with this product's CODCBM<:!@ Do
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'r'fotreuse.tbem. F.ollowm.anufacturer'sinstructions for cleaning or maintaining PPE. If no such instructions for washables,
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use detergent and hot water. Keep and wash PPE separately from other laundry.
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Engineering Controls Statement:
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If the mechanical system is used in a manner that meets the requirements listed in the Worker Protection Standard
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(WPS) for agricultural pesticides [40 CFR 170.240 (d) (4-6)], the handler PPE requirements may be reduced or
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modified as specified in the WPS.
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When handlers use closed systems, enclosed cabs, or aircraft, in a manner that meets the requirements listed in the
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Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d) (4-6)], the handler PPE requirements
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may be reduced or modified as specified in the WPS.
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Pilots must use an enclosed cockpit that meets the requirements listed in the WPS for agricultural pesticides [40 CFR
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170.240(d)(6)].
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USER SAFETY RECOMMENDATIONS
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Users should:
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- Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet.
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- Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing.
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- Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as
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possible, wash thoroughly and chang~ into clean clothing.
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ENVIRONMENTAL HAZARDS
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.his.-pestiGiGe-may-be-t auatic invertebrat a uatic lants. a not apply directly to water, to areas where
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surface water is present, or to intertidal areas below mean high water ma.. 0 not contaminate water when disposing of
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equipment washwater or rinsate. Drift and runoff may be hazardous to aquatic organisms in water adjacent to treated
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~re~s. Runoff of this oroduct will be reduced by avoiding applications when rainfall is forecasted to occur within 48 hours.
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-This cnemU::;i:\1 IIi:\::; lJ!ulJt!nles and characteristics associated with chemicals detected in groundwater. The use of this
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chemical in areas where soils are permeable, particularly where the water table is shallow, may result in groundwater
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contamination.
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Nlost cases of groundwater contamination involving phenoxy herbicide such as MCPA have been associated with
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mixinglloading and disposal sites. Caution should be exercised when handling MCPA pesticides at such sites to prevent
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contamination of groundwater supplies. Use of closed systems for mixing and transferring this pestiCide will reduce the
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probability of spills. Placement of. mixinglloading equipment on an impervious pad to contain spills will help prevent
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~roundwater contamination.
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DIRECTIONS FOR USE
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It is a violation of Federal Law to use this product in a manner inconsistent with its labeling.
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Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected
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handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency
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responsible for pesticide regulation. .
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AGRICULTURAL USE REQUIREMENTS
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Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR Part 170. This
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standard contains requirements for the protection of agricultural workers on farms, forest, nurseries, and greenhouses
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and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency
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assistance. It also contains specific instructions and exceptions pertainingto statements on this label about personal
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protective equipment (PPE) and restricted-entry interval. The requirements of this box apply only to those uses of this
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product that are covered by the Worker Protection Standard.
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Do not enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 12 hours.
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PPE required for ~arly entry to tref' -I areas that is permitted ~nder the VYorker,P'l)tection Standard and that involves 5/,
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contact With anything that has beef'. .:lated, such as plants, SOil, or water IS: \ /10
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- Coveralls,
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- Chemical-resistant gloves made of any waterproof material,
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- Shoes plus socks, and
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- Protective eyewear.
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NON-AGRICULTURAL USE REQUIREMENTS
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The requirements in this box apply to uses of this product that are NOT within the scope of the Worker Protection Standard
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for agriculture Pesticides (40 CFR Part 170). The WPS applieswhen this product is used to produce agricultural plants on
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farms, forests, nurseries, or greenhouses.
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Do not enter treated areas without protective clothing until sprays have dried.
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GENERAL INFORMATION
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USE PRECAUTIONS: This product will kill or seriously injure many desirable forms of vegetation. Do not apply directly to
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flowers, fruits, vegetables, grapes, ornamentals, cotton or other desirable plants. Do not apply by aerial application in the
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vicinity of sugar beets. Do not use when there is hazard from drifting mists. (Coarse sprays are less likely to drift). Vapors
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from this product may injure susceptible plants in the immediate vicinity.
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Local conditions may affect the use of this chemical. Consult State Agricultural Extension or Experiment Station weed
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specialists for specific recommendations for local weed problems and for information on possible lower dosages.
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CONTROLS THESE AND OTHER WEEDS
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Susceptible (most areas): Lambsquarters (goosefoot), marsh elder, mustards· (annual), puncturevine, ragweed, stinkweed
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(pennycress, fanweed), wild radish, yellow rocket or wintercress, cocklebur, goats beard, field pepper grass, dragon heat mint,
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beggarticks, pOison hemlock, hempnettle, shepherdspurse, annual sow thistle.
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Less susceptible: Buttercups, Canada thistle, dandelions, plantains, stinging nettle, perennial sow thistle, vetch, white top or
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hoary cress, Russian pigweed, sunflower, chervil, miner's lettuce, purslane, kochia.
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PREPARATION OF THE SPRAY
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Fill the spray tank with half the required amount of water, then add the recommended amount of MCPA LV ESTER and
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continue filling the spray tank with the balance of water. Keep agitator running when filling spray tank and during spray
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operations. For crop uses, do not mix with oil, surfactant or other adjuvants as this may reduce selectivity to crops resulting in
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crop damage or kill.
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AMOUNT OF SPRAY TO APPLY
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Apply 5 to 15 gallons of total spray per acre when making applications with ground equipment and 3 to 10 gallons of total spray
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per acre when making applications by aircraft unless directed otherwise under specific directions. Carefully read the
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ENVIRONMENTAL HAZARDS section of the PRECAUTIONARY STATEMENTS for further information on spray volume.
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SPRAY DRIFT MANAGEMENT
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Avoiding spray drift at the application site is the responsibility of the applicator. The interaction of many equipment-and
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weather-related factors determines the potential for spray drift. The applicator and the grower are responsible for
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considering all these factors when making decisions.
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Apply only as a medium or coarser spray (ASAE standard 572) or a volume mean diameter of 300 microns or greater for
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spinning atomizer nozzles.
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Apply only then the wind speed is 2-10 mph at the application site.
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Additional requirements for aerial application: .
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The boom length must not exceed 75% of the wingspan or 90% or the rotor blade diameter.
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Release spray at the lowest height consistent with efficacy and flight safety. Do not release spray at a height greater than
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10 feet above the crop canopy.
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When applications are made with a crosswind, the swath will be displaced downwind. The applicator must compensate for
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this displacement at the downwind edge of the application area by adjusting the path ofthe aircraft upwind.
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Do not make applications into temperature inversions.
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Additional requirements for grounl Jam application:
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Do not apply with a nozzle height greater than 4 feet above the crop canopy.
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SELECTIVE SPRAYING
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Wheat, oats, barley and rye--Apply as a water mix spray by ground sprayer or airplane. Use Y2 to 1 pint per acre for the more
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susceptible weeds after crop has reached the 3 to 4 leaf stage up to boot stage. Use up to 1-5/8 pints per acre for the less
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susceptible weeds after crop has tillered and up to early boot stage. Do not spray from boot to dough stage.
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Do not forage or graze dairy animals on treated areas within 7 days after treatment. Do not apply more than 1-5/8 pints (314
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lb. ae) MCPA LV Ester per acre per year.
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FLAX
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Use 1/4 to 1/2 pint per acre. Apply by ground sprayer or by airplane. Apply only when weeds are up and when flax in 4 to
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8 inches high and before it comes into bud. Treatment after early bud stage may result in severe damage. If Canada
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thistle is present, it may be necessary to go as high as 3/4 pint per acre to prevent seed head production. Some injury to
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the flax may result.
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Do not forage or graze dairy animals on treated areas within 7 days after treatment. Do not apply more than 1/2 pint (1/4 lb.
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ae) MCPA LV Ester per acre per year.
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GRASSES
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Established grassland--Use 1 to 3 pints per acre in sufficient water (10 to 100 gallons) by airplane or ground sprayer
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application and give thorough coverage. Use higher rate for white top, Canada thistle, and other less susceptible weeds.
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Spray perennials in early bud to full bloom stage and regrowth in fall; other weeds in spring or fall, when actively growing.
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Do not forage or graze dairy animals on treated areas within 7 days after treatment. Do not apply more than 3% pints (1-1/2
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Ibs. ae) MCPA LY Ester per acre per year. Do not apply more than 2 applications per year with a minimum retreatment
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interval of 21 days.
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NON-CROP SPRAYING ALONG FENCE ROWS AND ROADSIDES
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Canada thistle, white top and meadow buttercup--For spot treatment, use % pint in 3 to 4 gallons of water, or 3-1/4 pints in
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sufficient water to give coverage for most extensive areas. Spray to wet weeds thoroughly when in bud to early bloom and
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again on fall regrowth.
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Broadcast Treatment: Do not apply more than 3% pints (1-1/2 Ibs. ae) MCPA LV Ester per acre per year. Do not apply
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more than 2 applications per year with a minimum retreatment interVal of 21 days. Spot Treatment: Do not apply more
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than 6 pints (3 Ibs. ae) MCPE Phenoxy Herbicide per acre per year.
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STORAGE AND DISPOSAL
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STORAGE: Store in a secure area, in original container only, away from fertilizers, food, or feed. Do not contaminate water,
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food, or feed by storage or disposal.
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PESTICIDE DISPOSAL: Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rinsate is a
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violation of Federal Law. If these wastes cannot be disposed of according to label instructions, contact your State Pesticide
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or Environmental Control Agency, or the Hazardous Waste Representative at the nearest EPA regional office for guidance.
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CONTAINER DISPOSAL: Metal containers: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or
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puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities. Plastic
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containers: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary
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landfill, or by incineration or, if allowed by state and local authorities, by burning. If burned, stay out of smoke.
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NOTICE OF WARRANTY
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Seller warrants that the product conforms to its chemical description and is reasonably fit for the purposes stated on
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the label when used in accordance with directions under normal conditions of use. SELLER MAKES NO OTHER
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EXPRESS OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, NOR
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IS ANY REPRESENTATIVE OF SELLER AUTHORIZED TO MAKE ANY SUCH WARRANTY OR MODIFY THESE
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TERMS. This warranty does not extend to the storage, handling or use of this product contrary to label instructions, or
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under abnormal conditions, or under conditions not reasonably foreseeable to Seller, and Buyer assumes the risk of
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any such storage, handling or use. Seller shall not be responsible for incidental orcom~equential damages, if any,
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resulting from a breach of warranty.
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In case of emergency involving this product or for user safety information on this product, contact Agriliance, LLC via
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CHEMTREC at 1-800-424-9300.
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